JPH02153304A - Production of color resolving filter - Google Patents

Production of color resolving filter

Info

Publication number
JPH02153304A
JPH02153304A JP63308329A JP30832988A JPH02153304A JP H02153304 A JPH02153304 A JP H02153304A JP 63308329 A JP63308329 A JP 63308329A JP 30832988 A JP30832988 A JP 30832988A JP H02153304 A JPH02153304 A JP H02153304A
Authority
JP
Japan
Prior art keywords
color
films
grooves
light
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63308329A
Other languages
Japanese (ja)
Other versions
JP2600867B2 (en
Inventor
Yasuhiro Sekine
康弘 関根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP30832988A priority Critical patent/JP2600867B2/en
Publication of JPH02153304A publication Critical patent/JPH02153304A/en
Application granted granted Critical
Publication of JP2600867B2 publication Critical patent/JP2600867B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To effectively prevent color mixing without lowering the opening rate of color filters by forming light shielding films selectively only in the microgrooves provided between the respective color filters. CONSTITUTION:A transparent conductive film 7 is formed on a transparent substrate 5 over the entire surface thereof or in the required regions. After 2 to 3 kinds of color filter patterns are formed at need thereon in the form of desired patterns 1 to 3, a smoothing layer 8 consisting of silicon oxide is laminated thereon. Patterned corrosion resistant films are then formed by a photolithographic method on the smoothing layer 8 and the grooves are formed to the boundary parts of the respective color filters by a reactive ion etching method. Nickel films 10 are selectively deposited on only the surface of the transparent conductive film 7 exposed in the bottom parts of the grooves by electroless nickel plating and thereafter, electroplating is executed with the film 7 as a cathode in a copper sulfate bath to deposit metallic copper layers 11 on the nickel films deposited on the surfaces of the films 7 exposed in the groove bottoms. The light shielding material consisting of nickel and copper is filled in the grooves in this way.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は色フィルターの製造方法に関するものであり、
特に単板式カラー固体撮像素子用色分解フィルターの製
造方法に関するものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for manufacturing a color filter,
In particular, the present invention relates to a method of manufacturing a color separation filter for a single-plate color solid-state image sensor.

〔従来の技術〕[Conventional technology]

単板式カラー固体撮像素子においては、第2図(a)■
)に示すように固体撮像素子の画素のそれぞれに対応し
て、色フイルタ−1,2,3をモザイク状に規則的に配
置することによって入射光に含まれる色情報を得ている
。その際隣接する異なる分光透過率を持った色フィルタ
ーからの透過光又は散乱光の洩れや、各色フイルタ−パ
タン間の位置合わせ誤差等による色フィルター同士の重
なり部分や色フィルター間に生ずる隙間からの透過光の
侵入による混色を防止するために、各色フィルターの境
界部分には通常第2図(a) (b)に示すような遮光
膜パタン4が形成されている。
In the case of a single-chip color solid-state image sensor, Fig. 2 (a) ■
), color information contained in incident light is obtained by regularly arranging color filters 1, 2, and 3 in a mosaic pattern corresponding to each pixel of a solid-state image sensor. At that time, leakage of transmitted light or scattered light from adjacent color filters with different spectral transmittances, overlapping parts of color filters due to alignment errors between color filter patterns, and gaps between color filters may occur. In order to prevent color mixing due to penetration of transmitted light, a light-shielding film pattern 4 as shown in FIGS. 2(a) and 2(b) is usually formed at the boundary between each color filter.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

一方、固体撮像素子が高解像度化するに従い画素面積が
縮小するため、色フィルターバクンのアスペクト比が増
大し色フィルター表面への斜め入射光による混色が発生
し易くなる。この場合色フイルタ−パタン自体が微細化
しているため遮光膜パタン4の幅を拡げることによって
斜め入射光による混色を減少させた場合には、固体撮像
素子の感光部への入射光の光量が大幅に減少するため撮
像素子としての感度が低下してしまう。このため、隣接
する色フイルタ−パタン等による混色を減少せる方法と
して、色フイルタ−パタンの境界部分でなく、色フイル
タ−パタンの間隙に遮光膜を充填配置する構成が考えら
れている。しかし色フイルタ−パタンの間隙にのみ選択
的に遮光膜を充填することは困難であるため、このよう
な構成による色分解フィルターを実現することはできな
かった。本発明の目的は単板式カラー固体撮像素子用色
分解フィルターの製造方法に関する上記の問題を解決し
、色フイルタ−パタンの間隙にのみ選択的に遮光膜を形
成する方法を提供することにある。
On the other hand, as the resolution of solid-state image sensors increases, the pixel area decreases, so the aspect ratio of the color filter backbone increases and color mixing due to obliquely incident light on the surface of the color filter becomes more likely to occur. In this case, since the color filter pattern itself is miniaturized, if the width of the light-shielding film pattern 4 is increased to reduce color mixing due to obliquely incident light, the amount of light incident on the photosensitive area of the solid-state image sensor will be significantly increased. As a result, the sensitivity of the image sensor decreases. Therefore, as a method for reducing color mixing caused by adjacent color filter patterns, a structure has been considered in which a light-shielding film is filled and placed in the gaps between color filter patterns instead of in the boundaries between the color filter patterns. However, it has been difficult to selectively fill only the gaps between the color filter patterns with a light-shielding film, so it has not been possible to realize a color separation filter with such a configuration. SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems regarding the method of manufacturing a color separation filter for a single-plate color solid-state image sensor, and to provide a method for selectively forming a light-shielding film only in the gaps between color filter patterns.

〔課題を解決する具体的手段〕[Specific means to solve the problem]

本発明では上記問題を解決するために色フイルタ−パタ
ンの間隙にのみ選択的に遮光膜を形成する方法について
鋭意検討した結果、基板上に透明導電膜を形成する工程
と、非導電性の色フィルターを所望パクン状に形成する
工程と、前記色フィルターが形成されていない部分の前
記透明導電膜にめっき法または電着法により遮光膜を析
出させる工程を経ることにより色フィルターパクンの間
隙にのみ選択的に遮光膜を形成することができることを
見い出した。
In order to solve the above-mentioned problems, the present invention has developed a method for selectively forming a light-shielding film only in the gaps between color filter patterns. By going through the steps of forming the filter into a desired shape and depositing a light-shielding film on the transparent conductive film in the areas where the color filter is not formed, by plating or electrodeposition, only the gaps between the color filter holes are formed. We have discovered that it is possible to selectively form a light-shielding film.

〔発明の詳述・作用〕[Details and operation of the invention]

本発明では、互いに異なる分光透過率を持つ2ないし3
種の色フィルターパクンを基板上に規則的に配置し、更
に色フイルタ−パタンの境界部分に遮光部分を設けるこ
とによって形成される色分解フィルターの製造法におい
て、まず低膨張ガラス等よりなる透明基板表面に透明導
電膜を全面もしくは必要領域に形成する6次いで該透明
導電膜りに必要に応じて2ないし3種の色フイルタ−パ
タンを所望パタン状に形成した後、前記色フイルタ−パ
タンがその表面に形成されていない前記透明導電膜が露
出している領域に無電解めっき法及び/または電解めっ
き法により選択的に遮光性被膜を成長させる。前記2な
いし3種の色フイルタ−パタンの境界部分が互いに接触
あるいは重畳している場合、あるいは境界部分の幅が所
定の値より狭い場合には、フォトリソグラフィー法及び
反応性イオンエツチング法により前記境界部分のみを1
〜lOμm程度の所定間隔に溝状に除去し、溝の底部に
前記透明導電膜を露出させた後に無電解めっき法及び電
解めっき法により選択的に遮光性被膜を成長させること
も可能である。本発明によれば各色フイルタ−パタンの
間隙部分に設けた1μm程度の微細な溝の内部にのみ選
択的に遮光性被膜を形成し、溝の内部を遮光性物質で満
たすことができるため色フィルターの開口率を低下させ
ることなく効果的に混色を防ぐことができる。第2図(
a)は表面に本発明による遮光膜を形成した色分解フィ
ルターを設けた透明基板12を固体撮像素子13に貼り
合わせて形成した単板式カラー固体撮像素子の貼り合わ
せ部分の断面を示す説明図である。
In the present invention, two to three spectral transmittances having different spectral transmittances are used.
In the manufacturing method of a color separation filter, which is formed by regularly arranging seed color filter patterns on a substrate and further providing a light-shielding part at the border of the color filter pattern, first a transparent substrate made of low expansion glass or the like is used. A transparent conductive film is formed on the entire surface or in necessary areas. 6. Next, two or three types of color filter patterns are formed on the transparent conductive film in a desired pattern as necessary, and then the color filter pattern is A light-shielding film is selectively grown on the exposed region of the transparent conductive film that is not formed on the surface by electroless plating and/or electrolytic plating. If the boundary portions of the two or three color filter patterns contact or overlap each other, or if the width of the boundary portion is narrower than a predetermined value, the boundary portions may be etched by photolithography and reactive ion etching. only part 1
It is also possible to remove the transparent conductive film in the form of grooves at predetermined intervals of about 10 μm, expose the transparent conductive film at the bottom of the grooves, and then selectively grow a light-shielding film by electroless plating or electrolytic plating. According to the present invention, a light-shielding film is selectively formed only inside the fine grooves of about 1 μm provided in the gaps between the filter patterns of each color, and the inside of the grooves can be filled with a light-shielding substance. Color mixing can be effectively prevented without reducing the aperture ratio. Figure 2 (
a) is an explanatory view showing a cross section of a bonded portion of a single-panel color solid-state image sensor formed by bonding a transparent substrate 12 provided with a color separation filter with a light-shielding film according to the present invention on its surface to a solid-state image sensor 13; be.

また本発明は、色フィルターが非導電性物質で形成され
ていれば有機フィルター、無機フィルターを問わず応用
することができ、遮光性被膜についてもニンケル、銅、
クロム等のような無電解めっき法又は電解めっき法によ
り析出可能な金属はもちろん、そのほかに電気泳動を利
用した電着法によって析出可能な黒色顔料によって形成
させることも可能である。
Further, the present invention can be applied to both organic and inorganic filters as long as the color filter is made of a non-conductive substance, and the light-shielding coating can also be applied to nickel, copper, copper, etc.
In addition to metals such as chromium that can be deposited by electroless plating or electrolytic plating, it is also possible to use black pigments that can be deposited by electrodeposition using electrophoresis.

さらに本発明では主にカラー固体IR像素子用色分解フ
ィルターの製造を例にとってその方法を説明しているが
、その他のカラー損像素子用色分解フィルターまたはカ
ラー液晶デイスプレィ用色分解フィルター等を製造する
際にも本発明による方法が応用できることはいうまでも
ない。
Further, in the present invention, the method is mainly explained by taking as an example the production of color separation filters for color solid-state IR image elements, but it is also possible to produce color separation filters for other color image loss elements, color separation filters for color liquid crystal displays, etc. It goes without saying that the method according to the present invention can also be applied when doing so.

以下本発明の実施例について第1図を用いて具体的に説
明する。
Embodiments of the present invention will be specifically described below with reference to FIG.

〔実施例1〕 厚さ0.5輪転直径3inchのAMガラス(旭硝子製
)からなる透明基板5上にスパッタリング法によりIT
Oの透明導電膜7(膜厚0.1m u )を形成した(
第1図(a)参照)、このITO膜付透明基板を300
°C2時間大気中で焼成した後ITO膜7上に所望パタ
ン状にしラド1.グリーン2.ブルー3の各色フィルタ
ーパクンを形成し、次いでスパッタリング法により酸化
シリコンよりなる平滑化層8を積層した(第1図(b)
参照)0次にフォトリソグラフィー法にてパタン状耐食
膜を平滑化層8の上に形成し、反応性イオンエツチング
法を用いて、各色フィルター境界部分に溝9を形成する
(第1図(c)参照)0次いで無電解ニッケルめっきに
より溝9次部に露出するITO膜7膜面表面み選択的に
ニッケル膜10を析出させた後、硫酸銅浴中でITO膜
7を陰極として電解めっきを行い溝9次部に露出するI
TO膜7膜面表面出したニッケル膜13上に金属銅層1
1を析出させた(第1図(d)参照)。
[Example 1] IT was deposited by sputtering on a transparent substrate 5 made of AM glass (manufactured by Asahi Glass) with a thickness of 0.5 and a rotary diameter of 3 inches.
A transparent conductive film 7 (film thickness 0.1 m u ) of O was formed (
(see Figure 1(a)), this transparent substrate with ITO film was
After firing in the atmosphere for 2 hours at °C, a desired pattern is formed on the ITO film 7 using a radish 1. Green 2. A filter patch for each color of blue 3 was formed, and then a smoothing layer 8 made of silicon oxide was laminated by sputtering (Fig. 1(b)).
0) Next, a patterned corrosion resistant film is formed on the smoothing layer 8 by photolithography, and grooves 9 are formed at the boundaries of each color filter using reactive ion etching (see Figure 1 (c). )) Next, a nickel film 10 was selectively deposited on the surface of the ITO film 7 exposed in the groove 9th part by electroless nickel plating, and then electrolytic plating was performed in a copper sulfate bath using the ITO film 7 as a cathode. I exposed in the 9th part of the running groove
A metallic copper layer 1 is placed on the nickel film 13 exposed to the surface of the TO film 7.
1 was precipitated (see FIG. 1(d)).

以上の工程を経ることにより各色フイルタ−パタンの境
界部分に設けた溝の内部をニッケル及び銅よりなる遮光
性物質で満たすことができた。
By going through the above steps, it was possible to fill the inside of the grooves provided at the boundaries between the filter patterns of each color with a light-shielding substance made of nickel and copper.

〔実施例2〕 厚さ0.5am、直径3inchのANガラス(旭硝子
製)からなる透明基板5上にスパッタリング法によりI
TO膜7(膜厚0.1mμ)を形成した(第1図(a)
参照)。
[Example 2] I was deposited by sputtering on a transparent substrate 5 made of AN glass (manufactured by Asahi Glass Co., Ltd.) with a thickness of 0.5 am and a diameter of 3 inches.
A TO film 7 (film thickness 0.1 mμ) was formed (Fig. 1(a)
reference).

このITO膜付透明基板を300°C2時間大気中で焼
成した後ITO膜7上に所望パタン状にレッド1.グリ
ーン2.ブルー3の各色フイルタ−パタンを形成し、次
いで透明樹脂よりなる平滑化層8を積層した(第1図(
b)参照)0次にフォトリソグラフィー法及び反応性イ
オンエツチング法を用いて、各色フィルター境界部分に
溝9を形成する(第1図(c)参照)0次いで電着法を
用いて溝9次部に露出す、るITO膜7膜面表面み選択
的にカーボンブラックの電着層12を析出させた後、1
50C’ 30分のベーキングを行った。(第1図(e
)参照) 以上の工程を経ることにより各色フィルターパクンの境
界部分に設けた溝の内部をカーボンブラックよりなる遮
光性物質で満たすことができた。
After baking this transparent substrate with an ITO film in the air at 300°C for 2 hours, a desired pattern of red 1. Green 2. A filter pattern for each color of blue 3 was formed, and then a smoothing layer 8 made of transparent resin was laminated (see Fig. 1).
(See Figure 1(c)) Next, form grooves 9 at the border of each color filter using photolithography and reactive ion etching (see Figure 1(c)) Next, form grooves 9 using electrodeposition. After selectively depositing an electrodeposition layer 12 of carbon black on the surface of the ITO film 7 exposed in the
Baking was carried out at 50C' for 30 minutes. (Figure 1(e)
)) By going through the above steps, it was possible to fill the inside of the grooves provided at the boundaries between the filter strips of each color with a light-shielding substance made of carbon black.

〔発明の効果〕〔Effect of the invention〕

本発明によれば色分解フィルターにおいて各色フイルタ
−パタン間に設けた微小な溝の内部を選択的に遮光性物
質で満たすことができる。従って各色フイルタ−パタン
の寸法が微細化した場合でも各色フイルタ−パタンへの
入射光が隣接する色フィルターバクンに斜め方向より進
入しないため混色を生ずることがない。
According to the present invention, in a color separation filter, the inside of the minute groove provided between each color filter pattern can be selectively filled with a light-shielding substance. Therefore, even if the dimensions of each color filter pattern are miniaturized, the light incident on each color filter pattern will not enter the adjacent color filter pattern from an oblique direction, so that color mixing will not occur.

また従来法による遮光膜の形成が遮光層の成膜、フォト
リソグラフィー、及びエツチングの各工程を経て行われ
るのと比較し、本発明では各色フイルタ−パタン間に生
じた間隙の内部にめっき法により選択的に遮光膜を形成
することができるため遮光膜の形成工程を簡略化できる
。さらに、隣接する色フィルターパクンの境界部分をエ
ツチング除去した後に遮光膜の形成を行う場合において
もフォトリソグラフィー、エツチング、及びめっきの各
工程のみで遮光膜が形成されるため本発明による方法は
、従来法と比較してパタン制度が格段に向上するものと
なる。
In addition, compared to the conventional method of forming a light-shielding film through the steps of forming the light-shielding layer, photolithography, and etching, the present invention uses a plating method to form the inside of the gap between each color filter pattern. Since the light shielding film can be selectively formed, the process of forming the light shielding film can be simplified. Furthermore, even when forming a light-shielding film after etching and removing the boundary portions of adjacent color filters, the method according to the present invention is different from conventional methods because the light-shielding film is formed only by the steps of photolithography, etching, and plating. The pattern system will be significantly improved compared to the law.

以上のように、本発明は実用上極めて優れている。As described above, the present invention is extremely superior in practical terms.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(a)〜(d)は本発明の色分解フィルター製造
方法の実施例を工程順に示す説明図である。 1、レッドフィルター 2、グリーンフィルター 3、ブルーフイルター 4、遮光膜 5、透明基板 6、中間層 7、透明導電膜 8、平滑化層 9、溝 10、ニッケル膜 11、銅層 12、電着塗料層
FIGS. 1(a) to 1(d) are explanatory drawings showing an example of the method for producing a color separation filter of the present invention in the order of steps. 1, red filter 2, green filter 3, blue filter 4, light shielding film 5, transparent substrate 6, intermediate layer 7, transparent conductive film 8, smoothing layer 9, groove 10, nickel film 11, copper layer 12, electrodeposition paint layer

Claims (2)

【特許請求の範囲】[Claims] (1)基板上に透明導電膜を形成する工程と、非導電性
の色フィルターを所望パタン状に形成する工程と、前記
色フィルターが形成されていない間隙の前記透明導電膜
上にめっき法または電着法により遮光膜を形成すること
を特徴とする色分解フィルターの製造方法。
(1) A step of forming a transparent conductive film on a substrate, a step of forming a non-conductive color filter in a desired pattern, and a plating method or A method for producing a color separation filter, characterized by forming a light-shielding film by an electrodeposition method.
(2)非導電性の色フィルターを所望パタン状に形成す
る工程のあと、色フィルターの境界部分を所定の間隔に
溝状に除去する工程を付加することを特徴とする請求項
(1)記載の色分解フィルターの製造方法。
(2) The method according to claim (1), characterized in that, after the step of forming the non-conductive color filter in a desired pattern, a step of removing the boundary portions of the color filter in the form of grooves at predetermined intervals is added. A method for manufacturing color separation filters.
JP30832988A 1988-12-06 1988-12-06 Manufacturing method of color separation filter Expired - Fee Related JP2600867B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30832988A JP2600867B2 (en) 1988-12-06 1988-12-06 Manufacturing method of color separation filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30832988A JP2600867B2 (en) 1988-12-06 1988-12-06 Manufacturing method of color separation filter

Publications (2)

Publication Number Publication Date
JPH02153304A true JPH02153304A (en) 1990-06-13
JP2600867B2 JP2600867B2 (en) 1997-04-16

Family

ID=17979747

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30832988A Expired - Fee Related JP2600867B2 (en) 1988-12-06 1988-12-06 Manufacturing method of color separation filter

Country Status (1)

Country Link
JP (1) JP2600867B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08122515A (en) * 1994-10-26 1996-05-17 Dainippon Toryo Co Ltd Production of color filter
KR100309211B1 (en) * 1997-04-23 2002-11-18 엘지.필립스 엘시디 주식회사 Lcd with wide viewing angle and fabricating method thereof
US7297451B2 (en) * 2004-07-21 2007-11-20 Samsung Corning Co., Ltd. Black matrix, method for the preparation thereof, flat display device and electromagnetic interference filter employing the same
JP2008116895A (en) * 2006-10-12 2008-05-22 Bridgestone Corp Method for manufacturing panel substrate with color filter, panel substrate with color filter, and information display panel
JP2009117570A (en) * 2007-11-06 2009-05-28 Sanyo Electric Co Ltd Photoelectric conversion device
JP2011085625A (en) * 2009-10-13 2011-04-28 Toppan Printing Co Ltd Camera module and method for manufacturing the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08122515A (en) * 1994-10-26 1996-05-17 Dainippon Toryo Co Ltd Production of color filter
KR100309211B1 (en) * 1997-04-23 2002-11-18 엘지.필립스 엘시디 주식회사 Lcd with wide viewing angle and fabricating method thereof
US7297451B2 (en) * 2004-07-21 2007-11-20 Samsung Corning Co., Ltd. Black matrix, method for the preparation thereof, flat display device and electromagnetic interference filter employing the same
JP2008116895A (en) * 2006-10-12 2008-05-22 Bridgestone Corp Method for manufacturing panel substrate with color filter, panel substrate with color filter, and information display panel
JP2009117570A (en) * 2007-11-06 2009-05-28 Sanyo Electric Co Ltd Photoelectric conversion device
JP2011085625A (en) * 2009-10-13 2011-04-28 Toppan Printing Co Ltd Camera module and method for manufacturing the same

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