JP7583017B2 - 尿素生成におけるビウレット生成の低減 - Google Patents
尿素生成におけるビウレット生成の低減 Download PDFInfo
- Publication number
- JP7583017B2 JP7583017B2 JP2022500697A JP2022500697A JP7583017B2 JP 7583017 B2 JP7583017 B2 JP 7583017B2 JP 2022500697 A JP2022500697 A JP 2022500697A JP 2022500697 A JP2022500697 A JP 2022500697A JP 7583017 B2 JP7583017 B2 JP 7583017B2
- Authority
- JP
- Japan
- Prior art keywords
- urea
- lines
- line
- unit
- granulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims description 137
- 239000004202 carbamide Substances 0.000 title claims description 137
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 title claims description 33
- 230000015572 biosynthetic process Effects 0.000 title claims description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 23
- 238000005469 granulation Methods 0.000 claims description 53
- 230000003179 granulation Effects 0.000 claims description 53
- 238000000034 method Methods 0.000 claims description 22
- 238000003786 synthesis reaction Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 5
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 28
- 239000000047 product Substances 0.000 description 22
- 239000000243 solution Substances 0.000 description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- 229910021529 ammonia Inorganic materials 0.000 description 13
- 239000001569 carbon dioxide Substances 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000003337 fertilizer Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- CYJRNFFLTBEQSQ-UHFFFAOYSA-N 8-(3-methyl-1-benzothiophen-5-yl)-N-(4-methylsulfonylpyridin-3-yl)quinoxalin-6-amine Chemical compound CS(=O)(=O)C1=C(C=NC=C1)NC=1C=C2N=CC=NC2=C(C=1)C=1C=CC2=C(C(=CS2)C)C=1 CYJRNFFLTBEQSQ-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229940124447 delivery agent Drugs 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
- C05C9/005—Post-treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/02—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
- C07C273/14—Separation; Purification; Stabilisation; Use of additives
- C07C273/16—Separation; Purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/16—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
- Glanulating (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2024002576A JP2024041900A (ja) | 2019-07-10 | 2024-01-11 | 尿素生成におけるビウレット生成の低減 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102019118702.8 | 2019-07-10 | ||
| DE102019118702.8A DE102019118702A1 (de) | 2019-07-10 | 2019-07-10 | Reduzierung der biuretgeneration in der harnstoffproduktion |
| PCT/EP2020/065784 WO2021004713A1 (de) | 2019-07-10 | 2020-06-08 | Reduzierung der biuretgeneration in der harnstoffproduktion |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2024002576A Division JP2024041900A (ja) | 2019-07-10 | 2024-01-11 | 尿素生成におけるビウレット生成の低減 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2022539824A JP2022539824A (ja) | 2022-09-13 |
| JP7583017B2 true JP7583017B2 (ja) | 2024-11-13 |
Family
ID=71103355
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022500697A Active JP7583017B2 (ja) | 2019-07-10 | 2020-06-08 | 尿素生成におけるビウレット生成の低減 |
| JP2024002576A Pending JP2024041900A (ja) | 2019-07-10 | 2024-01-11 | 尿素生成におけるビウレット生成の低減 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2024002576A Pending JP2024041900A (ja) | 2019-07-10 | 2024-01-11 | 尿素生成におけるビウレット生成の低減 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP3997051A1 (de) |
| JP (2) | JP7583017B2 (de) |
| DE (1) | DE102019118702A1 (de) |
| WO (1) | WO2021004713A1 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116212419B (zh) * | 2022-12-28 | 2025-11-11 | 重庆建峰化工股份有限公司 | 一种降低二氧化碳尿素工艺产品中缩二脲含量的反应系统 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070059446A1 (en) | 2003-11-10 | 2007-03-15 | Mutsers Stanislaus M P | Process for the preparation of urea granules |
| JP2007534585A (ja) | 2004-02-05 | 2007-11-29 | ウーデ・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 尿素含有顆粒肥料を製造する方法でのビウレットおよび有利アンモニアの軽減 |
| US20140206902A1 (en) | 2011-08-17 | 2014-07-24 | Stamicarbon B.V. | Urea production process characterized by short urea melt transportation time between last concentrator and prilling tower |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IE32160B1 (en) | 1967-07-03 | 1973-05-02 | Ici Ltd | Improvements in and relating to the production of auto-condensation products of urea,in particular biuret |
| AT281609B (de) | 1968-08-21 | 1970-05-25 | Paul Bungartz | Vertikale Kreiselpumpe |
| AT291003B (de) | 1969-04-28 | 1971-06-25 | Paul Bungartz | Kreiselpumpe mit axialem Eintritt und fliegend gelagertem Laufrad |
| GB1404098A (en) | 1973-05-16 | 1975-08-28 | Mexico Guanos | Process for reducing the biuret content in urea |
| IE46841B1 (en) | 1977-06-09 | 1983-10-05 | Azote Sa Cie Neerlandaise | Improvements in or relating to urea granulation |
| JPS57171956A (en) | 1981-04-16 | 1982-10-22 | Toyo Eng Corp | Concentration of aqueous solution of urea |
| US4947308A (en) | 1989-04-17 | 1990-08-07 | Zdzislaw Gulczynski | High power switching power supply |
| NZ331531A (en) | 1997-09-04 | 2000-01-28 | Toyo Engineering Corp | method for granulation and granulator |
| DE19744404A1 (de) | 1997-10-08 | 1999-04-15 | Piesteritz Stickstoff | Verfahren zur Herstellung von Dicyandiamid enthaltenden Harnstoff-Düngemittel-Granulaten |
| JP6306571B2 (ja) | 2012-05-03 | 2018-04-04 | スタミカーボン・ベー・フェー | 尿素製造プラント |
| DE102017108842A1 (de) * | 2017-04-25 | 2018-10-25 | Thyssenkrupp Ag | Verfahren und Vorrichtung zur Herstellung von Harnstoff |
-
2019
- 2019-07-10 DE DE102019118702.8A patent/DE102019118702A1/de active Pending
-
2020
- 2020-06-08 JP JP2022500697A patent/JP7583017B2/ja active Active
- 2020-06-08 EP EP20733371.7A patent/EP3997051A1/de active Pending
- 2020-06-08 WO PCT/EP2020/065784 patent/WO2021004713A1/de not_active Ceased
-
2024
- 2024-01-11 JP JP2024002576A patent/JP2024041900A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070059446A1 (en) | 2003-11-10 | 2007-03-15 | Mutsers Stanislaus M P | Process for the preparation of urea granules |
| JP2007534585A (ja) | 2004-02-05 | 2007-11-29 | ウーデ・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 尿素含有顆粒肥料を製造する方法でのビウレットおよび有利アンモニアの軽減 |
| US20140206902A1 (en) | 2011-08-17 | 2014-07-24 | Stamicarbon B.V. | Urea production process characterized by short urea melt transportation time between last concentrator and prilling tower |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2024041900A (ja) | 2024-03-27 |
| WO2021004713A1 (de) | 2021-01-14 |
| JP2022539824A (ja) | 2022-09-13 |
| DE102019118702A1 (de) | 2021-01-14 |
| EP3997051A1 (de) | 2022-05-18 |
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