JPH02232054A - Deodorant for beauty parlor - Google Patents

Deodorant for beauty parlor

Info

Publication number
JPH02232054A
JPH02232054A JP1052671A JP5267189A JPH02232054A JP H02232054 A JPH02232054 A JP H02232054A JP 1052671 A JP1052671 A JP 1052671A JP 5267189 A JP5267189 A JP 5267189A JP H02232054 A JPH02232054 A JP H02232054A
Authority
JP
Japan
Prior art keywords
carbonized
reduced pressure
alcohol
tea
deodorant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1052671A
Other languages
Japanese (ja)
Inventor
Tomoyuki Kondo
近藤 友之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAKIHIYOO KEMIKA KK
Original Assignee
TAKIHIYOO KEMIKA KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAKIHIYOO KEMIKA KK filed Critical TAKIHIYOO KEMIKA KK
Priority to JP1052671A priority Critical patent/JPH02232054A/en
Publication of JPH02232054A publication Critical patent/JPH02232054A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To deodorize a nasty smell and further to prevent a sweet smell such as perfume, etc., from being canceled by carbonizing tea under reduced pressure, dissolving a specified carbonized component by alcohole, diluting this component with the large quantity of water and charging this liquid to a pump type spray. CONSTITUTION:The tea is carbonized under the reduced pressure and in the case of 20mmHg, the carbonized component, for which the range of a boiling point is 180-200 deg.C, is dissolved by the alcohole, diluted with the large quantity of the water and charged to the pump type spray. Otherwise, the alcohole solvent of the carbonized component is charged to a high pressure gas spray container together with the large quantity of liquefied gas. Otherwise, the tea is circulated and extracted together with the solvent such as the alcohole, etc., and a solid-state object, which is obtained by drying and setting the filtered liquid under the reduced pressure, is carbonized under the reduced pressure. In the case of 20mmHg, the carbonized component, for which the range of the boiling point is 180-200 deg.C, is dissolved by the alcohole, diluted with the large quantity of the water and charged to the pump type spray. Otherwise, the alcohole solvent of the carbonized component is charged to the high pressure gas spray container together with the large quantity of the liquefied gas.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、美容院用消臭剤に関し,更に詳しくは、パー
パネント用薬液の放散ガス(主に、アンモニア系、アミ
ン系ガス)による悪臭を消臭するも美容院で不可避的に
使用される香水等の香りは滅殺しない新規な美容院用消
臭剤に関する。尚、最近では理容院に於いてもパーマネ
ントが行なわれている場合もあるので、以下では美容院
の概念にこのような場合も含むものとする。
Detailed Description of the Invention (Industrial Field of Application) The present invention relates to a deodorant for beauty salons, and more specifically, to a deodorant for beauty salons, and more specifically, to a deodorizer for use in beauty salons, and more specifically to a deodorant for use in beauty salons, and more specifically, it is a deodorizer for use in beauty salons, and more specifically, it is a deodorizer for use in beauty salons. To provide a novel deodorant for beauty salons that deodorizes but does not eliminate the scent of perfumes and the like inevitably used in beauty salons. Incidentally, recently, there are cases in which hairdressing is performed at barber salons, so in the following, such cases will be included in the concept of beauty salon.

(従来の技術) 美容院に於いて,頭髪をパーマネント処理する場合、チ
オグリコール酸塩系の所ill液を刷毛等で頭髪に塗布
し(約180cc)、その後シュウ素酸塩系の所謂2液
を塗布し(約180cc)、10分位放置しこれを洗い
流す、と云う工程がとられるのが一般的である.この場
合、特に1液を塗布した時,アンモニア系乃至アミン系
の悪臭が放散する.その為周囲に芳香剤等を散布して、
この悪臭による不快感を低減する措置が講じられたりす
る.(発明が解決しようとする課IQ) 然し乍ら、上記のような芳香剤等の散布は、悪臭成分を
芳香成分によって紛らすだけであるから,上記不快感を
完全に拭いさることが出来ず、いつまでも悪臭が体につ
きまとうことになり、これが顧客及び美容師にとって大
きな悩みとなっていた。
(Prior art) When hair is permanently treated at a beauty salon, a thioglycolate-based ill solution is applied to the hair with a brush (approximately 180 cc), and then an oxalate-based so-called two-solution solution is applied to the hair. The common process is to apply (approximately 180cc), leave it on for about 10 minutes, and then wash it off. In this case, especially when one liquid is applied, an ammonia-based or amine-based odor is emitted. Therefore, spray aromatics etc. around the area,
Measures are taken to reduce the discomfort caused by this foul odor. (IQ problem to be solved by the invention) However, since the above-mentioned spraying of air fresheners, etc. only distracts the malodorous components with the aromatic components, the above-mentioned discomfort cannot be completely wiped away, and the malodor remains forever. This has become a big problem for customers and hairdressers.

本発明者等はこの点に着目し、各種消臭剤について鋭意
検討した結果、特公昭61−8964号公報で開示され
た消臭剤を溶液に溶かし、上記悪臭に噴霧したところた
ちどころにこの悪臭が消え、しかも美容院で不可避的に
使用される香水等の芳香は全く滅殺されないことを知見
し、ここに本発明を完成するに至った。
The present inventors focused on this point, and as a result of intensive study on various deodorants, the deodorant disclosed in Japanese Patent Publication No. 61-8964 was dissolved in a solution, and when sprayed on the above-mentioned foul odor, the odor was immediately detected. It was discovered that the bad odor disappears, and that the aromas of perfumes and the like that are unavoidably used in beauty salons are not destroyed at all, leading to the completion of the present invention.

(課題を解決する為の手段) 本発明の美容院用消臭剤は,茶を減圧下乾留し、2 0
 m H Hの場合に沸点範囲が180〜200℃にあ
る乾留成分をアルコールで溶解し、これを多量の水で希
釈してポンプ式噴霧器に充填し、或いは上記乾留成分の
アルコール溶液を多量の液化ガスと共に高圧ガススプレ
ー容器に充填したものである. 亦、茶をアルコール等の溶媒と共に還流抽出し、その濾
液を減圧乾固して得た固形物を減圧下乾留し、2 0 
+m H gの場合に沸点範囲が180〜2oO℃にあ
る乾留成分をアルコールで溶解し、これを多量の水で希
釈してポンプ式噴霧器に充填し、或いは上記乾留成分の
アルコール溶液を多量の液化ガスと共に高圧ガススプレ
ー容器に充填したものも含む。
(Means for Solving the Problems) The deodorant for beauty salons of the present invention is produced by carbonizing tea under reduced pressure.
In the case of m H H, a carbonized component with a boiling point range of 180 to 200°C is dissolved in alcohol, diluted with a large amount of water, and filled into a pump sprayer, or the alcoholic solution of the carbonized component is liquefied in a large amount. It is filled with gas into a high-pressure gas spray container. In addition, tea is extracted under reflux with a solvent such as alcohol, and the filtrate is dried under reduced pressure.
In the case of +mHg, a carbonized component with a boiling point range of 180~2oO℃ is dissolved in alcohol, diluted with a large amount of water, and filled into a pump sprayer, or the alcoholic solution of the carbonized component is liquefied in a large amount. This also includes those filled with gas in a high-pressure gas spray container.

そして、上記乾留成分は、いずれも、1000倍水溶液
の紫外線吸収スペクトルが276±2mμで極大吸収を
示し,また該乾留成分の20重量%プロピレングリコー
ル溶液の 屈折率が: n oO=1 . 4 1 8±0.02
旋光度が: a ’60= + O − 0 0 7°
±0.002゜比 重が;d絽=1.025±0.02
であるものである。また、該乾留成分の出発物質として
の茶は、主として茶の葉部から得られるものである。
The ultraviolet absorption spectrum of a 1000 times aqueous solution of each of the above carbonized components shows maximum absorption at 276±2 mμ, and the refractive index of a 20% by weight propylene glycol solution of the carbonized component is: n oO = 1. 4 1 8±0.02
The optical rotation is: a '60= + O - 0 0 7°
±0.002° specific gravity; d = 1.025±0.02
It is something that is. Furthermore, tea as a starting material for the carbonized component is obtained mainly from tea leaves.

乾留成分を溶解するアルコールとしては,エチルアルコ
ール、プロピレングリコール等が望ましく,特にこれら
は水で希釈してポンプ式噴霧器に充填する場合に水の腐
敗防止に有効である。このポンプ式噴霧器は、操作部の
手動操作により容器内に空気を圧スし、押し出された溶
液をノズルより霧状に噴出させるもので,従来周知のも
のが採用される. 上記乾留成分のアルコール溶液と共に高圧スプレー容器
に充填される液化ガスとして、常温で気体のジグ口口フ
ルオ口メタン、ジクロ口ジフルオ口メタン等が採用され
る.この高圧スプレー容器は、上記乾留成分のアルコー
ル溶液と共に加圧液化された上記液化ガスが充填され,
弁の手動操作により液化ガスを急激にガス化して吐出さ
せ、この吐出ガスをキャリアーガスとして乾留成分を含
むアルコール溶液をミスト化して同時に吐出させんとす
るものであり,これも従来周知のものが採用される. 上記アルコール溶液中には、乾留成分が15〜25重量
%含まれ,水成いは液化ガスによって希釈された状態で
は、全体量中上記乾留成分は0.001〜0.05重量
%含まれるようにすることが望ましい。また、これら希
釈溶液中には植物性の香料を若干量含ませることも可能
である.尚,上記乾留時の沸点範囲は、減圧度が変れば
これに応じて変化することは云うまでもない。
Ethyl alcohol, propylene glycol, etc. are preferable as the alcohol for dissolving the carbonized components, and these are particularly effective in preventing water from spoiling when diluted with water and filled into a pump sprayer. This pump-type sprayer presses air into the container by manual operation of the operating part, and sprays the extruded solution in the form of a mist from the nozzle, and a well-known type is used. As the liquefied gas that is filled into the high-pressure spray container together with the alcohol solution of the above-mentioned carbonized components, jig-fluid methane, dichloro-difluoro-methane, etc., which are gaseous at room temperature, are used. This high-pressure spray container is filled with the liquefied gas that has been liquefied under pressure together with the alcohol solution of the carbonized component.
This method uses manual operation of a valve to rapidly gasify and discharge liquefied gas, and uses this discharged gas as a carrier gas to form a mist of an alcoholic solution containing carbonized components, which is also discharged at the same time. Adopted. The alcohol solution contains 15 to 25% by weight of the carbonized component, and when diluted with water or liquefied gas, the carbonized component is contained in the total amount of 0.001 to 0.05% by weight. It is desirable to do so. It is also possible to include a small amount of vegetable fragrance in these diluted solutions. It goes without saying that the boiling point range during carbonization will change depending on the degree of reduced pressure.

(作用) 上記の如くポンプ式噴霧器或いは高圧ガススプレー容器
に充填された消臭剤を、パーマネント処理をしている至
近位置に或いはその室内に散布すると,上記薬液から発
生する悪臭は速やかに消える。上記乾留成分の化学組成
はまだ判明していないが、フラバノール、フラボノール
,その他の多数の有機化合物より構成されると推定され
、上記消臭作用は、これら有機化合物の悪臭成分に対す
る包摂作用、付加作用及び中和作用の複合によるものと
考えられる。
(Function) When the deodorizing agent filled in the pump-type sprayer or high-pressure gas spray container as described above is sprayed in the vicinity of the permanent treatment or in the room thereof, the bad odor generated from the chemical solution disappears quickly. Although the chemical composition of the carbonization component is not yet known, it is presumed to be composed of flavanols, flavonols, and many other organic compounds. This is thought to be due to a combination of the following:

しかも,特筆すべきは、上記消臭剤の散布の際、人体に
塗布或いは室内に散布された植物性香水の香りを滅殺し
ないことである.これは、茶などのつばき科植物は、ア
ンモニア,アミン系物質,硫化水素或いはメルカブタン
系物質等から発生する代表的な悪臭を忌避し、レモン、
ジャスミン或いは木犀等の如き香水の原料となる代表的
な樹木の芳香は忌避しないと云う性質によるものと推察
される。
Moreover, it is worth noting that when the deodorant is sprayed, it does not destroy the scent of the vegetable perfume applied to the human body or sprayed indoors. This is because Camellia family plants such as tea avoid typical bad odors generated from ammonia, amine-based substances, hydrogen sulfide, or mercabutan-based substances, and lemon,
This is thought to be due to the fact that the aromas of typical trees used as raw materials for perfumes, such as jasmine and xerox, are not repellent.

従って,植物性の香水を不可避的に用いる美容院に於い
ては、上記特性はその適正が極めて高いと云うことが出
来る。
Therefore, it can be said that the above characteristics are extremely appropriate for beauty salons that unavoidably use vegetable perfumes.

(実施例) 次に、実施例について述べる. (1)乾燥茶葉25kgを乾留釜中、20mmHg減圧
下で乾留し、180〜200℃で留出する淡黄色芳香性
成分をプロピレングリコール中に受けた.この場合の留
出分は約50gであった.(2)茶乾燥葉末250gと
イソブロパノール600ccとをソックスレー抽出器に
入れ、20時間還流を行なった.抽出液より原料残渣を
濾去し、濾液を減圧乾固することにより濃緑色の固形物
約80gを得た.この還流固形物を20mHg減圧下で
乾留し、180〜200℃の乾留分をプロピレングリコ
ール中に留出させた.この留出分は1gであった. (3)上記(1)、(2)で得た乾留成分を1000倍
水溶液とし,紫外線吸収スペクトルを測定したところ、
いずれも276±2mμに極大吸収を示した。また、2
0重量%プロピレングリコール溶液とし、その屈折率、
旋光度、比重を測定したところ,いずれも 屈折率;’n20= 1 . 4 1 8±0.02D 旋光度; a20=+0.007’ +0.002”D 比重;d20=1.025±0.02 であった。
(Example) Next, an example will be described. (1) 25 kg of dried tea leaves were carbonized in a carbonization pot under a reduced pressure of 20 mmHg, and the pale yellow aromatic component distilled out at 180 to 200°C was collected in propylene glycol. The distillate in this case was approximately 50g. (2) 250 g of dried tea leaf powder and 600 cc of isopropanol were placed in a Soxhlet extractor and refluxed for 20 hours. The raw material residue was filtered off from the extract, and the filtrate was dried under reduced pressure to obtain about 80 g of a dark green solid. This refluxed solid was carbonized under a reduced pressure of 20 mHg, and the dry distillate at 180 to 200°C was distilled into propylene glycol. This distillate amount was 1 g. (3) The carbonized components obtained in (1) and (2) above were made into a 1000 times aqueous solution, and the ultraviolet absorption spectrum was measured.
All showed maximum absorption at 276±2 mμ. Also, 2
0% by weight propylene glycol solution, its refractive index,
When the optical rotation and specific gravity were measured, the refractive index was 'n20=1. 4 1 8 ± 0.02D Optical rotation; a20 = +0.007' + 0.002''D Specific gravity; d20 = 1.025 ± 0.02.

(4)消臭試験 上記(1)(2)の乾留成分を20重量%プロピレング
リコール溶液とし,これらを各40重量部秤量して、7
60重量部の水で希釈してポンプ式噴霧器に充填し、ま
た500容量部のジクロロフルオロメタンと共,に高圧
ガススプレー容器に充填し、都合4種の消臭剤サンプル
を作成した.次に、パーマネント用1液から採取した悪
臭ガスを充満させ、同時にレモン系香水を噴震した5o
ooiの密閉容器を4個準備した。この容器内に上記4
種の消臭剤サンプルを1秒間噴霧注入し、一定時間毎に
容器内のガスを取り出し、中和滴定法によりガス濃度を
測定して悪臭除去率を算出した.同時にレモン臭による
芳香性を比較した.その結果を第1表に示す. 々上記(1)及び(2)によって得た乾留成分を意味し
、またa及びbは,夫々水で希釈してポンプ式噴霧器に
充填した場合及び液化ガスと共に高圧ガススプレー容器
に充填した場合を意味する。比較例は、特開昭53=6
6434号公報に準じ、茶菓粉末のインプロバノール乾
留による抽出液のプロピレングリコール20%溶液をa
と同様に水で希釈してポンプ式噴霧器に充填した消臭剤
を用いた場合を示す.また、各欄の上欄は悪臭の除去率
(%)を、下欄はレモン臭減衰度を夫々示す。レモン臭
減衰度の0は正常であることを、Δは稍々低下している
ことを意味する。
(4) Deodorization test The carbonized components of (1) and (2) above were made into a 20% by weight propylene glycol solution, and 40 parts by weight each of these were weighed.
Four types of deodorant samples were prepared by diluting the deodorant with 60 parts by weight of water and filling it into a pump sprayer, and then filling it with 500 parts by volume of dichlorofluoromethane into a high-pressure gas spray container. Next, it was filled with foul-smelling gas collected from the first liquid for permanent use, and at the same time, 5 odor was sprayed with lemon-based perfume.
Four airtight containers of ooi were prepared. In this container, put the above 4
A seed deodorizer sample was sprayed for 1 second, the gas inside the container was taken out at regular intervals, and the gas concentration was measured by neutralization titration to calculate the odor removal rate. At the same time, we compared the aromatic properties of lemon odor. The results are shown in Table 1. a and b respectively refer to the carbonized components obtained by (1) and (2) above, and a and b refer to the case where they are diluted with water and filled into a pump-type sprayer, and the case where they are filled into a high-pressure gas spray container with liquefied gas, respectively. means. A comparative example is JP-A-53=6
According to Publication No. 6434, a 20% propylene glycol solution of the extract obtained by dry distilling improbanol from tea confectionery powder was
The case is shown in which a deodorant is diluted with water and filled into a pump-type sprayer in the same way as above. Further, the upper column of each column indicates the removal rate (%) of bad odor, and the lower column indicates the degree of lemon odor attenuation. A lemon odor attenuation degree of 0 means normal, and Δ means a slight decrease.

第1表の結果から、本発明の消臭剤を用いた場合,いず
れも顕著な消臭効果を示すことが理解される。また,レ
モン香水による芳香性が全く低下しないことも明らかで
ある。尚、レモン臭が初期で低く観測されたのは、パー
マネント用1液の発する悪臭が強く、レモン臭の判別が
し難いからであると考えられる。
From the results in Table 1, it is understood that all of the deodorants of the present invention exhibit remarkable deodorizing effects. It is also clear that the aromatic properties of the lemon perfume do not decrease at all. The reason why the lemon odor was observed to be low at the initial stage is considered to be because the permanent liquid 1 has a strong bad odor and it is difficult to distinguish the lemon odor.

(発明の効果) 叙上の如く、本発明の消臭剤はパーマネント用薬液の発
する悪臭の消臭に極めて効果的であり、顧客及び美容師
の大きななやみがこれで一掃されることになる。しかも
美容院で不可避的に用いられる各種香水の芳香性を滅殺
することかなく,これらを総合すると美容院用としての
適正は極めて大であると云える. 一以上一 出願人 株式会社 タキヒョーケミ力 代理人 弁理士(6235)松野英彦
(Effects of the Invention) As described above, the deodorant of the present invention is extremely effective in deodorizing the bad odor emitted by permanent care solutions, and this will eliminate a great deal of anxiety from customers and beauticians. Furthermore, it does not destroy the aromatic properties of the various perfumes that are inevitably used in beauty salons, and when taken together, it can be said that it is extremely suitable for use in beauty salons. One or more applicants: Takihyo Chemiriki Co., Ltd. Patent attorney (6235) Hidehiko Matsuno

Claims (1)

【特許請求の範囲】 1、茶を減圧下乾留し、20mmHgの場合に沸点範囲
が180〜200℃にある乾留成分をアルコールで溶解
し、これを多量の水で希釈してポンプ式噴霧器に充填し
て成る美容院用消臭剤。 2、茶を減圧下乾留し、20mmHgの場合に沸点範囲
が180〜200℃にある乾留成分をアルコールで溶解
し、これを多量の液化ガスと共に高圧ガススプレー容器
に充填して成る美容院用消臭剤。 3、茶をアルコール等の溶媒と共に還流抽出し、その濾
液を減圧乾固して得た固形物を減圧下乾留し、20mm
Hgの場合に沸点範囲が180〜200℃にある乾留成
分をアルコールで溶解し、これを多量の水で希釈してポ
ンプ式噴霧器に充填して成る美容院用消臭剤。 4、茶をアルコール等の溶媒と共に還流抽出し、その濾
液を減圧乾固して得た固形物を減圧下乾留し、20mm
Hgの場合に沸点範囲が180〜200℃にある乾留成
分をアルコールで溶解し、これを多量の液化ガスと共に
高圧ガススプレー容器に充填して成る美容院用消臭剤。 5、上記乾留成分の1000倍水溶液の紫外線吸収スペ
クトルが276±2mμで極大吸収を示し、また該乾留
成分の20重量%プロピレングリコール溶液の 屈折率が;n^2^0_D=1.418±0.02旋光
度が;a^2^0_D=+0.007°±0.002°
比重が;d^2^0_2_0=1.025±0.02で
ある請求項1、2、3又は4記載の美容院用消臭剤。
[Claims] 1. Tea is carbonized under reduced pressure, and the carbonized components whose boiling point ranges from 180 to 200°C at 20 mmHg are dissolved in alcohol, diluted with a large amount of water, and charged into a pump-type atomizer. A deodorant for beauty salons. 2. Tea is carbonized under reduced pressure, the carbonized component with a boiling point range of 180 to 200°C at 20 mmHg is dissolved in alcohol, and this is filled together with a large amount of liquefied gas into a high-pressure gas spray container. Odorant. 3. Extract the tea under reflux with a solvent such as alcohol, dry the filtrate under reduced pressure, and dry distill the obtained solid material under reduced pressure.
A deodorant for beauty salons, which is made by dissolving a carbonized component having a boiling point range of 180 to 200°C in the case of Hg in alcohol, diluting it with a large amount of water, and filling it into a pump-type sprayer. 4. Extract the tea under reflux with a solvent such as alcohol, dry the filtrate under reduced pressure, and dry distill the obtained solid material under reduced pressure.
A deodorant for beauty salons, which is made by dissolving a carbonized component having a boiling point range of 180 to 200°C in the case of Hg in alcohol, and filling this together with a large amount of liquefied gas into a high-pressure gas spray container. 5. The ultraviolet absorption spectrum of a 1000 times aqueous solution of the above carbonized component shows maximum absorption at 276±2 mμ, and the refractive index of a 20% by weight propylene glycol solution of the carbonized component is; n^2^0_D=1.418±0 .02 optical rotation; a^2^0_D=+0.007°±0.002°
The deodorant for beauty salons according to claim 1, 2, 3, or 4, which has a specific gravity of; d^2^0_2_0=1.025±0.02.
JP1052671A 1989-03-03 1989-03-03 Deodorant for beauty parlor Pending JPH02232054A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1052671A JPH02232054A (en) 1989-03-03 1989-03-03 Deodorant for beauty parlor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1052671A JPH02232054A (en) 1989-03-03 1989-03-03 Deodorant for beauty parlor

Publications (1)

Publication Number Publication Date
JPH02232054A true JPH02232054A (en) 1990-09-14

Family

ID=12921336

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1052671A Pending JPH02232054A (en) 1989-03-03 1989-03-03 Deodorant for beauty parlor

Country Status (1)

Country Link
JP (1) JPH02232054A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04128717U (en) * 1991-05-11 1992-11-25 共同ゴールドパツケイジング株式会社 Temporary storage bag for dentures

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04128717U (en) * 1991-05-11 1992-11-25 共同ゴールドパツケイジング株式会社 Temporary storage bag for dentures

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