JPH0330102B2 - - Google Patents
Info
- Publication number
- JPH0330102B2 JPH0330102B2 JP58167983A JP16798383A JPH0330102B2 JP H0330102 B2 JPH0330102 B2 JP H0330102B2 JP 58167983 A JP58167983 A JP 58167983A JP 16798383 A JP16798383 A JP 16798383A JP H0330102 B2 JPH0330102 B2 JP H0330102B2
- Authority
- JP
- Japan
- Prior art keywords
- alumina
- gas
- solid electrolyte
- concentration
- reference electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 28
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 26
- RPMPQTVHEJVLCR-UHFFFAOYSA-N pentaaluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3] RPMPQTVHEJVLCR-UHFFFAOYSA-N 0.000 claims description 26
- 239000007784 solid electrolyte Substances 0.000 claims description 24
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 21
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 19
- 238000005259 measurement Methods 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 14
- 239000007772 electrode material Substances 0.000 claims description 11
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 239000004020 conductor Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 45
- 239000011734 sodium Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 5
- 230000004043 responsiveness Effects 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229910000528 Na alloy Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000003780 insertion Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 101100066898 Mus musculus Flna gene Proteins 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/0042—SO2 or SO3
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
- G01N27/4074—Composition or fabrication of the solid electrolyte for detection of gases other than oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pathology (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Electrochemistry (AREA)
- Combustion & Propulsion (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58167983A JPS6058549A (ja) | 1983-09-12 | 1983-09-12 | 二酸化イオウ用固体電解質ガスセンサ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58167983A JPS6058549A (ja) | 1983-09-12 | 1983-09-12 | 二酸化イオウ用固体電解質ガスセンサ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6058549A JPS6058549A (ja) | 1985-04-04 |
JPH0330102B2 true JPH0330102B2 (fr) | 1991-04-26 |
Family
ID=15859628
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58167983A Granted JPS6058549A (ja) | 1983-09-12 | 1983-09-12 | 二酸化イオウ用固体電解質ガスセンサ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6058549A (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2651931C2 (ru) * | 2016-06-08 | 2018-04-24 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Способ и устройство для определения состава электролита |
-
1983
- 1983-09-12 JP JP58167983A patent/JPS6058549A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6058549A (ja) | 1985-04-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4632732A (en) | Ion-selective measuring electrode device and method for measuring hydrogen ion | |
US9028671B2 (en) | Hydrogen sensing apparatus and method | |
JPH11223617A (ja) | 二酸化硫黄ガスセンサ | |
US6368479B1 (en) | Carbon monoxide sensor, method for making the same, and method of using the same | |
JPS63738B2 (fr) | ||
JPS60500382A (ja) | 酸素センサ−電極 | |
Sadaoka et al. | CO 2 sensing characteristics of a solid-state electrochemical sensor based on a sodium ionic conductor | |
JPH0330102B2 (fr) | ||
JPH0131586B2 (fr) | ||
EP1376117A1 (fr) | Capteur de cellules de concentration de type hydrogene et procede de preparation d'electrolyte solide pouvant conduire un proton | |
US4842698A (en) | Solid state arsenic probe for use in pyrometallurgical processes | |
GB2316178A (en) | Solid electrolyte gas sensor | |
US4037773A (en) | Bonding of metals to solid electrolytes | |
Balaish et al. | Design of triple and quadruple phase boundaries and chemistries for environmental SO 2 electrochemical sensing | |
Ochin et al. | Thermodynamic study of point defects in Cu2− δO. Electrical conductivity measurements at low oxygen partial pressures | |
CA1137168A (fr) | Dispositif destine au controle d'un element dans un melange fluide | |
JP3770456B2 (ja) | ガス濃度の測定方法 | |
US6231734B1 (en) | Process for no-detection in fluid media | |
JPH0128338B2 (fr) | ||
JP3290809B2 (ja) | 塩素化合物ガスセンサ | |
JPH0327862B2 (fr) | ||
Kishi et al. | A stable solid-reference electrode of BiCuVOx/perovskite-oxide for potentiometric solid electrolyte CO2 sensor | |
Fray | Potentiometric gas sensors for use at high temperatures | |
JPS61260155A (ja) | 溶融金属中に溶けている金属元素の濃度を測定する装置 | |
CN100480696C (zh) | 用于SOx测量的气体传感器 |