JPH03148601A - Multi-layered film reflecting mirror - Google Patents

Multi-layered film reflecting mirror

Info

Publication number
JPH03148601A
JPH03148601A JP28750489A JP28750489A JPH03148601A JP H03148601 A JPH03148601 A JP H03148601A JP 28750489 A JP28750489 A JP 28750489A JP 28750489 A JP28750489 A JP 28750489A JP H03148601 A JPH03148601 A JP H03148601A
Authority
JP
Japan
Prior art keywords
film
reflecting mirror
layered film
multilayer film
rays
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28750489A
Other languages
Japanese (ja)
Inventor
Masaaki Sudo
正昭 須藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP28750489A priority Critical patent/JPH03148601A/en
Publication of JPH03148601A publication Critical patent/JPH03148601A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the reflecting film which has a high reflection factor and small absorptivity by forming the multi-layered film of the multi-layered film reflecting mirror by laminating many couples of films made of specific light elements having small coefficients of absorption. CONSTITUTION:The multi-layered reflecting mirror consists of a substrate 1 of SiC, etc., where a mirror surface is formed, the multi-layered film 2, and a protection film 3. Then the multi-layered film 2 is formed by laminating, for example, 31 couples of films 4 and 5 of different kinds which have <=4g/cm<2> density and >=100 deg.C fusion points alternately. There are Al and Ca, Al and Li, B and Ca, B and C, B and Li, Si and Ca, Si and C, and Si and Li, etc., for X rays with 44.7Angstrom wavelength as combinations of films constituting the multi-layered film 2. Consequently, temperature rise heat accumulation by the X rays is reduced and the reflecting mirror is easily cooled with water, etc.

Description

【発明の詳細な説明】[Detailed description of the invention]

[発明の目的] (産業上の利用分野) 本発明は、X線用光学系として広範囲に用いられる多層
膜反射鏡に関する。 (従来の技術) 近時、X線リソグラフィー、X@顕微鏡、シンクロトロ
ン放射(SOR)分光、X線レーザーなどの軟X線用光
学系として、多層膜反射鏡が、広範囲に用いられている
。従来、X線用多層膜反射鏡の多層膜としては、複素屈
折率の異なる二つの物質の組み合わせが用いられている
。たとえば、Au/C,Mo/C,Ta/C,W/C。 AuPd/C,ReW/C等の組み合わせが報告されて
いる(特開昭62−297800号公報、特開昭63−
88501号公報、特開昭63−18502号公報、特
開昭63−88503号公報、特開昭63−95400
号公報、特開昭63−266396号公報、特開昭63
−266397号公報、特開昭63−266398号公
報、特開昭63−266399号公報、特開昭63−2
66400号公報、特開昭63−271200号公報、
特開昭63−273099号公報、特開昭63−284
498号公報、特開昭63−284499号公報、特開
昭64−180911号公報)。つまりーこれらの物質
対の組み合わせは重元素と軽元素の組合せで複素屈折率
の差が大きくなるように構成されている。 (発明が解決しようとする課題) しかしながら、一般的に重元素は吸収係数が大きいため
、熱吸収による多層膜構造の劣化の原因ともなる。 本発明は、上記事情を参酌してなされたもので、反射率
が高く、かつ、吸収率の小さい多層膜反射鏡を提供する
ことを目的とする。 [発明の構成] (課題を解決するための手段と作用) 吸収係数の小さい軽元素のみにより多層膜を形成するこ
とにより、反射率が高く、かつ吸収率の小さい多層膜反
射鏡を得るようにしたものである。 (実施例) 以下、本発明の一実施例を図面を参照して詳述する。 第1図は、この実施例の多層膜反射鏡を示している。こ
の多層膜反射鏡は、例えばSiCなど平面または曲面に
形成された基板(1)と、この基板(1)上に着設され
た多層膜(2)と、この多層膜(2)の最上層に被着さ
れた例えばC(炭素)などからなる極薄(10八以下)
の保護膜(3)とからなっている。そうして、前記多層
膜(2)は、例えば密度が4 g/ci以下の軽元素か
らなる一対の膜(4)、(5)が交互に例えば31層積
層されてなるものであり、各膜(4) 、 (5)の膜
厚は、それぞれの層中におけるX線吸収および各層の界
面からの反射X線の位相の重なりによる反射X線の強め
合いの両者を考慮し、多層膜反射鏡全体として最も高い
反射率かえられるようにする。また、膜(4)、(5)
の材種の選択は、両者のフレネル係数の差の絶対値が大
きいこと、及び膜(5)の軽元素は複素屈折率の吸収係
数が小さいことの二つの条件を満たすようになされてい
る。さらに、多層膜の最上層は、膜(4)とするほうが
反射率が高まる。以上を考慮して、例えば波長44.1
人のX線を効率よく反射するには、膜(4)は膜厚dA
4g人の八1−(アルミニウム)で、また膜(5)は膜
厚dB36人のC(炭素)で構成すると良い。 つぎに、上記構成の多層膜反射鏡の作用について述べる
。    多層膜(2)に対して、波長44.7人のX線を投射す
る。すると、この多層膜(2)にては、反射X線が反射
率Rで反射する。このときの入射角θと反射率Rとの関
係を第2図に示す。すなわち、この第2図が示すように
、14″の入射角で極大の反射率19.5%を得ること
ができる。この反射率では、SOR分光用、X線顕微鏡
用などのxIl用光学系として、十分使用できるものと
なる。しかも、膜(4) 、 (5)は、複素屈折率の
吸収係数が小さい軽元素からなっているので、X線によ
る昇温蓄熱が小さくなり、反射鏡全体の冷却が容易とな
る。 なお、膜(4)、(5)の膜厚は、必ずしも一定でなく
てもよい。さらに、多層膜を構成する膜対の組み合わせ
は、波長44.7人のX線に対してはAi/Ca、A 
I/L i、B/Ca、B/C,B/L t。 5 i/Ca、S i/C,S i/L t、Be/C
。 Be/Ca、Be/Li等、密度4g/d以下で融点1
00℃以上のものの組合せであるならばどのようなもの
でもよい。
[Object of the Invention] (Industrial Application Field) The present invention relates to a multilayer film reflecting mirror that is widely used as an optical system for X-rays. (Prior Art) Recently, multilayer film reflecting mirrors have been widely used as optical systems for soft X-rays such as X-ray lithography, X@microscopes, synchrotron radiation (SOR) spectroscopy, and X-ray lasers. Conventionally, a combination of two materials having different complex refractive indexes has been used as a multilayer film of a multilayer film reflecting mirror for X-rays. For example, Au/C, Mo/C, Ta/C, W/C. Combinations of AuPd/C, ReW/C, etc. have been reported (Japanese Patent Application Laid-open No. 62-297800, Japanese Patent Application Laid-open No. 63-
88501, JP 63-18502, JP 63-88503, JP 63-95400
No. 1, JP-A-63-266396, JP-A-63
-266397, JP 63-266398, JP 63-266399, JP 63-2
66400, Japanese Patent Application Laid-Open No. 63-271200,
JP-A-63-273099, JP-A-63-284
498, JP-A-63-284499, JP-A-64-180911). In other words, the combination of these substance pairs is such that the difference in complex refractive index becomes large due to the combination of heavy elements and light elements. (Problem to be Solved by the Invention) However, since heavy elements generally have a large absorption coefficient, they also cause deterioration of the multilayer film structure due to heat absorption. The present invention has been made in consideration of the above circumstances, and an object of the present invention is to provide a multilayer film reflecting mirror with high reflectance and low absorption. [Structure of the invention] (Means and effects for solving the problem) A multilayer film reflecting mirror with high reflectance and low absorption coefficient is obtained by forming a multilayer film using only light elements with small absorption coefficients. This is what I did. (Example) Hereinafter, an example of the present invention will be described in detail with reference to the drawings. FIG. 1 shows a multilayer reflective mirror of this embodiment. This multilayer film reflecting mirror consists of a substrate (1) formed on a flat or curved surface such as SiC, a multilayer film (2) deposited on this substrate (1), and the topmost layer of this multilayer film (2). Ultra-thin (108 or less) made of, for example, C (carbon) adhered to
and a protective film (3). The multilayer film (2) is made up of, for example, a pair of films (4) and (5) made of a light element having a density of 4 g/ci or less, which are alternately laminated, for example, 31 layers. The film thicknesses of films (4) and (5) are determined by considering both the X-ray absorption in each layer and the reinforcement of the reflected X-rays due to the phase overlap of the reflected X-rays from the interface of each layer. The mirror as a whole has the highest reflectance. Also, membranes (4), (5)
The selection of the material is made so as to satisfy two conditions: the absolute value of the difference in Fresnel coefficients between the two is large, and the light element of the film (5) has a small absorption coefficient of complex refractive index. Furthermore, the reflectance increases when the film (4) is used as the top layer of the multilayer film. Considering the above, for example, the wavelength is 44.1
In order to efficiently reflect human X-rays, the film (4) must have a film thickness of dA.
It is preferable that the film (5) is made of carbon (aluminum) with a film thickness of 4 g and 36 dB. Next, the operation of the multilayer mirror having the above configuration will be described. X-rays with a wavelength of 44.7 are projected onto the multilayer film (2). Then, the reflected X-rays are reflected by the multilayer film (2) with a reflectance R. The relationship between the incident angle θ and the reflectance R at this time is shown in FIG. In other words, as shown in Fig. 2, a maximum reflectance of 19.5% can be obtained at an incident angle of 14''.With this reflectance, xIl optical systems such as SOR spectroscopy and X-ray microscopes can be used. Moreover, since the films (4) and (5) are made of light elements with a small absorption coefficient of complex refractive index, the heat accumulation caused by X-rays is small, and the entire reflecting mirror is The thickness of the films (4) and (5) does not necessarily have to be constant.Furthermore, the combination of the film pairs constituting the multilayer film has a wavelength of 44.7 For the line, Ai/Ca, A
I/L i, B/Ca, B/C, B/L t. 5 i/Ca, S i/C, S i/L t, Be/C
. Be/Ca, Be/Li, etc., with a density of 4 g/d or less and a melting point of 1
Any combination of temperatures of 00° C. or higher may be used.

【発明の効果】【Effect of the invention】

本発明の多層膜反射鏡は、膜対が、複素屈折率の係数が
小さい軽元素からなっているので、X線による昇温蓄熱
が小さくなり、水冷などによる反射鏡の冷却が容易とな
る。
In the multilayer film reflecting mirror of the present invention, since the film pair is made of a light element with a small coefficient of complex refractive index, heat accumulation caused by X-rays is reduced, and the reflecting mirror can be easily cooled by water cooling or the like.

【図面の簡単な説明】[Brief explanation of the drawing]

(2):多層膜 (3)、(4) 、膜 (2): Multilayer film (3), (4), membrane

Claims (1)

【特許請求の範囲】[Claims] 鏡面が形成された基板と、上記鏡面上に形成された多層
膜とを具備し、上記多層膜は、密度が4g/cm^2以
下かつ融点100℃以上の種類の異なる軽元素からなる
一対の膜が積層されてなることを特徴とする多層膜反射
鏡。
It comprises a substrate on which a mirror surface is formed, and a multilayer film formed on the mirror surface, and the multilayer film includes a pair of light elements made of different kinds of light elements having a density of 4 g/cm^2 or less and a melting point of 100° C. or more. A multilayer film reflector characterized by being made up of laminated films.
JP28750489A 1989-11-06 1989-11-06 Multi-layered film reflecting mirror Pending JPH03148601A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28750489A JPH03148601A (en) 1989-11-06 1989-11-06 Multi-layered film reflecting mirror

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28750489A JPH03148601A (en) 1989-11-06 1989-11-06 Multi-layered film reflecting mirror

Publications (1)

Publication Number Publication Date
JPH03148601A true JPH03148601A (en) 1991-06-25

Family

ID=17718196

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28750489A Pending JPH03148601A (en) 1989-11-06 1989-11-06 Multi-layered film reflecting mirror

Country Status (1)

Country Link
JP (1) JPH03148601A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5505805A (en) * 1992-03-05 1996-04-09 Industrieanlagen-Betriebsgesellschaft Gmbh Method for the production of reflectors
US5825565A (en) * 1992-03-05 1998-10-20 Industrieanlagen-Betriebsgesellschaft Gmbh Reflector

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5505805A (en) * 1992-03-05 1996-04-09 Industrieanlagen-Betriebsgesellschaft Gmbh Method for the production of reflectors
US5825565A (en) * 1992-03-05 1998-10-20 Industrieanlagen-Betriebsgesellschaft Gmbh Reflector

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