JPH01319563A - Melamine resin molding material - Google Patents
Melamine resin molding materialInfo
- Publication number
- JPH01319563A JPH01319563A JP15170388A JP15170388A JPH01319563A JP H01319563 A JPH01319563 A JP H01319563A JP 15170388 A JP15170388 A JP 15170388A JP 15170388 A JP15170388 A JP 15170388A JP H01319563 A JPH01319563 A JP H01319563A
- Authority
- JP
- Japan
- Prior art keywords
- melamine resin
- molding material
- melamine
- resin molding
- molar ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000877 Melamine resin Polymers 0.000 title claims abstract description 44
- 239000004640 Melamine resin Substances 0.000 title claims abstract description 32
- 239000012778 molding material Substances 0.000 title claims abstract description 14
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 glycidyl compound Chemical class 0.000 claims abstract description 15
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000007974 melamines Chemical class 0.000 claims abstract description 11
- 239000012765 fibrous filler Substances 0.000 claims abstract description 8
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- CUGZWHZWSVUSBE-UHFFFAOYSA-N 2-(oxiran-2-ylmethoxy)ethanol Chemical compound OCCOCC1CO1 CUGZWHZWSVUSBE-UHFFFAOYSA-N 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000006188 syrup Substances 0.000 description 3
- 235000020357 syrup Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000010517 secondary reaction Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001744 Polyaldehyde Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は電気器具、家庭用品、スポーツ用品等に用いら
れるメラミン樹脂成形材料に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a melamine resin molding material used for electrical appliances, household goods, sporting goods, and the like.
従来、メラミン樹脂成形材料から得られるメラミン樹脂
成形材料は、その優れた機械的強度、電気的性能、着色
性等の点で広い分野に用（八られてｂるが強靭性に劣る
問題があり、耐衝撃性を必要とする分野では用いること
ができなかった。Conventionally, melamine resin molding materials obtained from melamine resin molding materials have been used in a wide range of fields due to their excellent mechanical strength, electrical performance, colorability, etc. (However, they have the problem of poor toughness. However, it could not be used in fields requiring impact resistance.
従来の技術で述べたように従来のメラミン樹脂成形品を
耐衝撃性を必要とする分野に用層ることができなかった
。本発明は従来の技術における上述の問題点に鑑みてな
されたもので、その目的とするところは、耐衝撃性に優
れた成形品が得られるメラミン樹脂成形材料を提供する
ことにある。As described in the prior art section, conventional melamine resin molded products could not be used in fields requiring impact resistance. The present invention has been made in view of the above-mentioned problems in the prior art, and an object thereof is to provide a melamine resin molding material from which a molded article with excellent impact resistance can be obtained.
（１）メラミンとグリシジル化合物との反応物に、ホル
ムアルデヒドを反応させてなる変性メラミン樹脂に少く
とも繊維質充填剤を含有させてなることを特徴とするメ
ラミン樹脂成形材料のため、強靭性を有する変性メラミ
ン樹脂と繊維質充填剤により耐衝撃性を著るしく向上す
ることができたもので、以下本発明の詳細な説明する。(1) It has toughness because it is a melamine resin molding material characterized by containing at least a fibrous filler in a modified melamine resin made by reacting formaldehyde with a reaction product of melamine and a glycidyl compound. The impact resistance can be significantly improved by using a modified melamine resin and a fibrous filler, and the present invention will be described in detail below.
本発明でメラミンと反応さぜるり１１シジル化合ルエー
テルも含むものである。本発明において用すて好まし−
グリシジル化合物を例示すれば、エチレングリコールグ
リシジルエーテル、ポリエチレングリコールジグ１１シ
ジルエーテル、ポリプロピレンダ１１コールグリシジル
エーテル、ネオペンナルク’ １１コールジグリシジル
エーテル、１．６ヘギサンジオールグリシジルエーテル
、トリメチロールプロパンボ１１り１１シジルエーテル
、ポリエチレングリコールジグリシジルエーテルなどで
ある。The present invention also includes 11-sidyl compound ether reacted with melamine. Preferably used in the present invention -
Examples of glycidyl compounds include ethylene glycol glycidyl ether, polyethylene glycol dig 11 cidyl ether, polypropylenda 11 call glycidyl ether, neopenalc' 11 call diglycidyl ether, 1.6 hegysandiol glycidyl ether, trimethylol propane 11 These include cidyl ether and polyethylene glycol diglycidyl ether.
本発明におめではこのグリシジル化合物によっテメラミ
ン樹脂を変性するものであり、グリシジル化合物で変性
したメラミン樹脂を調製するＪこあたりては、まず−次
反応としてメラミンとグリシジル化合物とを反応させ、
次ぎに二次反応としてこの反応物とホルム“アルデヒド
とを反応させることによっておこなうことができる。−
次反応は８゜−１００℃で１０〜１５０分間程度反応さ
せることが好ましく、二次反応は７０〜９０℃で５〜６
０分間反応させることが望ましいことである。また、上
記反応の際の各成分の配合蛍は、メラミンのモル数ヲＩ
ＶＩ’ｓグ１ｊシシル化合物のモル数を０１ホルムアル
デヒドのセル数をＦとすると、
メラミンに対するグリシジル化合物のモル比がＧ ／
Ｍ、 ＝ ｖ、ｏ １〜５．ｓメラミンとグリシジル化
合物のセル数の差に対するホルムアルデヒドのモル比が
Ｆ／ ＩＭ−Ｇｌ＝ （Ｊ、５〜４０となるようにそ
の範囲を設定するのが望ましい。In the present invention, temelamine resin is modified with this glycidyl compound, and in order to prepare a melamine resin modified with a glycidyl compound, first, as a second reaction, melamine and a glycidyl compound are reacted,
Next, a secondary reaction can be carried out by reacting this reactant with formaldehyde.
The next reaction is preferably carried out at 8°-100°C for about 10-150 minutes, and the secondary reaction is carried out at 70-90°C for 5-6 minutes.
It is desirable to react for 0 minutes. In addition, the composition of each component in the above reaction is determined by the number of moles of melamine.
If the number of moles of the glycidyl compound is 01 and the number of cells of formaldehyde is F, then the molar ratio of the glycidyl compound to melamine is G/
M, = v, o 1-5. It is desirable to set the range so that the molar ratio of formaldehyde to the difference in the number of cells between melamine and the glycidyl compound is F/IM-Gl=(J, 5 to 40).
メラミンに対するグリシジル化合物のモル比が（１，０
１未満であるとり］１シジル化合物による変性が不士分
で、メラミン樹脂の可撓性を旨めて強靭性を同上させる
効果を十分ｊこ得ることができず、才たこのモル比が５
．８を超えると反応系でのグリシジル化合物の匍か多く
なり過きてアミンの作用でゲル化し易くなり、同様にメ
ラミン樹脂の可撓性を旨めて強靭性を向上させる効果を
十分に得ることかできない。一般的にはメラミン樹脂の
モル数Ｍはグリシジル化合物のモル数Ｇよりも大きく設
定される。さらｌこメラミンとグリシジル化合物のモル
数の差に対するホルムアルデヒドのモル比が０．５未満
であるとホルムアルデヒドの配合蓋カゴ不十分でメラミ
ン樹脂を十分に硬化させることができず、またこのモル
比が４．０を超えるとポルムアルデヒドが過多となって
メラミン樹脂の架橋密度が高くなり過ぎ、メラミン樹脂
の可撓性を高めて強靭性を向上させる効果を十分に得る
ことができない。The molar ratio of glycidyl compound to melamine is (1,0
If the molar ratio is less than 1, the modification with the 1 cidyl compound is insufficient, and the effect of improving the flexibility and toughness of the melamine resin cannot be sufficiently achieved, and the molar ratio of the melamine resin is less than 5.
．． If it exceeds 8, the amount of glycidyl compound in the reaction system will be too large and will easily gel due to the action of the amine. Similarly, the effect of improving the flexibility and toughness of the melamine resin should be sufficiently obtained. I can't do it. Generally, the number of moles M of the melamine resin is set larger than the number G of moles of the glycidyl compound. If the molar ratio of formaldehyde to the difference in the number of moles between melamine and glycidyl compound is less than 0.5, the melamine resin will not be sufficiently cured due to insufficient formaldehyde, and if this molar ratio is If it exceeds 4.0, there will be too much polyaldehyde and the crosslinking density of the melamine resin will become too high, making it impossible to sufficiently obtain the effect of increasing the flexibility and toughness of the melamine resin.
このように反応させることによって得られるものはシラ
ーｌプ状で、このまま充填剤等に含浸、乾燥、粉砕して
用（八ることができるが、好ましくは該シラリプ状変性
メラミン」η↑脂を真空加熱脱水法、スプレー、ドライ
ヤー法、薄膜蒸発法等の脱水法ｌこよ−て固型化し、固
型変性メラミン樹脂として用層ることがより強靭性が大
となるため望まし込ことである。繊維質充填剤としては
ガラス繊維、アラミド繊維、カーボン繊維、スチールフ
ァイバーやアルミ繊維や真鍮繊維等の金属繊維等で繊維
質充填剤の繊維長は１〜１５ｆｌのものが好ましｌＡ。The product obtained by this reaction is in the form of a syrup, which can be used as it is by impregnating it with a filler, etc., drying, and pulverizing it, but it is preferable to use the modified melamine in the form of a syrup. Dehydration methods such as vacuum heating dehydration method, spray, dryer method, thin film evaporation method, etc. are preferably used to solidify and use as a solid modified melamine resin layer, as this will increase the toughness. The fibrous filler includes glass fibers, aramid fibers, carbon fibers, steel fibers, and metal fibers such as aluminum fibers and brass fibers, and the fiber length of the fibrous filler is preferably 1 to 15 fl.
樹脂、繊維質充填剤以外の充填剤、強化剤、硬化剤、着
色剤、離型剤、分散助剤等にっ層ては必要ｌこ応１″、
て添加することカｊできるものである。For resins, fillers other than fibrous fillers, reinforcing agents, curing agents, coloring agents, mold release agents, dispersion aids, etc., 1" is required.
It can be added to
以下本発明を実施例にもとっ論て説明する。The present invention will be explained below with reference to Examples.
実施例
メラミンｘｓｏｏＦ、ポリエチレフグリコールジグリシ
シルエーテル７５ｏｙ１水１４３ｏｙ をそり、 ソ
ｆＬ５１！の三つロフラスコｌこ仕込み、昇温して９５
℃の温度で４５分間反応させた。次き′にこれに４０４
ホルマリンを１９３５９ 注入したのちｌこ昇温して
８５℃で３５分間反応させることによって、グリシジル
化合物で変性したメラミン樹脂シラｉプを得た。この配
合にお−てＧ、／Ｍ＝（Ｊ、１２ であり、Ｆ／ＣＭ
−Ｇ）＝２．４６ である。Example Melamine Prepare a three-bottle flask and raise the temperature to 95.
The reaction was carried out for 45 minutes at a temperature of .degree. Next' to this 404
A melamine resin syrup modified with a glycidyl compound was obtained by injecting 19359 ml of formalin, raising the temperature to 85° C., and reacting for 35 minutes. In this formulation, G,/M=(J, 12, and F/CM
-G)=2.46.
とのシラ・・プ状変性メラミン樹脂を薄膜蒸発脱水法で
固型化して固型変性メラミン樹脂を得た。A solid modified melamine resin was obtained by solidifying the silica-shaped modified melamine resin using a thin film evaporation dehydration method.
次（こ上記固型変性メラミン樹脂１００重量部（以下朧
に部と記す）に対しスチールファイバー１００部、ステ
ア’ ＩＩン酸亜鉛２部、無水フタルｍＩ Ｏ，５部を
添加しニーダ−で混練後、粉砕してメラミン樹脂成形材
料を得た。Next (to 100 parts by weight of the above solid modified melamine resin (hereinafter referred to as Oboroni parts), 100 parts of steel fiber, 2 parts of zinc stear' II phosphate, and 5 parts of anhydrous phthalic mI O were added and kneaded in a kneader. Thereafter, it was crushed to obtain a melamine resin molding material.
比較例
変性してな（ハメラミン樹脂成形材料（松下電工株式会
社製、品妃’ＣＰ−９０１２）を比較例とした。Comparative Example A modified Hamelamine resin molding material (manufactured by Matsushita Electric Works Co., Ltd., Shinhi'CP-9012) was used as a comparative example.
実施例及び比較例のメラミン防服成形材料を、成形圧力
２００１ｃｑ／ｃｔＩ、 １４５℃で２分ｍＪ圧粗ｈｋ
形してメラミン樹脂成形品を得、衝撃強度を測定した結
果は第１表のようである。The melamine clothing molding materials of Examples and Comparative Examples were subjected to a molding pressure of 2001 cq/ctI, 2 minutes mJ pressure roughening hk at 145°C.
A melamine resin molded article was obtained, and the impact strength was measured. The results are shown in Table 1.
第１表
〔発明の効果〕
本発明は上述した如く構成されており、本発明のメラミ
ン樹脂成形材料にお−ては、メラミン樹脂成形品の耐ｆ
ｆ＊ｊ＊注を儲るしく向上させる効果を有している。Table 1 [Effects of the Invention] The present invention is constructed as described above, and the melamine resin molding material of the present invention has a high f resistance of melamine resin molded products.
It has the effect of profitably improving f*j*note.
Claims (2)
ムアルデヒドを反応させてなる変性メラミン樹脂に少く
とも繊維質充填剤を含有させてなることを特徴とするメ
ラミン樹脂成形材料。(1) A melamine resin molding material comprising at least a fibrous filler contained in a modified melamine resin obtained by reacting formaldehyde with a reaction product of melamine and a glycidyl compound.
特許請求の範囲第１項記載のメラミン樹脂成形材料。(2) The melamine resin molding material according to claim 1, wherein the modified melamine resin is solid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15170388A JPH01319563A (en) | 1988-06-20 | 1988-06-20 | Melamine resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15170388A JPH01319563A (en) | 1988-06-20 | 1988-06-20 | Melamine resin molding material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01319563A true JPH01319563A (en) | 1989-12-25 |
Family
ID=15524423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15170388A Pending JPH01319563A (en) | 1988-06-20 | 1988-06-20 | Melamine resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01319563A (en) |
-
1988
- 1988-06-20 JP JP15170388A patent/JPH01319563A/en active Pending
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