CN109437802A - A kind of sulphate aluminium cement assembled integrated interior wall and preparation method thereof - Google Patents

A kind of sulphate aluminium cement assembled integrated interior wall and preparation method thereof Download PDF

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Publication number
CN109437802A
CN109437802A CN201811539482.2A CN201811539482A CN109437802A CN 109437802 A CN109437802 A CN 109437802A CN 201811539482 A CN201811539482 A CN 201811539482A CN 109437802 A CN109437802 A CN 109437802A
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Prior art keywords
sulphate aluminium
aluminium cement
water
interior wall
insulation board
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CN109437802B (en
Inventor
程志
裴晓波
王晓依
刘兰
郭宏
韩云山
靳小俊
王万月
董彦莉
王元龙
张兆鹏
赵致艺
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North University of China
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North University of China
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/144Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/66Sealings
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/88Insulating elements for both heat and sound
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B2/00Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Architecture (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Civil Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Electromagnetism (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Acoustics & Sound (AREA)
  • Building Environments (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)

Abstract

The invention belongs to building material technical fields, and in particular to a kind of sulphate aluminium cement assembled integrated interior wall and preparation method thereof.Sulphate aluminium cement assembled integrated interior wall provided by the invention is using sulphate aluminium cement as primary raw material, have the characteristics that hydration and hardening rate is fast, early strong, have the advantages that low alkalinity, stabilization is fast, drying shrinkage expansion rate is small again, it is used to prepare porous foam thermal insulation material, the rapid condensation cure of foam generated can be made to form pore structure in cementitious material, be conducive to improve the stability of foam and the performance of product.Embodiment the result shows that, in above-mentioned sulphate aluminium cement assembled integrated interior wall the thermal coefficient of insulation board be 0.033~0.035W/ (mk), compression strength reaches 0.7~1.0MPa, meets the performance requirement of assembled integrated interior wall.

Description

A kind of sulphate aluminium cement assembled integrated interior wall and preparation method thereof
Technical field
The invention belongs to building material technical fields, and in particular to a kind of sulphate aluminium cement assembled integrated interior wall and Preparation method.
Background technique
With the fast development of building trade and housing industrialization, people are higher and higher to the performance requirement of construction material, In addition to security performance demand, the heat insulation effect of construction material is also increasingly paid attention to.To obtain the Building wood with thermal insulation property Material, researcher has developed a variety of materials with thermal insulation property, such as organic insulation material, inorganic heat insulation material and inorganic coagulates Glue material and the compound thermal insulation material of heat preserving aggregate are all relatively conventional thermal insulation materials.Existing organic insulation material, it is such as poly- Polystyrene board heat-insulatation material, polyurathamc cellular insulant etc., although having good thermal insulation property, fire resistance is poor, deposits In security risk;Existing inorganic heat insulation material, such as: alumina silicate fibre thermal insulation material, rock wool heat-preservation material, preparation cost compared with Height limits its large-scale application.
Summary of the invention
The purpose of the present invention is to provide a kind of sulphate aluminium cement assembled integrated interior wall and preparation method thereof, this hairs The sulphate aluminium cement foaming insulation board thermal coefficient of bright offer is lower, prepares that raw material sources are extensive, reduces thermal insulation material Cost.
To achieve the goals above, the invention provides the following technical scheme:
The present invention provides a kind of sulphate aluminium cement assembled integrated interior walls, including sulphate aluminium cement foamed heat insulating Plate and the finish coat for being bonded in two opposite of sulphate aluminium cement foaming insulation board;
The raw material for preparing of the sulphate aluminium cement foaming insulation board includes sulphate aluminium cement, Desulphurization, water-reducing agent, hair Infusion, graphite powder, polypropylene fibre and water;
The raw material for preparing of the finish coat includes desulfurized gypsum;
The sulphate aluminium cement foaming insulation board with a thickness of 45~50mm.
Preferably, the sulphate aluminium cement foaming insulation board prepares the component that raw material includes following mass parts: 69~ 81 parts of sulphate aluminium cements, 23~27 parts of Desulphurizations, 3.7~7.2 parts of foaming agents, 0.6~1.4 part of water-reducing agent, 0.5~1.4 part Graphite powder, 0.1~0.3 part of polypropylene fibre and 40~49 parts of water.
Preferably, the foaming agent includes hydrogen peroxide or a- alkylene sodium sulfonate;
The water-reducing agent includes Lignins water-reducing agent or polycarboxylate high-efficiency water-reducing agent;
The Desulphurization includes the component of following mass percentage: SiO241.87~42.51%, Al2O325.37~ 26.43%, CaO10.42~11.56%, SO35.47~6.35%.
Preferably, the single side thickness of the finish coat independently is 10~15mm.
Preferably, the raw material for preparing of the finish coat includes desulfurized gypsum, retarder, water-retaining agent and water;
The mass ratio of the desulfurized gypsum and water is 1:(0.40~0.45);
The quality of the retarder is the 0.015~0.03% of desulfurized gypsum quality;
The quality of the water-retaining agent is the 0.10~0.20% of desulfurized gypsum quality.
Preferably, the insulating layer and finish coat are bonded by interfacial agents, and the composition of the interfacial agents includes cement paste.
The present invention provides the preparation method of sulphate aluminium cement assembled integrated interior wall described in above-mentioned technical proposal, packets Include following steps:
(1) sulphate aluminium cement, Desulphurization, graphite powder and polypropylene fibre are mixed, obtains admixture;
(2) foaming agent and water-reducing agent are mixed with the admixture in the step (1), water is then added, obtains pouring material;
(3) pouring material that the step (2) obtains successively is poured and is conserved, obtained sulphate aluminium cement foaming and protect Warm plate;
(4) the surface adhesion finish coat of the sulphate aluminium cement foaming insulation board obtained in the step (3) prepares raw material Mixture, sulphate aluminium cement assembled integrated interior wall is obtained after maintenance.
Preferably, maintenance is that room temperature conserves in the step (3), and the temperature of the room temperature maintenance is 20~25 DEG C, described The time of room temperature maintenance is 7~14d.
The present invention provides a kind of sulphate aluminium cement assembled integrated interior walls, including sulphate aluminium cement foamed heat insulating Plate and the finish coat for being bonded in two opposite of sulphate aluminium cement foaming insulation board;The sulphate aluminium cement foaming insulation board The raw material for preparing include sulphate aluminium cement, water-reducing agent, foaming agent, graphite powder, polypropylene fibre and water;The system of the finish coat Standby raw material includes desulfurized gypsum;The sulphate aluminium cement foaming insulation board with a thickness of 45~50mm.Sulphur provided by the invention Aluminate cement assembled integrated interior wall has hydration and hardening rate fast, early strong using sulphate aluminium cement as primary raw material Feature, and have the advantages that low alkalinity, stabilization is fast, drying shrinkage expansion rate is small, it is used to prepare porous foam thermal insulation material, can make to generate The rapid condensation cure of foam pore structure is formed in cementitious material, be conducive to improve foam stability and product performance; Foaming agent can form closed aperture, and then obtain having compared with low-density, excellent waterproof performance, thermal insulation property and compression strength Plate reduces the production cost of construction material.Embodiment the result shows that, sulphate aluminium cement assembled one provided by the invention The thermal coefficient of body interior wall is 0.033~0.035W/ (mk), and compression strength reaches 0.7~1.0MPa, meets aluminium sulfate The performance requirement of cement assembled integrated interior wall.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of sulphate aluminium cement assembled integrated interior wall provided by the invention;
Fig. 2 is the explosive view of sulphate aluminium cement assembled integrated interior wall structure schematic diagram provided by the invention;
In figure, 1-1 is finish coat, and 2 be sulphate aluminium cement foaming insulation board, and 1-2 is finish coat.
Specific embodiment
The present invention provides a kind of sulphate aluminium cement assembled integrated interior walls, including sulphate aluminium cement foamed heat insulating Plate and the finish coat for being bonded in two opposite of sulphate aluminium cement foaming insulation board;
The raw material for preparing of the sulphate aluminium cement foaming insulation board includes sulphate aluminium cement, Desulphurization, water-reducing agent, hair Infusion, graphite powder, polypropylene fibre and water;
The raw material for preparing of the finish coat includes desulfurized gypsum;
The sulphate aluminium cement foaming insulation board with a thickness of 45~50mm.
As shown in Fig. 1~2, sulphate aluminium cement assembled integrated interior wall provided by the invention, including aluminium sulfate water Mud foaming insulation board 2 and the finish coat 1-1 and 1-2 for being bonded in 2 liang of opposites of the sulphate aluminium cement foaming insulation board.
Sulphate aluminium cement assembled integrated interior wall provided by the invention includes sulphate aluminium cement foaming insulation board, institute The raw material for preparing for stating sulphate aluminium cement foaming insulation board includes sulphate aluminium cement, Desulphurization, water-reducing agent, foaming agent, graphite Powder, polypropylene fibre and water.
In terms of mass parts, the raw material for preparing of sulphate aluminium cement foaming insulation board provided by the invention preferably includes 69~81 Part sulphate aluminium cement, more preferably 71~78 parts, be further preferably 74~75 parts.In the present invention, the sulphate aluminium cement Mineral constituent including following mass content: SiO29.63%, CaO 42.58%, Al2O3 34.05、Fe2O31.20%, MgO 1.31%, SO38.63%, remaining is inevitable impurity.In the present invention, the low alkalinity wins sulfate cement firmly fastly Loss on ignition be 0.28.Present invention preferably employs the sulphate aluminium cements of said components, have hydration and hardening rate fast, early strong Feature, and have low alkalinity, stablize advantage fast, that drying shrinkage expansion rate is small.
On the basis of the mass parts of the sulphate aluminium cement, sulphate aluminium cement foaming insulation board provided by the invention It prepares raw material and preferably includes 23~27 parts of Desulphurizations, more preferable 24~26 parts of Desulphurizations are further preferably 25 parts.In the present invention, It include the component of following mass percentage, SiO described in the Desulphurization241.87~42.51%, Al2O325.37~ 26.43%, CaO 10.42~11.56%, SO35.47~6.35%.In embodiments of the present invention, the Desulphurization preferably comes Derived from Shanxi Pingshou coal-refuse fragment dimension.
On the basis of the mass parts of the sulphate aluminium cement, sulphate aluminium cement foaming insulation board provided by the invention It prepares raw material and preferably includes 3.7~7.2 parts of foaming agents, more preferably 4.3~6.7 parts, be further preferably 5.4~5.7 parts.In this hair In bright, the foaming agent preferably includes hydrogen peroxide or a- alkylene sodium sulfonate, more preferably hydrogen peroxide.In the present invention, The hydrogen peroxide is preferably used in a manner of hydrogenperoxide steam generator, and the mass concentration of the hydrogenperoxide steam generator is preferably 20~ 30%, more preferably 25~28%.The present invention is preferably used using hydrogen peroxide as foaming agent, is decomposed using hydrogen peroxide itself Oxygen and water are generated, blind bore gap structure can be formed on the surface of cement admixture and inside during oxygen evolution, make institute Obtaining plate has excellent thermal insulation property, sound insulation property and light performance.
On the basis of the mass parts of the sulphate aluminium cement, sulphate aluminium cement foaming insulation board provided by the invention It prepares raw material and preferably includes 0.6~1.4 part of water-reducing agent, more preferably 0.8~1.3 part, be further preferably 0.9~1.2 part.In this hair In bright, the water-reducing agent preferably includes Lignins water-reducing agent and/or polycarboxylate high-efficiency water-reducing agent, more preferably polycarboxylic acids Salt series high-efficiency water-reducing agent.When the water-reducing agent is the mixture of two kinds of components, use of the present invention to each component in the mixture Amount is than no particular/special requirement.The present invention preferably by the use of polycarboxylate high-efficiency water-reducing agent, is guaranteeing foam concrete material It starches in the identical situation of workability, significantly reduces the slurry ratio of mud, the consistency of cell wall is improved, to improve the mechanics of product Performance and thermal property etc..
On the basis of the mass parts of the sulphate aluminium cement, sulphate aluminium cement foaming insulation board provided by the invention It prepares raw material and preferably includes 0.6~1.4 part of graphite powder, more preferably 0.8~1.3 part, be further preferably 0.9~1.3 part.In this hair In bright, in the graphite powder, C atom content is no less than 90%;The calcination residual of the graphite powder is preferably 20~30%, more excellent It is selected as 25%, loss on drying is preferably 45~50%, and more preferably 50%.In the present invention, the graphite powder is in aluminium sulfate Cement foaming insulation board prepares dispersibility in the mixture of raw material preferably, can be to thermosetting high-efficiency reflective;And contain in graphite powder Some infrared ray absorbing objects can significantly promote the thermal and insulating performance of plate;In addition, graphite powder can also improve efficiency, and improve The comprehensive performance of slurry.
On the basis of the sulphate aluminium cement mass parts, the system of sulphate aluminium cement foaming insulation board provided by the invention Standby raw material preferably includes 0.1~0.3 part of polypropylene fibre, more preferably 0.2 part.In the present invention, the polypropylene fibre Length is preferably 3~6mm, more preferably 4~5mm;The diameter of the polypropylene fibre is preferably 18~48 μm, more preferably 20 ~40 μm;The tensile strength of the polypropylene fibre preferably >=358MPa.The present invention, which preferably passes through polypropylene fibre, enhances plate Resisting fractre ability, the ability that plate generates plastic deformation under external force is substantially improved, improves the toughness of heat preservation plate material.
On the basis of the mass parts of the sulphate aluminium cement, sulphate aluminium cement foaming insulation board provided by the invention Preparing raw material includes 40~49 parts of water, preferably 43~47 parts, more preferably 43~46 parts.The present invention is not special to the water It is required that using well known to those skilled in the art.
The present invention is using sulphate aluminium cement, Desulphurization, water-reducing agent, foaming agent, graphite powder, polypropylene fibre and water as raw material Sulphate aluminium cement foaming insulation board is prepared, the dosage and complementary contraction of cement are reduced using Desulphurization, improves board dimension Stability.Under the action of foaming agent, the surface of the mixtures such as cement, Desulphurization and water and the internal closed hole knot of formation Structure makes gained heat preservation plate material have excellent thermal insulation property, sound insulation property and light performance.The present invention is also improved by water-reducing agent Foam concrete slurry workability reduces the slurry ratio of mud, the consistency of cell wall is improved, to improve heat preservation plate material product Mechanical property and thermal property.In the present invention, graphite powder can be stably dispersed in the slurry of the raw material components such as cement, Desulphurization, water In material, can reflective thermal radiation, further promoted plate thermal and insulating performance;Polypropylene fibre can enhance sulphate aluminium cement Resisting fractre ability significantly promotes the ability that plate generates plastic deformation under external force, this makes the toughness of heat preservation plate material Benign development is presented.
The density of sulphate aluminium cement foaming insulation board of the present invention is lower than 170kg/m3, hence it is evident that it is lower than existing insulation board The 200kg/m of material3, belong to typical low-density insulation board.In the present invention, the sulphate aluminium cement foaming insulation board has Hole, the aperture of the hole are preferably 1~5mm, more preferably 2~3mm;Porosity is with volume aluminium sulfate water shared by hole The porosity of mud foaming insulation board total volume meter, the sulphate aluminium cement foaming insulation board is preferably 90.3~91.2%, more Preferably 90.5~90.8%.Sulphate aluminium cement foaming insulation board of the present invention refers to the aluminium sulfate with above-mentioned porosity Cement foaming insulation board.
In the present invention, the thickness of the sulphate aluminium cement foaming insulation board is preferably 45~50mm, more preferably 50mm.The thermal coefficient of the sulphate aluminium cement foaming insulation board is 0.033~0.035W/ (mk);Compression strength is preferred For 0.7~1.0MPa;Maximum oise insulation factor reaches 50dB.
Sulphate aluminium cement assembled integrated interior wall provided by the invention further includes being bonded in the sulphate aluminium cement The raw material for preparing of the finish coat on two opposite of foaming insulation board, the finish coat includes desulfurized gypsum.In the present invention, the facing The raw material for preparing of layer preferably includes desulfurized gypsum, retarder, water-retaining agent and water.
In the present invention, CaSO in the desulfurized gypsum4Mass content preferably >=90%, more preferably 91~95%; The mass ratio of the desulfurized gypsum and water is preferably 1:(0.40~0.45), be further preferably 1:(0.4~0.45), more preferably 1: 0.43。
In the present invention, the retarder preferably includes calcareous synthesizing polyamides;The quality of the retarder preferably accounts for de- The 0.015~0.03% of sulphur gypsum quality is further preferably 0.02~0.025%.
In the present invention, the water-retaining agent preferably includes hydroxypropyl methyl cellulose (HPMC);The viscosity of the water-retaining agent Preferably 80000~120000Pas, more preferably 100000Pas;The quality of the water-retaining agent preferably accounts for desulfurized gypsum matter The 0.10~0.20% of amount, is further preferably 0.15~0.20%.
In the present invention, the single side thickness of the finish coat is preferably independently 10~15mm, more preferably 13~15mm. In the present invention, the thickness of the finish coat on same two opposite of sulphate aluminium cement foaming insulation board is preferably identical.In the present invention In, the sulphate aluminium cement foaming insulation board and finish coat are preferably bonded by interfacial agents, and the composition of the interfacial agents is preferred Including cement paste.
The present invention provides the preparation methods of sulphate aluminium cement assembled integrated interior wall described in above-mentioned technical proposal Preparation method, comprising:
(1) sulphate aluminium cement, Desulphurization, graphite powder and polypropylene fibre are mixed, obtains admixture;
(2) foaming agent and water-reducing agent are mixed with the admixture in the step (1), water is then added, obtains pouring material;
(3) pouring material that the step (2) obtains successively is poured and is conserved, obtained sulphate aluminium cement foaming and protect Warm plate;
(4) the surface adhesion finish coat of the sulphate aluminium cement foaming insulation board obtained in the step (3) prepares raw material Mixture, sulphate aluminium cement assembled integrated interior wall is obtained after maintenance.
The present invention mixes sulphate aluminium cement, Desulphurization, graphite powder and polypropylene fibre, obtains admixture.The present invention There is no particular/special requirement to the hybrid mode of the sulphate aluminium cement, Desulphurization, graphite powder and polypropylene fibre, using this field Known to technical staff.In embodiments of the present invention, the mixing carries out preferably in cement mortar mixer.
After obtaining admixture, the present invention mixes foaming agent and water-reducing agent with the admixture, and water is then added, is poured Build material.In the present invention, the mixing preferably carries out under agitation, and the speed of the stirring is preferably 80~100r/ Min, more preferably 85~90r/min;The time of the stirring is preferably 1~2min, more preferably 2min.In the present invention, The foaming agent and water-reducing agent are preferably mixed in a manner of solution, to promote point of foaming agent and water-reducing agent in admixture It dissipates;The foaming agent and water-reducing agent be preferably independently configured to mass concentration be 20~30% solution, more preferably 25~ 30%.In the present invention, configuring diminishing agent solution and foaming agent solution with water is preferably sulphate aluminium cement foaming insulation board system The part water of standby raw material.
After obtaining pouring material, the pouring material is successively poured and is conserved by the present invention, obtains sulphate aluminium cement hair Steep insulation board.The present invention is to the specific embodiment poured and pours and does not have particular/special requirement with mold, using basic neck Known to field technique personnel.
After pouring, the present invention will pour gained and pour base and conserve, and obtain sulphate aluminium cement foaming insulation board.At this In invention, the maintenance is preferably room temperature maintenance;The temperature of the room temperature maintenance is preferably 20~25 DEG C, more preferably 22~23 ℃;The time of the room temperature maintenance is preferably 7~14d, more preferably 10~14d;
The present invention conserves under normal temperature conditions, makes foaming agent with slow and uniform resolution of velocity, in board cavity at big Small uniform hole, improves the thermal insulation property of plate.
After obtaining sulphate aluminium cement foaming insulation board, the present invention is on the surface of the sulphate aluminium cement foaming insulation board Adherency finish coat prepares the mixture of raw material, and sulphate aluminium cement assembled integrated interior wall is obtained after maintenance.
The present invention does not have particular/special requirement to the generation type for the mixture that the finish coat prepares raw material, and each component is direct Mixing, stirs evenly.The present invention does not have particular/special requirement to the mode of the adherency, and use is well known to those skilled in the art ?.
In the present invention, the adherency preferably includes interfacial agents with binder;The interfacial agents are preferably cement paste, institute It states cement paste and preferably includes cement and water, the cement is preferably portland cement.In the present invention, the cement paste The ratio of mud is preferably 0.35~0.37, and more preferably 0.35.In the present invention, the cement paste preferably mixes cement and water It stirs.
In the present invention, coated weight of the interfacial agents on insulation board is preferably 18.5~20.3g/m2, more preferably 19.2~19.8g/m2, it is further preferably 19.4~19.6g/m2.The coating method of the interfacial agents preferably includes trowelling, such as can Think artificial trowelling.After coating, preferably the insulation board for coating interfacial agents is dried by the present invention, in order to coat finish coat. The present invention does not have particular/special requirement, including drying or naturally dry to the mode of the drying.In embodiments of the present invention, described dry Dry mode is preferably naturally dry.
In the present invention, the finish coat prepares finish coat described in raw material and above-mentioned technical proposal in the mixture of raw material The component prepared in raw material is consistent with dosage, is not repeated herein.
The finish coat is prepared raw material and mixed by the present invention, obtains desulfurized gypsum slurry;The desulfurized gypsum slurry coagulates Tying the time is preferably 50~75min, more preferably 55~60min;The consistency of the desulfurized gypsum slurry is preferably 90~95mm, More preferably 92~94mm.
The hybrid mode that the present invention prepares raw material to the finish coat does not have particular/special requirement, under agitation by each component It is uniformly mixed.
In the present invention, the mixture that the spray finish layer prepares raw material is desulfurized gypsum slurry.In the present invention, The thickness of the desulfurized gypsum slurry of the mineral wool board single side coating is preferably 10~15mm, more preferably 12~15mm;It is described The coated weight of desulfurized gypsum slurry is preferably 6000~6500g/m2, more preferably 6200~6500g/m2;It is further preferably 6500g/ m2.In the present invention, the coating method of the desulfurized gypsum slurry preferably sprays.
In the present invention, the coating method of the desulfurized gypsum slurry preferably includes:
The desulfurized gypsum slurry is entered spray gun by delivery pipe to spray.In the present invention, the mobile side of the spray gun To preferably from top to bottom, the movement speed of the spray gun is preferably 30~60cm/s, more preferably 40~50cm/s.After spraying, The present invention preferably carries out levelling and press polish to the desulfurized gypsum pulp layer of spraying, levelling preferably be selected from down and upper progress;It is described Press polish uses conventional technical means.After press polish, the present invention conserves the insulation board of spraying desulfurized gypsum layer, described to support Shield preferably carries out under conditions of gravity-flow ventilation.In the present invention, the temperature of the maintenance is preferably 20~25 DEG C, more preferably 20℃;The humidity when maintenance is preferably 40-65%, more preferably 45-55%;The time of the maintenance is preferably 7~ 14d, more preferably 10~14d.
In order to further illustrate the present invention, with reference to the accompanying drawings and examples to a kind of aluminium sulfate water provided by the invention Mud assembled integrated interior wall is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
The preparation of insulation board: according to component described in table 1 provide raw material, by sulphate aluminium cement, Desulphurization, graphite powder and Then it is efficient that hydrogenperoxide steam generator, polycarboxylate system that mass fraction is 25% is added in polypropylene fibre mixing into mixture Water-reducing agent and a certain amount of water after mixing evenly, pour in a mold, after being sealed with polyethylene film, conserve 14d at 25 DEG C, Obtain sulphate aluminium cement foaming insulation board.
42.5 grades of portland cements are mixed with water according to 1:0.35, interfacial agents are obtained, interfacial agents are coated in gained sulphur Two opposites of aluminate cement foaming insulation board, are spontaneously dried, and adhesive layer is formed.
By CaSO4Mass content be 100 parts of desulfurized gypsum of 90%, 15 parts of calcareous synthesizing polyamides, viscosity is 2 parts of the hydroxypropyl methyl cellulose of 100000Pas, 43 parts of water mixing, obtain desulfurized gypsum slurry, by desulfurized gypsum pulp spraying It is coated on the adhesive layer on two opposite of insulation board, quantity for spray 6500g/m2, finish coat is formed after natural drying, obtains aluminium sulfate Cement assembled integrated interior wall, design parameter are shown in Table 2.
Embodiment 2~5
Sulphate aluminium cement foaming insulation board and sulphate aluminium cement assembled integrated are prepared according to the method for embodiment 1 Interior wall, the difference is that dosage of each component is different, referring specifically to table 1;Wherein 3 foaming agent of embodiment is a- alkylene sulfonic acid Sodium, water-reducing agent are Lignins water-reducing agent, and water-reducing agent is Lignins water-reducing agent and the efficient diminishing of polycarboxylate system in embodiment 4 The mixture that agent is formed according to the mass ratio of 1:1, other are the same as embodiment 1.
1 Examples 1 to 5 sulphate aluminium cement foaming insulation board raw material dosage of table and technological parameter
2 sulphate aluminium cement assembled integrated interior wall structure thickness parameter (mm) of table
Embodiment Finish coat Insulating layer Overall thickness
1 15 50 65
2 14 50 64
3 14 48 62
4 13 49 62
5 15 45 60
Performance test and result
Sulphur aluminium obtained by measurement Examples 1 to 5 according to GB/T10294-2008 Technology of Steady State Thermal Resistance of Thermal Insulating Material and in relation to characteristic The heating conduction of acid salt cement foaming insulation board;
According to 1~5 gained sulphate aluminium cement of GB50107-2010 Standard for inspection and assessment of strength of concrete testing example The compressive property of foaming insulation board;
It is sent out according to 1~5 gained sulphate aluminium cement of GB/T 19889.3-2005 Code for measurement of building sound insulation testing example Steep the sound insulation property of insulation board;
According to 1~5 gained aluminium sulfate of GB 22631-2008-T building vertical member impact test testing example The shock resistance of cement foaming insulation board;
According to 1~5 gained aluminium sulfate of GB/T 9978.1-2008 construction material non-combustibility test method testing example The fire resistance of cement foaming insulation board, test result are shown in Table 3.
The performance test results of sulphate aluminium cement foaming insulation board obtained by 3 Examples 1 to 5 of table
By 3 test result of table it is found that sulphate aluminium cement foaming insulation board provided by the invention has lower thermally conductive system Number, illustrates that the thermal insulation property of plate is preferable;In addition, the density of sulphate aluminium cement foaming insulation board is smaller, illustrate that plate has Light advantage, is readily transported;The oise insulation factor of sulphate aluminium cement foaming insulation board is larger, has excellent sound insulation property, energy Reduce the noise of Indoor environment;Fire resistance, shock resistance and compression strength are excellent, further enhance aluminium sulfate water The security performance of mud foaming insulation board.
The density of foamed concrete thermal-insulating material used is generally in 200kg/m at this stage3More than, compared to organic architecture Thermal insulation material, its density is excessively high, thermal and insulating performance is poor, thus can not effectively replace organic architecture thermal insulation material to answer on a large scale With.The present invention is lower than 200kg/m using sulphate aluminium cement cement and Desulphurization as cementitious material preparation density3Foam coagulation Native thermal insulation material (abbreviation low density foam concrete thermal-insulating material) is reducing extrudate density, is improving its thermal and insulating performance Under the premise of, that is, reduce production cost and improve article durable again, and by be added polypropylene fibre improve its poor toughness, Disadvantage easy to crack.Finally making it i.e. has the advantages that non-ignitable, ageing-resistant, dimensionally stable etc. are original, keeps the temperature but also with organic architecture Material low-density, high thermal and insulating performance advantage, can effectively substitute organic architecture thermal insulation material, can be applied to new building In the reducing energy consumption engineering of insulation and existent building.
According to GB/T17146-2015 standard criterion to the vapor of gained sulphate aluminium cement assembled integrated interior wall It is tested through wet current density;
According to GB/T35605-2017 to the feature of environmental protection of sulphate aluminium cement assembled integrated interior wall provided by the invention It can be carried out evaluation;
It is mixed according to solid waste in the regulation detection sulphate aluminium cement assembled integrated wall of GB/T32989-2016 Dosage;
Frost resistance is to carry out repeated freeze-thaw cycle test by slow cooling method, is no more than 25% to meet loss of strength rate simultaneously, Mass loss rate is no more than the 5% maximum freezing-thawing cycles that can bear to indicate.Test result is shown in Table 4.
The performance test results of sulphate aluminium cement assembled integrated interior wall obtained by 4 Examples 1 to 5 of table
By the test result of table 4 it is found that solid gives up in sulphate aluminium cement assembled integrated interior wall provided by the invention Gurry doping reaches 43%, improves the utilization rate of waste;Wall is recyclable to be recycled, and is reduced and is accounted for building waste Ground area and processing cost;And there is insulated wall excellent anti-freezing property, coefficient of softing and town hydrophone to penetrate current density, explanation The water resistance of wall is preferable.
As seen from the above embodiment, lightweight foam material is made in sulphate aluminium cement by the present invention, improves material entirety Thermal insulation property, sound insulation property, transport and installation capability;In addition, plate also has high-intensitive and excellent properties resistant to high temperature, meet The technology technical requirements of inner wall of building.
A kind of sulphate aluminium cement assembled integrated interior wall provided by the invention forms finish coat using desulfurized gypsum, Adjustable indoor humidity, has excellent fire protecting performance and good decorative performance;The utilization of solid waste is realized simultaneously.
The present invention combines finish coat and sulphate aluminium cement foaming insulation board, forms sulphate aluminium cement assembly Formula integration interior wall can make the comprehensive performance of wall entirety more superior, improve compression strength, the insulation ability of wall Ability, waterproof ability with isolation noise, make safety, confidentiality, heat insulating ability and the comfort of building obtain comprehensive promotion.This Outside, sulphate aluminium cement assembled integrated interior wall provided by the invention can make construction material production intensification, effectively improve labor Dynamic production efficiency avoids environmental pollution, and the traditional cast-in-place construction working-noise of elimination is big, dust is more, building waste is more, environmental pollution The drawbacks such as serious.
Although above-described embodiment is made that detailed description to the present invention, it is only a part of the embodiment of the present invention, Rather than whole embodiments, people can also obtain other embodiments under the premise of without creativeness according to the present embodiment, these Embodiment belongs to the scope of the present invention.

Claims (8)

1. a kind of sulphate aluminium cement assembled integrated interior wall, including sulphate aluminium cement foaming insulation board and it is bonded in described The finish coat on two opposite of sulphate aluminium cement foaming insulation board;
The raw material for preparing of the sulphate aluminium cement foaming insulation board includes sulphate aluminium cement, Desulphurization, water-reducing agent, foaming Agent, graphite powder, polypropylene fibre and water;
The raw material for preparing of the finish coat includes desulfurized gypsum;
The sulphate aluminium cement foaming insulation board with a thickness of 45~50mm.
2. sulphate aluminium cement assembled integrated interior wall as described in claim 1, which is characterized in that the aluminium sulfate water Mud foaming insulation board prepares the component that raw material includes following mass parts: 69~81 parts of sulphate aluminium cements, 23~27 parts of desulfurization Ash, 3.7~7.2 parts of foaming agents, 0.6~1.4 part of water-reducing agent, 0.5~1.4 part of graphite powder, 0.1~0.3 part of polypropylene fibre and 40~49 parts of water.
3. sulphate aluminium cement assembled integrated interior wall as claimed in claim 2, which is characterized in that the foaming agent includes Hydrogen peroxide or a- alkylene sodium sulfonate;
The water-reducing agent includes Lignins water-reducing agent or polycarboxylate high-efficiency water-reducing agent;
The Desulphurization includes the component of following mass percentage: SiO241.87~42.51%, Al2O325.37~ 26.43%, CaO10.42~11.56%, SO35.47~6.35%.
4. sulphate aluminium cement assembled integrated interior wall as claimed in any one of claims 1 to 3, which is characterized in that described The single side thickness of finish coat independently is 10~15mm.
5. sulphate aluminium cement assembled integrated interior wall as described in claim 1, which is characterized in that the system of the finish coat Standby raw material includes desulfurized gypsum, retarder, water-retaining agent and water;
The mass ratio of the desulfurized gypsum and water is 1:(0.40~0.45);
The quality of the retarder is the 0.015~0.03% of desulfurized gypsum quality;
The quality of the water-retaining agent is the 0.10~0.20% of desulfurized gypsum quality.
6. sulphate aluminium cement assembled integrated interior wall as described in claim 1, which is characterized in that the insulating layer and decorations Surface layer is bonded by interfacial agents, and the composition of the interfacial agents includes cement paste.
7. the preparation method of any one of the claim 1~6 sulphate aluminium cement assembled integrated interior wall, including walk as follows It is rapid:
(1) sulphate aluminium cement, Desulphurization, graphite powder and polypropylene fibre are mixed, obtains admixture;
(2) foaming agent and water-reducing agent are mixed with the admixture in the step (1), water is then added, obtains pouring material;
(3) pouring material that the step (2) obtains successively is poured and is conserved, obtain sulphate aluminium cement foamed heat insulating Plate;
(4) the surface adhesion finish coat of the sulphate aluminium cement foaming insulation board obtained in the step (3) prepares the mixed of raw material Object is closed, sulphate aluminium cement assembled integrated interior wall is obtained after maintenance.
8. preparation method as claimed in claim 7, which is characterized in that maintenance is that room temperature conserves in the step (3), described normal The temperature of temperature maintenance is 20~25 DEG C, and the time of the room temperature maintenance is 7~14d.
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