JPH02167398A - 金属材料の冷間塑性加工用水系潤滑処理液および処理方法 - Google Patents

金属材料の冷間塑性加工用水系潤滑処理液および処理方法

Info

Publication number
JPH02167398A
JPH02167398A JP63167849A JP16784988A JPH02167398A JP H02167398 A JPH02167398 A JP H02167398A JP 63167849 A JP63167849 A JP 63167849A JP 16784988 A JP16784988 A JP 16784988A JP H02167398 A JPH02167398 A JP H02167398A
Authority
JP
Japan
Prior art keywords
water
treatment liquid
solid lubricant
metal material
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63167849A
Other languages
English (en)
Other versions
JP2583285B2 (ja
Inventor
Noriyuki Fujii
敬之 藤井
Tokuo Shirai
白井　徳雄
Takanori Mizutani
水谷　高規
Yoshio Nagaei
永栄　義勇
Koji Totsugi
戸次　幸二
Yasuo Tanizawa
谷沢　康雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Parkerizing Co Ltd
Denso Corp
Original Assignee
Nihon Parkerizing Co Ltd
NipponDenso Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Parkerizing Co Ltd, NipponDenso Co Ltd filed Critical Nihon Parkerizing Co Ltd
Priority to JP63167849A priority Critical patent/JP2583285B2/ja
Priority to DE3922464A priority patent/DE3922464C2/de
Publication of JPH02167398A publication Critical patent/JPH02167398A/ja
Priority to US07/564,461 priority patent/US5116521A/en
Application granted granted Critical
Publication of JP2583285B2 publication Critical patent/JP2583285B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/24—Compounds containing phosphorus, arsenic or antimony
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
    • C10M135/10—Sulfonic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/28—Polyoxyalkylenes of alkylene oxides containing 2 carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/36—Polyoxyalkylenes etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/38—Polyoxyalkylenes esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/40—Polysaccharides, e.g. cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/18—Complexes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/003—Inorganic compounds or elements as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/0403—Elements used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/043—Sulfur; Selenenium; Tellurium
    • C10M2201/0433—Sulfur; Selenenium; Tellurium used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/105—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/16—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/09—Metal enolates, i.e. keto-enol metal complexes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/042—Sulfate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/09—Complexes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2080/00—Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は金属材料の冷間塑性加工用水系潤滑処理液およ
び処理方法に関するものである。
更に詳しく述べるならば、本発明は、鋼材・ステンレス
鋼材・チタン系金属材・銅系金属材・アルミ系金属材な
どの金属材料を冷間塑性加工（鍛造・伸管・伸線など）
するために用いられる水系潤滑処理液（以下水系潤滑処
理液と略称する）及び、化成皮膜を有する金属材料を、
冷間塑性加工するために水系潤滑処理液で処理する方法
に関するものである。
〔従来の技術〕
金属材料の冷間塑性加工のための従来の水系潤滑処理液
としては、例えば二硫化モリブデン又はグラファイトな
どの固体潤滑剤と、無段バインダーおよび有機バインダ
ーから選ばれた一種又は−種以上と、界面活性剤とを含
むものが知られている。また比較的に軽度の冷間塑性加
工の際は、油気のない金属材料の表面に直接水系潤滑処
理液を接触させ、次いで乾燥して固体潤滑皮膜を形成さ
せる方法が知られており、強加工度の冷間塑性加工の際
は、金属材料の表面に化成皮膜を形成させた後、その表
面を水系潤滑処理液に接触させ、乾燥するか、或は固体
潤滑粉末を付着させ化成皮膜上に固体潤滑皮膜を形成さ
せる方法が採用されている。しかし、固体潤滑剤を粉末
状で使用する場合、その粉層により作業環境が悪化する
等の問題があり、作業性を考えた場合、これを水系処理
液として使用するのが最も好ましい。しかし、既存の水
系固体潤滑処理液は、処理後放置しておくと被処理金属
材料に錆が発生する等の欠点がある。
上記いずれの場合も、従来の処理剤は潤滑性能が安定せ
ず、かつ不十分であり、しばしば焼き付きかじりなどの
問題を起こすという問題点がある。
〔発明が解決しようとする課題〕
本発明は、従来の金属材料冷間塑性加工用水系潤滑処理
液および処理方法の問題点、すなわち金属材料に錆を発
生することがなく、作業性が良好で、金属材料との密着
性が良好で、潤滑性能の高い水系潤滑処理液、および、
このような水系潤滑処理液を用いる処理方法の提供を課
題とするものである。
〔課題を解決するための手段〕
本発明の金属材料の冷間塑性加工用水系潤滑処理液は、
５０〜４００　ｇ　／　１の固体潤滑剤と、ｌ〜４０ｇ
／ｎの界面活性剤と、チタン濃度として１０ｐｐｍ以上
のコロイド状チタン化合物と、水とを含むことを特徴と
するものである。
本発明の水系潤滑処理液は、上記成分に加えて、更に５
〜１５０ｇ／Ｉ！の無機バインダーおよび有機バインダ
ーから選ばれた少なくとも１種を含んでいてもよい。
また、本発明の、金属材料の冷間塑性加工のための水系
潤滑処理方法は、化成皮膜により被覆された金属材料の
表面を、上記本発明の水系潤滑処理液のいづれかにより
処理することを特徴とするものである。
本発明の水系潤滑処理液に用いられる固体潤滑剤は、例
えば、二硫化モリブデン、グラファイト、二硫化タング
ステン、ふっ化黒釦、ちっ化はう素、及びタルクなどか
ら選ばれた、少なくとも一種類の化合物からなるもので
ある。
処理液中の固体潤滑剤の含有量は、５０〜４００　ｇ　
／ｌであり、１００〜１５０ｇ／Ａであることが好まし
い。この固体潤滑剤の含有量が５０　ｇ　／　１未満の
ときは、金属材料表面における固体潤滑皮膜の形成が不
充分となり易く、逆に４００　ｇ　／　ｎを越えて添加
しても、潤滑効果が飽和し性能向上が期待出来ず、かつ
水系潤滑処理液のコストが高くなるという不都合を生ず
る。
本発明の水系潤滑処理液において、界面活性剤が、固体
潤滑剤を水に分散させるために加えられるが、その種類
に格別の限定はない。一般に非イオン系界面活性剤とし
てポリオキシエチレンアルキルエーテル類、ポリオキシ
エチレンアルキルフェニルエーテル類、ポリオキシエチ
レンアルキルエステル類、ポリオキシエチレンソルビタ
ンアルキルエステル類等が用いられる。陰イオン系界面
活性剤としては、脂肪酸塩、硫酸エステル塩、スルホン
酸塩、りん酸エステル塩、ジチオりん酸エステル塩など
が挙げられる。また陽イオン系界面活性剤としては、脂
肪族ア【ン塩、第四級アンモニウム塩等が挙げられる。
また、両性界面活性剤としては、ア〔）酸型及びヘタイ
ン型のカルボン酸塩、硫酸エステル塩、スルホン酸塩及
びりん酸エステル塩などが挙げられる。
本発明の水系潤滑処理液中における界面活性剤の含有量
は１〜４０ｇ／ｆ、好ましくは５〜１０ｇ／Ｅであり、
この含有量を固体潤滑剤の含有量に応して１曽滅させる
ことが好ましい。界面活性剤の含有量がＩｇ／Ａ未満の
場合、処理液中における固体潤滑剤の温潤が不十分にな
り易く、また、４０ｇ／ｌより大量に用いられても、そ
の効果が著るしく向上することはない。
本発明の水系潤滑処理液に用いられるコロイト状チタン
化合物としては、例えば硫酸とチタンの化合物又は、り
ん酸とチタンの化合物等を苛性ソーダ等で中和して得ら
れた白濁液が挙げられる。
コロイド状チタンの、水系潤滑処理液中の含有量は、チ
タン濃度として１０ｐｐｍ以上であり、５０ｐｐｍ以上
であることが好ましい。コロイド状チタン化合物の含有
率が、１０ｐｐｍ未満のときは、コロイド状チタン化合
物添加による潤滑性能の向上効果が不明瞭になる。従っ
てコロイド状チタン化合物の含有率を１０ｐｐｍ以上に
することにより、得られる水系潤滑処理液の潤滑性向上
効果は、コロイド状チタン化合物の含有率の増大ととも
に増大する。従って、本発明の水系潤滑処理液における
コロイド状チタン化合物の含有率に格別の上限値はなく
、水系潤滑処理液の調製が可能な限り高含有率とするこ
とができる。
本発明の水系潤滑処理液に消泡剤および／又は防錆添加
剤などを添加して使用してもよい。
本発明の水系潤滑処理液は、上記成分に加えて、バイン
ダーを含んでいてもよい。このバインダーは、無機バイ
ンダーおよび有機バインダーから選ばれた少なくとも１
種からなるものである。このようなバインダーの添加に
より水系潤滑処理液の性能を更に向上させることができ
る。
無機バインダーは、本発明に有効である限り、その種類
に格別の限定はないが下記化合物を包含するものである
。
ａ、はう酸塩 ＨＢ（ｈ・ＨＪ（ｈ・１１．Ｂ、０．・ＨＪ４０ｔ・１
ｌＢｓＯａ・ＨＪｂＯ＋。・Ｈ２ＢＢＯ０などのアルカ
リ金属塩、アルカリ土類金属塩及びアンモニウム塩 す、りん酸塩 ＩＩ　Ｉ　Ｐ　Ｏａ・１ｌＰＯ３・Ｈ４Ｆ　２０６・１
１ｆｆＰ（ｈ・ｕ４ｐｚｏｓ・ＨＰＯ□・）ｈＰＯ□・
ＨａＰ３０ｑ及びポリりん酸、例えばＨ４Ｐ２Ｏ，・）
ｌ’５ｈ０１０　　・）Ｉｓ、Ｐ４０＋３などの酸のア
ルカリ金属塩、アルカリ土類金属塩及びアンモニウム塩
Ｃ１けい酸塩 一般弐Ｍｈｏ・ｘＳｉＯ□の塩、 〔但し、Ｍはアルカリ金属またはアルカリ土類金属を表
わし、Ｘは１〜５の正の整数を表わす。〕有機バインダ
ーも、それが本発明に有効である限り格別の限定はなく
、既知のものから選択することができるが、水溶性高分
子化合物を用いることが好ましい。このような水溶性高
分子化合物としては、デンプン・海藻・植物粘質物・動
物性タンパク・発酵粘質などのような天然高分子材料ミ
、デンプン質材料、およびセルロース材料などから得ら
れる半合成高分子材料、およびＰＶＰ、　　ＰＥＧＰＶ
Ａなどの合成高分子材料などを用いることができる。
本発明の水系潤滑処理液中における上記バインダー成分
の含有量は、５〜１５０ｇ／／であり、１０〜５０ｇ／
ｌであることが好ましく、一般に固体潤滑剤の含有量に
応して設定される。バインダー成分の含有量が５ｇ／１
未満のときは、固体潤滑皮膜の金属材料面に対する結合
力が不十分であり、また、それが１５０ｇ／６より多く
しても、固体潤滑皮膜と金属材料面との結合力が更に強
くなるわけではなく、却って、水系潤滑処理液の粘度が
過度に高くなり、そのため金属材料表面に対する固体潤
滑皮膜の付着量が過多となって型詰まりの原因になるな
どの不都合を生ずる。
本発明の上記水系潤滑処理液は、従来の方法によって、
所定量の上記成分を、水中に分散、溶解することによっ
て１用型することができる。
本発明において、化成皮膜により被覆されている金属材
料表面が、本発明の上述の水系潤滑処理）仮により処理
される。
金属材料上の化成皮膜の種灯１に特に制限はないが、一
般に、金属材料の種類に応して従来慣用の化成皮膜、例
えばりん酸亜鉛皮膜・しゅう酸鉄皮膜・亜酸化銅皮膜・
ふっ化アルミニウム皮膜・ふっ化チタン皮膜等を挙げる
ことができる。
本発明の水系潤滑処理ｆ夜は、含有成分が比較的に低濃
度の場合には、そのまま処理液として使用することがで
きるが、高濃度の場合には金属素材の種類、冷間塑性加
工の種類・加工度などに応して、そのまま使用するか、
又はこれを適量の水にて希釈して使用すればよい。本発
明の水系潤滑処理液は、通常漫消法により金属材料に適
用されるが、その際は常温〜８０℃の任意の温度に維持
される。水系潤滑処理液の温度を上げれば、金属材料の
蓄熱により表面に付着した潤滑剤の乾燥性が向上するの
で、−船釣には加熱して使用されるが、その際は水系潤
滑処理液の粘度管理が必要であり、このため、水系潤滑
処理液の補給に加えて適性濃度に維持するための水分の
補給が必要である。
本発明の水系潤滑処理液による潤滑処理工程は一般に下
記のように行われる。これらの工程、条件は金属素材の
種類・表面状態、冷間塑性加工の種類・加工強度などに
応して選択される。
■脱脂−水洗−本発明水系潤滑処理一乾燥■脱脂−水洗
一酸洗一水洗一木発明水系潤滑処理−乾燥 （酸洗は錆・スケールの除去のために行う）■脱脂−水
洗−酸洗一水洗一化成処理一水洗一本発明水系潤滑処理
一乾燥 ■脱脂−水洗−化成処理一水洗一本発明水系潤滑処理一
乾燥 （但し、脱脂工程は必要のある場合にのみ行う）上記の
水系潤滑処理工程において、金属材料の表面又はその化
成皮膜表面に固体潤滑皮膜が形成され、その潤滑皮膜中
のコロイド状チタン化合物微粒子と、固体潤滑剤の相乗
作用効果によって、優れた潤滑効果を発渾するのである
。また、錆発生原因成分へのコロイド状チタン化合物の
吸着により、金属表面の防錆性を高める作用効果をも合
わせ有するものである。
〔実施例〕
以下に、本発明の水系潤滑処理液および処理方法を、下
記実施例により更に説明する。
１〜１２および　′　ｌ〜８ 実施例１〜１２および比較例１〜８の各々において、第
１表に示す金属材料について、下記工程の処理を施した
。
脱脂−水洗一酸洗一水洗一（化成処理）−水系潤滑処理
一乾燥 脱脂工程においては、金属材料に、２０ｇ／ｎのファイ
ンクリーナー４３６０　（脱脂剤の商標、日本パー力ラ
イジング社製）を含む処理液中で、７０℃、１０分間の
処理を施した。
各水洗工程においては、金属材料に、水道水流水により
Ｒ，Ｔ２Ｏ秒の処理を施した。
酸洗および化成処理工程においては、第１表記載の処理
を施した。
潤滑処理工程においては、第２表記載組成を有する潤滑
剤を用い、第２表記載の条件で処理を施した。
乾燥工程は、熱風乾燥器を用い、１２０℃、３０分間の
条件で実施した。
以下余色 第１表、酸洗及び化成条件 注： ＊１朝日化学■製、商標：イビソト７００Ａ＊２日本パ
ー力ライジング＋４１製、製品内容を概説すると りん酸亜鉛系皮膜化成剤 りん酸亜鉛系皮膜化戒促進剤 号剤−しゅう酸塩皮膜化成主剤 号剤−しゅう酸塩皮膜化成助剤 しゅう酸塩皮膜化成促進剤 −ふっ化物皮膜化成剤 ＰＢ−１８１Ｘ Ｃ−１３１ ＦＢ−＾Ｉ ＦＢ−八２ ＾Ｃ−１６ ＮＥＴ−３８５１ 以下余白 各実施例および比較例において処理された金属材料の潤
滑性能を、後方穿孔試験（ｍ材）および伸線試験（チタ
ン材〉により評価し、またその防錆性を恒温恒湿発錆試
験により評価した。
上記各試験の使用試験機、試験条件、および評価方法を
第３，４および５表に示す。
第３表、後方穿孔試験 注：＊１ ・・・パンチ加工品のカップ内壁面にたてすし状のかじ
り疵が発生しないで加工 できる最大穿孔深さ、この数値が大き い程潤滑性が良好である。
第５表。
恒温恒湿発錆試験 各実施例および比較例の上記試験結果を、第６゜７およ
び８表に示す。
皿子余白 第４表。
イ申線雪式験 第６表。
炭素鋼後方穿孔試験 第７表、ステンレス鋼後方穿孔試験 第８表、チタン材の伸線試験 第６表の炭素鋼冷間鍛造試験すなわち後方穿孔試験の結
果から明らかなように、コロイド状チタン化合物を使用
した実施例１〜７は、それを使用しない比較例１〜４と
比較して、著しく潤滑性能が向上している。実施例６と
比較例１の比較では、従来の水系潤滑処理液よりも本発
明の水系潤滑処理液が優れており、軽度の加工には十分
耐え得ることが解る。更に実施例２と比較例２〜３の比
較において、バインダーを含む、本発明の水系潤滑処理
液は、化成皮膜処理を施さなくても、従来使用されてい
る化成皮膜処理と水系潤滑処理液処理により得られるも
のと同等の性能を示した。また、本発明方法の実施例１
〜５は、比較例１〜４と比較して数段優れており、従来
なし得ないとされていた高加工度の冷間鍛造を可能とす
るものであった。
また第６表から明らかなように、本発明の実施例におい
て得られた製品は、５０℃、９０％湿度、２４時間の恒
温恒湿発錆試験において、いずれの場合も錆発生がなく
、比較例では従来品が錆発生したことと比較して、良好
な防錆性を示した。
第７表のステンレス鋼冷間鍛造試験結果においても、本
発明実施例の製品は比較例の従来製品と比較して良好穿
孔深さが深く、この結果は本発明の水系潤滑処理ｌ＆が
優れた潤滑効果を有することを示した。
第８表のチタン材の伸線試験結果でも、本発明の水系潤
滑処理液を施した実施例１０〜１２の製品は、５パス実
施においても疵の発生が見られず、本発明の製品が、５
パス目で疵が発生した比較例７〜８の製品と比較して、
斥間塑性加工用潤滑剤としてより優れた性能を有してい
ることを示した。
〔発明の効果〕
本発明の金属材料冷間塑性加工用水系潤滑処理液および
処理方法は、金属材料に対し、焼き付き発生なしに強加
工度の冷間塑性加工に十分耐え得る潤滑性を付与するこ
とができ、作業性にすぐれ、かつ高い防錆性を与えるこ
とができるものである。

Claims (1)

  1. 【特許請求の範囲】 １、５０〜４００ｇ／ｌの固体潤滑剤と、１〜４０ｇ／
    ｌの界面活性剤と、チタン濃度として１０ｐｐｍ以上の
    コロイド状チタン化合物と、水とを含む、金属材料の冷
    間塑性加工用水系潤滑処理液。 ２、５０〜４００ｇ／ｌの固体潤滑剤と、１〜４０ｇ／
    ｌの界面活性剤と、５〜１５０ｇ／ｌの無機バインダー
    および有機バインダーから選ばれた少なくとも１種と、
    チタン濃度として１０ｐｐｍ以上のコロイド状チタン化
    合物と、水とを含む、金属材料の冷間塑性加工用水系潤
    滑処理液。 ３、化成皮膜により被覆された金属材料表面を、請求項
    １または請求項２記載の水系潤滑処理液によって処理す
    る、金属材料の冷間塑性加工のための水系潤滑処理方法
    。
JP63167849A 1988-07-07 1988-07-07 金属材料の冷間塑性加工用水系潤滑処理液および処理方法 Expired - Lifetime JP2583285B2 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP63167849A JP2583285B2 (ja) 1988-07-07 1988-07-07 金属材料の冷間塑性加工用水系潤滑処理液および処理方法
DE3922464A DE3922464C2 (de) 1988-07-07 1989-07-07 Wäßrige Schmierbehandlungsflüssigkeit und Verfahren zur kalten, plastischen Bearbeitung metallischer Materialien
US07/564,461 US5116521A (en) 1988-07-07 1990-08-08 Aqueous lubrication treatment liquid and method of cold plastic working metallic materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63167849A JP2583285B2 (ja) 1988-07-07 1988-07-07 金属材料の冷間塑性加工用水系潤滑処理液および処理方法

Publications (2)

Publication Number Publication Date
JPH02167398A true JPH02167398A (ja) 1990-06-27
JP2583285B2 JP2583285B2 (ja) 1997-02-19

Family

ID=15857230

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63167849A Expired - Lifetime JP2583285B2 (ja) 1988-07-07 1988-07-07 金属材料の冷間塑性加工用水系潤滑処理液および処理方法

Country Status (2)

Country Link
JP (1) JP2583285B2 (ja)
DE (1) DE3922464C2 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH061994A (ja) * 1992-06-18 1994-01-11 Daido Steel Co Ltd 冷温間鍛造加工用潤滑処理方法
KR100714143B1 (ko) * 2004-07-19 2007-05-02 에프톤 케미칼 코포레이션 개선된 내마모성을 갖는 윤활 금속 부품, 내마모 윤활제 조성물 및 윤활 방법
CN107384567A (zh) * 2017-08-15 2017-11-24 肥西县通力机械有限公司 一种铜锌合金冷冲压用高性能水基润滑油

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0747756B2 (ja) * 1989-08-09 1995-05-24 日本電装株式会社 金属の冷間塑性加工用水系潤滑処理液
JPH0433998A (ja) * 1990-05-30 1992-02-05 Nippon Parkerizing Co Ltd 鋼管の潤滑処理法
CN100369687C (zh) * 2006-04-17 2008-02-20 江苏华阳金属管件有限公司 用于冷挤压成型金属制品的表面涂层

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5429866A (en) * 1977-08-10 1979-03-06 Daikin Ind Ltd Lubricant composition for use of drawing of steel material

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4808245A (en) * 1986-11-10 1989-02-28 Nihon Parkerizing Co., Ltd. Method for drawing iron and steel wire rod

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5429866A (en) * 1977-08-10 1979-03-06 Daikin Ind Ltd Lubricant composition for use of drawing of steel material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH061994A (ja) * 1992-06-18 1994-01-11 Daido Steel Co Ltd 冷温間鍛造加工用潤滑処理方法
KR100714143B1 (ko) * 2004-07-19 2007-05-02 에프톤 케미칼 코포레이션 개선된 내마모성을 갖는 윤활 금속 부품, 내마모 윤활제 조성물 및 윤활 방법
CN107384567A (zh) * 2017-08-15 2017-11-24 肥西县通力机械有限公司 一种铜锌合金冷冲压用高性能水基润滑油
CN107384567B (zh) * 2017-08-15 2020-12-04 广州杜朗介质科技有限公司 一种铜锌合金冷冲压用高性能水基润滑油

Also Published As

Publication number Publication date
JP2583285B2 (ja) 1997-02-19
DE3922464A1 (de) 1990-01-11
DE3922464C2 (de) 1997-05-28

Similar Documents

Publication Publication Date Title
CA2078117C (en) Surface conditioner for formed metal surfaces
US5030323A (en) Surface conditioner for formed metal surfaces
US5116521A (en) Aqueous lubrication treatment liquid and method of cold plastic working metallic materials
EP0412788B1 (en) Lubrication method for cold plastic working of metallic materials
CA1110611A (en) Preparation of metals for cold forming
US4088585A (en) Lubricant containing MoS2, lubricating process, and lubricated workpiece
JP2003055682A (ja) 保護皮膜処理剤および保護皮膜を有する金属材料
EP2220200B1 (en) Dry-film, anti-corrosive cold forming lubricant
CA2040859C (en) Activating agent for use in phosphating processes
AU604395B2 (en) Process for phosphating metal surfaces
JPH02167398A (ja) 金属材料の冷間塑性加工用水系潤滑処理液および処理方法
CA1240908A (en) Compositions and methods for removing sealant compositions
JPS638489A (ja) 金属の冷間加工用潤滑剤
KR0144646B1 (ko) 금속냉간가공용 복합피막형성을 위한 금속표면처리화학조성물 및 복합피막의 형성방법
US6376433B1 (en) Process and product for lubricating metal prior to cold forming
CN107523404B (zh) 水基防锈金属冷锻润滑剂及其制备方法
KR20180044997A (ko) 내식성 및 가공 후의 외관이 우수한 강선재
WO2000060034A1 (en) Process for cleaning a metal container providing enhanced mobility
JPS61183394A (ja) 冷間塑性加工用潤滑剤
JP3217072B2 (ja) 硫黄を配位原子とする水系潤滑剤とその使用方法
JPS63277298A (ja) 塑性加工用水溶性潤滑剤
CA1135250A (en) Metal coating process and compositions
CN108930039A (zh) 一种适用于冷硬钢卷的防锈方法
JPS6254157B2 (ja)
JPS61159494A (ja) 防錆性を有する潤滑剤組成物

Legal Events

Date Code Title Description
R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20071121

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081121

Year of fee payment: 12

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081121

Year of fee payment: 12