JPH03109218A - Platy nickel hydroxide and production thereof - Google Patents
Platy nickel hydroxide and production thereofInfo
- Publication number
- JPH03109218A JPH03109218A JP24498389A JP24498389A JPH03109218A JP H03109218 A JPH03109218 A JP H03109218A JP 24498389 A JP24498389 A JP 24498389A JP 24498389 A JP24498389 A JP 24498389A JP H03109218 A JPH03109218 A JP H03109218A
- Authority
- JP
- Japan
- Prior art keywords
- nickel hydroxide
- several
- soln
- platy
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 title claims abstract description 16
- 241000276425 Xiphophorus maculatus Species 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000002245 particle Substances 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 7
- 150000002815 nickel Chemical class 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 230000032683 aging Effects 0.000 abstract description 4
- 239000000919 ceramic Substances 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 4
- 239000000945 filler Substances 0.000 abstract description 3
- 239000010419 fine particle Substances 0.000 abstract description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 3
- 239000007858 starting material Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- -1 organic acid salts Chemical class 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、盤状水酸化ニッケル及びその製造方法に関す
る。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a plate-like nickel hydroxide and a method for producing the same.
本発明の盤状水酸化ニッケルは、電子セラミックス用原
料、充填材等として利用することができる。The plate-shaped nickel hydroxide of the present invention can be used as a raw material for electronic ceramics, a filler, and the like.
（従来の技術およびその問題点）
水酸化ニッケルは、ニッケル塩をアルカリで中和して得
られるが、形状としては不定形であったり、ｌａｍ以上
の大きい粒子であったりして、電子セラミックス用の原
料としては適していなかった。(Prior art and its problems) Nickel hydroxide is obtained by neutralizing nickel salt with an alkali, but it is amorphous or has large particles larger than lam, so it cannot be used for electronic ceramics. It was not suitable as a raw material.
微粒子で形状の揃った水酸化ニッケルが得られれば、電
子セラミックス用原料、充填材等の分野において粒子形
態に基づく特性を利用した新規用途開発が期待される。If fine particles of nickel hydroxide with a uniform shape can be obtained, it is expected that new applications will be developed in the fields of raw materials for electronic ceramics, fillers, etc. by utilizing the characteristics based on the particle morphology.
本発明の目的は、盤状水酸化ニッケル及びその製造方法
を提供することにある。An object of the present invention is to provide a plate-like nickel hydroxide and a method for producing the same.
（問題点を解決するための手段）
本発明は、粒子径が０．０１〜０．２μｍである盤状水
酸化ニッケル及びその製造方法に関する。(Means for Solving the Problems) The present invention relates to a disc-shaped nickel hydroxide having a particle size of 0.01 to 0.2 μm and a method for producing the same.
本発明の水酸化ニッケルは、粒子径が０．０１〜０．２
μｍである０粒子形態は盤状であり、さらに詳しくは六
角盤状ないしはそれに近位した形態を有する。The nickel hydroxide of the present invention has a particle size of 0.01 to 0.2
The particle shape of 0 μm is disc-shaped, and more specifically, it has a hexagonal disc-shape or a shape close to it.
本発明の盤状水酸化ニッケルは、ニッケル塩水溶液にア
ルカリを加えてｐＨを１０以上とした後、１０〜３００
℃の温度で熟成することにより製造される。The plate-shaped nickel hydroxide of the present invention is prepared by adding an alkali to a nickel salt aqueous solution to adjust the pH to 10 or higher, and then adjusting the pH to 10 to 300.
It is produced by ripening at a temperature of °C.
ニッケル塩としては、硝酸塩、硫酸塩、塩化物等の無機
塩、カルボン酸塩等の有機酸塩が用いられる。ニッケル
塩水溶液の濃度は、０．０１〜５Ｍが好ましい。As the nickel salt, inorganic salts such as nitrates, sulfates, and chlorides, and organic acid salts such as carboxylates are used. The concentration of the nickel salt aqueous solution is preferably 0.01 to 5M.
アルカリとしては、水酸化ナトリウム、水酸化カリウム
、アンモニア、炭酸ソーダ、炭酸アンモニウム等が用い
られる。As the alkali, sodium hydroxide, potassium hydroxide, ammonia, soda carbonate, ammonium carbonate, etc. are used.
アルカリは、添加後の溶液のｐＨが１０以上となるよう
に添加する。ｐＨが１０よりも小さい場合には、不純物
が生成し易いので好ましくない。The alkali is added so that the pH of the solution after addition is 10 or more. If the pH is less than 10, impurities are likely to be generated, which is not preferable.
熟成は、１０〜３００°Ｃで行う。１０°Ｃよりも低い
と、反応に長時間を要し、また、３００℃よりも高いと
安全性、経済性から不利である。Aging is performed at 10-300°C. When the temperature is lower than 10°C, the reaction takes a long time, and when it is higher than 300°C, it is disadvantageous from the viewpoint of safety and economy.
熟成の時間は、温度により異なるが、低温では数日〜数
十日、高温では数時間〜数十時間で充分である。The aging time varies depending on the temperature, but several days to several tens of days at low temperatures and several hours to several tens of hours at high temperatures are sufficient.
（実施例）
以下に実施例および比較例を示し、さらに詳しく本発明
について説明する。(Example) The present invention will be explained in more detail by showing Examples and Comparative Examples below.
実施例１
１Ｍの硝酸ニッケル［Ｎ１（ＮＯｚ）ｚ・６１１□０１
水溶液を攪拌しながら、ＩＭの水酸化ナトリウム水溶
液を徐々に滴下して中和を行い、溶液のｐＨを１２とし
た。Example 1 1M nickel nitrate [N1(NOz)z・611□01
While stirring the aqueous solution, an aqueous IM sodium hydroxide solution was gradually added dropwise to neutralize the solution, and the pH of the solution was adjusted to 12.
得られたスラリを３０°Ｃで２０日間熟成した後、洗浄
、濾過して、水酸化ニッケルを得た。The resulting slurry was aged at 30°C for 20 days, then washed and filtered to obtain nickel hydroxide.
得られた水酸化ニッケルは第１図に示すように盤状であ
り、粒子径は０．０５８μｍであった。The obtained nickel hydroxide was disk-shaped as shown in FIG. 1, and the particle size was 0.058 μm.
第１図は、実施例１で得られた水酸化ニッケルの粒子形
状を示す図面に代える透過型電子顕微鏡写真（倍率２０
０００倍）である。FIG. 1 is a transmission electron micrograph (magnification: 20
000 times).
Claims (2)
ニッケル。(1) Disc-shaped nickel hydroxide having a particle size of 0.01 to 0.2 μm.
以上とした後、１０〜３００℃の温度で熟成することを
特徴とする特許請求の範囲第１項記載の盤状水酸化ニッ
ケル。(2) Add alkali to the nickel salt aqueous solution to adjust the pH to 10
The plate-shaped nickel hydroxide according to claim 1, wherein the plate-shaped nickel hydroxide is aged at a temperature of 10 to 300°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24498389A JPH03109218A (en) | 1989-09-22 | 1989-09-22 | Platy nickel hydroxide and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24498389A JPH03109218A (en) | 1989-09-22 | 1989-09-22 | Platy nickel hydroxide and production thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03109218A true JPH03109218A (en) | 1991-05-09 |
Family
ID=17126848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24498389A Pending JPH03109218A (en) | 1989-09-22 | 1989-09-22 | Platy nickel hydroxide and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03109218A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06127947A (en) * | 1992-06-15 | 1994-05-10 | Inco Ltd | Preparation of nickel hydroxide |
| JP2005194156A (en) * | 2004-01-09 | 2005-07-21 | Ishikawajima Harima Heavy Ind Co Ltd | Method of manufacturing nickel hydroxide powder |
| JP2010037163A (en) * | 2008-08-06 | 2010-02-18 | Univ Of Miyazaki | Nickel hydroxide hexagonal plate and its manufacturing method |
| JP2010064910A (en) * | 2008-09-09 | 2010-03-25 | Sumitomo Metal Mining Co Ltd | Plate-like nickel-containing hydroxide and method for producing the same, and plate-like nickel-containing oxyhydroxide using the hydroxide and method for producing the same |
| JP2013075826A (en) * | 2012-12-27 | 2013-04-25 | Univ Of Miyazaki | Nickel hydroxide hexagonal plate and its production method |
-
1989
- 1989-09-22 JP JP24498389A patent/JPH03109218A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06127947A (en) * | 1992-06-15 | 1994-05-10 | Inco Ltd | Preparation of nickel hydroxide |
| JP2005194156A (en) * | 2004-01-09 | 2005-07-21 | Ishikawajima Harima Heavy Ind Co Ltd | Method of manufacturing nickel hydroxide powder |
| JP2010037163A (en) * | 2008-08-06 | 2010-02-18 | Univ Of Miyazaki | Nickel hydroxide hexagonal plate and its manufacturing method |
| JP2010064910A (en) * | 2008-09-09 | 2010-03-25 | Sumitomo Metal Mining Co Ltd | Plate-like nickel-containing hydroxide and method for producing the same, and plate-like nickel-containing oxyhydroxide using the hydroxide and method for producing the same |
| JP2013075826A (en) * | 2012-12-27 | 2013-04-25 | Univ Of Miyazaki | Nickel hydroxide hexagonal plate and its production method |
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