JPH02229775A - Method for curing hydraulic system - Google Patents

Method for curing hydraulic system

Info

Publication number
JPH02229775A
JPH02229775A JP3102989A JP3102989A JPH02229775A JP H02229775 A JPH02229775 A JP H02229775A JP 3102989 A JP3102989 A JP 3102989A JP 3102989 A JP3102989 A JP 3102989A JP H02229775 A JPH02229775 A JP H02229775A
Authority
JP
Japan
Prior art keywords
curing
water
steam
cement
cured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3102989A
Other languages
Japanese (ja)
Inventor
Koji Mitsuo
満尾 浩治
Mitsuko Mitsuo
満尾 ミツ子
Hiroshi Mitsuo
満尾 浩志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP3102989A priority Critical patent/JPH02229775A/en
Publication of JPH02229775A publication Critical patent/JPH02229775A/en
Pending legal-status Critical Current

Links

Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE:To prevent cracking and efflorescence and to increase strength by impregnating water, steam, etc., into a water absorbing hydraulic system and wet-curing this hydraulic system. CONSTITUTION:A water absorbing hydraulic system is formed, e.g. by adding a proper amt. of a reactive agent. Steam, water or a reactive soln. is impregnated into the hydraulic system and this hydraulic system is wet-cured, cured with steam or cured in an autoclave.

Description

【発明の詳細な説明】 [産業上の利用分野] この発明は、透水性を少なくしたり、収縮率を小さくし
てクラツクを防止したり、強度を大にしたり、或いは更
に表面や型枠接面に光沢を出すことや、白華を抑制する
こと等が可能な水硬系の養生法に関する。
[Detailed Description of the Invention] [Industrial Application Field] This invention can reduce water permeability, reduce shrinkage rate to prevent cracks, increase strength, or further improve surface and formwork contact. This article relates to a hydraulic curing method that can make surfaces glossy and suppress efflorescence.

[従来の技術] セメント系も含めた水硬系の養生法として、気乾養生、
湿潤養生、水中養生、蒸気養生、及びオートクレーブ養
生が知られている。また収縮を小さくするため膨脹剤を
使用することが知られている。
[Conventional technology] As curing methods for hydraulic systems including cement systems, air dry curing,
Moist curing, underwater curing, steam curing, and autoclave curing are known. It is also known to use an expansion agent to reduce shrinkage.

[発明が解決しようとする課題] セメント系の気乾養生は、永和反応が少ししか進まぬう
ちに水が蒸発し多くの水隙ができて吸水性が大になるば
かりか、蒸発時セメント粒子間に凝集力が作用し収縮し
てクラツクの原囚となり、生成ざれた白華成分(セメン
トに水を加えたとき生成ざれる水酸化カルシウムを主体
とする水溶性塩類》がセメント粒子や骨材の周囲に乾燥
固着し、雨水等を吸って乾燥する時、水の気化に伴って
表面に移行し、炭酸ガスと反応して2次白華が発生する
[Problem to be solved by the invention] Air-drying of cement-based materials not only causes water to evaporate before the eternal reaction progresses, creating many water gaps and increasing water absorption, but also causes cement particles to evaporate during evaporation. The cohesive force acts between them, causing them to contract and form cracks, and the generated efflorescence components (water-soluble salts mainly composed of calcium hydroxide that are generated when water is added to cement) become cement particles and aggregates. When it dries and dries by absorbing rainwater, etc., it migrates to the surface as the water evaporates, reacts with carbon dioxide gas, and produces secondary efflorescence.

セメント系の水中養生は、乾燥した硬化物を水中養生す
るから、既に吸水性が大であるばかりか、白華成分が溶
出して外部に逃げ更に吸水性が大になり、白華成分が少
なくなった分だけ強度も低・くなる。また水中には白華
成分が溶出しているから、そのまま取出して乾燥させる
と表面に白華成分が付着し2次白華が発生する。
In the case of cement-based curing in water, the dry hardened material is cured in water, so not only does it already have high water absorption, but the efflorescence component elutes and escapes to the outside, further increasing its water absorption and reducing the amount of efflorescence component. The strength also decreases accordingly. Furthermore, since efflorescence components are eluted in water, if the water is taken out and dried, the efflorescence components will adhere to the surface and secondary efflorescence will occur.

セメント系の湿潤養生でもつとも効率的なものとして、
水を張った養生室内で養生する方法が知られているが、
養生室の容積とセメント系の表面積の関係、戸の開閉、
養生室の密閉度の関係等から、湿度を100%に維持す
ることは極めて困難で水の気化を避けられず、省エネで
最良の方法であるが完全養生とは言い難い。
As a very efficient moist curing method for cement,
There is a known method of curing in a curing chamber filled with water.
The relationship between the volume of the curing room and the surface area of the cement system, the opening and closing of the door,
Due to the degree of airtightness of the curing room, it is extremely difficult to maintain the humidity at 100% and evaporation of water is unavoidable.Although this is the best energy-saving method, it cannot be called complete curing.

レメント系の蒸気養生は、熱エネルギーを必要とするの
で、略500度時程度以内と、脱型強度を出すためにだ
け使用され、充分に水和反応か行われず、脱型後気乾養
生されているので水が気化し、永和反応も少なくなり、
さしたる強度が出す吸水性も大である。
Element-based steam curing requires thermal energy, so it is only used within approximately 500 degrees Celsius to increase demolding strength, and the hydration reaction does not take place sufficiently, resulting in air-dry curing after demolding. Because of this, the water evaporates and the Eiwa reaction is reduced.
It has great strength and water absorption.

商品名イトン等の通称AICのオートクレーブ養生も、
発泡後直ぐオー1・クレープ養生覆ると、圧力により泡
が漬れるので、発泡さけて後数時間経過してからオート
クレーブ養生するから、養生迄の間に水が蒸発して水隙
ができ、吸水性が大である。セメント系のオートクレー
ブ養生でも、水滴による表面汚損や型枠の腐蝕防止のた
め脱型後養生され、上記同様である。
Autoclave curing of AIC, commonly known as product name Iton, etc.
If you cover the O-1 crepe curing immediately after foaming, the foam will be soaked by the pressure, so avoid foaming and wait a few hours before curing in the autoclave.Water evaporates and creates water gaps during curing, causing water absorption. The sex is great. In autoclave curing of cement-based products, curing is performed after demolding to prevent surface staining due to water droplets and corrosion of the mold, and the same applies to the above.

即ら、水の気化が目に見えないため、水の気化により水
隙ができて吸水性となり、初明収縮を生じ、強度を充分
に出すことができず、更に白華成分を表面に移動させ炭
酸ガスとの反応により白華が生じること等について、誰
も気が付かず、水中養生は繁雑に過ぎるので実際的には
殆ど行われてJ3らず、湿潤養生や蒸気養生も早明IB
2型のためにしか利用ざれていないと言うのが現状であ
る。
In other words, since the evaporation of water is invisible, water evaporation creates water gaps and becomes water absorbent, causing initial shrinkage, making it impossible to obtain sufficient strength, and furthermore, the efflorescence component moves to the surface. No one notices that efflorescence occurs due to the reaction with carbon dioxide gas, underwater curing is too complicated and is rarely practiced in practice, and wet curing and steam curing are also used in Waseda IB.
The current situation is that it is only used for type 2.

尚、膨脹剤の使用はコスト高となるばかりか水隙もでき
使用法にも練度を要求される。
Incidentally, the use of an expanding agent not only increases the cost but also creates water gaps and requires skill in its usage.

この発明は上記問題点を解消するセメント系の養生法を
提供することを目的としている。
The object of the present invention is to provide a cement-based curing method that solves the above problems.

[課題を解決するための手段] 上記目的を達成するため、この発明の水硬系の養生法は
、適量の反応剤を加えるか加えることなくつくった吸水
性水硬系に、水蒸気、水、または反応液を含浸させ、引
続き該水硬系を湿潤養生、蒸気養生、またはオートクレ
ーブ養生する.ことを特徴とする。
[Means for Solving the Problems] In order to achieve the above object, the hydraulic system curing method of the present invention adds water vapor, water, Alternatively, the hydraulic system is impregnated with a reaction solution and subsequently subjected to wet curing, steam curing, or autoclave curing. It is characterized by

尚、適量の反応剤を加えるか加えることなくつくり密閉
養生、湿潤養生、または蒸気養生した水硬系に、脱型後
水蒸気、水、または反応液を含浸させ・、引続き該水硬
系を湿潤養生、蒸気養生、またはオートクレーブ養生し
てもよい。
In addition, after demolding, a hydraulic system made with or without addition of an appropriate amount of reactant and cured in a sealed manner, wet-cured, or steam-cured is impregnated with steam, water, or a reaction liquid, and the hydraulic system is subsequently moistened. Curing, steam curing, or autoclave curing may be used.

また、適吊の反応剤を加えてつくり密閉養生湿潤養生、
または蒸気養生した水硬系を、脱型後湿潤養生、蒸気養
生、またはオートクレーブ養生してもよい。
In addition, it is made by adding an appropriate amount of reactant and is sealed and moistened.
Alternatively, the steam-cured hydraulic system may be moist-cured, steam-cured, or autoclaved after demolding.

[作用] 適量の反応剤を加えるか加えることなくつくった吸水性
水硬系に、水蒸気、水、または反応液を含浸させ、引続
き湿潤養生、蒸気養生、またはオートクレーブ養生する
と、水硬系は充分に含水した状態で水の気化を押えて養
生されるから、セメント系、珪灰系、或いはセメント珪
灰系であれ、反応に必要な水が不足することなく水和反
応は順調に進み、しかも水中に漬けて養生するものでな
いから、セメント系またはセメント珪灰系の場合白華成
分が外部に溶出することなく硬化し、ち密で水を吸い難
く、収縮も小で強度の大なる硬化物を得る。尚、吸水性
水硬系は、硬化物であってもよく、厚型スレートのプレ
ス脱水後の生瓦や、バイブレーションプレス成型復のコ
ンクリートブロックのように、水セメント比が40%以
下の未硬化物(セメントに対する水の水和最は結合水2
5%、ゲル水15%、計40%と言われている。》であ
ってもよい。また適吊の反応剤を加えてつくった水硬系
ヤ、反応液を含浸させて養生したものは、水硬系がセメ
ント系またはセメント珪灰系の場合、反応剤や反応液が
白華成分と反応して硬化物は更にら密で難吸水性、低収
縮、高強度になり、白華成分が消費されるので白華抑制
に効果的である。
[Effect] When a water-absorbing hydraulic system prepared with or without the addition of an appropriate amount of reactant is impregnated with steam, water, or a reaction liquid, and subsequently subjected to moist curing, steam curing, or autoclave curing, the hydraulic system is sufficiently cured. The hydration reaction proceeds smoothly without running out of the water necessary for the reaction, regardless of whether it is a cement-based, silica-based, or cement-silica-based product, as it is cured in a water-containing state while suppressing the evaporation of water. Since it is not soaked and cured, in the case of cement or cement silica, the efflorescence component hardens without being eluted to the outside, resulting in a hardened product that is dense, difficult to absorb water, has little shrinkage, and has high strength. The water-absorbing hydraulic system may be a cured product, and may be an uncured product with a water-cement ratio of 40% or less, such as green roof tiles after press dewatering of thick slate or concrete blocks after vibration press molding. Hydration of water to cement (mostly bound water 2
5%, gel water 15%, total 40%. ]. In addition, if the hydraulic system is made by adding an appropriate amount of reactant or is cured by impregnating it with a reaction liquid, if the hydraulic system is cement-based or cement-silica-based, the reactant or reaction liquid may be an efflorescence component. As a result of the reaction, the cured product becomes denser, less water absorbent, less shrinkable, and has higher strength, and the efflorescence component is consumed, which is effective in suppressing efflorescence.

尚、七記吸水性水硬系が、密閉養生、湿濶養生、または
蒸気養生して脱型したものであるときは、気乾養生した
ものに比し永和反応が良好に進捗しており、作用効果が
更に顕著である。
In addition, when the water-absorbing hydraulic system described in Section 7 is demolded by closed curing, humid curing, or steam curing, the permanent reaction progresses better than that of air-dry curing. The action and effect are even more remarkable.

また、適量の反応剤を加えてつくり、密閉養生、湿潤養
生、または蒸気養生した水硬系を、脱型後湿潤養生、蒸
気養生、またはオートクレーブ養生するときは、脱型前
の養生で永和反応に加えて白華成分と反応剤が反応し、
キャピラリー水中にセメントグルと反応物が生成され、
保水作用も生じてよりち密″C難吸水性、低収縮かつ高
強度になり、脱型後の養生で上記作用は史に進み、しか
も水を含浸させずに養生するがら白華の抑制にはちっと
も効果的で必る。
In addition, when a hydraulic system made by adding an appropriate amount of a reactant and cured in a hermetically sealed state, moist-cured, or steam-cured is subjected to moist-curing, steam-curing, or autoclave curing after demolding, the curing before demolding will cause a permanent reaction. In addition, the efflorescence component and the reactant react,
Cement glue and reactants are generated in the capillary water,
It also has a water-retaining effect and becomes more compact, less water-absorbent, has low shrinkage, and has high strength.The above-mentioned effects progress during curing after demolding, and even though it is cured without water impregnation, it is effective in suppressing efflorescence. Most effective and necessary.

[実施例] 反応剤(練込用)、及び反応液(含浸用)を使用した場
合と、使用しない場合を比較しながら実施例を説明する
。尚、セメントはボルトランドセメンl〜を使用、部数
は重量部を示す。また湿潤養生は何れも、発泡スチロー
ル製養生函の底部に水を入れておき、その上にすのこを
載U、すのこの上に水に濡れないように試験体を載せ、
発泡スチロール製の蓋をし密閉して養生した。
[Example] Examples will be described while comparing cases where a reactant (for kneading) and a reaction liquid (for impregnation) are used and cases where they are not used. Incidentally, Boltland Cement 1~ was used as the cement, and the numbers indicate parts by weight. In addition, in both wet curing methods, water is poured into the bottom of a Styrofoam curing box, a slatted board is placed on top of it, and the test specimen is placed on top of the slatted board to prevent it from getting wet.
It was covered with a styrofoam lid and sealed tightly for curing.

実施例1 セメント:砂=1:2の生モルタルをプレス脱水して成
型し、2日間気乾養生した後反応液に2時間漬けて取出
し、引続き濡れた侭湿潤養生を8日間行い、取出して4
日間気乾養生したもの(試験体B)の曲げ強度は165
.2Kgで、反応液に代え水に漬けて湿潤養生したもの
(試験体C)の曲げ強度は、157Kg、気間養生した
もの(試験体A》の同日曲げ強度は、123.2KQで
あった。尚試験体A,B.Cの上にスボイドで水を滴下
して吸水状態を調査したところへが最も水を吸いやすく
、Cは成程度水を吸い難く、Bは最も水を吸い難かった
Example 1 Raw mortar with cement:sand = 1:2 was pressed and dehydrated, molded, air-dried for 2 days, immersed in a reaction solution for 2 hours, taken out, kept wet for 8 days, and taken out. 4
The bending strength of the specimen that was air-dried for one day (test specimen B) was 165
.. The flexural strength of the specimen weighing 2 kg and wet-cured by soaking in water instead of the reaction solution (test specimen C) was 157 kg, and the same-day flexural strength of the specimen cured in air (test specimen A) was 123.2 KQ. Water was dropped on test specimens A, B, and C to investigate the state of water absorption, and test specimens A, B, and C were the easiest to absorb water, while specimens B were the least likely to absorb water.

実施例2 セメン1〜:砂=1=3、水セメント比55%(セメン
ト量の1%の反応剤を添加した水を使用)の生モルタル
を、成型後直ちに24時間湿濶養生し、取出して脱型後
5分間水に漬け、濡れた侭引続き9日間湿潤養生し、そ
の後気乾養生したもの(試験体B)の14日圧縮強度は
286KCIであり、湿潤養生せずに気乾養生したもの
(試験体A)の14日圧縮強度は、142Kqであった
。尚、試験体Bにスポイドで水を滴下したところ、はっ
水性を示していると見間違う位水を吸い難く、試験体A
は容易に水を吸った。
Example 2 Fresh mortar with cement 1~:sand = 1 = 3, water-cement ratio 55% (using water to which 1% of the cement amount of reactant was added) was wet-cured for 24 hours immediately after molding, and then taken out. After demolding, the sample was soaked in water for 5 minutes, kept wet for 9 days, and then air-dried (test specimen B). The 14-day compressive strength was 286 KCI; The 14-day compressive strength of the specimen (test specimen A) was 142 Kq. In addition, when water was dropped onto test specimen B with a dropper, it was difficult to absorb water, so much so that it could be mistaken for water repellency.
absorbed water easily.

実施例3 水100部に、反応剤1部と起泡剤1部を加えて起泡液
をつくっておき、該起泡液34部とセメント100部を
混練してペーストをつくり、これに同一起泡液でつくっ
た泡13部を加え混練して含泡ペーストをつくり、成型
後直ちに湿潤養生し、24時間後に脱型した気泡コンク
リートを5分間水に漬け、濡れた侭引続き14日間湿潤
養生し、その後気乾養生した気泡コンクリートの28日
圧縮強度は54.9KCJ (比重0.68)と、略A
LCと同等の強度を示し、はっ水性を呈していると見間
違える位の難吸水性を示した。
Example 3 A foaming solution was prepared by adding 1 part of a reactant and 1 part of a foaming agent to 100 parts of water, and 34 parts of the foaming solution and 100 parts of cement were kneaded to make a paste. Add 13 parts of foam made with the foaming liquid and knead to make a foam-containing paste. Immediately after molding, the aerated concrete is soaked in water for 5 minutes, and after 24 hours it is soaked in water for 5 minutes. The 28-day compressive strength of the aerated concrete, which was then air-dried and cured, was 54.9 KCJ (specific gravity 0.68), approximately A
It exhibited strength equivalent to that of LC, and exhibited so little water absorption that it could be mistaken for water repellency.

実施例4 セメント100部、砂200部、反応剤1部水59部を
混練して上面解放のプラスチック容器に入れ、この俊直
ちに90度の湯を入れた養生函に入れ密閉して72時間
湿潤養生し、取出して脱型したものは、気乾養生したも
のに比し容器接面の光沢が大であり、かつ吸水性が小で
あった。
Example 4 100 parts of cement, 200 parts of sand, 1 part of reactant, and 59 parts of water were mixed together and placed in a plastic container with an open top.The mixture was then immediately placed in a curing box filled with hot water at 90 degrees Celsius, sealed, and kept moist for 72 hours. Those that were cured, taken out, and demolded had greater gloss on the surface in contact with the container and lower water absorption than those that had been air-dried and cured.

実施例5 セメント100部、紅殻10部、及び反応剤を1%加え
た水38部を混練してプラスチック板上で板状に成型し
、成型直後35度で16時間即ち560度時蒸気養生し
たものは、表面に光沢を生じた。脱型直後水に漬け、2
4時間後取出して乾燥したところ表面に溶出物が付着し
たが、容易に拭取ることとができ、しかも光沢が消えず
、少し色が濃くなった。ここで24時間の水漬けを10
回行い、その都度溶出物を拭き取ったところ、最後には
溶出物が出なくなり光沢も消えず色は更に濃くなり、吸
水性も少なくなってはつ水性すら示した。
Example 5 100 parts of cement, 10 parts of red husk, and 38 parts of water to which 1% of the reactant was added were kneaded and molded into a plate shape on a plastic plate. Immediately after molding, the mixture was steam-cured at 35 degrees for 16 hours, i.e., at 560 degrees. The object had a shiny surface. Immediately after demolding, soak in water, 2
When taken out after 4 hours and dried, eluate adhered to the surface, but it could be easily wiped off, the gloss did not disappear, and the color became slightly darker. Here, soak in water for 24 hours for 10 minutes.
When the eluate was wiped off each time, no eluate came out, the luster did not disappear, the color became even darker, and the water absorbency decreased, even showing water repellency.

実施例6 実施例5の成型直後の供試体を40度で72時間蒸気養
生したものは、表面に光沢を生じ、水に24時間漬けて
も光沢が消えず、白華の発生も見られなかった。
Example 6 The molded specimen of Example 5 was steam-cured at 40 degrees for 72 hours, and the surface became glossy. Even after soaking in water for 24 hours, the gloss did not disappear, and no efflorescence was observed. Ta.

実施例7 セメント:シャモット=1:2、水セメント比60%の
生モルタルを、混練直後プレス脱水して板状に成型し、
成型直後乾燥炉で乾燥させゆう掛けして1200度で焼
き、徐冷した後24時間湿潤益生じ、これを1時間反応
液に漬けて、表面が施ゆうされかつモルタル自体が難吸
水性化した硬化物を得た。
Example 7 Fresh mortar with a cement:chamotte ratio of 1:2 and a water-cement ratio of 60% was dehydrated by pressing immediately after kneading and molded into a plate shape.
Immediately after molding, the mortar was dried in a drying oven, baked at 1200 degrees, and slowly cooled for 24 hours. It was soaked in the reaction solution for 1 hour, and the surface was coated and the mortar itself became difficult to absorb water. A cured product was obtained.

以上実施7例につき説明したが、この発明はセメント系
を水の気化蒸発を押えて養生し、セメントグルの順調な
生成を促し、更には白華成分と反応剤または反応液とを
反応させ、生成セメントゲル或いは更に反応物でキャピ
ラリーを充満させ、セメント系の初期収縮を小さくし、
強度を増加させ、非吸水性化或いは白華抑制をも行おう
とするもので、水の気化蒸発を押えての養生は密閉養生
、湿iff養生、蒸気養生、オートクレーブ養生の何れ
でもよく、実施例における湿rJI養生と蒸気養生は、
湿潤養生、蒸気養生オートクレーブ養生の何れであって
もよい。また、セメント系に不足した水或いは反応液の
補足は、刷毛引き、スプレー、水漬等、含浸法を選ばな
い。また、水の補足は硬化物に限定されず、水セメント
比の少ない未硬化物であってもよい。尚硬化物に対する
水や反応液の補足は、セメントゲルの生成、或いは反応
剤または反応液と白華成分が反応するに充分なロが望ま
しいが、白華成分が溶出して表面に移行するような多聞
の含浸は、2次白華の発生を押える点からも避けること
が好ましい。
As described above with respect to the seven embodiments, the present invention cures the cement system by suppressing the vaporization of water, promotes the smooth production of cement glue, and further reacts the efflorescence component with the reactant or reaction liquid. filling the capillary with the produced cement gel or further reactants to reduce the initial shrinkage of the cement system;
The purpose is to increase the strength, make it non-water absorbent, or suppress efflorescence, and the curing to suppress water evaporation may be airtight curing, moist IF curing, steam curing, or autoclave curing. Examples Humid rJI curing and steam curing in
Either moist curing, steam curing or autoclave curing may be used. In addition, to supplement the water or reaction solution that is insufficient in the cement system, impregnation methods such as brushing, spraying, dipping, etc. can be used. Moreover, the supplement of water is not limited to a cured product, but may be an uncured product with a low water-to-cement ratio. It is desirable to supplement the cured product with enough water or reaction solution to form a cement gel or to allow the reaction agent or reaction solution to react with the efflorescence component, but do not add enough water or reaction solution to prevent the efflorescence component from eluting and migrating to the surface. It is preferable to avoid impregnating with a thick layer in order to suppress the occurrence of secondary efflorescence.

非吸水性化と強度増加を目的とするときは、当初セメン
ト系の表面に養生室天井からの結露水の滴下がない程度
の高湿(80%以上100%以下)養生を行い、セメン
ト系が結露水の滴下で汚損しなくなったら、より高湿例
えば湿度100%程度の養生が望ましく、水不足の場合
は不足水(反応液でもよい。》を含浸させて谷生すれば
よい。
When the purpose is to make the cement non-absorbent and increase its strength, the surface of the cement-based material is initially cured at high humidity (80% or more and 100% or less) to the extent that there is no dripping of dew condensation from the ceiling of the curing room. Once it is no longer contaminated by dripping with dew condensation water, it is desirable to cure it at a higher humidity, for example around 100% humidity, and if there is insufficient water, it may be impregnated with insufficient water (reaction liquid may be used) and cured.

白華抑制を目的とする時は、湿度を100%にせず、情
露しない範囲で高湿にして養生し、しかも温度時をより
大にすることが好ましい。
When the purpose is to suppress efflorescence, it is preferable that the humidity is not 100%, but the humidity is kept high enough to avoid exposure, and the temperature is increased.

しかし湿度100%以下で養生すると水が気化するので
、必要に応じ不足水を補足して益生を続ける。上記方法
は、湿潤養生または蒸気養生中、一定時間毎に養生室を
開き湿度100%の時間を短くし後は高湿養生したり、
常時高湿養生し、必要に応じ撒水等で不足水を補足する
こと等により達成される。
However, if the humidity is below 100%, the water will evaporate, so supplement the lack of water as needed to continue growing. The above method involves opening the curing chamber at regular intervals during humid curing or steam curing to shorten the period of 100% humidity, and then performing high-humidity curing.
This is achieved by constantly curing at high humidity and supplementing the lack of water by sprinkling water as necessary.

また、気化を押えた養生を約30度以上の温度で行うと
上面に光沢を生じ、約30度以下の温度で行うと型枠接
面に光沢を生じ、略30度程度の温度で行うと上面及び
型枠接面に光沢を生じるようである。即ち養生初期(約
3〜6時間以内)の温度の選択により、表面及びまたは
底面に光沢を生じさせたり、艶消しとすることができる
が(艶消しの場合は必ずしも反応剤の添加を必要としな
い。)、型枠接面に光沢をつくるときは、剥離剤を使用
することなく、プラスチック等の滑面を有する型枠を使
用する。尚反応剤と反応液の使用不使用は、用途に応じ
て行うことができる。上記した上面光沢は水の気化が行
われないか極めて少なければ30度以下の温度でも光沢
を出すことができるが、30U以上の場合反応速度も早
く、白華成分が表面に移行する間もなく表面層の反応が
進み、光沢を容易に出すことができるものと考えられる
。また型枠接面の光沢は、接面が空気に接しないことか
ら30度以上でもできるが、結露して接面に水が回ると
光沢が消えやすい。光沢を有するものは実施例4〜6も
含めて2次白華抑制が重要であり、前記した白華抑制法
を行うことが好ましい。
In addition, if curing with suppressed vaporization is performed at a temperature of about 30 degrees or higher, a gloss will appear on the top surface, if it is carried out at a temperature of about 30 degrees or less, a gloss will appear on the surface in contact with the formwork, and if it is carried out at a temperature of about 30 degrees, a gloss will appear on the top surface. It appears that the upper surface and the surface in contact with the formwork are glossy. That is, by selecting the temperature at the initial stage of curing (within about 3 to 6 hours), the surface and/or bottom surface can be made glossy or matte (although matte does not necessarily require the addition of a reactant). ), when creating a gloss on the surface in contact with the formwork, use a formwork with a smooth surface such as plastic without using a release agent. Incidentally, the use or non-use of the reactant and the reaction solution can be carried out depending on the purpose. The above-mentioned top surface gloss can be achieved even at temperatures below 30 degrees if there is no or very little water evaporation, but if the water is 30 U or higher, the reaction rate is fast, and the surface layer is formed quickly before the efflorescence component migrates to the surface. It is thought that the reaction progresses and gloss can be easily produced. Also, the gloss of the surface in contact with the formwork can be maintained even at temperatures above 30 degrees because the surface does not come into contact with the air, but the luster tends to disappear when water condenses and circulates around the surface. For glossy materials, including Examples 4 to 6, it is important to suppress secondary efflorescence, and it is preferable to perform the efflorescence suppression method described above.

この発明の養生法は以下の実施態様をとることができる
The regimen of this invention can take the following embodiments.

(1)実施例7ではシャモットに代え抗大石、火成岩、
焼物屑等の耐火性骨材を使用することができ、成型はプ
レス脱水成型に限定されない。また乾燥時水和反応の進
行が少なければ1 200度以下の温度で焼いてもよく
、永和反応が相当進んでいる場合は1450度程度で焼
いてもよい。
(1) In Example 7, instead of chamotte, large stones, igneous rocks,
Refractory aggregates such as pottery scraps can be used, and the molding is not limited to press dehydration molding. Further, if the progress of the hydration reaction during drying is small, baking may be carried out at a temperature of 1,200 degrees or less, and if the hydration reaction is progressing considerably, baking may be carried out at a temperature of about 1,450 degrees.

(2)蒸気養生や湿潤養生中等の不足水の補足は必要に
応じ何回行ってもよい。
(2) Supplementation of insufficient water such as steam curing or moist curing may be performed as many times as necessary.

(3)容器に入れ密閉して行う養生は湿潤養生に含まれ
る。
(3) Curing in a sealed container is included in wet curing.

(4)生モルタルや生コンクリート等未硬化物の表面に
合成樹脂エマルジョン(反応剤を加えたものが好ましい
。尚塗料として使用するときは顔料を加えておく。)を
塗設したり、ビニールシ一トや発泡スチロール等の非透
水性材や非透水断熱材で覆って養生してもよい。
(4) Coat a synthetic resin emulsion (preferably one with a reactive agent added to it.Add a pigment when using it as a paint) on the surface of uncured materials such as fresh mortar or fresh concrete, or apply a vinyl coating. It may be cured by covering it with a non-water permeable material such as foam or styrofoam, or a non-water permeable heat insulating material.

これらは湿潤養生に含まれ、シート等を除去することは
脱型に含まれる。
These are included in wet curing, and removing sheets etc. is included in demolding.

(5)養生に際し、地面やコンクリート上等に未硬化物
を打設するとき、地面等が湿っていて吸湿しなければ、
地面等との間に必ずしも非透水性材層を設ける必要がな
い。
(5) When placing an uncured material on the ground or concrete for curing, if the ground is damp and does not absorb moisture,
It is not necessarily necessary to provide an impermeable material layer between the ground and the like.

(6)養生室に、多段に水を設けたり、砂や砂利を敷詰
めて水を張ることができ、水を入れた養生室に蒸気を送
り露点或いは高湿にして蒸気を止めてもよく、湯を循環
させて蒸発させかつ加温したり、加熱空気を送ること等
により、湿度と温度を調整することができる。また養生
室内を区画し各区画を適温適湿にして養生してもよい。
(6) The curing chamber can be filled with water in multiple stages or filled with sand or gravel, and steam can be sent to the curing chamber filled with water to raise the dew point or high humidity and stop the steam. Humidity and temperature can be adjusted by circulating hot water to evaporate and heat it, or by sending heated air. Alternatively, the curing room may be divided into sections and each section may be kept at an appropriate temperature and humidity for curing.

(7)養生覆いや養生室内に空気を圧送し、加圧して水
の気化を押え養生してもよく、これも湿i1’.ll養
生に含まれる。
(7) Air may be pumped into a curing cover or a curing chamber and pressurized to suppress the vaporization of water for curing. Included in ll regimen.

(8)圧力変化を利用して空気や炭酸ガスを圧入し内部
の白華成分と反応させてもよい。
(8) Air or carbon dioxide gas may be injected using pressure changes to react with the efflorescence component inside.

(9)未硬化物は、肴色料、砂利、砕石、繊維等を加え
たものであってもよい。
(9) The uncured product may be one to which flavoring agents, gravel, crushed stone, fibers, etc. are added.

(10)セメントはボルトランドセメントに限定されず
、白色ボルトランドセメントや高炉セメント或いはフラ
イアツシュセメント等であってもよい。また未硬化物は
合成樹脂エマルジョンを加えてつくってもよい。尚この
発明で言う合成樹脂エマルジョンには合成ゴムエマルジ
ョンも含まれる。
(10) The cement is not limited to Boltland cement, and may be white Boltland cement, blast furnace cement, fly ash cement, or the like. Further, the uncured product may be prepared by adding a synthetic resin emulsion. The synthetic resin emulsion referred to in this invention also includes a synthetic rubber emulsion.

(11)型枠や容器或いは養生室は、非透水性材または
発泡スチロール等の非透水性断熱材でつくられ、或いは
囲まれていてもよい。非透水性断熱材を使用したもので
は、熱エネルギーを節約できるばかりか、永和反応熱を
利用して高温高湿養生を行うこともできる。
(11) The formwork, container, or curing chamber may be made of or surrounded by a non-water permeable material or a non-water permeable heat insulating material such as styrofoam. Those using non-water-permeable insulation materials not only save thermal energy, but also enable high-temperature, high-humidity curing by utilizing the heat of Eiwa reaction.

(12)未硬化物は湯で練ったり、蒸気を吹付けて練っ
た高温のものでもよい。
(12) The uncured product may be a high-temperature product kneaded with hot water or sprayed with steam.

《13》気化を押えての養生は少なくとも500度時以
上、好ましくは2000度時以上、更に好ましくは30
00〜5000度時以上が望ましい。
<<13>> Curing while suppressing vaporization is carried out at at least 500 degrees Celsius or higher, preferably at 2000 degrees Celsius or higher, and more preferably at 30 degrees Celsius or higher.
00 to 5000 degrees or more is desirable.

(14)養生室を2室設け、1室で成型後の養生(第1
養生)を、他室で脱型後の養生(第2養生)を行ってよ
い。水を入れた養生室で当初蒸気養生を行い、蒸気を止
めて湿潤養生に切替え(第1養生)、脱型後、水に漬け
るか水を入れた養生室で当初蒸気養生を行って不足水を
補足し、次に湿潤養生に切替え、必要に応じ不足水を補
足して湿潤養生(第2養生)すると、型枠の腐蝕少なく
、熱エネルギーを節約して経済的かつ良好な養生を行う
ことができ、合計3〜5日程度の養生で強度特性等顕著
な硬化物を得る。尚養生温度は目的に応じて選択するこ
とができる。
(14) Two curing rooms will be provided, one for curing after molding (the first
Curing) and curing after demolding (second curing) may be performed in another room. Initially, steam curing is performed in a curing chamber filled with water, then the steam is stopped and the curing is switched to wet curing (first curing).After demolding, immersion in water or initial steam curing is performed in a curing chamber filled with water, resulting in insufficient water. Supplementing water, then switching to moist curing, supplementing the insufficient water as necessary and performing moist curing (second curing) will reduce corrosion of the formwork, save thermal energy, and provide economical and good curing. A cured product with remarkable strength properties can be obtained after curing for about 3 to 5 days in total. The curing temperature can be selected depending on the purpose.

(15)ヒ1−ム管等の中空体を養生する場合、型枠の
両側を非透水性蓋で密閉し、蒸気を圧入する等して中空
部の湿度を100%または高湿にしたり、合成樹脂エマ
ルジョンを内側面に塗設造膜させて1次養生を行い、脱
型後不足水を補足し、養生室や養生覆い内で養生したり
、外側面に合成樹脂エマルジョンを塗設し造膜させて2
次養生を行ってもよい。
(15) When curing a hollow body such as a hem pipe, seal both sides of the formwork with non-water permeable lids and pressurize the hollow part to 100% or high humidity by, for example, injecting steam. First curing is performed by coating the inner surface with a synthetic resin emulsion to form a film, supplementing the lack of water after demolding, and curing in a curing room or within a curing cover, or by coating the outer surface with a synthetic resin emulsion. Membrane 2
You may carry out subsequent curing.

(16)反応液を成型後の硬化物に含浸させて1次白華
を、脱型後の硬化物に含浸させて2次白華を抑制しても
よい。
(16) The cured product after molding may be impregnated with the reaction liquid to suppress primary efflorescence, and the cured product after demolding may be impregnated to suppress secondary efflorescence.

(17)硬化物を成型して養生室に搬入する迄に時間が
経過して水の気化が進んでいるときや水セメント比が4
0%以下の未硬化成型物の場合、水を噴霧したり蒸気を
吹付けて蒸発した水や足りない水の補給を行い、養生室
に搬入し気化を押えて養生してもよい。
(17) When the time has passed and the water has evaporated by the time the cured product is molded and transported to the curing room, or when the water-to-cement ratio is 4.
In the case of an uncured molded product with a content of 0% or less, water may be sprayed or steam may be sprayed to replenish evaporated water or insufficient water, and the product may be transported to a curing room and cured while suppressing vaporization.

(18)原料はセメント系に限定ざれず、単なる永和反
応のみに限定ざれない。例えばボルトランドセメントに
珪砂微粉等と水を加え、或いは更に起泡剤や発泡剤を使
用して含泡または発泡させたものを、オートクレーブ養
生してもよい。また石灰とボゾラン或いは更にセメント
を主原料にしてもよく、従来のA L Cのようにアル
ミニウム粉等を発泡剤として使用し発泡させてもよい。
(18) The raw material is not limited to cement-based materials, nor is it limited to mere Eiwa reaction. For example, a product obtained by adding silica sand fine powder or the like and water to Bortland cement or foaming or foaming using a foaming agent or a foaming agent may be cured in an autoclave. In addition, lime and bozolan or cement may be used as the main raw materials, and aluminum powder or the like may be used as a foaming agent for foaming, as in conventional ALC.

尚発泡剤やオートクレーブ養生については昭和39年3
月15日株式会社オーム社発行の「気泡コンクリート」
に商品名イトン、シポレツクス、デュロツクス及びサー
モコン等の製造技術が紹介されているので、詳細な説明
を省略するが、アルミニウム粉等の発泡剤で発泡させる
とき、減水剤を加えてつくったものを発泡させてもよく
減水性起泡剤、起泡剤と減水剤、または起泡剤を使用し
含泡させてもよい。ALGも含め一般のセメント系をオ
ートクレーブ養生するときは、養生室に搬入する前に気
化を押えて養生するか不足水を補足してオートクレーブ
養生することが好ましい。I!酸カルシウム板を製造す
るときも同様である。
Regarding foaming agents and autoclave curing, please refer to March 1963.
"Aerated Concrete" published by Ohmsha Co., Ltd. on May 15th
The manufacturing technology for the product names Iton, Ciporex, Durox, and Thermocon is introduced in , so detailed explanations are omitted. Foaming may be carried out by using a water-reducing foaming agent, a foaming agent and a water-reducing agent, or a foaming agent. When curing a general cement system, including ALG, in an autoclave, it is preferable to cure it by suppressing vaporization or supplementing insufficient water before carrying it into a curing room. I! The same applies when producing calcium acid plates.

(19)遠心力成型によるポール等の成型時、最初に着
色料を加えた未硬化物を成型し、次に着色料を加えない
未硬化物を積層し成型してもよい。
(19) When molding a pole or the like by centrifugal force molding, an uncured material to which a coloring agent has been added may be molded first, and then an uncured material to which no coloring material has been added may be laminated and molded.

(20)カルバートボックス等の中空体を養生するとき
、凹部を形成したコンクリートや非透水性シート等の上
に砂や砂利を敷いて水を注いでおき、この上で成型後ま
たは脱型後のものに養生覆いを被せ、蒸気を送る等して
湿度を100%を含む高湿にし養生してもよい。
(20) When curing a hollow body such as a culvert box, sand or gravel is spread on top of the concrete or non-water permeable sheet that has formed the recesses, and water is poured on top of it. It is also possible to cure the item by covering it with a curing cover and increasing the humidity to 100% by, for example, sending steam.

(21)反応剤及び反応液には、マンガン酸、過マンガ
ン酸、オルト燐酸、メタ燐酸、次燐酸、亜燐酸、珪酸、
流酸、硝酸、塩酸、カルボン酸類(タルトロン酸、リン
ゴ酸、酒石酸、グルコン酸、グロン酸、クエン酸、アス
コルビン酸等),等の酸類や、重曹、アンモニア水、水
ガラス等のアルカリ類、また市販ざれているものとして
は触媒化成工業(株)製の商品名力タロイド等のシリカ
ゾル、花王(株)製の商品名マイティー150(ナフタ
リンスルホン酸・ホルマリン高縮合塩》、マイテイー2
000、或いは山陽国策バルプ(株)製の商品名サンフ
ローMA(リグニン系)等の減水剤、信越化学工業(株
)製の商品名メトローズ、ハイメトローズ等の増粘剤、
各種のシリコンやマイクロシリカ、各種AE剤や流動化
剤、白華抑制剤、膨脹剤、界面活性剤、起泡剤、ステア
リン酸カリウム等のはっ水剤、或いはこれらの混合物等
、水の存在下でセメントまたはその生成物と反応するも
のならどれでも使用することができ、複数剤が反応して
キャピラリー空間を少なくするものでおってもよい。実
施例の反応剤には、水セメント比を少なくする目的でマ
イティー150またはこれに酸、アルカリ、及び塩類の
うちの適量を加えたものを使用したが、反応剤はこれに
限定されるものではなく、反応剤と反応液には、具体的
には、例えば以下のようなものを使用することができる
(21) Reactants and reaction solutions include manganic acid, permanganic acid, orthophosphoric acid, metaphosphoric acid, hypophosphoric acid, phosphorous acid, silicic acid,
Acids such as sulfuric acid, nitric acid, hydrochloric acid, carboxylic acids (tartronic acid, malic acid, tartaric acid, gluconic acid, gulonic acid, citric acid, ascorbic acid, etc.), alkalis such as baking soda, ammonia water, water glass, etc. Commercially available products include silica sol such as Taloid (trade name) manufactured by Catalysts & Chemicals Co., Ltd., Mighty 150 (high condensation salt of naphthalene sulfonic acid/formalin), and Mighty 2 manufactured by Kao Corporation.
000, or water-reducing agents such as Sunflow MA (lignin-based) manufactured by Sanyo Kokusaku Valp Co., Ltd., thickeners such as Metroose and Hi-Metrose manufactured by Shin-Etsu Chemical Co., Ltd.
The presence of water, such as various silicones and microsilicas, various AE agents, fluidizing agents, efflorescence inhibitors, swelling agents, surfactants, foaming agents, water repellents such as potassium stearate, or mixtures thereof, etc. Any agent that reacts with the cement or its products under the conditions can be used, including those that react with multiple agents to reduce capillary space. Mighty 150 or Mighty 150 to which an appropriate amount of acid, alkali, and salts were added was used as the reactant in the examples, but the reactant is not limited to this. Specifically, for example, the following can be used as the reactant and reaction solution.

(A)流酸や塩酸或いは硝酸等の強酸類は、1 ,/ 
1 00万〜1/1000万程度の稀釈液を使用するこ
とができる。
(A) Strong acids such as hydrochloric acid, hydrochloric acid, or nitric acid are 1,/
A dilution solution of about 1 million to 1/10 million can be used.

(8)タル1〜ロン酸、リンゴ酸、酒石酸、グルコン酸
、グロン酸、クエン酸、アスコルビン酸等のカルボン酸
類は、1/200〜1/50万程度の稀釈液または溶解
液を使用することができる。
(8) For carboxylic acids such as tal-1-ronic acid, malic acid, tartaric acid, gluconic acid, gulonic acid, citric acid, ascorbic acid, etc., use a dilution or dissolution solution of about 1/200 to 1/500,000. Can be done.

(c)lvJ、アンモニア水、水ガラス等のアルカリ類
は、1/100〜1/20万程度の稀釈液または溶解液
を使用することができる。
(c) For alkalis such as lvJ, aqueous ammonia, and water glass, a dilution or solution of about 1/100 to 1/200,000 can be used.

(0)シリカゾノレ、シリコン、マイクロシリカ等のシ
リカ類、メトローズ等の増粘剤、減水剤、はっ水剤、そ
の他AE剤や流動化剤等のけメン用添加剤は、3〜1/
100程度の稀釈液を使用することができる。
(0) Silicas such as silica, silicone, and microsilica, thickeners such as Metrose, water reducers, water repellents, and other additives for coatings such as AE agents and fluidizers are 3 to 1/2
Dilutions as high as 100 can be used.

([)上記薬剤の2種以上を混合したものを使用するこ
とができる。
([) A mixture of two or more of the above drugs can be used.

尚反応剤として使用する場合の使用量は、使用セメント
量に対し0.3〜100%程度の添加が好ましく、反応
液として使用する場合はそまま使用することができる。
When used as a reaction agent, the amount used is preferably about 0.3 to 100% based on the amount of cement used, and when used as a reaction liquid, it can be used as is.

(22)セメント系を載せるパレットやラックの下に容
器を設け、砂や砂利或いは繊維等と一緒に水を入れて養
生することができる。
(22) A container can be provided under the pallet or rack on which the cement-based material is placed, and water can be added together with sand, gravel, fibers, etc. for curing.

(23)セメント系に着色するには、前記した反応剤を
加えた塗料や、合成樹脂エマルジョンに顔料、反応剤或
いは更に安定剤を加えたものを塗設して白華を抑制する
ことができる。
(23) To color cement-based materials, efflorescence can be suppressed by applying a paint containing the above-mentioned reactive agent or a synthetic resin emulsion containing a pigment, a reactive agent, or a stabilizer. .

(24)湿潤養生には、密閉された養生室内を市販の加
湿器で加湿して養生することも含まれ、水を張った養生
室内を加湿器で加湿して、湿度を100%を含む高湿に
するこども含まれる。またヒューム管やカルバートボッ
クス等の中空部を加湿器で加湿して100%を含む高湿
にしてもよい。ヒューム管等の場合、両側の密閉蓋を非
透水性断熱材とし、更に筒状に形成ざれる型枠を断熱材
で作るか、断熱材で覆っておけば、反応熱を利用して高
温高湿養生を行うことができる。
(24) Humidity curing includes curing the airtight curing chamber by humidifying it with a commercially available humidifier. Includes children who get wet. Alternatively, a humidifier may be used to humidify a hollow part such as a fume pipe or a culvert box to provide high humidity containing 100%. In the case of a fume pipe, etc., if the sealing lids on both sides are made of non-water permeable heat insulating material, and the formwork for forming the cylinder is made of heat insulating material, or if it is covered with heat insulating material, the heat of reaction can be used to increase the temperature. Moist curing can be performed.

(25)水硬系に対する不足水の補足で蒸気を含浸させ
ることには、上記した加湿器等による湿分の含浸も含ま
れる。
(25) Impregnating the hydraulic system with steam to supplement insufficient water includes impregnating moisture with the above-mentioned humidifier or the like.

(26)セメン1〜ゲル或いは更に反応剤や反応液と白
華成分との反応物でキVピラリーが成程度充満すると、
保水性が生じ白華成分も閉込められる。従って適宜圧力
変化または圧力を加え、空気または炭酸ガスを圧入して
、炭酸ガスと内部白華成分を反応させてもよい。
(26) When the KiV pillar is filled to a certain extent with cement 1 to gel or the reaction product of the reactant or reaction solution with the efflorescence component,
Water retention occurs and efflorescence components are also trapped. Therefore, the internal efflorescence component may be reacted with the carbon dioxide gas by applying a pressure change or pressure as appropriate and injecting air or carbon dioxide gas.

(27)この発明では、1実施例で使用した物または方
法が他の実施例に適切であるときは、これを他の実施例
に使用し、利用し、若しくは応用することができる。
(27) In this invention, if an object or method used in one embodiment is appropriate for the other embodiment, it can be used, utilized, or applied to the other embodiment.

[発明の効果] 従来の養生は、型枠の回転をよくするため主として脱型
強度を早く出すことに使用され、養生前やIQ型後の水
の気化量が大で、これが収縮や吸水或いは白菜の発生や
低強度に関係することに気付かず、成型後略5日以内の
最も小要な初期養生がなおざりにされてさた。
[Effects of the invention] Conventional curing is mainly used to quickly develop demolding strength in order to improve the rotation of the mold, and the amount of water vaporized before curing and after IQ molding is large, which causes shrinkage, water absorption, and Unaware that it was related to the development of Chinese cabbage and low strength, the most essential initial curing within about 5 days after molding was neglected.

しかるにこの発明は前記のように構成ざれ、水の気化を
押えて養生することにより、1次白拍を抑制することが
できるばかりか、水隙少なく吸水性が小さいか吸水性の
ない、或いははつ水性すら示す、また収縮が小でクラツ
クが発生し難く、強度が大で、2次白華抑制にも効果的
なセメント系硬化物をつくることができ、水に漬けても
消滅しない光沢を有する硬化物やゆう■トけした硬化物
の!S!造も可能であり、湿潤養生するときは熱エネル
ギーを節約することも可能で、製造される硬化物は耐久
性に勝れ、内臓鉄筋を腐蝕さt!難く、炭素繊維や節付
きアクリル繊維等の繊維或いは網材等を入れたり、プレ
ストレッシングすること等により、曲げ強度や引張り強
度の大なる硬化物をつくることができ、また含泡した未
硬化物は金庫、建具、パネル、調理台等の空間に充填し
て養生するこや硬質パーライト等の軽量骨材の混入も可
能で、厚型スレート、テラゾー、有孔ブロック、インタ
ーロッキングブロツク、その他の各種ブロック、魚礁、
昆布の根巻、テトラポット、コンクリートボール、擁壁
、擬木、PC板、大平板、各種装飾板、万年塀、杭、ヒ
ューム管、カルバートボックス、側溝等、セメント2次
製品の製造に広く利用ざれるばかりか、現場における鉄
筋コンクリート、気泡゛鉄筋コンクリート等のセメン下
系構造物の築造(密閉して養生し、脱型後水または反応
液を含浸させ、表面に粘着テープを利用する等してプラ
スチックシ一ト等の非透水性材を設けて覆い養生する。
However, this invention is constructed as described above, and by curing while suppressing water evaporation, it is possible not only to suppress primary white spots, but also to suppress water pores and have low water absorption, or no water absorption, or water absorption. It is possible to create a cement-based hardened product that exhibits even water repellency, has low shrinkage, is hard to crack, has high strength, and is effective in suppressing secondary efflorescence, and has a luster that does not disappear even when immersed in water. Cured products that have been cured and cured products that have melted! S! It is also possible to save heat energy when wet curing, and the cured product produced has excellent durability and does not corrode the internal reinforcing steel! However, by adding fibers such as carbon fibers or knotted acrylic fibers or net materials, or by pre-stressing, it is possible to create cured products with high bending and tensile strength. It can be used to fill and cure spaces such as safes, fittings, panels, and countertops, and can also be mixed with lightweight aggregates such as hard perlite. block, reef,
Widely used in the production of secondary cement products such as kelp root wraps, tetra pots, concrete balls, retaining walls, artificial trees, PC boards, large flat boards, various decorative boards, permanent walls, piles, hume pipes, culvert boxes, side gutters, etc. In addition to construction of reinforced concrete, cellular reinforced concrete, and other cement-based structures on site (sealing and curing, impregnation with water or reaction solution after demolding, and use of adhesive tape on the surface, etc.) Cover and cure using non-permeable material such as sheets.

また塗りモルタルの場合は、生モルタル塗設後合成樹脂
エマルジョンを塗設し造膜させて養生するが、生モルタ
ル塗設後プラスチックシ一トで覆って養生し、水の気化
が見られる場合はプラスチックシ一トを外し、モルタル
に水または反応液を含浸させて再度プラスチックシ一ト
で覆い養生する。尚プラスチックシ一トは発泡したもの
でもよい。またモルタル下地は非透水性であることが望
ましく、凹凸模様を施した発泡プラスチックをモルタル
表面に圧着しめりこませてもよい。》や、コンクリート
舗装通路、アスファルト舗装道路の下地コンクリート、
地下室工事等、建築及び土木工事等にも利用することが
できるのみならず、従来のALCを非吸水性化し強度を
高めることもでき、原子炉廃棄物の埋設コンクリ−1へ
の製造や、原子炉構築物の製造にも利用することができ
る等、極めて用途が広い。
In addition, in the case of painted mortar, a synthetic resin emulsion is applied after the raw mortar is applied and cured by forming a film, but after the raw mortar is applied, it is covered with a plastic sheet and cured, and if water evaporation is observed. The plastic sheet is removed, the mortar is impregnated with water or the reaction solution, and the mortar is covered again with a plastic sheet and cured. Note that the plastic sheet may be foamed. Further, the mortar base is preferably water-impermeable, and a foamed plastic with an uneven pattern may be pressed and pressed onto the mortar surface. 》, concrete paved paths, concrete base for asphalt paved roads,
Not only can it be used for construction and civil engineering works such as basement construction, but it can also be used to make conventional ALC non-water absorbent and increase its strength. It is extremely versatile, as it can also be used to manufacture furnace structures.

Claims (3)

【特許請求の範囲】[Claims] (1)適量の反応剤を加えるか加えることなくつくつた
吸水性水硬系に、水蒸気、水、または反応液を含浸させ
、引続き該水硬系を湿潤養生、蒸気養生、またはオート
クレーブ養生することを特徴とする、水硬系の養生法。
(1) Impregnating a water-absorbing hydraulic system, prepared with or without the addition of an appropriate amount of reactant, with steam, water, or a reaction liquid, and subsequently moist-curing, steam-curing, or autoclaving the hydraulic system. A hydraulic curing method characterized by:
(2)適量の反応剤を加えるか加えることなくつくり密
閉養生、湿潤養生、または蒸気養生した水硬系に、脱型
後水蒸気、水、または反応液を含浸させ、引続き該水硬
系を湿潤養生、蒸気養生、またはオートクレーブ養生す
ることを特徴とする、水硬系の養生法。
(2) After demolding, a hydraulic system made with or without the addition of an appropriate amount of reactant and sealed, wet, or steam-cured is impregnated with steam, water, or a reaction solution, and the hydraulic system is subsequently moistened. A hydraulic curing method characterized by curing, steam curing, or autoclave curing.
(3)適量の反応剤を加えてつくり密閉養生、湿潤養生
、または蒸気養生した水硬系を、脱型後湿潤養生、蒸気
養生、またはオートクレーブ養生することを特徴とする
、水硬系の養生法。
(3) Curing of a hydraulic system, which is characterized by adding an appropriate amount of a reactant and curing the hydraulic system in a hermetically sealed, moist, or steam-cured state, followed by demolding and then moist-curing, steam-curing, or autoclave curing. Law.
JP3102989A 1989-02-13 1989-02-13 Method for curing hydraulic system Pending JPH02229775A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3102989A JPH02229775A (en) 1989-02-13 1989-02-13 Method for curing hydraulic system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3102989A JPH02229775A (en) 1989-02-13 1989-02-13 Method for curing hydraulic system

Publications (1)

Publication Number Publication Date
JPH02229775A true JPH02229775A (en) 1990-09-12

Family

ID=12320087

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3102989A Pending JPH02229775A (en) 1989-02-13 1989-02-13 Method for curing hydraulic system

Country Status (1)

Country Link
JP (1) JPH02229775A (en)

Similar Documents

Publication Publication Date Title
CN102561532B (en) Functionally-graded cellular-concrete thermal-insulating material and preparation method thereof
CA1050244A (en) Casting of articles containing calcined gypsum
US5681385A (en) Method for retarding efflorescence in building materials and building material that exhibits reduced efflorescence
WO2014090790A1 (en) Thermally insulating aerogel based rendering materials
AU2015239093B2 (en) Method for producing an insulating composite building block
Klisińska-Kopacz et al. Effect of hydrophobization treatment on the hydration of repair Roman cement mortars
CN101691800B (en) General insulation composite material for exterior wall and application method
Goel et al. A Comparative Study on the Effect of Curing on the Strength of Concrete
JP2002178444A (en) Decorative veneer-clad humidity controlling fireproof building material
CN104402375A (en) Interior decoration mortar
CN110451916A (en) A kind of expanded perlite light thermal insulation decoration integrated board and preparation method thereof
JPH02229775A (en) Method for curing hydraulic system
CN109437802A (en) A kind of sulphate aluminium cement assembled integrated interior wall and preparation method thereof
CN110218067B (en) Efficient heat insulation plate and preparation method thereof
KR100795837B1 (en) Negative Ion Emission Wall Structure Of Building Using Environmental Porous Rock
CA1038140A (en) Constructional units
US6110270A (en) Method for influencing moisture content and migration in building materials
WO1990011258A1 (en) Hydraulic substance, method of producing and curing the same, curing chamber, and paint
US5534292A (en) Method for producing and curing hydraulic material
JPH02229774A (en) Method for curing hydraulic system and production of hardened hydraulic system
JPH0426534A (en) Production of hydraulic material and method and chamber for ageing the same
JP2614143B2 (en) Hydraulic materials and methods of manufacturing, curing, and curing rooms for hydraulic materials
JPH03265580A (en) Curing method of hydraulic system
JP2001335385A (en) Inorganic cured body
KR20030056411A (en) A covering method using loess mortar