JPH0235913A - Dry desulfurization or denitration device - Google Patents

Dry desulfurization or denitration device

Info

Publication number
JPH0235913A
JPH0235913A JP63185654A JP18565488A JPH0235913A JP H0235913 A JPH0235913 A JP H0235913A JP 63185654 A JP63185654 A JP 63185654A JP 18565488 A JP18565488 A JP 18565488A JP H0235913 A JPH0235913 A JP H0235913A
Authority
JP
Japan
Prior art keywords
particle diameter
louver
outlet side
particles
much
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63185654A
Other languages
Japanese (ja)
Other versions
JPH0620509B2 (en
Inventor
Teruo Watabe
渡部 輝雄
Kazuhiko Yamamoto
一彦 山本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Heavy Industries Ltd
Original Assignee
Sumitomo Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Heavy Industries Ltd filed Critical Sumitomo Heavy Industries Ltd
Priority to JP63185654A priority Critical patent/JPH0620509B2/en
Publication of JPH0235913A publication Critical patent/JPH0235913A/en
Publication of JPH0620509B2 publication Critical patent/JPH0620509B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

PURPOSE:To prevent the generation channeling by setting elements constituting outlet side louvers inclined to a horizontal surface by 30 deg. or more and making their width 0.2-2.0 times as much as the maximum particle diameter or 0.4-4.0 times as much as the average particle diameter. CONSTITUTION:A particle layer 3 is moved between inlet side louvers 4 and outlet side louvers 2a and desulfurization or denitration is carried out by passing the gas to be treated therethrough. The outlet side louvers 2a are constituted of inclined elements 7 inclined to a horizontal surface by 30 deg. or more, and respective elements are connected in the grating or mesh form. The maximum opening width of the inclined element 7 is made 0.1-1.0 times as much as maximum particle diameter or 0.4-4.0 times as much as average particle diameter, and the element width is 0.2-2.0 or 0.4-4.0 times as much as maximum particle diameter. Thus, channeling can be prevented.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は乾式の脱硫装置、又は脱硝装置、特にその出口
側ルーバーの構造に関するものである。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a dry desulfurization device or a denitrification device, particularly to the structure of the outlet side louver.

(従来技術) 活性炭等の粒子状吸着剤、又は粒子状触媒をゆっくり移
動させながら処理ガスと接触させ、脱硫又は脱硝を行な
わせる装置に於て、吸着剤又は触媒粒子を充満して一定
方向に移動させる反応層のガス入口側とガス出口側は、
ガスは通過できるが、粒子はこぼれ出ない構造としなけ
ればならない。
(Prior art) In an apparatus that performs desulfurization or denitration by slowly moving a particulate adsorbent such as activated carbon or a particulate catalyst and bringing it into contact with a process gas, the adsorbent or catalyst particles are filled and moved in a fixed direction. The gas inlet side and gas outlet side of the reaction layer to be moved are
The structure must allow gas to pass through but prevent particles from spilling out.

この為該仕切板の構造をルーバー構造としているが、ガ
ス出口側のルーバーはその開口部を大きくすると、粒子
がガス流により吹き飛ばされ、逆に開口部を小さくする
と目詰りを起して、ガスの偏流を起したり圧損の上昇を
まねくことになる。
For this reason, the structure of the partition plate is a louver structure, but if the opening of the louver on the gas outlet side is made large, particles will be blown away by the gas flow, and conversely, if the opening is made small, it will become clogged and the gas This may cause a drift in the flow or an increase in pressure loss.

第9図は従来型のルーバー構造を示し、1は入口側ルー
バー、2は出口側ルーバー、3はルーバー1と2間に詰
められた粒子層の移動方向を示す。
FIG. 9 shows a conventional louver structure, where 1 is an inlet louver, 2 is an outlet louver, and 3 is the moving direction of the particle layer packed between the louvers 1 and 2.

4はガス流れ方向で、ガスは入口側ルーバーから粒子層
を貫通し、出口側ルーバー2から出てゆく。
Reference numeral 4 indicates the gas flow direction, in which the gas passes through the particle layer from the inlet side louver and exits from the outlet side louver 2.

5はこのようなガス流によって出口側ルーバーから吹き
とばされた粒子で、流速の低い部分にはダストロが堆積
することを示している。
5 indicates particles blown away from the outlet side louver by such a gas flow, indicating that dust is deposited in areas where the flow velocity is low.

第9図(b)は第9図(a)におけるルーバー開口部の
部分拡大図を示し、この開口部におけるガス流速は図の
曲線aにて示すような、ガス流速分布を呈する。すなわ
ちルーバーの出口開口を構成する上側素材に近い程流速
が大きくなっている。このため第9図(c)の如く、流
速の大きい部分(図の上側)で粒子5がとび出し、流速
の小さい部分(図の下側)ではダスト6が堆積する。
FIG. 9(b) shows a partially enlarged view of the louver opening in FIG. 9(a), and the gas flow velocity at this opening exhibits a gas flow velocity distribution as shown by curve a in the figure. That is, the flow velocity increases closer to the upper material forming the outlet opening of the louver. Therefore, as shown in FIG. 9(c), particles 5 are ejected in areas where the flow rate is high (upper side of the figure), and dust 6 is deposited in areas where the flow rate is low (lower side of the figure).

第10図(a)は従来型の別の例を示し、この場合には
入口側ルーバー1の開口巾は大きいが、出口側ルーバー
2は断面が二等辺三角形をなした素材C・・・で構成さ
れており、その二等辺三角形の底辺間の巾は極めて小さ
くできている。即ち粒子径よりもj\さい開口巾となっ
ている。このような構造の場合は長期間の運転をするこ
とにより、摩耗又は破損により、小粒径になった粒子が
開口部を詰らせる(第10図(b))という問題を生ず
る。
FIG. 10(a) shows another example of the conventional type. In this case, the opening width of the entrance side louver 1 is large, but the exit side louver 2 is made of material C... whose cross section is an isosceles triangle. The width between the bases of the isosceles triangle is extremely small. In other words, the opening width is smaller than the particle diameter. In the case of such a structure, after long-term operation, a problem arises in that particles of small diameter due to wear or breakage clog the opening (FIG. 10(b)).

第10図(c)、(d)、(e)、(f)、(g)、(
h)、(i)、 (j)は夫々出口側ルーバー2の種々
の例であるが、これらは何れも粒子径よりも小さい開口
巾になるよう構成されており、夫々前記した如き問題を
有している。
Figure 10 (c), (d), (e), (f), (g), (
h), (i), and (j) are various examples of the outlet side louver 2, but all of these are configured to have an opening width smaller than the particle diameter, and each has the problems described above. are doing.

(発明が解決しようとする課題) 従来技術の問題点に鑑み、ガス出口側で粒子の目詰りを
起してガスの偏流を起したり、圧損の上昇を来すことの
ない出口側ルーバーを提供することを課題とする。
(Problems to be Solved by the Invention) In view of the problems of the prior art, an outlet side louver that does not cause clogging of particles on the gas outlet side, which causes uneven flow of gas, and does not cause an increase in pressure loss, has been developed. The challenge is to provide.

(発明による課題の解決手段) 入口側ルーバーと出口側ルーバーとの間に粒子層を移動
させ、該移動粒子層を横切って被処理ガスを流動させる
乾式の脱硫脱硝装置において、前記出口側ルーバーを格
子状、網目状又は多孔板状に形成し、その開口部が粒子
層の移動方向に対して粒子を内側に押し込む方向に傾斜
するよう、ルーバーを構成する素材を水平面に対し30
°以上の傾斜角で傾斜させ、該素材の傾斜面の巾W2を
最大粒子径の0.2〜2.0倍、又は平均粒子径の0.
4〜4.0倍とし、前記素材の最大開口巾W工を最大粒
子径の0.1〜1,0倍、又は平均粒子径の0.2〜2
.0倍とした。
(Means for Solving the Problems by the Invention) In a dry desulfurization and denitrification apparatus in which a particle layer is moved between an inlet side louver and an outlet side louver, and a gas to be treated is made to flow across the moving particle layer, the outlet side louver is The material constituting the louver is formed in the shape of a lattice, a mesh, or a perforated plate, and the material constituting the louver is set at 30 degrees with respect to the horizontal plane so that the openings thereof are inclined in a direction that pushes the particles inward with respect to the direction of movement of the particle layer.
The width W2 of the inclined surface of the material is set to 0.2 to 2.0 times the maximum particle diameter, or 0.2 to 2.0 times the average particle diameter.
4 to 4.0 times, and the maximum opening width W of the material is 0.1 to 1.0 times the maximum particle diameter, or 0.2 to 2 times the average particle diameter.
.. It was set to 0 times.

(実施例) さて、実験結果によると、粒子は移動中に摩耗や機械的
な破損が生じ、第11図に示す如き粒度分布となる。即
ち初充填粒子又は運転中の補給粒子の粒度分布は分布曲
線aの如くであるが、長期間運転後には5分布曲線すの
如く全体的に小径側に移行する。本願発明は、このよう
に粒子が小径化しても目詰りを生じない出口側ルーバー
を提供するものである。
(Example) Now, according to the experimental results, the particles undergo wear and mechanical damage during movement, resulting in a particle size distribution as shown in FIG. 11. That is, the particle size distribution of the initially filled particles or the replenishing particles during operation is as shown in distribution curve a, but after a long period of operation, the overall diameter shifts to the smaller diameter side as shown in the 5-distribution curve. The present invention provides an outlet-side louver that does not become clogged even when the particle diameter is reduced in this manner.

第1図は本発明に係る出口側ルーバー2aを用いた脱硫
脱硝装置の断面図である。第1図(b)に示す如く、出
口側ルーバー28は粒子の移動方向に向って傾斜した傾
斜素材7・・・を平行に配列して構成されている。各傾
斜素材7・・・は互に連結され、格子状又は網目状をな
している。
FIG. 1 is a sectional view of a desulfurization and denitration apparatus using an outlet side louver 2a according to the present invention. As shown in FIG. 1(b), the outlet side louver 28 is constructed by arranging inclined materials 7 in parallel in the direction of particle movement. Each inclined material 7... is connected to each other to form a lattice or mesh shape.

傾斜素材7間の最大開口巾W工(第3図)は最大粒子径
dの0.1〜1.0倍、又は平均粒子径の0.2〜2.
0倍である。又、各傾斜素材7の素材中W2(第3図)
は最大粒子径dの0.2〜2.0倍又は平均粒子径の0
.4〜4.0倍、各傾斜素材の傾斜角αは水平面に対し
て30’以上となっている。なお、こ)で粒子径とはJ
IS標準ふるいによって測定した重量表示の値をいうも
のとする。
The maximum opening width W between the inclined materials 7 (Fig. 3) is 0.1 to 1.0 times the maximum particle diameter d, or 0.2 to 2.0 times the average particle diameter.
It is 0 times. Also, W2 in the material of each inclined material 7 (Fig. 3)
is 0.2 to 2.0 times the maximum particle diameter d or 0 times the average particle diameter
.. 4 to 4.0 times, and the inclination angle α of each inclined material is 30' or more with respect to the horizontal plane. In addition, the particle size in this) is J
It refers to the weight value measured using an IS standard sieve.

第2図はこのような出口側ルーバー2をエキスバンドメ
タルにて構成した例を示す。第3図は同じく出口側ルー
バーの第2例を示し、出口側ルーバーは格子で構成され
ている。さらに第4図〜第8図ぼ出口側ルーバー2を多
孔板状に成形した例を示し、その開口部は第4図(b)
、第5図(b)。
FIG. 2 shows an example in which such an exit side louver 2 is made of expanded metal. FIG. 3 similarly shows a second example of the exit side louver, and the exit side louver is composed of a lattice. Further, FIGS. 4 to 8 show an example in which the outlet side louver 2 is formed into a perforated plate shape, and the opening portion is shown in FIG. 4(b).
, FIG. 5(b).

第6図(b)、第7図(b)、第8図(b)に示す如く
構成されている。
The configuration is as shown in FIG. 6(b), FIG. 7(b), and FIG. 8(b).

即ち、第4図はパンチプレート、第5図は網目状にプレ
ス成形したものでエキスバンドしないもの、第6図は多
孔板状に成形し、傾斜角αを大きくとったもの、第7図
は多孔板状に成形し、開口部配列を千鳥状以外にしたも
の、そして第8図は多孔板状に成形し、傾斜面を粒子層
の外偏に向けた例を示す。
That is, Fig. 4 shows a punch plate, Fig. 5 shows one press-formed into a mesh shape without expanding, Fig. 6 shows one formed into a perforated plate shape with a large inclination angle α, and Fig. 7 shows one formed into a perforated plate shape with a large inclination angle α. FIG. 8 shows an example in which the particles are formed into a perforated plate shape and the openings are arranged in a pattern other than staggered, and FIG.

(効果) 出口側ルーバーを形成する傾斜素材の巾W2が、最大粒
子径の0.2〜2.0倍、又は平均粒子径の0.4〜4
.0倍程度と小さいことにより、第9図(a)、(b)
、(c)に示す如きガスの極部的偏流現象を起すことが
ない。すな力ち、かSる構造である為、その開口率を大
きくすることができ、出口ルーバ一部におけるガス流速
は均一で、かつ遅く保たれる為、開口巾W、より小さい
粒子であっても吹き飛ばされることがなく、粒子が開口
部を塞ぐことがない。
(Effect) The width W2 of the inclined material forming the outlet side louver is 0.2 to 2.0 times the maximum particle diameter, or 0.4 to 4 times the average particle diameter.
.. Due to the small size of about 0 times, Figure 9 (a) and (b)
, the phenomenon of localized gas flow as shown in (c) does not occur. In other words, since the structure has a structure in which both forces and forces are applied, the aperture ratio can be increased, and the gas flow rate in a part of the exit louver is kept uniform and slow, so the aperture width W can be reduced by smaller particles. No particles will block the openings.

更に粒子を粒子層側に押込む方向に出口側ルーバーを構
成する素材が傾斜している為、移動粒子に対しこれを素
材間の開口に向って押し込もうとする粒体からの力が作
用することもない。
Furthermore, since the material that makes up the exit side louver is inclined in the direction of pushing the particles into the particle layer side, a force from the particles that tries to push the moving particles toward the opening between the materials acts on the moving particles. There's nothing to do.

又かきる形状を有している為、開口部の最大寸法が最大
粒子径よりかなり大きくても、粒子が出口側ルーバーの
開口部を通り抜けてこぼれ落ちることがない。勿論出口
側ルーバーに接触している粒子は傾斜素材の巾W2が小
さい為、停滞することなく全てが移動しており、第9図
(c)の符号6に示すようなダストの堆積を起さないの
で、圧損の上昇を招くことがない。
Furthermore, because of this shape, even if the maximum dimension of the opening is considerably larger than the maximum particle diameter, particles will not fall through the opening of the outlet side louver. Of course, since the width W2 of the inclined material is small, all of the particles in contact with the outlet side louver are moving without stagnation, causing dust accumulation as shown at 6 in Fig. 9(c). There is no increase in pressure loss.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(a)は本発明に係るルーバーを使用した脱硫装
置の断面図。 第1図(b)は第1図(a)のA矢視部拡大図。 第2図(a)はエキスバンドメタル状に構成したルーバ
ー 第2図(b)は第2図(a)の一部拡大図。 第2図(c)は第2図(b)のB−B断面図。 第3図は格子状ルーバー 第4図(a)2第5図(a)、第6図〔a)、第7図(
a)、第8図(a)は多孔板状に成形した出口側ルーバ
ーの実施例を示す。 第4図(b)、第5図(b)、第6図(b)、第7図(
b)、第8図(b)は、第4図(a)、第5図(a)、
第6図(a)、第7図(a)、第8図(a)のc−c断
面図。 第9図(a)は従来型ルーバー 第9図(b)は第9図(a)のD部拡大図で流速分布状
態を示す。 第9図(c)は第9図(b)と同様部分を示し、この部
分で粒子の状態を示す。 第10図(a)は従来型脱硫装置の断面図。 第10図(b)は第10図(a)のE部拡大図。 第10図(c)〜(j)は従来型の出口側ルーバーの諸
例を示す。 第11図は脱硫装置における粒子径の変化状態を示すグ
ラフ。 図において; 1 人口側ルーバー  2 出口側ルーバー2a  (
本発明の)出口側ルーバー 3 粒子の移動方向 4 ガス流れ方向5 粒子   
    6 ダスト 7 傾斜素材 以上 出願人 住友重機械工業株式会社 復代理人 弁理士 大 橋   実 弟1図 第1図 B−。 (b) 第2 図 (c) 第3図 C 第4図 第7図 第8i 9i4図 (b) 第7図 (b) 第8図 (b) 第5図 (o) 第5図 (b) 第6図 第6図 (b) 第9図 第9 図 (b) 第9図 (C) 第1○図 第10図 (b) H実間1転後のH廣今今 第11図 第10図(C)( 第10図 第10図 (j)
FIG. 1(a) is a sectional view of a desulfurization device using a louver according to the present invention. FIG. 1(b) is an enlarged view of the section viewed from arrow A in FIG. 1(a). FIG. 2(a) shows a louver constructed in an expanded metal shape. FIG. 2(b) is a partially enlarged view of FIG. 2(a). FIG. 2(c) is a sectional view taken along line BB in FIG. 2(b). Figure 3 shows the lattice-shaped louvers Figure 4 (a), Figure 5 (a), Figure 6 [a], Figure 7 (
a) and FIG. 8(a) show an example of an outlet side louver formed into a perforated plate shape. Figure 4(b), Figure 5(b), Figure 6(b), Figure 7(
b), FIG. 8(b), FIG. 4(a), FIG. 5(a),
FIG. 6(a), FIG. 7(a), and FIG. 8(a) are cc sectional views. FIG. 9(a) is a conventional louver. FIG. 9(b) is an enlarged view of section D in FIG. 9(a), showing the state of flow velocity distribution. FIG. 9(c) shows the same part as FIG. 9(b), and shows the state of the particles in this part. FIG. 10(a) is a sectional view of a conventional desulfurization device. FIG. 10(b) is an enlarged view of section E in FIG. 10(a). FIGS. 10(c) to 10(j) show various examples of conventional exit side louvers. FIG. 11 is a graph showing changes in particle size in the desulfurization equipment. In the figure: 1 Population side louver 2 Exit side louver 2a (
(of the present invention) Exit side louver 3 Movement direction of particles 4 Gas flow direction 5 Particles
6 Dust 7 Graded materials and above Applicant: Sumitomo Heavy Industries, Ltd. Sub-agent Patent attorney Ohashi Younger brother 1 Figure 1 B-. (b) Figure 2 (c) Figure 3C Figure 4Figure 7Figure 8i 9i4(b) Figure 7(b) Figure 8(b) Figure 5(o) Figure 5(b) Fig. 6 Fig. 6 (b) Fig. 9 Fig. 9 (b) Fig. 9 (C) Fig. 1○ Fig. 10 (b) Figure (C) ( Figure 10 Figure 10 (j)

Claims (1)

【特許請求の範囲】[Claims] 入口側ルーバーと出口側ルーバーとの間に粒子層を移動
させ、該移動粒子層を横切って被処理ガスを流動させる
乾式の脱硫脱硝装置において、前記出口側ルーバーを格
子状、網目状又は多孔板状に形成し、その開口部が粒子
層の移動方向に対して粒子を粒子層側に押し込む方向に
傾斜するよう、ルーバーを構成する素材を水平面に対し
30°以上の傾斜角で傾斜させ、該素材の傾斜面の巾W
_2を最大粒子径の0.2〜2.0倍、又は平均粒子径
の0.4〜4.0倍とし、前記素材の最大開口巾W_1
を最大粒子径の0.1〜1.0倍、又は平均粒子径の0
.2〜2.0倍としたことを特徴とする乾式の脱硫又は
脱硝装置。
In a dry type desulfurization and denitrification equipment in which a particle layer is moved between an inlet side louver and an outlet side louver, and the gas to be treated is made to flow across the moving particle layer, the outlet side louver is formed into a grid, a mesh, or a perforated plate. The material constituting the louver is inclined at an inclination angle of 30° or more with respect to the horizontal plane so that the opening is inclined in the direction of pushing the particles into the particle layer with respect to the moving direction of the particle layer. Width of the sloped surface of the material W
_2 is 0.2 to 2.0 times the maximum particle diameter, or 0.4 to 4.0 times the average particle diameter, and the maximum opening width W_1 of the material
0.1 to 1.0 times the maximum particle size, or 0 times the average particle size
.. A dry desulfurization or denitrification device characterized in that the ratio is 2 to 2.0 times.
JP63185654A 1988-07-27 1988-07-27 Dry desulfurization or denitration equipment Expired - Lifetime JPH0620509B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63185654A JPH0620509B2 (en) 1988-07-27 1988-07-27 Dry desulfurization or denitration equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63185654A JPH0620509B2 (en) 1988-07-27 1988-07-27 Dry desulfurization or denitration equipment

Publications (2)

Publication Number Publication Date
JPH0235913A true JPH0235913A (en) 1990-02-06
JPH0620509B2 JPH0620509B2 (en) 1994-03-23

Family

ID=16174542

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63185654A Expired - Lifetime JPH0620509B2 (en) 1988-07-27 1988-07-27 Dry desulfurization or denitration equipment

Country Status (1)

Country Link
JP (1) JPH0620509B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7622089B1 (en) * 2006-07-19 2009-11-24 Uop Llc Conically shaped screenless internals for radial flow reactors
JP2010132754A (en) * 2008-12-03 2010-06-17 Mitsubishi Heavy Ind Ltd Gas adsorption purification apparatus and biomass gasification system
AU2008201461B2 (en) * 2006-07-19 2011-02-10 Uop Llc Louver front faced inlet ducts
US8747768B2 (en) 2006-07-19 2014-06-10 Uop Llc Screenless internals for radial flow reactors

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5535056U (en) * 1978-08-29 1980-03-06
JPS5687426A (en) * 1979-12-18 1981-07-16 Mitsubishi Heavy Ind Ltd Solid-gas contact apparatus
JPS5843231A (en) * 1981-09-10 1983-03-12 Babcock Hitachi Kk Moving bed type reactor
JPS6325138A (en) * 1986-07-18 1988-02-02 Fuji Heavy Ind Ltd Four-wheel drive device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5535056U (en) * 1978-08-29 1980-03-06
JPS5687426A (en) * 1979-12-18 1981-07-16 Mitsubishi Heavy Ind Ltd Solid-gas contact apparatus
JPS5843231A (en) * 1981-09-10 1983-03-12 Babcock Hitachi Kk Moving bed type reactor
JPS6325138A (en) * 1986-07-18 1988-02-02 Fuji Heavy Ind Ltd Four-wheel drive device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7622089B1 (en) * 2006-07-19 2009-11-24 Uop Llc Conically shaped screenless internals for radial flow reactors
US7842259B2 (en) 2006-07-19 2010-11-30 Uop Llc Conically shaped screenless internals for radial flow reactors
AU2008201461B2 (en) * 2006-07-19 2011-02-10 Uop Llc Louver front faced inlet ducts
AU2008201461B8 (en) * 2006-07-19 2011-06-02 Uop Llc Louver front faced inlet ducts
US8747768B2 (en) 2006-07-19 2014-06-10 Uop Llc Screenless internals for radial flow reactors
JP2010132754A (en) * 2008-12-03 2010-06-17 Mitsubishi Heavy Ind Ltd Gas adsorption purification apparatus and biomass gasification system

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