JPH0159285B2 - - Google Patents
Info
- Publication number
- JPH0159285B2 JPH0159285B2 JP57040978A JP4097882A JPH0159285B2 JP H0159285 B2 JPH0159285 B2 JP H0159285B2 JP 57040978 A JP57040978 A JP 57040978A JP 4097882 A JP4097882 A JP 4097882A JP H0159285 B2 JPH0159285 B2 JP H0159285B2
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- weight
- chloroprene
- hydroxyalkylamine
- latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 claims description 36
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229910001414 potassium ion Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 24
- 239000004816 latex Substances 0.000 description 15
- 229920000126 latex Polymers 0.000 description 15
- 239000000243 solution Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229920001084 poly(chloroprene) Polymers 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- -1 alkali metal salts Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- AOPRFYAPABFRPU-UHFFFAOYSA-N amino(imino)methanesulfonic acid Chemical compound NC(=N)S(O)(=O)=O AOPRFYAPABFRPU-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/14—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
- C08F36/16—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen
- C08F36/18—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen containing chlorine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813111138 DE3111138A1 (de) | 1981-03-21 | 1981-03-21 | Verfahren zur polymerisation von chloropren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57162709A JPS57162709A (en) | 1982-10-06 |
| JPH0159285B2 true JPH0159285B2 (US06653308-20031125-C00197.png) | 1989-12-15 |
Family
ID=6127925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57040978A Granted JPS57162709A (en) | 1981-03-21 | 1982-03-17 | Chloroprene polymerization |
Country Status (5)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02107123U (US06653308-20031125-C00197.png) * | 1989-02-10 | 1990-08-27 | ||
| JPH0318721A (ja) * | 1989-06-16 | 1991-01-28 | Stanley Electric Co Ltd | 面光源モジュール |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3605332A1 (de) * | 1986-02-19 | 1987-08-20 | Bayer Ag | Chloropren-polymerisation |
| DE102006045128A1 (de) | 2006-09-25 | 2008-03-27 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Polychloropren-Latices |
| KR101558070B1 (ko) | 2011-03-24 | 2015-10-06 | 와이케이케이 가부시끼가이샤 | 간이 로크 기구를 갖는 슬라이드 파스너 및 슬라이더 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL131752C (US06653308-20031125-C00197.png) * | 1960-09-08 | |||
| DE2003147C3 (de) * | 1970-01-24 | 1980-08-21 | Bayer Ag, 5090 Leverkusen | Herstellung von schwefelmodifizierten Polychloroprene« mit verbesserter Lagerstabilität |
| DE2301158A1 (de) * | 1973-01-11 | 1974-07-18 | Bayer Ag | Emulsionspolymerisation von chloropren mit diaethylhydroxylamin als desaktivator |
| US3929752A (en) * | 1974-04-05 | 1975-12-30 | Du Pont | Preparation of sol chloroprene polymers |
-
1981
- 1981-03-21 DE DE19813111138 patent/DE3111138A1/de not_active Withdrawn
-
1982
- 1982-03-08 US US06/356,019 patent/US4417036A/en not_active Expired - Fee Related
- 1982-03-08 DE DE8282101804T patent/DE3260427D1/de not_active Expired
- 1982-03-08 EP EP82101804A patent/EP0061054B1/de not_active Expired
- 1982-03-17 JP JP57040978A patent/JPS57162709A/ja active Granted
- 1982-03-19 CA CA000398893A patent/CA1173184A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02107123U (US06653308-20031125-C00197.png) * | 1989-02-10 | 1990-08-27 | ||
| JPH0318721A (ja) * | 1989-06-16 | 1991-01-28 | Stanley Electric Co Ltd | 面光源モジュール |
Also Published As
| Publication number | Publication date |
|---|---|
| US4417036A (en) | 1983-11-22 |
| DE3111138A1 (de) | 1982-09-30 |
| EP0061054A1 (de) | 1982-09-29 |
| CA1173184A (en) | 1984-08-21 |
| DE3260427D1 (en) | 1984-08-30 |
| EP0061054B1 (de) | 1984-07-25 |
| JPS57162709A (en) | 1982-10-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100431675B1 (ko) | 디엔고무라텍스의세미배치식유화제조방법,이에의해제조되는고무라텍스,및이로부터제조된그래프트공중합체 | |
| US3878181A (en) | Emulsion polymerisation of chloroprene with diethylhydroxy-amines as inactivator | |
| JPH0159285B2 (US06653308-20031125-C00197.png) | ||
| CA1193047A (en) | Continuous polymerization of chloroprene | |
| JP3165534B2 (ja) | 選択的モノマー付加および重合によるカルボキシル化ラテックスの製造方法 | |
| US4839447A (en) | Polymerization of chloroprene | |
| US3055855A (en) | Process for emulsion polymerization of butadiene-unsaturated carboxylic acid copolymers and product thereof | |
| EP0437293B1 (en) | Process for shortstopping an emulsion polymerization | |
| US3082262A (en) | Polymerizable emulsion and process of polymerization | |
| JPS6340204B2 (US06653308-20031125-C00197.png) | ||
| US3347837A (en) | Process for isolating carboxylic acidbearing chloroprene polymers | |
| JP3480003B2 (ja) | 硫黄変性クロロプレン重合体の製造方法 | |
| US4000222A (en) | Mixture of benzene-soluble and benzene-insoluble chloroprene polymers wherein the former polymer is prepared in the presence of a dialkoxyxanthogendisulphide | |
| US3021301A (en) | Process for producing a novel hydrolyzed polyacrylonitrile reaction product containing polyvinyl alcohol and the product produced thereby | |
| CA1206691A (en) | Production of sulfur-modified solid chloroprene rubbers | |
| Laundrie et al. | Low Temperature Chemical Rubber by a Continuous Pilot Plant Process | |
| US2676951A (en) | High solids synthetic rubber latex | |
| US3432563A (en) | Prevention of "popcorn" polymer in the manufacture of rubber latex | |
| JP4238021B2 (ja) | ポリクロロプレン系重合体の製造方法 | |
| WO2019022227A1 (ja) | 重合体の製造方法 | |
| US2604466A (en) | Emulsion polymerization in the presence of a dioxane | |
| US4130704A (en) | Process for producing sulfur modified polychloroprene in the presence of quaternary ammonium salts | |
| US2635091A (en) | Polymerization method | |
| RU2745264C1 (ru) | Натриевые соли 2-гидрокси-6-нафтолсульфокислоты и глицидилового аддукта в качестве диспергатора эмульсионной полимеризации и способ получения латексов с их использованием | |
| US4076927A (en) | Process for producing sulfur modified polychloroprene |
