JPH0117414B2 - - Google Patents
Info
- Publication number
- JPH0117414B2 JPH0117414B2 JP55106010A JP10601080A JPH0117414B2 JP H0117414 B2 JPH0117414 B2 JP H0117414B2 JP 55106010 A JP55106010 A JP 55106010A JP 10601080 A JP10601080 A JP 10601080A JP H0117414 B2 JPH0117414 B2 JP H0117414B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- alumina
- diameter
- carrier
- pores
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 71
- 239000010457 zeolite Substances 0.000 claims description 38
- 229910021536 Zeolite Inorganic materials 0.000 claims description 37
- 229910052751 metal Inorganic materials 0.000 claims description 37
- 239000002184 metal Substances 0.000 claims description 37
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 35
- 239000011148 porous material Substances 0.000 claims description 32
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 25
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 21
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 12
- 239000010937 tungsten Substances 0.000 claims description 12
- 229910052721 tungsten Inorganic materials 0.000 claims description 12
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 9
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052753 mercury Inorganic materials 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 238000002459 porosimetry Methods 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000011159 matrix material Substances 0.000 description 15
- 239000000295 fuel oil Substances 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000008188 pellet Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 239000011973 solid acid Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003631 expected effect Effects 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000007327 hydrogenolysis reaction Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229950006191 gluconic acid Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- -1 rare earth chloride Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10601080A JPS5730550A (en) | 1980-07-31 | 1980-07-31 | Catalyst composition for hydrogenolysis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10601080A JPS5730550A (en) | 1980-07-31 | 1980-07-31 | Catalyst composition for hydrogenolysis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5730550A JPS5730550A (en) | 1982-02-18 |
| JPH0117414B2 true JPH0117414B2 (ru) | 1989-03-30 |
Family
ID=14422693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10601080A Granted JPS5730550A (en) | 1980-07-31 | 1980-07-31 | Catalyst composition for hydrogenolysis |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5730550A (ru) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57141492A (en) * | 1981-02-26 | 1982-09-01 | Res Assoc Residual Oil Process<Rarop> | Hydrogenolysis of heavy oil |
| JPS60238150A (ja) * | 1984-05-14 | 1985-11-27 | Res Assoc Residual Oil Process<Rarop> | ニツケル含有結晶質アルミノシリケ−トの製造方法 |
| JPH0536099B1 (ru) * | 1985-03-29 | 1993-05-28 | ||
| JP4808172B2 (ja) * | 2006-03-30 | 2011-11-02 | Ｊｘ日鉱日石エネルギー株式会社 | 水素化分解触媒および燃料基材の製造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3449070A (en) * | 1963-02-21 | 1969-06-10 | Grace W R & Co | Stabilized zeolites |
| US3835027A (en) * | 1972-04-17 | 1974-09-10 | Union Oil Co | Hydrogenative conversion processes and catalyst for use therein |
| JPS50157300A (ru) * | 1973-11-24 | 1975-12-19 |
-
1980
- 1980-07-31 JP JP10601080A patent/JPS5730550A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3449070A (en) * | 1963-02-21 | 1969-06-10 | Grace W R & Co | Stabilized zeolites |
| US3835027A (en) * | 1972-04-17 | 1974-09-10 | Union Oil Co | Hydrogenative conversion processes and catalyst for use therein |
| JPS50157300A (ru) * | 1973-11-24 | 1975-12-19 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5730550A (en) | 1982-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4517073A (en) | Hydrocracking process and catalyst therefor | |
| KR100478078B1 (ko) | 중간 증류물을 생산하기 위한 하이드로크래킹 촉매 및 이의 제조방법 | |
| US4576711A (en) | Hydrocracking process and catalyst therefor | |
| CN1332757C (zh) | 一种裂化催化剂及其应用 | |
| RU2100074C1 (ru) | Композиция, пригодная для использования в качестве основного катализатора гидрогенизационных процессов, каталитическая композиция для превращения углеводородных нефтепродуктов и способ превращения углеводородов нефтепродуктов | |
| KR20070084402A (ko) | 철 함유 결정성 알루미노실리케이트 및 상기알루미노실리케이트를 포함하는 수소화 분해 촉매 및 상기촉매를 이용하는 수소화 분해법 | |
| JPH0239305B2 (ru) | ||
| US4563434A (en) | Hydrocracking catalyst | |
| JPH0536099B1 (ru) | ||
| US10723960B2 (en) | Method for hydrocracking hydrocarbon feedstocks using a catalyst comprising a zeolite and an amorphous mesoporous alumina | |
| JP7366043B2 (ja) | 炭化水素油の水素化処理触媒、その製造方法、および炭化水素油の水素化処理方法 | |
| JPH051290A (ja) | 酸化安定で、低温安定な基油及び中間留分の製法 | |
| JPH02214544A (ja) | 重質石油類の水素化分解触媒 | |
| JPH0228522B2 (ru) | ||
| JPH0117414B2 (ru) | ||
| JPS6148979B2 (ru) | ||
| JP2000086233A (ja) | 鉄含有結晶性アルミノシリケート | |
| JPH03273092A (ja) | 残油の水素化処理触媒 | |
| JPS6244974B2 (ru) | ||
| US4554263A (en) | Catalysts for hydrotreating heavy oils | |
| US4572779A (en) | Process for the dewaxing of hydrocarbon fractions | |
| JPH0112540B2 (ru) | ||
| US3346482A (en) | Hydrocracking heavy hydrocarbon oils | |
| US4263172A (en) | Cracking catalysts | |
| JPS6225418B2 (ru) |