JPH02165001A - Block gauge - Google Patents

Block gauge

Info

Publication number
JPH02165001A
JPH02165001A JP63321275A JP32127588A JPH02165001A JP H02165001 A JPH02165001 A JP H02165001A JP 63321275 A JP63321275 A JP 63321275A JP 32127588 A JP32127588 A JP 32127588A JP H02165001 A JPH02165001 A JP H02165001A
Authority
JP
Japan
Prior art keywords
oxide
weight
gauge
rectangular parallelepiped
block gauge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63321275A
Other languages
Japanese (ja)
Other versions
JPH0468561B2 (en
Inventor
Tetsuo Kosuda
小須田 哲雄
Yoshiro Kamata
鎌田 芳郎
Kinji Takizawa
滝沢 欣司
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitutoyo Corp
Mitsutoyo Kiko Co Ltd
Original Assignee
Mitutoyo Corp
Mitsutoyo Kiko Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitutoyo Corp, Mitsutoyo Kiko Co Ltd filed Critical Mitutoyo Corp
Priority to JP63321275A priority Critical patent/JPH02165001A/en
Priority to GB9001710A priority patent/GB2240396B/en
Priority to DE4002986A priority patent/DE4002986C2/en
Publication of JPH02165001A publication Critical patent/JPH02165001A/en
Priority to US07/907,047 priority patent/US5272120A/en
Publication of JPH0468561B2 publication Critical patent/JPH0468561B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B3/00Measuring instruments characterised by the use of mechanical techniques
    • G01B3/30Bars, blocks, or strips in which the distance between a pair of faces is fixed, although it may be preadjustable, e.g. end measure, feeler strip

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Length-Measuring Instruments Using Mechanical Means (AREA)
  • Laser Beam Processing (AREA)

Abstract

PURPOSE:To improve resistance to abrasion and fragility without dimensional errors by constituting a gauge through sintering of Zr oxide which is a main component, 3-7 weight % of Y oxide and 0-20 weight % of Al oxide, and marking said gauge through irradiation of a laser light in an ambience of an inert gas. CONSTITUTION:Zr oxide which is a main component, 3-7 weight % of Y oxide and 0-20 weight % of Al oxide are respectively crushed to a predetermined particle size, then mixed and stirred to be uniform. Thereafter, the uniform raw material is pressed, heated and sintered. The obtained ceramic body of Zr (in a lump) is cut by a diamond cutter to be a rectangular parallelepiped slightly larger than a predetermined size. The rectangular parallelepiped is ground so that each face has its predetermined flatness, parallelism of confronting faces is secured, and moreover nominal dimension becomes a given value, which is further shaped into a block gauge. Laser beams are cast by a YAG laser to the surface of the rectangular parallelepiped where a mark is to be patterned while N2 gas is blown with a given angle. The nominal dimension, product number and trade mark are marked.

Description

【発明の詳細な説明】 [産業上の利用分野] この発明は、長さ寸法を精密に測定する際に基準器とし
て用いるブロックゲージに関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a block gauge used as a standard when measuring a length dimension precisely.

[従来の技術] 従来、ブロックゲージとして、金属材料からなるものが
知られている。
[Prior Art] Conventionally, block gauges made of metal materials are known.

[発明が解決しようとする課題] 金属材料からなるブロックゲージでは、耐蝕性が完全と
いえず腐蝕が生じ易い。このため、例えば保管は完全な
防蝕環境下でおこなう必要があったり、取扱いは常に防
蝕用手袋を着用しておこなうといったように、取扱いが
極めて煩雑であるという問題がある。又、腐蝕が生じる
と、寸法を示すための面の表面状態が損われて正しい寸
法が確保できなかったり、他のブロックゲージに密着さ
せる、いわゆるリンギングが得られないという問題が生
じる。
[Problems to be Solved by the Invention] Block gauges made of metal materials are not completely corrosion resistant and are prone to corrosion. For this reason, there is a problem that handling is extremely complicated, for example, storage must be carried out in a completely corrosion-proof environment, and corrosion-proof gloves must be worn at all times when handling. Further, when corrosion occurs, the surface condition of the surface for indicating dimensions is damaged, resulting in problems such as not being able to secure correct dimensions, or not being able to achieve so-called ringing, which means that the gauge cannot be brought into close contact with other block gauges.

尚、耐蝕性を増加させるために、例えばクロムCrによ
って鍍金するということが考えられる。
Additionally, in order to increase the corrosion resistance, it is conceivable to plate it with chromium Cr, for example.

しかし、鍍金を施したブロックゲージでは製造工程が増
加し、且つ所定の呼び寸法を得ることがむずかしく、製
造が煩雑になるという問題がある。
However, the plated block gauge has the problem that the number of manufacturing steps is increased, and it is difficult to obtain a predetermined nominal size, making the manufacturing process complicated.

この発明は上記の事情に鑑みてなされたものであり、ブ
ロックゲージが耐蝕性の材料を用いて形成され、加えて
ブロックゲージが有する、材料の均質性、耐摩耗性、取
扱のし易さ、呼び寸法等のマーキング等の要件を全て満
たすべくなされたものである。
This invention was made in view of the above circumstances, and the block gauge is formed using a corrosion-resistant material, and in addition, the block gauge has material homogeneity, wear resistance, ease of handling, This was done to meet all the requirements for marking such as nominal dimensions.

[課題を解決するための手段及び作用]かくしてこの発
明の発明者は、まず耐蝕性の問題を解決するために複数
の耐蝕性材料の検討をおこない、且つその中からブロッ
クゲージの全ての要件を満たし得るものを選択し、更に
その選択した耐蝕性材料に適合した加工方法を発明し、
その加工を施すことに基づいて完成に到達したものであ
る。
[Means and effects for solving the problem] Thus, the inventor of this invention first studied a plurality of corrosion-resistant materials in order to solve the problem of corrosion resistance, and selected from among them all the requirements for a block gauge. We selected the material that satisfies the requirements and invented a processing method that is suitable for the selected corrosion-resistant material.
Completion was achieved based on that processing.

発明の詳細な構成は、主成分である酸化ジルコニウムと
、3〜7重量%の酸化イツトリウム及び0〜20重量%
の酸化アルミニウムとを焼結してなるセラミックスから
形成され、且つそのセラミックスのマークを施すべき部
位を、不活性ガス雰囲気内に置く状態又は減圧の状態に
保ち、前記マークを施すべき部位にレーザ光を照射する
ことでマーキングされてなるブロックゲージである。
The detailed composition of the invention includes zirconium oxide as the main component, 3 to 7% by weight of yttrium oxide, and 0 to 20% by weight.
The part of the ceramic to be marked is kept in an inert gas atmosphere or under reduced pressure, and a laser beam is applied to the part to be marked. It is a block gauge that is marked by irradiating it.

つまり、発明者は、耐蝕性材料であって材料が均質性を
有するということからセラミックスを選択した。ここで
更に、ブロックゲージを使用する′現場の周囲に対して
コントラストがあって見やすいということから白色もし
くは薄黄色であって、且つ耐摩耗性が十分に確保され、
更に比較測定の対象が主に鋼であることより鋼の熱膨張
係数とほぼ等しい熱膨張係数を有し、加えて材料の均質
性が緻密な組織の均質性であり、又焼結後において・も
体積変化が生じないことを満たすセラミックスとして、
酸化ジルコニュウムZrO*を主成分とし、この主成分
の7.rOtに対する重量比が3〜7重量%の酸化イツ
トリウムY 20 g及び0〜20重量%の酸化アルミ
ニウムAl201の助剤とを焼結してなるジルコニアセ
ラミックス体を材料とした。又、成分を上記のものとす
ることにより、得られるジルコニアセラミックスは立方
晶と単斜晶との混合相の状態、いわゆる部分安定化状態
となり、高い強度と共に高い靭性が得られ、耐脆性が確
保されたものとなっている。
That is, the inventor selected ceramics because it is a corrosion-resistant material and has homogeneity. Furthermore, when using a block gauge, it is white or light yellow because it contrasts with the surroundings of the site and is easy to see, and it has sufficient wear resistance.
Furthermore, since the object of comparison measurement is mainly steel, it has a thermal expansion coefficient almost equal to that of steel, and in addition, the homogeneity of the material is the homogeneity of a dense structure, and after sintering, As a ceramic that satisfies the fact that no volume change occurs,
Zirconium oxide ZrO* is the main component, and 7. A zirconia ceramic body was used as a material by sintering 20 g of yttrium oxide Y in a weight ratio of 3 to 7% by weight to rOt and an auxiliary agent of aluminum oxide Al201 in a weight ratio of 0 to 20% by weight. In addition, by using the above ingredients, the resulting zirconia ceramic becomes a mixed phase of cubic and monoclinic crystals, a so-called partially stabilized state, which provides high strength and toughness, ensuring brittle resistance. It has become something that has been done.

又、呼び寸法、商品番号、商標等といったブロックゲー
ジに施すべきマークは、上記ジルコニアセラミックス体
が白色もしくは薄クリーム色であり、この色に対して高
いコントラストが得られる黒色が好ましく、且つリンギ
ングができるためにはリンギングする面と等しい高さで
もしくは低い高さで形成されることが必要である。然る
に、発明者はマークの色彩及びリンギングする面に対す
るマークの高さの問題を、マークを施すべき部位を不活
性ガス雰囲気内に置く状態又は減圧の状態に保ちレーザ
光を照射することによって解決した。
In addition, the marks to be applied to the block gauge, such as nominal dimensions, product numbers, trademarks, etc., are preferably black because the zirconia ceramic body is white or light cream color, and provides a high contrast with this color, and also allows for ringing. In order to achieve this, it is necessary to form the ringing surface at the same height or at a lower height than the ringing surface. However, the inventor solved the problem of the color of the mark and the height of the mark with respect to the ringing surface by placing the part to be marked in an inert gas atmosphere or under reduced pressure and irradiating it with laser light. .

尚、ここで不活性ガスとは、好適なものとして窒素ガス
Nt、ヘリウムHe、アルゴンAr、又はこれらの混合
ガスが挙げられる。又、不活性ガスによる雰囲気とは具
体的に、前記不活性ガスをジルコニアセラミックスの被
マーキング面に吹きつける、もしくは密封チェンバ内に
ジルコニアセラミックスを入れてから密封チェンバ内に
上記不活性ガスを流込むことによって得られる。
Here, the inert gas is preferably nitrogen gas Nt, helium He, argon Ar, or a mixed gas thereof. Furthermore, the inert gas atmosphere specifically refers to spraying the inert gas onto the marking surface of the zirconia ceramics, or placing the zirconia ceramics in a sealed chamber and then flowing the inert gas into the sealed chamber. obtained by

又、上記の減圧の状態とは、気圧が5〜46mmHgで
あることを指す。
Moreover, the above-mentioned state of reduced pressure refers to an atmospheric pressure of 5 to 46 mmHg.

更に、レーザ光の照射とは具体的に、YAGレーザ発生
装置をQスイッチモードで使用することが挙げられる。
Furthermore, irradiation with laser light specifically includes using a YAG laser generator in Q-switch mode.

もちろん、CO2レーザ発生装置を用いたレーザ光の照
射であってもよい。
Of course, laser light irradiation using a CO2 laser generator may also be used.

[実施例] この発明を、以下に詳述する実施例によって説明する。[Example] The invention will be explained by the examples detailed below.

しかし、この実施例によりこの発明が限定されるもので
はない。
However, the invention is not limited to this example.

主成分としてのZr0zと、助剤としてのY t Os
及びAl2O3を所定粒径となるまで破砕し、次にそれ
らを混合し攪拌して均一な状態とする。
Zr0z as main component and Y t Os as auxiliary agent
and Al2O3 are crushed to a predetermined particle size, and then mixed and stirred to a uniform state.

均一な状態の原料を押圧することによってすきまのない
状態、いわゆるツマリの状態で塊状に成形し、ここで加
熱することによって焼結させる。
By pressing the uniform raw material, it is formed into a block with no gaps, so-called a lump, and then sintered by heating.

焼結することによって得られたジルコニアセラミックス
体(塊状体)を、ダイヤモンドカッターを用いて所定寸
法よりわずかに大きい大きさの直方体(ブロックゲージ
形状)に切断する。
The zirconia ceramic body (lump body) obtained by sintering is cut into a rectangular parallelepiped (block gauge shape) having a size slightly larger than a predetermined size using a diamond cutter.

直方体のジルコニアセラミックスに、各面がそれぞれ所
定の平面度を持ち、且つ互いに対向する面同士がそれぞ
れの平行度を確保し、更に呼び寸法が所定の寸法となる
ように、ダイヤモンドを用いたラッピング等により研暦
加工を施し、ブロックゲージ形状に整形する。
A rectangular parallelepiped zirconia ceramic is wrapped with diamonds, etc. so that each surface has a predetermined flatness, the opposing surfaces are parallel to each other, and the nominal dimensions are the predetermined dimensions. Then, the block is processed into a block gauge shape.

最後に、整形したジルコニアセラミックスのマークを施
すべき面に、30〜60度の角度でN2ガスノズルから
の距離を3cmとして約0.40kg/ cm ’の圧
力のN2ガスを吹付けながら、YAGレーザ発生装置の
出力がIOWで、周波数が8KHzで、レーザ光照射点
の移動の速さが22 mm/secであってQスイッチ
モードとして、レーザ光を照射して、呼び寸法、商品番
号及び商標のマーキングをおこなった。
Finally, while spraying N2 gas at a pressure of approximately 0.40 kg/cm' at an angle of 30 to 60 degrees and at a distance of 3 cm from the N2 gas nozzle, a YAG laser is generated. The output of the device is IOW, the frequency is 8 KHz, the moving speed of the laser beam irradiation point is 22 mm/sec, and the laser beam is irradiated in Q-switch mode to mark the nominal dimensions, product number, and trademark. was carried out.

上述した工程によって得られたジルコニアブロックゲー
ジは、ジルコニアセラミックスからなり腐蝕することが
ないので防蝕状態下で保存するとか防蝕用手袋を着用す
るといった取扱い上の問題が解消され、又均質性を有し
ていて寸法上の変化は全くと言ってよいほどない。
The zirconia block gauge obtained by the above-mentioned process is made of zirconia ceramics and does not corrode, which eliminates handling problems such as storing it under corrosion-resistant conditions or wearing corrosion-resistant gloves, and it also has homogeneity. However, there is almost no dimensional change at all.

ジルコニアブロックゲージは乳白色であって使用する周
囲に対して十分なコントラストが得られ見やすく、又紛
失が完全なほどに避けることができる。
The zirconia block gauge is milky white, provides sufficient contrast to the surroundings, is easy to see, and can be completely prevented from being lost.

又、特定条件下でのレーザ光照射によって、黒色であっ
て溝状にわずかに凹んだマークが得られる。従って、マ
ークは下地の乳白色に対して十分なコントラストが得ら
れ、マークの内容が読取り易い。加えて、上記の方法に
よるマーキングではジルコニアブロックゲージの各面に
突出部が形成されることもなく平面度が保たれたままで
あることより、他のジルコニアブロックゲージとの密着
に何ら支障がなかった。尚、マークにカーボンアーク燈
を用いた耐光試験(10年間相当分)を施したが、マー
クはそのまま保たれ何の変化も生じなかった。
Further, by irradiating the laser beam under specific conditions, a black mark with a slightly depressed groove shape can be obtained. Therefore, the mark has sufficient contrast against the milky white color of the base, making it easy to read the contents of the mark. In addition, marking by the above method did not cause protrusions to be formed on each surface of the zirconia block gauge and the flatness was maintained, so there was no problem in adhering it to other zirconia block gauges. . Although the mark was subjected to a light resistance test (equivalent to 10 years) using a carbon arc lamp, the mark remained as it was and no change occurred.

ジルコニアブロックゲージの熱膨張係数を測定したとこ
ろ、約10 X 10−’/’Cであった。因に鋼の熱
膨張係数は、約11.5 X 10−’/”Cである。
When the thermal expansion coefficient of the zirconia block gauge was measured, it was approximately 10 x 10-'/'C. Incidentally, the coefficient of thermal expansion of steel is approximately 11.5 x 10-'/''C.

従って、使用環境の温度が変化した際、被測定物が鋼製
の場合には被測定物の熱膨張にジルコニアブロックゲー
ジの熱膨張が近似的に追従し、温度変化によって大きな
誤差が生じるということはない。
Therefore, when the temperature of the usage environment changes, if the object to be measured is made of steel, the thermal expansion of the zirconia block gauge will approximately follow the thermal expansion of the object to be measured, causing a large error due to temperature changes. There isn't.

ジルコニアブロックゲージをFC定盤(鋳鉄板)に載置
し、一定荷重をかけながら260cm/minの速さで
遊星運動の状態で、且つ摩擦距離を8000mとして移
動させるという耐摩耗性の試験を施したところ、約0.
07μmの摩耗が認められた。因に、同じ条件の耐摩耗
性の試験において、鋼では約0. 7μmの摩耗が、超
鋼では約0,25μmの摩耗がそれぞれ認められた。つ
まり、ジルコニアブロックゲージでは鋼に対して約10
倍の耐摩耗性が、超鋼に対して約3,5倍の耐摩耗性が
確保されていることになる。
A wear resistance test was conducted in which a zirconia block gauge was placed on an FC surface plate (cast iron plate) and moved in planetary motion at a speed of 260 cm/min while applying a constant load and with a friction distance of 8000 m. As a result, it was about 0.
Abrasion of 0.07 μm was observed. Incidentally, in a wear resistance test under the same conditions, steel had a wear resistance of about 0. Abrasion of 7 μm was observed in the case of the super steel, and wear of approximately 0.25 μm was observed in the case of the super steel. In other words, the zirconia block gauge is about 10
This means that the wear resistance is approximately 3.5 times that of cemented carbide.

なお、ジルコニアブロックゲージの耐摩耗性の試験にお
いてひびがはいる、割れる、及びかけるといった現象は
発生せず、十分な耐脆性が確保されていることが認めら
れた。
In addition, in the wear resistance test of the zirconia block gauge, no phenomena such as cracking, splitting, or chipping occurred, and it was confirmed that sufficient brittleness resistance was ensured.

[発明の効果] この発明によれば、耐蝕性が確保されていることより素
手で取扱え、使用後の防蝕処理が不用で更に特別な条件
下での保管を必要としないという取扱い上の簡便さが得
られると共に、材料が均質であることにより寸法に誤差
が全くといってよいほど生じず、耐摩耗性と耐脆性が共
に確保され、下地が白色もしくは薄黄色であることより
周囲に対してコントラストがよく且つマークが黒色で下
地に対してコントラストがよく、熱膨張係数が鋼のそれ
に近いので被測定物が鋼製の場合には温度変化による誤
差は極めて小さくて済むという効果が得られている。
[Effects of the Invention] According to the present invention, since corrosion resistance is ensured, it can be handled with bare hands, does not require anti-corrosion treatment after use, and does not require storage under special conditions, making it easy to handle. In addition, the material is homogeneous, so there are almost no errors in dimensions, and both abrasion resistance and brittleness are ensured, and the white or pale yellow base makes it easy to stand against the surroundings. The markings are black and have good contrast against the background, and the coefficient of thermal expansion is close to that of steel, so if the object to be measured is made of steel, errors due to temperature changes can be minimized. ing.

Claims (1)

【特許請求の範囲】[Claims] 1、主成分である酸化ジルコニウムと、3〜7重量%の
酸化イットリウム及び0〜20重量%の酸化アルミニウ
ムとを焼結してなるセラミックスから形成され、且つそ
のセラミックスのマークを施すべき部位を、不活性ガス
雰囲気内に置く状態又は減圧の状態に保ち、前記マーク
を施すべき部位にレーザ光を照射することでマーキング
されてなるブロックゲージ。
1. It is formed from a ceramic made by sintering zirconium oxide as the main component, 3 to 7% by weight of yttrium oxide, and 0 to 20% by weight of aluminum oxide, and the part where the ceramic mark is to be applied, A block gauge that is placed in an inert gas atmosphere or under reduced pressure, and marked by irradiating the area to be marked with a laser beam.
JP63321275A 1988-12-19 1988-12-19 Block gauge Granted JPH02165001A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP63321275A JPH02165001A (en) 1988-12-19 1988-12-19 Block gauge
GB9001710A GB2240396B (en) 1988-12-19 1990-01-25 Block gauge and method of marking ceramic material
DE4002986A DE4002986C2 (en) 1988-12-19 1990-02-01 Ceramic block jig and process for their manufacture
US07/907,047 US5272120A (en) 1988-12-19 1992-07-01 Block guage and method of marking ceramic material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63321275A JPH02165001A (en) 1988-12-19 1988-12-19 Block gauge

Publications (2)

Publication Number Publication Date
JPH02165001A true JPH02165001A (en) 1990-06-26
JPH0468561B2 JPH0468561B2 (en) 1992-11-02

Family

ID=18130754

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63321275A Granted JPH02165001A (en) 1988-12-19 1988-12-19 Block gauge

Country Status (3)

Country Link
JP (1) JPH02165001A (en)
DE (1) DE4002986C2 (en)
GB (1) GB2240396B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0464705U (en) * 1990-10-13 1992-06-03
US6238847B1 (en) 1997-10-16 2001-05-29 Dmc Degussa Metals Catalysts Cerdec Ag Laser marking method and apparatus
US6503310B1 (en) 1999-06-22 2003-01-07 Dmc2 Degussa Metals Catalysts Cerdec Ag Laser marking compositions and method
US6503316B1 (en) 2000-09-22 2003-01-07 Dmc2 Degussa Metals Catalysts Cerdec Ag Bismuth-containing laser markable compositions and methods of making and using same
US7238396B2 (en) 2002-08-02 2007-07-03 Rieck Albert S Methods for vitrescent marking
CN104949595A (en) * 2015-05-18 2015-09-30 青岛文创科技有限公司 Gauge material and its application
CN113462924A (en) * 2021-06-18 2021-10-01 中国地质大学(武汉) Titanium-plated diamond copper composite material and preparation method thereof

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DE4140111A1 (en) * 1991-12-05 1993-06-09 Man Technologie Ag, 8000 Muenchen, De Marking arrangement for objects by means of laser beams - involves silver resinate contrast sheet applied to object prior to laser application

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JPS6126561A (en) * 1984-07-13 1986-02-05 東芝モノフラツクス株式会社 Zirconia ceramics
JPS63188701A (en) * 1987-01-31 1988-08-04 Toshiba Corp Block gauge
JPS63148804U (en) * 1987-03-20 1988-09-30

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JPS6126561A (en) * 1984-07-13 1986-02-05 東芝モノフラツクス株式会社 Zirconia ceramics
JPS63188701A (en) * 1987-01-31 1988-08-04 Toshiba Corp Block gauge
JPS63148804U (en) * 1987-03-20 1988-09-30

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0464705U (en) * 1990-10-13 1992-06-03
US6238847B1 (en) 1997-10-16 2001-05-29 Dmc Degussa Metals Catalysts Cerdec Ag Laser marking method and apparatus
US6503310B1 (en) 1999-06-22 2003-01-07 Dmc2 Degussa Metals Catalysts Cerdec Ag Laser marking compositions and method
US6503316B1 (en) 2000-09-22 2003-01-07 Dmc2 Degussa Metals Catalysts Cerdec Ag Bismuth-containing laser markable compositions and methods of making and using same
US6680121B2 (en) 2000-09-22 2004-01-20 Dmc2 Degussa Metals Catalysts Cerdec Ag Bismuth-containing laser markable compositions and methods of making and using same
US7238396B2 (en) 2002-08-02 2007-07-03 Rieck Albert S Methods for vitrescent marking
CN104949595A (en) * 2015-05-18 2015-09-30 青岛文创科技有限公司 Gauge material and its application
CN113462924A (en) * 2021-06-18 2021-10-01 中国地质大学(武汉) Titanium-plated diamond copper composite material and preparation method thereof

Also Published As

Publication number Publication date
GB2240396A (en) 1991-07-31
JPH0468561B2 (en) 1992-11-02
DE4002986A1 (en) 1991-08-08
GB2240396B (en) 1994-04-27
DE4002986C2 (en) 1997-04-03
GB9001710D0 (en) 1990-03-28

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