JPH01216909A - Cosmetic composition - Google Patents
Cosmetic compositionInfo
- Publication number
- JPH01216909A JPH01216909A JP63040960A JP4096088A JPH01216909A JP H01216909 A JPH01216909 A JP H01216909A JP 63040960 A JP63040960 A JP 63040960A JP 4096088 A JP4096088 A JP 4096088A JP H01216909 A JPH01216909 A JP H01216909A
- Authority
- JP
- Japan
- Prior art keywords
- horse
- oil
- horse oil
- color
- odor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 title claims description 12
- 239000003921 oil Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000003463 adsorbent Substances 0.000 claims abstract description 8
- 239000012454 non-polar solvent Substances 0.000 claims abstract description 8
- 238000001179 sorption measurement Methods 0.000 claims abstract description 6
- 241001550224 Apha Species 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 230000009965 odorless effect Effects 0.000 claims description 5
- 238000007670 refining Methods 0.000 claims description 3
- 239000003760 tallow Substances 0.000 claims description 3
- 238000004440 column chromatography Methods 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004927 clay Substances 0.000 abstract description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000741 silica gel Substances 0.000 abstract description 3
- 229910002027 silica gel Inorganic materials 0.000 abstract description 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract description 2
- 238000004458 analytical method Methods 0.000 abstract description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003208 petroleum Substances 0.000 abstract description 2
- 239000010457 zeolite Substances 0.000 abstract description 2
- 239000003925 fat Substances 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 235000014593 oils and fats Nutrition 0.000 abstract 1
- 239000012264 purified product Substances 0.000 abstract 1
- 238000007655 standard test method Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 6
- 238000004587 chromatography analysis Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- -1 glycerin fatty acid triester Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- PVNIQBQSYATKKL-UHFFFAOYSA-N Glycerol trihexadecanoate Natural products CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Zoology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明はカラムクロマトグラフ的手法で精製された馬
油な含有することを特徴とする化粧Ｉ″Ｉ組成物に間し
、その目的は従来、色、におい等が化粧料原料として不
満足な状態であり、又、経日酸化安定性が、よくなかっ
た馬油の欠点をほぼ完全に改良して、色においがなく、
安全な化粧料のための原料として提供することにある。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a cosmetic composition containing horse oil purified by a column chromatographic method, and its purpose is to The disadvantages of horse oil, which is unsatisfactory as a raw material for cosmetics such as color and odor, and poor oxidation stability over time, have been almost completely improved, and it has no color and odor.
The goal is to provide it as a raw material for safe cosmetics.
（従来技術 及び その欠点）
−ｍに馬油（馬脂を含む）は馬（ＥｑｕｕｓＣａｂａｌ
１ｕｓ）の種々の部位を高圧蒸気処理する等の方法で
得られる油で通常の動物油と同様、主としてグリセリン
の脂肪酸トリエステルからなるが、その脂肪酸構成は一
例としてパルミチンｉｌ！ ２８．５％
ステアリン酸 ６．８％オレイン酸
５５．２％リノール酸
６．７％リルン酸 １．７％
ｂ）７らなり、常温では液状のもの（馬油）、固型状の
もの（馬脂）、その混合したものがあり形状は一定では
ない、その粗製の油脂は淡褐色で、特異な臭気を持って
いる。これを脱色、脱臭、或いは蒸留したりすることは
公知であるが、従来の方法では色、においも完全に除去
できず、又経日安定性にも問題があり過酸化物価の上昇
が化粧料の原料として使用した時、皮膚刺激の原因とな
り問題であった。(Prior art and its drawbacks) - Horse oil (including horse fat) is
This oil is obtained by high-pressure steam treatment of various parts of 1 us), and like normal animal oils, it mainly consists of glycerin fatty acid triester, but its fatty acid composition is, for example, palmitin il! 28.5%
Stearic acid 6.8% oleic acid
55.2% linoleic acid
6.7% rinnic acid 1.7% b) 7. At room temperature, there are liquid (horse oil), solid (horse tallow), and mixtures thereof, and the shape is not constant. The oil is light brown in color and has a distinctive odor. It is known to bleach, deodorize, or distill this, but conventional methods cannot completely remove color and odor, and there are also problems with stability over time, and an increase in peroxide value may affect cosmetics. When used as a raw material, it caused skin irritation and was a problem.
（解決手段）
本願の発明者は馬油を化粧料の配合成分として上記のよ
うな欠点のないものにするため鋭意研究した結果この発
明に到達したものである。(Solution Means) The inventor of the present application has arrived at the present invention as a result of intensive research in order to make horse oil a component of cosmetics that does not have the above-mentioned drawbacks.
即ちこの発明は殆んど無色、無臭で経日安定性に優れた
馬油を含有することからなる化粧料組成物に係り、特に
原料馬油を非極性溶媒に溶解し、この溶液を吸着剤を充
填した吸着種に通液し、カラムクロマトグラフ的手法で
不純物を除去し、次いて非極性溶媒を留去することによ
り色、においがなく、経日安定性に優れた化粧料の原料
を提供するものである。That is, the present invention relates to a cosmetic composition containing horse oil that is almost colorless, odorless, and has excellent stability over time. By passing the liquid through an adsorbent filled with adsorbent, removing impurities using a column chromatographic method, and then distilling off the non-polar solvent, we can create raw materials for cosmetics that are colorless, odorless, and have excellent stability over time. This is what we provide.
（発明の構成）
本発明の使用する原料馬油は、粗製のものだ −けでな
く、これを従来の精製方法例えば蒸留、活性白土、活性
炭等を油中に混合する吸着処理−蒸気吹込処理、ウィン
タリング又は種々の程度に水素添加処理したものをすべ
て含む。(Structure of the Invention) The raw material horse oil used in the present invention is not only crude, but also purified by conventional refining methods such as distillation, adsorption treatment by mixing activated clay, activated carbon, etc. into the oil, and steam blowing treatment. , wintered or hydrogenated to varying degrees.
本発明のカラムクロマトグラフ的手法に用いる非極性溶
媒としては、石油エーテル、ｎ−ヘキサン、ｎ−ペンタ
ンのような脂肪族炭化水素、及び四塩化炭素のようなハ
ロゲン化炭素が好適に用いられる。又吸着剤としては、
例えばシリカゲル、珪酸マグネシウム、活性白土、ゼオ
ライト等、及びこれらの混合物があげられ、必要に応じ
て適宜選択できる。As the nonpolar solvent used in the column chromatographic method of the present invention, aliphatic hydrocarbons such as petroleum ether, n-hexane, and n-pentane, and halogenated carbons such as carbon tetrachloride are preferably used. Also, as an adsorbent,
Examples include silica gel, magnesium silicate, activated clay, zeolite, etc., and mixtures thereof, and can be appropriately selected as required.
ここで、カラムクロマトグラフ的手法とは上記非極性溶
媒に溶解した原料の馬油（馬脂を含む）を上記吸着剤を
充填した吸着種（又は吸着管）に通液して不純物を除去
する手法をいう、この処理の後の溶媒の留去は単に加熱
蒸留するだけでも減圧、蒸気吹込を併用してもよい。Here, the column chromatographic method is a method in which impurities are removed by passing the raw material horse oil (including horse tallow) dissolved in the above non-polar solvent through an adsorbent (or adsorption tube) filled with the above adsorbent. The method for distilling off the solvent after this treatment may be performed simply by heating distillation, or by using reduced pressure and steam blowing in combination.
本願に使用した色調ＡＰ ＨＡと言う語は日本油化学協
会制定の「基準油脂分析試験法」の色（ＡＰＨＡ法）、
に記載された方法で測定された価を意味する。又、この
発明の化粧料組成物は薬事法に言う化粧品、医薬部外品
、及び、医薬品にかかわらず、化粧のために使用される
すべての組成物を含む。The term APHA used in this application refers to the color of the "Standard Oil and Fat Analysis Test Method" established by the Japan Oil Chemists' Association (APHA method).
means the value measured by the method described in . Furthermore, the cosmetic composition of the present invention includes all compositions used for cosmetics, regardless of whether they are cosmetics, quasi-drugs, or pharmaceuticals as defined in the Pharmaceutical Affairs Law.
（効果）
本発明によって精製された精製馬油と従来法のものの一
例を比較すると次表のようになる。(Effects) A comparison of an example of refined horse oil refined by the present invention and that produced by the conventional method is as shown in the following table.
従来法 本発明の方法
におい 特有の動物臭 はとんど無臭色調（Ａ
Ｐ）ＩＡ） １００以上 １００以下以下にこ
の発明の実施例を示すことによってこの発明の効果をよ
り一層明確なものとする。Conventional method In the method of the present invention, the characteristic animal odor is mostly odorless color (A
P) IA) 100 or more and 100 or less By showing examples of the present invention below, the effects of the present invention will be made even clearer.
しかし、本発明はこの実施例によって限定されるもので
はない。However, the present invention is not limited to this example.
実施例１
淡褐色で特有の動物臭のある粗製馬油５０ｇを非極性溶
媒ｎ−ヘキサン１５０ｍ１に溶解し、吸着剤シリカゲル
１００ｇを充填したカラムに徐々に通液した後、更にｎ
−ヘキサン１００ｍ１を通液する。これらの通過液がら
ｎ−ヘキサンを蒸発留去して、精製油４３．ｇを得た。Example 1 50 g of crude horse oil, which is pale brown and has a characteristic animal odor, was dissolved in 150 ml of non-polar solvent n-hexane, and the solution was gradually passed through a column packed with 100 g of adsorbent silica gel, and then further n-hexane was dissolved.
- 100 ml of hexane is passed through. N-hexane was distilled off from these permeates to produce a refined oil of 43. I got g.
二〇Ｍ製油は殆んど無臭で、色調Ａ Ｐ １１ Ａ ５
０であった。20M oil is almost odorless and has a color tone of A P 11 A 5
It was 0.
実施例２
実施例１の方法で試作した精製馬油を用いて次の処方で
乳液を製造した。Example 2 A milky lotion was produced using the refined horse oil prepared by the method of Example 1 according to the following formulation.
重量％
精製馬油 ３２．０吸着精製ラ
ノリン １． ８コレステロール
１． ４シュガーエステルＳ−１１０
３，７
グリセリン ０．９防腐剤
０． １精製氷
６０．１計
１００．０この乳液は特に皮
膚に対するエモリエント性が高く、又、純白て殆ど簾臭
で安全性の高いものであった。Weight% Refined horse oil 32.0 Adsorption refined lanolin 1. 8 cholesterol
1. 4 Sugar ester S-110
3,7 Glycerin 0.9 Preservative
0. 1 purified ice
60.1 total
100.0 This emulsion had particularly high emollient properties for the skin, and was pure white with almost a blind odor and was highly safe.
比較例１
実施例１に使用した組成馬油１００ｇに活性白土５ｇを
混合し、吸着処理し、ろ退役水蒸気を吹き込んで脱臭処
理をした精製油はわずかではあるが特有の動物臭を持ち
、わずかに褐色（ＡＰＨＡ２００）であった、この精製
油を使用し実施例２の処方で作った乳液はわずかである
が、褐色を帯びにおいも実施例２のものより悪かった。Comparative Example 1 Composition used in Example 1 100 g of horse oil was mixed with 5 g of activated clay, treated with adsorption treatment, and deodorized by blowing in filtered water vapor.The refined oil had a slight but characteristic animal odor, and had a slight odor. The emulsion made using this refined oil according to the formulation of Example 2 was slightly brown in color (APHA 200), but had a brown color and a worse odor than that of Example 2.
Claims (1)
着剤を充填した吸着搭に通液し、カラムクロマトグラフ
的手法にて、不純物を吸着除去し、ついで非極性溶媒を
留去する精製方法で精製して得られた実質的に無臭で色
調はＡＰＨＡ１００以下の精製馬油を含有することを特
徴とする化粧料組成物。Raw horse oil (including horse tallow) is dissolved in a non-polar solvent, passed through an adsorption tower filled with an adsorbent, impurities are adsorbed and removed using a column chromatography method, and the non-polar solvent is then distilled off. 1. A cosmetic composition comprising purified horse oil that is substantially odorless and has an APHA of 100 or less in color, which is obtained by refining the oil by a refining method according to the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63040960A JPH01216909A (en) | 1988-02-24 | 1988-02-24 | Cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63040960A JPH01216909A (en) | 1988-02-24 | 1988-02-24 | Cosmetic composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01216909A true JPH01216909A (en) | 1989-08-30 |
Family
ID=12595049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63040960A Pending JPH01216909A (en) | 1988-02-24 | 1988-02-24 | Cosmetic composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01216909A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10194948A (en) * | 1997-01-17 | 1998-07-28 | Nippon Shizen Shokuhin Kk | Skin lotion |
| JPH10194923A (en) * | 1997-01-13 | 1998-07-28 | Nippon Zetotsuku Kk | Emulsified composition |
-
1988
- 1988-02-24 JP JP63040960A patent/JPH01216909A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10194923A (en) * | 1997-01-13 | 1998-07-28 | Nippon Zetotsuku Kk | Emulsified composition |
| JPH10194948A (en) * | 1997-01-17 | 1998-07-28 | Nippon Shizen Shokuhin Kk | Skin lotion |
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