JPH0247238A - High-damping alloy and its production - Google Patents
High-damping alloy and its productionInfo
- Publication number
- JPH0247238A JPH0247238A JP19752088A JP19752088A JPH0247238A JP H0247238 A JPH0247238 A JP H0247238A JP 19752088 A JP19752088 A JP 19752088A JP 19752088 A JP19752088 A JP 19752088A JP H0247238 A JPH0247238 A JP H0247238A
- Authority
- JP
- Japan
- Prior art keywords
- hydrogen
- added
- temp
- heat treatment
- damping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000013016 damping Methods 0.000 title claims abstract description 22
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 20
- 239000000956 alloy Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 26
- 239000001257 hydrogen Substances 0.000 claims abstract description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 7
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 229910052738 indium Inorganic materials 0.000 claims abstract description 7
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 7
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 229910052718 tin Inorganic materials 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 7
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 7
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 6
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 6
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 6
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 6
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 6
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 239000011159 matrix material Substances 0.000 claims abstract description 4
- 239000006104 solid solution Substances 0.000 claims abstract description 4
- -1 hydrogen compound Chemical class 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract description 15
- 229910052797 bismuth Inorganic materials 0.000 abstract description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 238000005242 forging Methods 0.000 abstract description 2
- 230000003993 interaction Effects 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 238000005096 rolling process Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 10
- 229910000861 Mg alloy Inorganic materials 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229910017060 Fe Cr Inorganic materials 0.000 description 2
- 229910002544 Fe-Cr Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910004337 Ti-Ni Inorganic materials 0.000 description 1
- 229910011209 Ti—Ni Inorganic materials 0.000 description 1
- 229910009369 Zn Mg Inorganic materials 0.000 description 1
- 229910007573 Zn-Mg Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- KHYBPSFKEHXSLX-UHFFFAOYSA-N iminotitanium Chemical compound [Ti]=N KHYBPSFKEHXSLX-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
Landscapes
- Heat Treatment Of Steel (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上利用分野）
本発明は、制振合金およびその製造方法、さらに詳細に
は軽量にして制振特性に優れたコンピュータ用、航空宇
宙用、自動車用などの機構部品材料およびその製造方法
に関するものである。Detailed Description of the Invention (Industrial Field of Application) The present invention relates to a vibration damping alloy and a method for manufacturing the same, and more particularly to a structure for use in computers, aerospace, automobiles, etc. that is lightweight and has excellent vibration damping properties. The present invention relates to component materials and manufacturing methods thereof.
（従来技術）
従来、制振合金としてＦｅ−Ｃｒ系合金や、Ｍｎ−Ｃｕ
合金、ＮｉＴｉ合金などが開発されている。(Prior art) Conventionally, Fe-Cr alloys and Mn-Cu alloys have been used as damping alloys.
alloys, NiTi alloys, etc. have been developed.
これらの合金は、鉄道線路の補修機、さく岩槻ドリル、
防音車輪など、大きなエネルギーで、かつ低周波の振動
を吸収する性能を有するものである。These alloys are used in railway track repair machines, Iwatsuki drills,
It has the ability to absorb large amounts of energy and low-frequency vibrations, such as soundproof wheels.
近年、メカトロニクス技術の進展に伴い、エネルギーが
小さくかつ高い周波数の振動を吸収する軽量な制振合金
の必要性が高まってきた。In recent years, with the advancement of mechatronics technology, there has been an increasing need for lightweight damping alloys that absorb low energy and high frequency vibrations.
例えば、コンピュータ記憶装置の記録媒体は高密度化の
一途をたどっているが、これに伴い、記憶装置用のアー
ムなどの機構部品には軽量であることは無論のこと、位
置決めなどの精度向上のため、エネルギーは小さいが高
い振動数の振動を吸収する必要が高まっている。For example, the recording media of computer storage devices are becoming more and more densely packed, and along with this, mechanical parts such as arms for storage devices need to be lightweight, as well as to improve precision in positioning. Therefore, there is an increasing need to absorb low-energy but high-frequency vibrations.
（発明が解決する問題点）
しかしながら、前述の既存制振合金では、重量が大きい
うえ、周波数が高い領域での制振特性が劣っているので
、軽量で高い周波数領域において制振特性の優れた材料
の出現が望まれている。(Problems to be solved by the invention) However, the existing vibration damping alloys mentioned above are heavy and have poor damping properties in high frequency ranges. It is hoped that new materials will emerge.
本発明は上述の問題点に鑑みなされたものであり、周波
数が高い領域での制振特性を改善した軽量機構部品材料
を提供することを目的とする。The present invention was made in view of the above-mentioned problems, and an object of the present invention is to provide a lightweight mechanical component material with improved vibration damping characteristics in a high frequency region.
（問題点を解決するための手段）
上述の問題点を解決するため、本発明による制振合金は
、Ｍｇに、Ａｌ、 Ｓｉ、 Ｐ、Ｃａ、Ｔｉ、Ｖ、Ｃｒ
、Ｍｎ、 Ｆｅ、 Ｃｏ、 Ｎｉ、 Ｃｕ、 Ｚｎ、
Ｇａ、 Ｇｅ、Ｙ、 Ｚｒ、Ｎｂ、Ｍｏ、 Ａｓ、 Ｃ
ｄ、Ｉｎ、 Ｓｎ、 Ｓｂ、Ｂｉのうち１種又は複数種
を０．１％以上１０％以下および水素をＭｇマトリック
ス中に固溶状態および前記添加元素との水素化合物の形
で添加したことを特徴としている。(Means for Solving the Problems) In order to solve the above-mentioned problems, the damping alloy according to the present invention contains Mg, Al, Si, P, Ca, Ti, V, and Cr.
, Mn, Fe, Co, Ni, Cu, Zn,
Ga, Ge, Y, Zr, Nb, Mo, As, C
d, In, Sn, Sb, and Bi in an amount of 0.1% to 10% and hydrogen in a solid solution state in the Mg matrix and in the form of a hydrogen compound with the additional element. It is a feature.
また本発明による制振合金の製造方法は、Ｍｇに、Ａｌ
、 Ｓｉ、 Ｐ、Ｃａ、 Ｔｉ、 Ｖ、 Ｃｒ、 Ｍｎ
、 Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ、 ＺｎＳＧａ、 Ｇｅ、
Ｙ、 Ｚｒ、 Ｎｂ、Ｍｏ、 Ａｓ、Ｃｄ、Ｉｎ、
Ｓｎ、 Ｓｂ、 Ｂｉのうち１種又は複数種を０．１％
以上１０％以下添加し、溶解、鍛造、圧延した後、Ｈ２
気流中において９０℃以上、固相線以下の温度で熱処理
を施したことを特徴とする。Further, the method for producing a damping alloy according to the present invention includes adding Al to Mg.
, Si, P, Ca, Ti, V, Cr, Mn
, Fe, Co, Ni, Cu, ZnSGa, Ge,
Y, Zr, Nb, Mo, As, Cd, In,
0.1% of one or more of Sn, Sb, and Bi
After adding 10% or more, melting, forging, and rolling, H2
It is characterized by being heat-treated in an air stream at a temperature of 90°C or higher and lower than the solidus line.
本発明は、Ｍｇに前記元素を添加し水素気流中にて熱処
理を施すことにより、水素原子をＭｇマトリックス中に
固溶させるのみでなく、添加元素と水素化合物粒子を生
成せしめたことに特徴がある。The present invention is characterized in that by adding the above-mentioned elements to Mg and performing heat treatment in a hydrogen stream, hydrogen atoms are not only dissolved in the Mg matrix, but also the added elements and hydrogen compound particles are generated. be.
この結果、固溶水素原子という点欠陥に起因する緩和型
内部摩擦を増加させるのみでなく、水素化合物粒子と転
位の相互作用に起因する内部摩擦を増加させることによ
り優れた制振特性を実現したものである。As a result, excellent vibration damping properties were achieved by not only increasing the relaxed internal friction caused by the point defects of solid solution hydrogen atoms, but also by increasing the internal friction caused by the interaction between hydrogen compound particles and dislocations. It is something.
従来技術である磁壁移動を利用したＦｅ−Ｃｒ系合金、
双晶境界を利用したＴｉ−Ｎｉ系合金などがあるが、こ
れらの合金はいずれもＭｇと比較し、比重が大であるう
え単一の内部摩擦増加機構を有しているに過ぎず、本発
明と比較し、重量の点および高い周波数領域での制振特
性に劣っている。Fe-Cr alloy using domain wall movement, which is a conventional technology,
There are Ti-Ni alloys that utilize twin boundaries, but all of these alloys have a higher specific gravity than Mg and only have a single internal friction increasing mechanism, Compared to the invention, it is inferior in terms of weight and vibration damping characteristics in a high frequency range.
本発明において添加する添加元素は、上述のようにに、
Ｓｉ、 Ｐ、 Ｃａ、 Ｔｉ、Ｖ、Ｃｒ、 Ｍｎ、 Ｆ
ｅ、 Ｃｏ、Ｎｉ、 Ｃｕ％Ｚｎ、 Ｇａ、Ｇｅ、 Ｙ
、Ｚｒ、 Ｎｂ、Ｍｏ、 Ａｓ、 Ｃｄ、Ｉｎ、 Ｓｎ
、 Ｓｂ、 Ｂｉのうち１種又は複数種であり、その添
加量は０．１％以上１０％以下である。The additive elements added in the present invention are, as described above,
Si, P, Ca, Ti, V, Cr, Mn, F
e, Co, Ni, Cu%Zn, Ga, Ge, Y
, Zr, Nb, Mo, As, Cd, In, Sn
, Sb, and Bi, and the amount thereof added is 0.1% or more and 10% or less.
上述の元素はＭｇ合金の特性を良好にすると共に、添加
される水素と水素化合物を形成させるために添加される
。上述のような添加元素の一種以上の添加量が０．１％
未満であると、Ｍｇ合金の改質効果がないと共に、水素
と化合物を生成しにくく、１０％を越えると、Ｍｇ合金
の特性を悪化させる恐れがあり、実用的ではないからで
ある。The above-mentioned elements are added to improve the properties of the Mg alloy and to form hydrogen compounds with added hydrogen. The amount of one or more of the above additive elements is 0.1%
If it is less than 10%, there is no effect of modifying the Mg alloy and it is difficult to form a compound with hydrogen, and if it exceeds 10%, the properties of the Mg alloy may be deteriorated, which is not practical.
本発明における制振合金の製造方法において、水素中で
の熱処理温度を９０℃以上としたのは、これより低い温
度においては水素がＭｇ合金中に充分固溶せず水素中熱
処理の効果が現われないためである。また、水素中での
熱処理温度を固相線以下の温度としたのはこれより高い
温度では液相を生成し、試料形状が維持できないためで
ある。In the method for producing a damping alloy in the present invention, the heat treatment temperature in hydrogen is set to 90°C or higher because at lower temperatures, hydrogen does not dissolve sufficiently in the Mg alloy and the effect of heat treatment in hydrogen is not apparent. This is because there is no Furthermore, the heat treatment temperature in hydrogen was set below the solidus line because at higher temperatures a liquid phase is generated and the sample shape cannot be maintained.
（実施例）
ＭｇにＺｎを６％、Ｚｒを０．５％添加し、溶解、鍛造
、圧延、切り出しにより、３ｍｍ Ｘ ３０ｍｍ Ｘ
１００ｍｍの短冊状試料を作製した。この試料を２７／
ｍｉｎ、のＨ２気流中において３００℃にて２時間の熱
処理を行なった。(Example) Add 6% Zn and 0.5% Zr to Mg, melt, forge, roll, and cut out 3 mm x 30 mm x
A 100 mm strip sample was prepared. This sample is 27/
A heat treatment was performed at 300° C. for 2 hours in a H2 gas flow of min.
この試料を両端自由振動状態に保ち、イナータンス伝達
関数応答加速度／加振力を測定し、固有振動モードの減
衰状悪を調べた。ただし、比較のため、水素中熱処理を
施す以前の状態でのイナータンス伝達関数も測定した。This sample was kept in a state of free vibration at both ends, and the inertance transfer function response acceleration/excitation force was measured to examine the damping condition of the natural vibration mode. However, for comparison, the inertance transfer function was also measured before the heat treatment in hydrogen.
結果を第１図および第２図に示す、第１図は水素中熱処
理を施した実施例に記した本発明材料のイナータンスと
周波数の関係を表す図、第２図は実施例に記した材料の
水素中熱処理を施さない場合のイナータンス（縦軸）と
周波数（横軸）の関係を示す図である。The results are shown in Figures 1 and 2. Figure 1 is a diagram showing the relationship between inertance and frequency of the material of the present invention described in the example subjected to heat treatment in hydrogen, and Figure 2 is a diagram showing the relationship between the inertance and frequency of the material described in the example which was subjected to heat treatment in hydrogen. FIG. 3 is a diagram showing the relationship between inertance (vertical axis) and frequency (horizontal axis) when heat treatment in hydrogen is not performed.
その結果、水素中熱処理を施す前のイナータンスの値は
１．５Ｋ）Ｌ！において６８ｄＢであったのが、水素焼
鈍後には６１ｄＢへと減少し、制振特性の著しい向上が
認められた。即ち、第１図および第２図から明らかなと
おり、本発明の材料が優れた制振特性を示し、軽量機構
部品材料として期待できることが明かとなった。As a result, the inertance value before heat treatment in hydrogen was 1.5K)L! It was 68 dB during hydrogen annealing, but it decreased to 61 dB after hydrogen annealing, indicating a significant improvement in the damping characteristics. That is, as is clear from FIGS. 1 and 2, it has become clear that the material of the present invention exhibits excellent vibration damping properties and can be expected as a material for lightweight mechanical parts.
同様な効果は、上記Ｚｎ−Ｍｇ系合金のほか、Ｎ、Ｓｉ
、 Ｐ、 Ｃａ、 Ｔｉ、Ｖ、Ｃｒ、 Ｍｎ、 Ｆｅ、
Ｃｏ、 Ｎｉ、Ｃｕ、Ｇａ、 Ｇｅ、 Ｙ、 Ｚｒ、
Ｎｂ、Ｍｏ、 Ａｓ、Ｃｄ、Ｉｎ、Ｓｎ、ｓｂ、Ｂｉ
のうち１種又は複数種添加したＭｇ合金系においても認
められた。Similar effects can be obtained with N, Si, in addition to the Zn-Mg alloys mentioned above.
, P, Ca, Ti, V, Cr, Mn, Fe,
Co, Ni, Cu, Ga, Ge, Y, Zr,
Nb, Mo, As, Cd, In, Sn, sb, Bi
It was also observed in Mg alloy systems in which one or more of these were added.
（発明の効果）
Ｍｇ合金は比重が１．１ｇ／ｃｃ程度と軽量であるうえ
、本発明の合金組成、水素中熱処理を施せば、ＩＫＨｚ
を越える高い周波数領域においても優れた割振特性を示
す。(Effect of the invention) Mg alloy is lightweight with a specific gravity of about 1.1 g/cc, and with the alloy composition of the present invention and heat treatment in hydrogen, IKHz
It exhibits excellent allocation characteristics even in high frequency ranges exceeding .
近年、コンピュータ記憶装置のアームなどの機構部品材
料においては、メカトロニクス技術の著しい進展に見合
った軽量、高制振特性が要求されてやまないが、本発明
はこれに答えるものである。In recent years, materials for mechanical parts such as arms of computer storage devices have been required to be lightweight and have high vibration damping properties commensurate with the remarkable progress in mechatronics technology, and the present invention is intended to meet these demands.
第１図は水素中熱処理を施した実施例に記した本発明材
料のイナータンスと周波数の関係を表す図、第２図は実
施例に記した材料の水素中熱処理を施さない場合のイナ
ータンス（縦軸）と周波数（横軸）の関係を示す図であ
る。Figure 1 is a diagram showing the relationship between inertance and frequency of the material of the present invention described in the example where heat treatment was performed in hydrogen, and Figure 2 is a diagram showing the inertance (vertical) of the material described in the example when heat treatment in hydrogen was not performed. FIG. 2 is a diagram showing the relationship between the frequency (axis) and the frequency (horizontal axis).
Claims (2)
、Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ、Ｚｎ、Ｇａ、Ｇｅ、
Ｙ、Ｚｒ、Ｎｂ、Ｍｏ、Ｍ、Ｃｄ、Ｉｎ、Ｓｎ、Ｓｂ、
Ｂｉのうち１種又は複数種を０．１％以上１０％以下お
よび水素をＭｇマトリックス中に固溶状態および前記添
加元素との水素化合物の形で添加したことを特徴とする
制振合金。(1) Mg, Al, Si, P, Ca, Ti, V, Cr
, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge,
Y, Zr, Nb, Mo, M, Cd, In, Sn, Sb,
A damping alloy characterized in that one or more of Bi is added in an amount of 0.1% to 10% and hydrogen in a solid solution state in an Mg matrix or in the form of a hydrogen compound with the above-mentioned additive element.
、Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ、Ｚｎ、Ｇａ、Ｇｅ、
Ｙ、Ｚｒ、Ｎｂ、Ｍｏ、Ａｓ、Ｃｄ、Ｉｎ、Ｓｎ、Ｓｂ
、Ｂｉのうち１種又は複数種を０．１％以上１０％以下
添加し、溶解、鍛造、圧延した後、Ｈ＿２気流中におい
て９０℃以上、固相線以下の温度で熱処理を施したこと
を特徴とする制振合金の製造方法。(2) Mg, Al, Si, P, Ca, Ti, V, Cr
, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge,
Y, Zr, Nb, Mo, As, Cd, In, Sn, Sb
, one or more of Bi is added from 0.1% to 10%, melted, forged, rolled, and then heat treated in an H_2 gas flow at a temperature of 90°C or more and below the solidus line. A manufacturing method for a characteristic damping alloy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19752088A JPH0247238A (en) | 1988-08-08 | 1988-08-08 | High-damping alloy and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19752088A JPH0247238A (en) | 1988-08-08 | 1988-08-08 | High-damping alloy and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0247238A true JPH0247238A (en) | 1990-02-16 |
Family
ID=16375834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19752088A Pending JPH0247238A (en) | 1988-08-08 | 1988-08-08 | High-damping alloy and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0247238A (en) |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0257657A (en) * | 1988-08-23 | 1990-02-27 | Furukawa Alum Co Ltd | High damping material of mg alloy and its manufacture |
| WO1994006945A1 (en) * | 1992-09-11 | 1994-03-31 | Nippon Kinzoku Co., Ltd. | Refined magnesium material and process for producing the same |
| WO1996019594A1 (en) * | 1994-12-22 | 1996-06-27 | Energy Conversion Devices, Inc. | Magnesium mechanical alloys for thermal hydrogen storage |
| US6755922B2 (en) * | 1999-12-03 | 2004-06-29 | Hitachi, Ltd. | High strength Mg based alloy and Mg based casting alloy and article made of the alloy |
| US7041179B2 (en) * | 2001-11-05 | 2006-05-09 | Dead Sea Magnesium Ltd. | High strength creep resistant magnesium alloys |
| CN100463989C (en) * | 2006-07-26 | 2009-02-25 | 哈尔滨工业大学 | Cariaceous high-damping deformation magnesium alloy and its prepn process |
| CN102383012A (en) * | 2011-11-01 | 2012-03-21 | 西安理工大学 | Low-rare-earth high-strength heat-resisting magnesium alloy and preparation method thereof |
| JP2012136727A (en) * | 2010-12-24 | 2012-07-19 | Sumitomo Electric Ind Ltd | Magnesium alloy for damping and damping material |
| CN103882272A (en) * | 2014-04-18 | 2014-06-25 | 重庆大学 | Mg-Sn-Ti wrought magnesium alloy and preparation method thereof |
| CN103981415A (en) * | 2014-05-09 | 2014-08-13 | 曹帅 | High-damping Mg-based damping alloy and preparation method thereof |
| CN104087804A (en) * | 2014-07-28 | 2014-10-08 | 农彩丽 | Creep resistant magnesium alloy and preparation method thereof |
| CN104099506A (en) * | 2014-08-06 | 2014-10-15 | 杨攀 | Multicomponent heat-resistant magnesium alloy and production method thereof |
| CN104233030A (en) * | 2014-09-30 | 2014-12-24 | 东北大学 | Magnesium, zinc, aluminum, chromium, bismuth and calcium alloy allowing age hardening and preparation method thereof |
| CN106011567A (en) * | 2016-06-23 | 2016-10-12 | 南京龙超金属制造科技有限公司 | Magnesium alloy casting and preparation method thereof |
| RU2615938C1 (en) * | 2016-06-16 | 2017-04-11 | Юлия Алексеевна Щепочкина | Alloy on base of magnesium |
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| CN109338187A (en) * | 2018-11-19 | 2019-02-15 | 河北工业大学 | A kind of low cost can high-speed extrusion the tough wrought magnesium alloy of height and preparation method thereof |
| US10344365B2 (en) | 2012-06-26 | 2019-07-09 | Biotronik Ag | Magnesium-zinc-calcium alloy and method for producing implants containing the same |
| CN110423928A (en) * | 2018-02-09 | 2019-11-08 | 河南科技大学 | A kind of high-strength anti-flaming magnesium alloy |
| CN110453124A (en) * | 2018-05-08 | 2019-11-15 | 有研工程技术研究院有限公司 | Stanniferous magnesium alloy and its preparation and processing method |
| US10895000B2 (en) | 2012-06-26 | 2021-01-19 | Biotronik Ag | Magnesium alloy, method for the production thereof and use thereof |
| US10995398B2 (en) | 2012-06-26 | 2021-05-04 | Biotronik Ag | Corrosion resistant stent |
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| JPS63128398A (en) * | 1986-11-19 | 1988-05-31 | 富士通株式会社 | Mg based composite vibration-proof material |
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| JPH0257657A (en) * | 1988-08-23 | 1990-02-27 | Furukawa Alum Co Ltd | High damping material of mg alloy and its manufacture |
| WO1994006945A1 (en) * | 1992-09-11 | 1994-03-31 | Nippon Kinzoku Co., Ltd. | Refined magnesium material and process for producing the same |
| US5613999A (en) * | 1992-09-11 | 1997-03-25 | Nippon Kinzoku Co., Ltd. | Method for producing magnesium |
| US6444056B1 (en) | 1992-09-11 | 2002-09-03 | Nippon Kinzoku Co., Ltd. | Refined magnesium material and method for producing the same |
| WO1996019594A1 (en) * | 1994-12-22 | 1996-06-27 | Energy Conversion Devices, Inc. | Magnesium mechanical alloys for thermal hydrogen storage |
| US5916381A (en) * | 1994-12-22 | 1999-06-29 | Energy Conversion Devices, Inc. | Magnesium mechanical alloys for thermal hydrogen storage |
| US6755922B2 (en) * | 1999-12-03 | 2004-06-29 | Hitachi, Ltd. | High strength Mg based alloy and Mg based casting alloy and article made of the alloy |
| US7041179B2 (en) * | 2001-11-05 | 2006-05-09 | Dead Sea Magnesium Ltd. | High strength creep resistant magnesium alloys |
| CN100463989C (en) * | 2006-07-26 | 2009-02-25 | 哈尔滨工业大学 | Cariaceous high-damping deformation magnesium alloy and its prepn process |
| JP2012136727A (en) * | 2010-12-24 | 2012-07-19 | Sumitomo Electric Ind Ltd | Magnesium alloy for damping and damping material |
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| CN103981415A (en) * | 2014-05-09 | 2014-08-13 | 曹帅 | High-damping Mg-based damping alloy and preparation method thereof |
| CN104087804A (en) * | 2014-07-28 | 2014-10-08 | 农彩丽 | Creep resistant magnesium alloy and preparation method thereof |
| CN104099506A (en) * | 2014-08-06 | 2014-10-15 | 杨攀 | Multicomponent heat-resistant magnesium alloy and production method thereof |
| CN104233030A (en) * | 2014-09-30 | 2014-12-24 | 东北大学 | Magnesium, zinc, aluminum, chromium, bismuth and calcium alloy allowing age hardening and preparation method thereof |
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| CN106011567A (en) * | 2016-06-23 | 2016-10-12 | 南京龙超金属制造科技有限公司 | Magnesium alloy casting and preparation method thereof |
| CN107739941A (en) * | 2017-10-27 | 2018-02-27 | 桂林市漓江机电制造有限公司 | A kind of carbide modified magnesium alloy materials and preparation method thereof |
| CN108179337A (en) * | 2017-12-25 | 2018-06-19 | 广东省材料与加工研究所 | The diecast magnesium alloy and its pressure casting method of a kind of high temperature creep-resisting |
| CN110423928A (en) * | 2018-02-09 | 2019-11-08 | 河南科技大学 | A kind of high-strength anti-flaming magnesium alloy |
| CN110453124A (en) * | 2018-05-08 | 2019-11-15 | 有研工程技术研究院有限公司 | Stanniferous magnesium alloy and its preparation and processing method |
| CN110453124B (en) * | 2018-05-08 | 2021-02-05 | 有研工程技术研究院有限公司 | Tin-magnesium alloy and preparation and processing method thereof |
| CN109161753A (en) * | 2018-10-20 | 2019-01-08 | 广州宇智科技有限公司 | A kind of antiflaming magnesium alloy of coupled surface liquid metal and matrix high heat-transfer performance |
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| US12123086B2 (en) | 2021-02-25 | 2024-10-22 | Biotronik Ag | Method for producing magnesium alloy |
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