JPH0273001A - Dust improved in fast-acting property against insect pest - Google Patents
Dust improved in fast-acting property against insect pestInfo
- Publication number
- JPH0273001A JPH0273001A JP63225063A JP22506388A JPH0273001A JP H0273001 A JPH0273001 A JP H0273001A JP 63225063 A JP63225063 A JP 63225063A JP 22506388 A JP22506388 A JP 22506388A JP H0273001 A JPH0273001 A JP H0273001A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- formula
- powder
- concentration
- pyrethroid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 14
- 241000238631 Hexapoda Species 0.000 title claims abstract description 11
- 239000000428 dust Substances 0.000 title abstract 3
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 9
- 239000002728 pyrethroid Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 34
- -1 organophosphorus Substances 0.000 claims description 14
- 239000002280 amphoteric surfactant Substances 0.000 claims description 12
- 239000000073 carbamate insecticide Substances 0.000 claims description 5
- 239000002917 insecticide Substances 0.000 abstract description 10
- 125000000217 alkyl group Chemical group 0.000 abstract description 8
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 abstract description 6
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 abstract description 5
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 5
- 229960005286 carbaryl Drugs 0.000 abstract description 4
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000004471 Glycine Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000002563 ionic surfactant Substances 0.000 abstract 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 22
- 229960003237 betaine Drugs 0.000 description 11
- 102100027336 Regenerating islet-derived protein 3-alpha Human genes 0.000 description 10
- 239000004927 clay Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 2
- XJFIKRXIJXAJGH-UHFFFAOYSA-N 5-chloro-1,3-dihydroimidazo[4,5-b]pyridin-2-one Chemical group ClC1=CC=C2NC(=O)NC2=N1 XJFIKRXIJXAJGH-UHFFFAOYSA-N 0.000 description 2
- 241000238657 Blattella germanica Species 0.000 description 2
- 239000005945 Chlorpyrifos-methyl Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 2
- 229960000490 permethrin Drugs 0.000 description 2
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 2
- 229960003536 phenothrin Drugs 0.000 description 2
- 229940108410 resmethrin Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 2
- SBNFWQZLDJGRLK-SFTDATJTSA-N (3-phenoxyphenyl)methyl (1r,3s)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-SFTDATJTSA-N 0.000 description 1
- URYMJNGKKCSNLD-UHFFFAOYSA-N 2,2-dimethylicosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C)(C)C(O)=O URYMJNGKKCSNLD-UHFFFAOYSA-N 0.000 description 1
- BKQYOENNVQBCNE-UHFFFAOYSA-N 2-[bis(2-aminoethyl)amino]acetic acid Chemical compound NCCN(CCN)CC(O)=O BKQYOENNVQBCNE-UHFFFAOYSA-N 0.000 description 1
- 101710176122 28 kDa heat- and acid-stable phosphoprotein Proteins 0.000 description 1
- 241000258963 Diplopoda Species 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241001149911 Isopoda Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- 101710121155 Poly(A) polymerase I Proteins 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- 241000975357 Salangichthys microdon Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 125000002887 hydroxy group Chemical class [H]O* 0.000 description 1
- ITNHSNMLIFFVQC-IUCAKERBSA-N methyl (1R,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound COC(=O)[C@@H]1[C@H](C=C(C)C)C1(C)C ITNHSNMLIFFVQC-IUCAKERBSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- SBOJXQVPLKSXOG-UHFFFAOYSA-N o-amino-hydroxylamine Chemical compound NON SBOJXQVPLKSXOG-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、害虫用粉剤に関し、さらに詳しくは、速効性
が改善された害虫用粉剤に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a powder for pests, and more particularly to a powder for pests with improved quick-acting properties.
従来の技術
両性界面活性剤を含有した害虫用粉剤は従来知られてい
なかった。PRIOR ART Pest powders containing amphoteric surfactants have not been known to date.
発明が解決しようとする課題
本発明は、速効性の改善された害虫用粉剤を提供するこ
とにある。Problems to be Solved by the Invention An object of the present invention is to provide a powder for insect pests with improved fast-acting properties.
課題を解決するための手段
本発明者らは、上記課題を解決すべく鋭意研究の結果、
意外にも、両性界面活性剤を含有することにより、薬剤
の速効性が著しく高まることを見出し、本発明を完成し
た。Means for Solving the Problems As a result of intensive research to solve the above problems, the inventors of the present invention have found that
Surprisingly, it was discovered that the immediate effect of the drug was significantly increased by containing an amphoteric surfactant, and the present invention was completed.
すなわち、本発明は、ピレスロイド系、有機リン系及び
カーバメート系殺虫剤から選ばれた少なくとも１種から
なる殺虫成分及び両性界面活性剤を含有することを特徴
とする速効性の改善された害虫用粉剤である。That is, the present invention provides a powder for insect pests with improved quick-acting properties, which is characterized by containing an insecticidal component consisting of at least one selected from pyrethroid, organophosphorus, and carbamate insecticides, and an amphoteric surfactant. It is.
本発明において用いられる殺虫剤としては、（１，３，
４，５，６，７−ヘキサヒドロ−１，３−ジオキソ−２
−イソインドリルメチル（＋）−シス／トランスークリ
サンテマート（以下ｄ−テトラメスリンと略す）、（５
−ベンジル−３−フリル〉メチル（＋）−シス／トラン
スクリサンテマート（以下ｄ−レスメトリンと略す）、
３−フェノキシベンジル（±）−シス／トランス−３−
（２，２−ジクロロビニル）−２，２−ジメチル−１−
シクロプロパン力ルポキシラート（以下ペルメトリンと
略す）、（±）−２−メチル−４−才キソー３−（２−
プロピニル）−２−シクロペンテニル−（±）−シス／
トランスークリサンテマート（以下ｄ、ｄ−ブラレトリ
ンと略す）、３−フェノキシベンジル−（＋）−シス／
トランスークリサンテマート（以下フエノトリンと略す
）、２−（４−エトキシフェニル）−２−メチルプロピ
ル−３−フェノキシベンジルエーテル（以下エトフェン
ブロックスと略ｔ）、（±）−α−シアノ−３−プエノ
キシベンジル＝（＋）−シス／トランスークリサンテマ
ート（以下ｄ−シフエツトリンと略す）等のピレスロイ
ド系及びピレスロイド様殺虫剤や０．０−ジメチル−〇
−（３−メチル−４−ニトロフェニル）チオホスフェー
ト（以下フェニトロチオンと略す）、０．０−ジエチル
−〇−（２，３−ジヒドロ−３＝オキソ−２−フェニル
−６−ビリダニル）ホスフオロチオエート（以下ピリダ
フェンチオンと略す）、Ｏ−３，５，６−トリクロロ−
２−ビリジルー０．０−ジメチルホスフオロエート（以
下クロルピリフォスメチルと略す）等の有機リン系殺虫
剤及び１−ナフチルメチルカーバメート（以下刃ルバリ
ルと略す）、２−インプロポキシフェニルメチルカーバ
メート（以下プロポクスルと略す〉、５−メトキシ−３
−〈０−メトキシフェニル）−１゜３．４−才キサジア
ゾール−２（３Ｈ）−才ン（以下メトキサシアシンと略
す）等のカーバメート系殺虫剤が掲げられる。Insecticides used in the present invention include (1, 3,
4,5,6,7-hexahydro-1,3-dioxo-2
-isoindolylmethyl(+)-cis/trans-chrysanthemate (hereinafter abbreviated as d-tetramethrin), (5
-benzyl-3-furyl>methyl(+)-cis/trans chrysanthemate (hereinafter abbreviated as d-resmethrin),
3-phenoxybenzyl (±)-cis/trans-3-
(2,2-dichlorovinyl)-2,2-dimethyl-1-
Cyclopropane lupooxylate (hereinafter abbreviated as permethrin), (±)-2-methyl-4-xo-3-(2-
propynyl)-2-cyclopentenyl-(±)-cis/
trans-chrysanthemate (hereinafter abbreviated as d, d-brarethrin), 3-phenoxybenzyl-(+)-cis/
Trans-chrysanthemate (hereinafter abbreviated as phenothrin), 2-(4-ethoxyphenyl)-2-methylpropyl-3-phenoxybenzyl ether (hereinafter abbreviated as ethofenbrox), (±)-α-cyano-3 Pyrethroid and pyrethroid-like insecticides such as -puenoxybenzyl (+)-cis/trans-chrysanthemate (hereinafter abbreviated as d-sifuettrin) and 0.0-dimethyl-〇-(3-methyl-4- nitrophenyl)thiophosphate (hereinafter abbreviated as fenitrothion), 0.0-diethyl-〇-(2,3-dihydro-3=oxo-2-phenyl-6-pyridanyl) phosphorothioate (hereinafter abbreviated as pyridafention), O-3,5,6-trichloro-
Organophosphorus insecticides such as 2-pyridyl-0.0-dimethylphosphoroate (hereinafter abbreviated as chlorpyrifosmethyl), 1-naphthylmethylcarbamate (hereinafter abbreviated as rubaryl), and 2-impropoxyphenylmethylcarbamate (hereinafter abbreviated as rubaryl). Propoxur〉, 5-methoxy-3
Examples include carbamate insecticides such as -<0-methoxyphenyl)-1<3.4-xadiazole-2(3H)-xadiazole (hereinafter abbreviated as methoxacyacin).
本発明に用いられる両性界面活性剤としては、下記式Ｉ
〜■で示きれる構造式をもつものである。As the amphoteric surfactant used in the present invention, the following formula I
It has a structural formula shown by ~■.
（式中、Ｒ１は炭素原子数８〜１８のアルキル基を示し
、Ｒ′はベンジル基またはメチル基を示す６）（式中、
Ｒ１は炭素原子数８〜１８のアルキル基を示す、）
Ｒ” −（Ｎ ＨＣＨｘＣＨ！＞−Ｎ ”ＨＣＨｘＣＯ
Ｏ−、、、、Ｉ
（式中、ｎは１〜３の整数、Ｒ８は炭素原子数８〜１８
のアルキル基を示す。）
ＣＨ。(In the formula, R1 represents an alkyl group having 8 to 18 carbon atoms, and R' represents a benzyl group or a methyl group6) (In the formula,
R1 represents an alkyl group having 8 to 18 carbon atoms, ) R"-(NHCHxCH!>-N"HCHxCO
O-,,,,I (wherein, n is an integer of 1 to 3, R8 is a carbon atom number of 8 to 18
represents an alkyl group. ) CH.
Ｒ”−Ｎ→０ ＣＨ。R”-N→0 CH.
、、、、ｍ
く式中、Ｒ１は炭素原子数８〜１８のアルキル基を示す
、）
Ｈｓ
Ｒ’−Ｎ”ＣＨＩＣＯＯ−
、、、、ｙ
ＣＨ。,,,,m (in the formula, R1 represents an alkyl group having 8 to 18 carbon atoms) Hs R'-N"CHICOO- ,,,y CH.
Ｒ’ ＣＯＮ Ｈ（ＣＨ！ ） ｓ Ｎ ” ＣＨ＊
Ｃ００−Ｈｘ
、、、、 Ｖ
（式中、Ｒ′は炭素原子数８〜１８のアルキル基を示す
。）
（ＣＨよ）、−ＣＯＯ−
、、、、Ｖｔ
（式中、Ｒ′は炭素原子数８〜１８のアルキル基を示し
、Ｒ’は水酸基または酸性塩を示し、Ｒ＠は水素原子ま
たはカルボキシメチル基あるいはそのナトノウム塩を示
し、ｎは１〜２の整数を示す。）（ＣＨ，）、−Ｃ００
−
１１，、■
（式中、Ｒ”は炭素原子数８〜１８のアルキル基を示し
、Ｒ”は水素原子またはカルボキシメチル基あるいはそ
のナトリウム塩を示し、ｎは１〜２の整数を示す。）
これらの代表的なものは、ポリオクチルポリアミノエチ
ルグリシン［以下ＴＥＧＯ５１（商品名：ゴールドシュ
ミット社）と称する。］、ポリアルキルジ（アミノエテ
ル）グリシン、ラウリルジメチルアンモニウムベタイン
、ステアリルジメチル酢酸ベタイン、ミリスチル酸プロ
パニルアミドジメチル酢酸ベタイン、ラウリルジメチル
アミンオキサイド、アルキルカルボキシメチルヒドロキ
シエチルイミタゾリニウムベタイン、２−アルキル−Ｎ
−ヒドロキシエチルイミダゾリニウムベタインなどが挙
げられる。R' CON H(CH!) s N” CH*
C00-Hx ,,,,V (In the formula, R' represents an alkyl group having 8 to 18 carbon atoms.) (CH), -COO- ,,,,Vt (In the formula, R' is a carbon atom represents an alkyl group of number 8 to 18, R' represents a hydroxyl group or an acid salt, R@ represents a hydrogen atom or a carboxymethyl group or a sodium salt thereof, and n represents an integer of 1 to 2.) (CH, ), -C00
- 11,, ■ (In the formula, R'' represents an alkyl group having 8 to 18 carbon atoms, R'' represents a hydrogen atom, a carboxymethyl group, or a sodium salt thereof, and n represents an integer of 1 to 2. ) A typical example of these is polyoctylpolyaminoethylglycine [hereinafter referred to as TEGO51 (trade name: Goldschmidt). ], polyalkyl di(aminoether) glycine, lauryl dimethyl ammonium betaine, stearyl dimethyl acetate betaine, myristate propanylamide dimethyl acetate betaine, lauryl dimethylamine oxide, alkyl carboxymethyl hydroxyethylimitazolinium betaine, 2-alkyl-N
-Hydroxyethylimidazolinium betaine and the like.
本両性界面活性剤の含量は鉱物粉末の性質、製造上の適
性及び効力増強の限界点等を考慮して、製剤に対し、０
．１〜５．０重量％、好ましくは０゜５〜３．０重量％
である。The content of the present amphoteric surfactant is determined by considering the properties of the mineral powder, suitability for manufacturing, and the limit of potency enhancement, etc.
．． 1 to 5.0% by weight, preferably 0.5 to 3.0% by weight
It is.
また、これらに、Ｎ−オフシル−ビシクロへブテンジカ
ルボキシイミド［以下ＭＧＫ２６４（商品名：吉富製薬
製）と称した。コなどの殺虫成分の共力剤及びエチレン
グリフールなどのグリコール類のその他の界面活性剤等
に添加剤等を併用することもできる。In addition, N-offsyl-bicyclohebutene dicarboximide [hereinafter referred to as MGK264 (trade name: manufactured by Yoshitomi Pharmaceutical) was added to these. Additives and the like can also be used in combination with synergists for insecticidal ingredients, such as Co, and other surfactants, such as glycols, such as ethylene glycol.
なお、安定化剤、例えばイソプロピルホスフェートなど
のリン酸エステル、ポリエチレングリコール脂肪酸エス
テル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エ
ステルなどの脂肪酸エステルと併用しても、その効力を
失うことはない。In addition, even if it is used in combination with a stabilizer, for example, a phosphoric acid ester such as isopropyl phosphate, a fatty acid ester such as a polyethylene glycol fatty acid ester, a sorbitan fatty acid ester, or a glycerin fatty acid ester, the effect will not be lost.
本発明の両性界面活性剤の添加には特別の手段は要せず
均一に混ぜるだけでよい。すなわち、粉剤は、殺虫成分
である殺虫剤及び両性界面活性を、必要に応じて殺虫成
分の共力剤並びに補助剤と共に鉱物担体に加え、粉砕混
合または篩過することにより製造できる。また、プレミ
ックスの製造を経てから製造する際でも同様で構わない
。No special means are required to add the amphoteric surfactant of the present invention, and it is sufficient to mix it uniformly. That is, a powder can be produced by adding an insecticidal ingredient, an insecticide and an amphoteric surfactant, to a mineral carrier together with a synergist and an auxiliary agent for the insecticidal ingredient, if necessary, and pulverizing and mixing or sieving the mixture. Further, the same may be applied when manufacturing the premix after it has been manufactured.
この際の鉱物担体としては、タルク、クレーカオリン、
珪藻土、ペンナイト、風化花崗岩、シラスなどが挙げら
れる。また、プレミックスを経て製造する際には必要に
応じ無水珪酸を加え、製造することができる。In this case, mineral carriers include talc, clay kaolin,
Examples include diatomaceous earth, pennite, weathered granite, and whitebait. Moreover, when producing through a premix, silicic anhydride can be added as necessary.
発明の効果
本発明により、殺虫剤の種類及び濃度に左右きれること
のない速効性の優れた害虫用粉剤が可能となる。Effects of the Invention The present invention makes it possible to provide a powder for insect pests with excellent fast-acting properties that are independent of the type and concentration of the insecticide.
火４１例 以下実施例及び試験例を挙げ、更に詳細に説明する。Tuesday 41 cases A more detailed explanation will be given below with reference to Examples and Test Examples.
実施例１
粉末クレー９６．８部、フエノトリン０．２部、ポリア
ルキルジ（アミノエチル）グリシンを１．０部及びイソ
プロピルアシドホスフェート（以下ＰＡＰと略す〉２．
０部をヤリャ粉砕機（ヤリャ社製）にて十分粉砕混合し
、粉剤とした。Example 1 96.8 parts of powdered clay, 0.2 parts of phenothrin, 1.0 parts of polyalkyldi(aminoethyl)glycine, and isopropyl acid phosphate (hereinafter abbreviated as PAP)2.
0 parts were thoroughly ground and mixed using a Yalla crusher (manufactured by Yalla Co., Ltd.) to form a powder.
実施例２
カオリン９５．０部、プロポジスル２．０部、ラウリル
ジメチルアンモニウムベタイン１．０部及びＰＡＰ２．
０部をヤリャ粉砕機にて十分粉砕混合し、粉剤とした。Example 2 95.0 parts of kaolin, 2.0 parts of propodisul, 1.0 part of lauryldimethylammonium betaine, and 2.0 parts of PAP.
0 parts were thoroughly ground and mixed using a Yalla grinder to form a powder.
実施例３
粉末クレー９５．０部、フェニトロチオン２．０部、ス
テアリルジメチル酢酸ベタイン１．０部及びＰＡＰ２．
０部をヤリャ粉砕機にて十分粉砕混合し、粉剤とした。Example 3 95.0 parts of powdered clay, 2.0 parts of fenitrothion, 1.0 part of betaine stearyldimethylacetate, and 2.0 parts of PAP.
0 parts were thoroughly ground and mixed using a Yalla grinder to form a powder.
実施例４
タルク９７．８部、ｄ−テトラメスリン０．１部、ＭＧ
Ｋ２６４を０．６部、ラウリルジメチルアミンオキサイ
ド０．５部及びＰＡＰｌ、０部をヤノヤ粉砕機にて十分
粉砕混合し、粉剤とした。Example 4 Talc 97.8 parts, d-tetramethrin 0.1 part, MG
0.6 parts of K264, 0.5 parts of lauryl dimethylamine oxide, and 0 parts of PAP1 were thoroughly ground and mixed using a Yanoya mill to obtain a powder.
実施例５
フラッシュミキサー混合機（宝工機社製）にカオリン８
３部、無水珪酸５．５部、エトフェンブロックス０，２
５部、ピリダフェンチオン３．７５部、ＴＥＧＯ５１を
２．５部及びＰＡＰ５．０部を仕込み、プレミックスを
得た。このプレミックス４０部とカオリン６０部を■型
混合機（徳寿工作所製）に仕込み、均一に混合した後、
３２メツシユで篩過して粉剤とした。Example 5 Kaolin 8 was added to a flash mixer mixer (manufactured by Takarakoki Co., Ltd.)
3 parts, 5.5 parts of silicic anhydride, 0.2 parts of ethofenbrox
5 parts, 3.75 parts of pyridafention, 2.5 parts of TEGO51, and 5.0 parts of PAP were added to obtain a premix. After putting 40 parts of this premix and 60 parts of kaolin into a ■ type mixer (manufactured by Tokuju Kosho) and mixing them uniformly,
It was sieved through a 32-mesh mesh to make a powder.
実施例６
フラッシュミキサー混合機に、クレー
７５．７５部、無水珪酸５．５部、カルバリル５．０部
、フェニトロチオン３．７５部、アルキル力ルボキシメ
チルヒドロキシエチルイミタゾリニウムベタイン５．０
部及びＰＡＰ５．０部を仕込み、プレミックスを得た。Example 6 In a flash mixer mixer, 75.75 parts of clay, 5.5 parts of silicic anhydride, 5.0 parts of carbaryl, 3.75 parts of fenitrothion, and 5.0 parts of alkyl carboxymethyl hydroxyethylimitazolinium betaine were added.
and 5.0 parts of PAP were added to obtain a premix.
このプレミックス４０部とクレー６０部をヤリＶ粉砕機
に仕込み、十分に粉砕して粉剤とした。40 parts of this premix and 60 parts of clay were charged into a spear V grinder and sufficiently ground to form a powder.
実施例７
フラシユミキサー混合機に、タルク
７５．２５部、無水珪酸５．５部、メトキサシアシン５
．０１．クロルピリフォスメチル３．７５ｉ、ｄ、ｄ−
ブラシ８９２０．５部、ミリスチル酸プロパニルアミド
ジメチル酢酸ベタイン５．０部及びＰＡＰ５．０部を仕
込み、プレミックスを得た。Example 7 In a flash mixer mixer, 75.25 parts of talc, 5.5 parts of silicic anhydride, and 5 parts of methoxacyacin were added.
．． 01. Chlorpyrifosmethyl 3.75i, d, d-
8920.5 parts of brush, 5.0 parts of propanylamide myristate dimethyl acetate betaine, and 5.0 parts of PAP were charged to obtain a premix.
このプレミックス４０部とクレー６０部をヤリＶ粉砕機
に仕込み、十分に粉砕して粉剤とした。40 parts of this premix and 60 parts of clay were charged into a spear V grinder and sufficiently ground to form a powder.
実施例８
フラッシュミキサー混合機に、カオリン７８．５部、無
水珪酸５．５部、ｄ−テトラメスリン０．２５部、ペル
メトリンｏ、ｓ部、フェニトロチオン３．７５部、ＭＧ
Ｋ２６４を１．５部、２アルキル−Ｎ−ヒドロキシエチ
ルイミダゾリニウムベタイン５．０部及びＰＡＰ５．０
部を仕込み、プレミックスを得た。このプレミックス４
０部とクレー６０部を■型混合機に仕込み、均一に混合
した後、３２メツシユで篩過して粉剤とした。Example 8 In a flash mixer mixer, 78.5 parts of kaolin, 5.5 parts of silicic anhydride, 0.25 parts of d-tetramethrin, parts o and s of permethrin, 3.75 parts of fenitrothion, and MG.
1.5 parts of K264, 5.0 parts of 2-alkyl-N-hydroxyethylimidazolinium betaine and 5.0 parts of PAP
I prepared a part and got a premix. This premix 4
0 parts and 60 parts of clay were placed in a type 2 mixer, mixed uniformly, and then passed through a 32 mesh sieve to obtain a powder.
実施例９
フラッシュミキサー混合機に、タルク
７８．５部、無水珪酸５．５部、ｄ−レスメトリン１．
０部、カルバリル５．０部、２−アルキル−Ｎ−ヒドロ
キジメチルイミクゾリニウムベタイン５．０部及びＰＡ
Ｐ５．０部を仕込み、プレミックスを得た。このプレミ
ックス４０部とクレー６０部をＶ型混合機に仕込み、均
一に混合した後、３２メツシユで篩過して粉剤とした。Example 9 In a flash mixer mixer, 78.5 parts of talc, 5.5 parts of silicic anhydride, and 1.5 parts of d-resmethrin were added.
0 parts, carbaryl 5.0 parts, 2-alkyl-N-hydroxydimethylimixzolinium betaine 5.0 parts and PA
A premix was obtained by adding 5.0 parts of P. 40 parts of this premix and 60 parts of clay were charged into a V-type mixer, mixed uniformly, and then passed through a 32-mesh sieve to form a powder.
実施例１０
フラ・ノシュミキサー混合機に、クレー７９部、無水珪
酸５５部、ｄ−シフエツトリン０．５部、プロボタスル
５．０部、ポリアルキルジくアミノエチル）グリシン５
０部及びＰＡＰ５．０部を仕込み、プレミックスを得た
。このプレミックス４０部とクレー６０部をＶ型混合機
に仕込み、均一に混合した後、３２メツシユで篩過して
粉剤とした。Example 10 In a Fura Nosch mixer mixer, 79 parts of clay, 55 parts of silicic anhydride, 0.5 parts of d-sifuettrin, 5.0 parts of probotasul, 5 parts of polyalkyl di(aminoethyl)glycine
0 parts and 5.0 parts of PAP were added to obtain a premix. 40 parts of this premix and 60 parts of clay were charged into a V-type mixer, mixed uniformly, and then passed through a 32-mesh sieve to form a powder.
試験例１
表−１に示すような本発明の粉剤である両性界面活性剤
及びｄ−テトラメスリン０．１重量％を含有した害虫用
粉剤及びその対照としてＰＡＰ単独の粉剤及び界面活性
剤無添加の粉剤について、実施例１〜３と同様に製造し
、チャバネゴキブリ（成虫オス）を用いて濾紙接触法に
て効力試験を行ない、各々のＫＴ５０値を調べた。濾紙
接触法については、直径９ｃｍのシャーレ底面に濾紙を
敷き、粉剤を５０＋Ｔｇ取り、面相筆にて粉剤を広げ、
その上に供試虫ＩＣ匹を一斉に放ち、３連３反復で試験
を行なった。Test Example 1 As shown in Table 1, a powder for insect pests containing an amphoteric surfactant and 0.1% by weight of d-tetramethrin, which is a powder of the present invention, and a powder containing PAP alone and a powder containing no surfactant were used as controls. Powders were manufactured in the same manner as in Examples 1 to 3, and efficacy tests were conducted using the filter paper contact method using German cockroaches (adult male) to determine the KT50 value of each powder. For the filter paper contact method, place a filter paper on the bottom of a Petri dish with a diameter of 9 cm, take a powder of 50 + Tg, spread the powder with a face brush,
Test insects IC were released all at once onto it, and the test was repeated in triplicate.
その結果は表−１に示す通りである。The results are shown in Table-1.
表−１チャバネゴキブリを用いた濾紙接触試験法この結
果より両性界面活性剤の適当な濃度は、０１〜５．０％
である。なお、５．０％以上入れた際には、流動性、散
布性が悪くなることから上記濃度が望ましい。Table 1 Filter paper contact test method using German cockroaches From this result, the appropriate concentration of amphoteric surfactant is 01 to 5.0%.
It is. Note that if it is added in an amount of 5.0% or more, fluidity and dispersibility will deteriorate, so the above concentration is desirable.
試験例２
表−２に示すような本発明による害虫用粉剤を実施例１
〜３と同様に製造し、各々について、才力ダンゴムシを
用いて濾紙接触法にて効力試験を行ない、以上のような
結果を得た。なお、方法は試験例１と同様であり、粉剤
量は１００ｎ’ｇとした。対照として、ＰＡＰ単独のも
ので行ない、試験頭数は１０頭、３反復とした。Test Example 2 The powder for pests according to the present invention as shown in Table 2 was tested in Example 1.
They were produced in the same manner as in Steps 3 to 3, and efficacy tests were conducted using pill bugs using the filter paper contact method, and the results described above were obtained. The method was the same as Test Example 1, and the amount of powder was 100 n'g. As a control, PAP alone was used, and the number of test animals was 10, and the test was repeated three times.
試験結果：この値は接触開始後３０分時に仰転した虫の
率で表わす。Test result: This value is expressed as the percentage of insects that turned over 30 minutes after the start of contact.
試験例３
表−２に用いた本発明による害虫用粉剤について、ヤケ
ヤスデを用いて濾紙接触法にて効力試験を行ない、以下
のような結果を得た。なお、方法は試験例２と同様であ
り、粉剤量は１００（とした。試験頭数は１０頭、３反
復で行なった。Test Example 3 Efficacy tests were conducted on the pest insect powders according to the present invention shown in Table 2 by the filter paper contact method using yellow millipedes, and the following results were obtained. The method was the same as Test Example 2, and the amount of powder was 100. The number of test animals was 10, and the test was repeated three times.
Claims (2)
殺虫剤から選ばれた少なくとも１種からなる殺虫成分及
び両性界面活性剤を含有することを特徴とする速効性の
改善された害虫用粉剤(1) A powder for insect pests with improved quick-acting properties, characterized by containing an insecticidal component consisting of at least one selected from pyrethroid, organophosphorus, and carbamate insecticides and an amphoteric surfactant.
殺虫剤から選ばれた少なくとも１種からなる殺虫成分の
濃度が０．０５〜５．０重量％である請求項１に記載の
害虫用粉剤（３）両性界面活性剤の濃度が０．１〜５．
０重量％である請求項１に記載の害虫用粉剤（４）ピレ
スロイド系、有機リン系及びカーバメート系殺虫剤から
選ばれた少なくとも１種からなる殺虫成分の濃度が０．
０５〜５．０重量％及び両性界面活性剤の濃度が０．１
〜５．０重量％である請求項１に記載の害虫用粉剤(2) The powder for pests according to claim 1, wherein the concentration of the insecticidal component consisting of at least one selected from pyrethroid, organophosphorus, and carbamate insecticides is 0.05 to 5.0% by weight. ) The concentration of amphoteric surfactant is 0.1 to 5.
(4) The pest insect powder according to claim 1, wherein the concentration of the insecticidal component consisting of at least one selected from pyrethroid, organophosphorus, and carbamate insecticides is 0.0% by weight.
05-5.0% by weight and the concentration of amphoteric surfactant is 0.1
The powder for pests according to claim 1, which is 5.0% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63225063A JP2737949B2 (en) | 1988-09-08 | 1988-09-08 | Pest powders with improved fast-acting properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63225063A JP2737949B2 (en) | 1988-09-08 | 1988-09-08 | Pest powders with improved fast-acting properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0273001A true JPH0273001A (en) | 1990-03-13 |
| JP2737949B2 JP2737949B2 (en) | 1998-04-08 |
Family
ID=16823455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63225063A Expired - Lifetime JP2737949B2 (en) | 1988-09-08 | 1988-09-08 | Pest powders with improved fast-acting properties |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2737949B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002068902A (en) * | 2000-08-31 | 2002-03-08 | Fumakilla Ltd | Repellant against unpleasant insect pest living in soil and repelling method using the same |
| JP2010083903A (en) * | 2002-05-31 | 2010-04-15 | Kao Corp | Agricultural chemical composition |
| FR2958500A1 (en) * | 2010-04-07 | 2011-10-14 | Jd Invest | Insecticide, insect repellent, ovicide, larvicide, nymphicide composition, useful to destruct flying and crawling insects, their eggs, larvae, and nymphs, comprises essential oil, proteolytic enzyme, and amphoteric surfactant |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6322502A (en) * | 1986-07-14 | 1988-01-30 | Kao Corp | Production of granular agricultural chemical |
-
1988
- 1988-09-08 JP JP63225063A patent/JP2737949B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6322502A (en) * | 1986-07-14 | 1988-01-30 | Kao Corp | Production of granular agricultural chemical |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002068902A (en) * | 2000-08-31 | 2002-03-08 | Fumakilla Ltd | Repellant against unpleasant insect pest living in soil and repelling method using the same |
| JP2010083903A (en) * | 2002-05-31 | 2010-04-15 | Kao Corp | Agricultural chemical composition |
| FR2958500A1 (en) * | 2010-04-07 | 2011-10-14 | Jd Invest | Insecticide, insect repellent, ovicide, larvicide, nymphicide composition, useful to destruct flying and crawling insects, their eggs, larvae, and nymphs, comprises essential oil, proteolytic enzyme, and amphoteric surfactant |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2737949B2 (en) | 1998-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU658417B2 (en) | Chemically stable granules containing insecticidal phosphoroamidothioates | |
| EP0566538B1 (en) | Synergistic fly attractant composition | |
| EP2090164B1 (en) | A rodenticide bait based on a synergetic association of anticoagulant active ingredients | |
| JPH09500367A (en) | Harmless pest control | |
| CA1119951A (en) | Method and composition for the long term controlled release of a non-persistent organotin pesticide from an inert monolithic thermpolastic dispenser | |
| US4122165A (en) | Insecticidal composition containing cis-9-tricosene and methomyl | |
| JPH0273001A (en) | Dust improved in fast-acting property against insect pest | |
| JP5680949B2 (en) | Chemical treatment method using pest control agent | |
| CH658365A5 (en) | STABILIZED MICROCAPSULATED INSECTICIDE COMPOSITIONS AND METHOD FOR THE PRODUCTION THEREOF. | |
| BRPI0617379A2 (en) | pesticide composition | |
| JPH01139515A (en) | Repellent composition for dog, cat and birds | |
| JPH08505368A (en) | Granular water-soluble or hygroscopic agricultural compound and method of making same | |
| GB2178316A (en) | Pesticidal compositions | |
| WO2004062362A2 (en) | Particulate composition for exterminating unwanted rodents | |
| JPS6145961B2 (en) | ||
| JP2776816B2 (en) | Detoxified pest control resin composition for controlling pests present in soil and method for preparing the same | |
| DE4233625C2 (en) | Animal baits and methods of making same | |
| KR100316145B1 (en) | Manufacturing method of controlled release pesticide composition and its pesticide composition | |
| JP4365967B2 (en) | Chibi cherry seed attractant | |
| JPH03170403A (en) | Animal repellent | |
| JPS59199616A (en) | Insecticidal composition | |
| JPH0327301A (en) | Stabilized insecticide powder preparation | |
| JPS6242903A (en) | Fly attractant | |
| JPH06500533A (en) | Pesticides containing metaldehyde | |
| JPH06298602A (en) | Granular agrichemical |