JPH0228796B2 - - Google Patents

Info

Publication number
JPH0228796B2
JPH0228796B2 JP60041281A JP4128185A JPH0228796B2 JP H0228796 B2 JPH0228796 B2 JP H0228796B2 JP 60041281 A JP60041281 A JP 60041281A JP 4128185 A JP4128185 A JP 4128185A JP H0228796 B2 JPH0228796 B2 JP H0228796B2
Authority
JP
Japan
Prior art keywords
heat
metal hydride
heat medium
heat exchanger
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP60041281A
Other languages
Japanese (ja)
Other versions
JPS61202091A (en
Inventor
Masayuki Kurooka
Kenji Nasako
Naojiro Pponda
Takashi Sakai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Electric Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd filed Critical Sanyo Electric Co Ltd
Priority to JP60041281A priority Critical patent/JPS61202091A/en
Publication of JPS61202091A publication Critical patent/JPS61202091A/en
Publication of JPH0228796B2 publication Critical patent/JPH0228796B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/003Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Description

【発明の詳細な説明】 (イ) 産業上の利用分野 本発明は蓄熱装置、ヒートポンプ、ケミカルコ
ンプレツサー、水素貯蔵装置等に好適な金属水素
化物利用装置に係り、特にその熱交換器部分の改
良に関する。
[Detailed description of the invention] (a) Industrial application field The present invention relates to a metal hydride utilization device suitable for a heat storage device, a heat pump, a chemical compressor, a hydrogen storage device, etc. Regarding improvements.

(ロ) 従来の技術 金属水素化物は大量の水素ガスを吸収、放出す
る能力を有し、その水素ガスの吸収、放出の際に
は、かなりの熱量を放出、吸収することが知られ
ている。これらの性質を利用して現在、金属水素
化物の蓄熱器や水素貯蔵器等への適用が盛んに試
みられ、各種構造の金属水素化物利用装置が提案
されている。尚、金属水素化物は脱水素化して金
属となるが、この場合も含めて本明細書中では金
属水素化物と称する。
(b) Prior art Metal hydrides have the ability to absorb and release large amounts of hydrogen gas, and are known to release and absorb a considerable amount of heat when absorbing and releasing hydrogen gas. . Utilizing these properties, there are currently many attempts to apply metal hydrides to heat storage devices, hydrogen storage devices, etc., and devices using metal hydrides with various structures have been proposed. Note that a metal hydride becomes a metal by dehydrogenation, and this case is also referred to as a metal hydride in this specification.

その金属水素化物利用装置の一つとして、第4
図に示すように金属水素化物収納容器1と熱交換
器2とをそれぞれ別個に設けてヒートパイプ3に
て結合した構造のものが知られている。即ち、こ
れは、パイプ4,水素フイルタ5を介して水素を
出し入れする水素導管6を設け、内部には金属水
素化物7を収納した金属水素化物収納容器1と、
熱の供給、回収を行なう熱媒8を連続して流す熱
媒出入口導管9,10を備えた熱交換器2とを伝
熱フイン11を有するヒートパイプ3にて結合し
て成るものである。
As one of the metal hydride utilization devices, the 4th
As shown in the figure, a structure is known in which a metal hydride storage container 1 and a heat exchanger 2 are provided separately and connected by a heat pipe 3. That is, this is provided with a hydrogen conduit 6 for supplying and discharging hydrogen via a pipe 4 and a hydrogen filter 5, and a metal hydride storage container 1 containing a metal hydride 7 inside;
A heat pipe 3 having heat transfer fins 11 connects a heat exchanger 2 provided with heat medium inlet and outlet conduits 9 and 10 through which a heat medium 8 for supplying and recovering heat continuously flows.

このような構造の金属水素化物容器において、
ヒートパイプの熱輸送能力およびその形状、大き
さ等の点から、ヒートパイプを複数本使用する必
要が生じた場合、熱交換器の構造としては、第5
図、第6図に示すものが考えられる。即ち、両図
ともヒートパイプ3に垂直な断面図を示したもの
で、第5図は個々のヒートパイプ3をそれぞれ熱
媒管12で囲み、その熱媒管12を連続し、熱媒
出入口導管9,10を取り付けたものである。一
方、第6図は1つの熱媒管12で全てのヒートパ
イプ3を囲んだ構造である。
In a metal hydride container with such a structure,
When it becomes necessary to use multiple heat pipes due to the heat transport capacity of the heat pipes, their shape, size, etc., the structure of the heat exchanger is the fifth heat pipe.
The one shown in Fig. 6 is conceivable. That is, both figures show a cross-sectional view perpendicular to the heat pipe 3, and in FIG. 9 and 10 are attached. On the other hand, FIG. 6 shows a structure in which all the heat pipes 3 are surrounded by one heat medium pipe 12.

しかしながら、上述第5図の構造の場合は、ヒ
ートパイプ3に伝熱フインを取り付け伝熱面積を
増大させたり、熱媒管12を細くして熱媒流速を
大きくし、ヒートパイプ3と熱媒との間の境膜伝
熱抵抗を減少させたりすることにより、容易にヒ
ートパイプ3と熱媒との熱伝導を向上させること
ができる反面、構造が複雑となり、ヒートパイプ
3の本数が増すと共に製作が困難となる。
However, in the case of the structure shown in FIG. Although it is possible to easily improve the heat conduction between the heat pipe 3 and the heat medium by reducing the film heat transfer resistance between the heat pipes 3 and 3, the structure becomes complicated and as the number of heat pipes 3 increases, It becomes difficult to manufacture.

一方、第6図の構造は比較的容易に製作できる
が、熱交換器内に滞溜する熱媒量が前者に比べて
多くなる結果、重量が大きくなり、また、熱媒出
口温度の応答が遅く、熱回収システムには不向き
である。更に、金属水素化物収納容器内における
金属水素化物と伝熱媒体との容積比の関係からあ
まりヒートパイプを密に配置することができない
ため、ヒートパイプ近傍での熱媒流速は遅く、位
置によりその大きさに差が生じ、全体的にみて良
好な熱伝導が得られなくなる。
On the other hand, although the structure shown in Fig. 6 can be manufactured relatively easily, the amount of heat medium accumulated in the heat exchanger is larger than that of the former, resulting in increased weight and the response of the heat medium outlet temperature. It is slow and unsuitable for heat recovery systems. Furthermore, because the volume ratio between the metal hydride and the heat transfer medium in the metal hydride storage container makes it impossible to arrange the heat pipes too closely together, the flow rate of the heat medium near the heat pipes is slow, and depending on the location, There will be a difference in size, making it impossible to obtain good heat conduction overall.

(ハ) 発明が解決しようとする問題点 本発明は、上記の点に鑑み、構造が簡単にして
熱伝導効率の良く熱媒出口温度の応答が速い熱交
換器を備えた金属水素化物収納容器を提供するこ
とを目的とする。
(c) Problems to be Solved by the Invention In view of the above points, the present invention provides a metal hydride storage container equipped with a heat exchanger that has a simple structure, good heat conduction efficiency, and quick response of the heat medium outlet temperature. The purpose is to provide

(ニ) 問題点を解決するための手段 このため本発明は、金属水素化物収納容器と熱
交換器を複数本のヒートパイプで結合して成る金
属水素化物利用装置において、熱交換器を1つの
熱媒管で全てのヒートパイプを囲む構造となし、
その熱媒管内の空いたスペースには円筒状の中空
容器を配置する一方、熱媒出入口間にヒートパイ
プと垂直に熱媒の流れを蛇行させる伝熱フイン兼
用の邪魔板を設けるようにしたことを特徴として
いる。
(d) Means for solving the problems Therefore, the present invention provides a metal hydride utilization device in which a metal hydride storage container and a heat exchanger are connected by a plurality of heat pipes, in which the heat exchanger is combined into one heat exchanger. A structure in which all heat pipes are surrounded by heat medium pipes,
A cylindrical hollow container is placed in the empty space inside the heat medium pipe, and a baffle plate that also serves as a heat transfer fin is provided between the heat medium inlet and outlet to meander the flow of the heat medium perpendicular to the heat pipe. It is characterized by

(ホ) 作用 熱交換器内に円筒状の中空容器を挿入すると共
に、ヒートパイプと垂直に伝熱フイン兼用の邪魔
板を設けることにより、熱媒流路断面が小さくな
り熱媒流速が増大し、熱媒側の境膜伝熱抵抗が小
さくなる。また、内部に滞溜する熱媒量が少なく
なると共に、伝熱フイン兼用邪魔板を介してヒー
トパイプからの熱は効率良く熱媒に伝達され、金
属水素化物の反応による熱媒の温度上昇、降下に
対する熱媒取り出し温度の応答遅れも小さくな
る。更に、固形物として軽量の物質(内部が中空
のものを含む)を選ぶことにより熱交換器内の熱
媒量が少なくなり、全体の重量を軽減することが
できる。
(E) Effect By inserting a cylindrical hollow container into the heat exchanger and providing a baffle plate that also serves as a heat transfer fin perpendicular to the heat pipe, the cross section of the heat medium flow path becomes smaller and the heat medium flow rate increases. , the film heat transfer resistance on the heating medium side becomes smaller. In addition, the amount of heat medium accumulated inside is reduced, and the heat from the heat pipe is efficiently transferred to the heat medium through the baffle plate that also serves as a heat transfer fin, and the temperature of the heat medium increases due to the reaction of metal hydrides. The response delay of the heat medium extraction temperature to the drop is also reduced. Furthermore, by selecting a lightweight material (including one with a hollow interior) as the solid material, the amount of heat medium in the heat exchanger can be reduced, and the overall weight can be reduced.

(ヘ) 実施例 以下、本発明の実施例を図面を参照して説明す
る。
(f) Examples Examples of the present invention will be described below with reference to the drawings.

第1図は本発明の一実施例に係る金属水素化物
利用装置の側断面図、第2図はその金属水素化物
容器側A−A断面図、第3図はその熱交換器側B
−B断面図である。各図を通じて第4図と同一符
号は同一または相当部分を示し、第4図と異なる
点は金属水素化物収納容器1内面を断熱材13で
覆つて内部を仕切板16で仕切つた上、金属水素
化物7と共に複数本の伝熱フイン11付きヒート
パイプ3を金属水素化物収納容器1内部に気密に
収納している点、および、それら複数本のヒート
パイプ3を気密に収納する熱交換器2の内部の空
いたスペース部分にはスペーサーとしての中空容
器14を設けると共に、熱媒出入口導管9,10
の間をヒートパイプ3に垂直に熱媒8の流れを蛇
行させる伝熱フイン兼用の邪魔板15を設けてい
る点である。尚、第1図におおける熱交換器2の
断面図は第3図のC−C線に沿つた断面図を示し
ている。
FIG. 1 is a side sectional view of a metal hydride utilization apparatus according to an embodiment of the present invention, FIG. 2 is a sectional view taken along line A-A on the metal hydride container side, and FIG. 3 is a side sectional view on the heat exchanger side B.
-B sectional view. Throughout each figure, the same reference numerals as in FIG. 4 indicate the same or equivalent parts, and the difference from FIG. A plurality of heat pipes 3 with heat transfer fins 11 are airtightly housed inside the metal hydride storage container 1 together with the metal hydride 7, and a heat exchanger 2 that airtightly houses the plurality of heat pipes 3. A hollow container 14 as a spacer is provided in the empty space inside, and heat medium inlet/outlet conduits 9, 10 are provided.
The point is that a baffle plate 15 that also serves as a heat transfer fin is provided to cause the flow of the heat medium 8 to meander perpendicularly to the heat pipe 3 between the heat pipes 3 and 3. Note that the cross-sectional view of the heat exchanger 2 in FIG. 1 shows a cross-sectional view taken along the line CC in FIG. 3.

即ち、金属水素化物収納容器1側は第2図のA
−A断面図に示す如く、仕切板16を設けて本実
施例では7本のヒートパイプ3を錯列配置(正三
角形を最小単位とするような配列方法)してい
る。これにより、各ヒートパイプ3の周囲に配置
される金属水素化物7の量は平均化し、伝熱フイ
ン11を介してヒートパイプ3と金属水素化物7
との間の熱伝達が効率良く行なわれる。
That is, the metal hydride storage container 1 side is A in FIG.
As shown in the -A sectional view, a partition plate 16 is provided, and in this embodiment, seven heat pipes 3 are arranged in a parallel array (an arrangement method in which an equilateral triangle is the minimum unit). As a result, the amount of metal hydride 7 arranged around each heat pipe 3 is averaged, and the metal hydride 7 is transferred between the heat pipe 3 and the metal hydride 7 through the heat transfer fins 11.
Heat transfer between the two is carried out efficiently.

一方、熱交換器2側は、第3図のB−B断面図
に示すように、熱交換器2内部にヒートパイプ3
が7本配置されるが、その間の空いたスペースに
両端を閉ざした円筒状の中空容器14を6本挿入
配置している。また、邪魔板15は上下方向に交
互に開口部を設けて熱媒入口導管9,熱媒出口導
管10間に6枚配設している。
On the other hand, the heat exchanger 2 side has a heat pipe 3 inside the heat exchanger 2, as shown in the BB sectional view in FIG.
Seven containers are arranged, and six cylindrical hollow containers 14 with both ends closed are inserted into the empty space between them. Further, six baffle plates 15 are arranged between the heat medium inlet conduit 9 and the heat medium outlet conduit 10 with openings provided alternately in the vertical direction.

熱交換器2をこのように構成することにより、
熱媒入口導管9から熱媒出口導管10に向つて矢
印方向に流れる熱媒8の流路断面積は大幅に減少
し、ヒートパイプ3および邪魔板15表面での熱
媒8の線流速が増し、境膜伝熱抵抗が小さくなる
と共に、熱媒滞溜量が減少する。従つて、ヒート
パイプ3内部の熱はヒートパイプ3の表面と、伝
熱フイン兼用の邪魔板15の表面から熱媒8に効
率良く伝達され、応答の良い熱交換器が得られ
る。
By configuring the heat exchanger 2 in this way,
The cross-sectional area of the heat medium 8 flowing in the direction of the arrow from the heat medium inlet conduit 9 to the heat medium outlet conduit 10 is significantly reduced, and the linear flow velocity of the heat medium 8 on the surfaces of the heat pipe 3 and baffle plate 15 is increased. , the film heat transfer resistance becomes smaller and the amount of heat medium accumulated decreases. Therefore, the heat inside the heat pipe 3 is efficiently transferred to the heat medium 8 from the surface of the heat pipe 3 and the surface of the baffle plate 15 which also serves as a heat transfer fin, and a heat exchanger with good response is obtained.

尚、中空容器14は円筒状のものに限らず、適
宜その形状を変化させることにより、熱交換器2
内部の熱媒流動状態を自由に選択でき、装置に最
適な熱伝導が容易に得られるようになる。
Note that the hollow container 14 is not limited to a cylindrical shape, and the shape of the hollow container 14 can be changed as appropriate to form the heat exchanger 2.
The internal flow state of the heat medium can be freely selected, making it easy to obtain optimal heat conduction for the device.

(ト) 発明の効果 以上述べたように、本発明によれば、熱交換器
内部の空いたスペースを中空容器で埋めると共
に、熱媒出入口導管内にヒートパイプと垂直に熱
媒の流れを蛇行させる複数枚の伝熱フイン兼用の
邪魔板を配設したので、熱媒の線流速が増し、境
膜伝熱抵抗が小さくなると共に、熱媒滞溜量が減
少し、構成もそれ程複雑にならず、製造が容易に
して熱交換効率の良い熱交換器を備えた金属水素
化物利用装置が得られる。
(g) Effects of the Invention As described above, according to the present invention, the empty space inside the heat exchanger is filled with a hollow container, and the flow of the heat medium is meandered perpendicular to the heat pipe in the heat medium inlet/outlet conduit. By installing multiple baffle plates that also serve as heat transfer fins, the linear flow velocity of the heating medium is increased, the film heat transfer resistance is reduced, and the amount of heating medium accumulated is reduced, making the configuration less complicated. First, it is possible to obtain a metal hydride utilization device that is easy to manufacture and equipped with a heat exchanger with high heat exchange efficiency.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例を示す金属水素化物
利用装置の側断面図、第2図はそのA−A断面
図、第3図はそのB−B断面概略図、第4図は従
来の金属水素化物利用装置の側断面図、第5図お
よび第6図は複数本のヒートパイプを有する熱交
換器の説明図である。 1……金属水素化物収納容器、2……熱交換
器、3……ヒートパイプ、6……水素導管、7…
…金属水素化物、8……熱媒、9,10……熱媒
出入口導管、12……熱媒管、13……断熱材、
14……中空容器、15……邪魔板。
Fig. 1 is a side sectional view of a metal hydride utilization device showing an embodiment of the present invention, Fig. 2 is a sectional view taken along line A-A, Fig. 3 is a schematic cross-sectional view taken along line B-B, and Fig. 4 is a conventional sectional view. 5 and 6 are explanatory diagrams of a heat exchanger having a plurality of heat pipes. 1... Metal hydride storage container, 2... Heat exchanger, 3... Heat pipe, 6... Hydrogen conduit, 7...
... Metal hydride, 8 ... Heat medium, 9, 10 ... Heat medium inlet/outlet conduit, 12 ... Heat medium pipe, 13 ... Heat insulating material,
14...Hollow container, 15...Baffle plate.

Claims (1)

【特許請求の範囲】[Claims] 1 金属水素化物収納容器と熱交換器とを複数本
のヒートパイプで結合して成る金属水素化物利用
装置において、前記熱交換器を前記複数本のヒー
トパイプ全体を前記熱交換器本体の外壁部分に相
当する一つのドラム状熱媒管で囲み軸方向対角線
位置に熱媒出入口を設けて内部に熱媒を流す構造
となし、その熱媒管の空いたスペースにはスペー
サーを配置する一方、前記熱媒出入口間に前記ヒ
ートパイプと垂直に熱媒の流れを蛇行させる伝熱
フイン兼用の邪魔板を配設して成ることを特徴と
する金属水素化物利用装置。
1. In a metal hydride utilization device comprising a metal hydride storage container and a heat exchanger connected by a plurality of heat pipes, the heat exchanger is connected to an outer wall portion of the heat exchanger main body by connecting the entire plurality of heat pipes to an outer wall portion of the heat exchanger body. The structure is such that the heating medium is surrounded by one drum-shaped heat medium tube corresponding to the above, and heat medium inlets and outlets are provided at diagonal positions in the axial direction to allow the heat medium to flow inside, and spacers are placed in the empty space of the heat medium tube. 1. A metal hydride utilization device, comprising: a baffle plate that also serves as a heat transfer fin that meanderes the flow of the heat medium perpendicular to the heat pipe between the heat medium inlet and outlet.
JP60041281A 1985-03-04 1985-03-04 Utilizing device for metallic hydrogen compound Granted JPS61202091A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60041281A JPS61202091A (en) 1985-03-04 1985-03-04 Utilizing device for metallic hydrogen compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60041281A JPS61202091A (en) 1985-03-04 1985-03-04 Utilizing device for metallic hydrogen compound

Publications (2)

Publication Number Publication Date
JPS61202091A JPS61202091A (en) 1986-09-06
JPH0228796B2 true JPH0228796B2 (en) 1990-06-26

Family

ID=12604061

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60041281A Granted JPS61202091A (en) 1985-03-04 1985-03-04 Utilizing device for metallic hydrogen compound

Country Status (1)

Country Link
JP (1) JPS61202091A (en)

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Publication number Priority date Publication date Assignee Title
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