JP7576580B2 - 熱可塑性ポリマーのための発泡剤ブレンド - Google Patents

熱可塑性ポリマーのための発泡剤ブレンド Download PDF

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JP7576580B2
JP7576580B2 JP2021576506A JP2021576506A JP7576580B2 JP 7576580 B2 JP7576580 B2 JP 7576580B2 JP 2021576506 A JP2021576506 A JP 2021576506A JP 2021576506 A JP2021576506 A JP 2021576506A JP 7576580 B2 JP7576580 B2 JP 7576580B2
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blowing agent
foam
thermoplastic polymer
hexafluoro
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JP2022539332A (ja
JP2022539332A5 (https=
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コントマリス コンスタンティノス
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ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/142—Compounds containing oxygen but no halogen atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22—After-treatment of expandable particles; Forming foamed products
    • C08J9/228—Forming foamed products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/20—Ternary blends of expanding agents
    • C08J2203/202—Ternary blends of expanding agents of physical blowing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C08J2325/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0019—Use of organic additives halogenated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)
JP2021576506A 2019-06-24 2020-06-23 熱可塑性ポリマーのための発泡剤ブレンド Active JP7576580B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962865743P 2019-06-24 2019-06-24
US62/865,743 2019-06-24
PCT/US2020/039053 WO2020263775A1 (en) 2019-06-24 2020-06-23 Blowing agent blends for thermoplastic polymers

Publications (3)

Publication Number Publication Date
JP2022539332A JP2022539332A (ja) 2022-09-08
JP2022539332A5 JP2022539332A5 (https=) 2023-04-25
JP7576580B2 true JP7576580B2 (ja) 2024-10-31

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JP2021576506A Active JP7576580B2 (ja) 2019-06-24 2020-06-23 熱可塑性ポリマーのための発泡剤ブレンド

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US (1) US20220235193A1 (https=)
EP (1) EP3986961A1 (https=)
JP (1) JP7576580B2 (https=)
CN (1) CN114026160A (https=)
CA (1) CA3138904A1 (https=)
WO (1) WO2020263775A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240158597A1 (en) * 2021-06-09 2024-05-16 The Chemours Company Fc, Llc Compositions comprising e-hfo-1336mzz and methyl formate and their use as expansion agents for thermoplastic foam
MX2024005280A (es) * 2021-11-16 2024-07-10 Honeywell Int Inc Agentes neumatogenos para espuma de poliestireno extrudido y espuma de poliestireno extrudido y métodos de espumado.
US20240301157A1 (en) * 2023-03-08 2024-09-12 Honeywell International Inc. Blowing agents for thermoplastic foam, thermoplastic foams and methods of foaming

Citations (6)

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Publication number Priority date Publication date Assignee Title
JP2010526171A (ja) 2007-04-27 2010-07-29 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Ｚ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンの共沸および共沸様組成物
JP2012177052A (ja) 2011-02-28 2012-09-13 Jsp Corp ポリスチレン系樹脂押出発泡板
JP2013514450A (ja) 2009-12-16 2013-04-25 ハネウェル・インターナショナル・インコーポレーテッド シス−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンの組成物及び使用
WO2018057571A1 (en) 2016-09-23 2018-03-29 The Chemours Company Fc, Llc Novel foams with z-1,1,1,4,4,4-hexafluoro-2-butene
WO2019075040A1 (en) 2017-10-10 2019-04-18 The Chemours Company Fc, Llc PROCESS FOR MANUFACTURING THERMOPLASTIC FOAM CONTAINING HFO-1336MZZ (Z) AND HFO-1336MZZ (E)
JP2019515112A (ja) 2016-05-06 2019-06-06 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー ポリスチレンを含む熱可塑性ポリマーを発泡させるためのＺ−ＨＦＯ−１３３６ｍｚｚ発泡剤

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US5221492A (en) * 1991-08-23 1993-06-22 E. I. Du Pont De Nemours And Company Azeotropic mixture of perfluoropropane and dimethyl ether
US8309619B2 (en) * 2004-09-03 2012-11-13 Pactiv LLC Reduced-VOC and non-VOC blowing agents for making expanded and extruded thermoplastic foams
EP2132257B1 (en) * 2007-03-27 2017-10-25 Dow Global Technologies LLC Alkenyl aromatic polymer foam comprising fluorinated alkene blowing agents
CA2708274C (en) * 2007-12-19 2016-10-18 E. I. Du Pont De Nemours And Company Foam-forming compositions containing azeotropic or azeotrope-like mixtures containing z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyisocyanate-based foams
CN102167842A (zh) * 2011-01-26 2011-08-31 南京法宁格节能科技有限公司 聚苯乙烯挤塑板生产用二氧化碳组合发泡剂及其制备方法
MX2017015181A (es) * 2015-05-29 2018-04-13 Owens Corning Intellectual Capital Llc Espuma de poliestireno extruido.
EP3452537B1 (en) * 2016-05-06 2024-08-21 The Chemours Company FC, LLC Foaming of styrene polymer
KR102579812B1 (ko) * 2017-05-10 2023-09-20 더 케무어스 컴퍼니 에프씨, 엘엘씨 폴리스티렌을 포함하는 열가소성 중합체를 발포시키기 위한 Z-HFO-1336mzz 발포제 블렌드
US20240158597A1 (en) * 2021-06-09 2024-05-16 The Chemours Company Fc, Llc Compositions comprising e-hfo-1336mzz and methyl formate and their use as expansion agents for thermoplastic foam

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010526171A (ja) 2007-04-27 2010-07-29 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Ｚ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンの共沸および共沸様組成物
JP2013514450A (ja) 2009-12-16 2013-04-25 ハネウェル・インターナショナル・インコーポレーテッド シス−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンの組成物及び使用
JP2012177052A (ja) 2011-02-28 2012-09-13 Jsp Corp ポリスチレン系樹脂押出発泡板
JP2019515112A (ja) 2016-05-06 2019-06-06 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー ポリスチレンを含む熱可塑性ポリマーを発泡させるためのＺ−ＨＦＯ−１３３６ｍｚｚ発泡剤
WO2018057571A1 (en) 2016-09-23 2018-03-29 The Chemours Company Fc, Llc Novel foams with z-1,1,1,4,4,4-hexafluoro-2-butene
WO2019075040A1 (en) 2017-10-10 2019-04-18 The Chemours Company Fc, Llc PROCESS FOR MANUFACTURING THERMOPLASTIC FOAM CONTAINING HFO-1336MZZ (Z) AND HFO-1336MZZ (E)

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EP3986961A1 (en) 2022-04-27
US20220235193A1 (en) 2022-07-28
CN114026160A (zh) 2022-02-08
JP2022539332A (ja) 2022-09-08
CA3138904A1 (en) 2020-12-30
WO2020263775A1 (en) 2020-12-30

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