JP7424985B2 - 少なくとも1つのバリアコート層を有する板紙構造物 - Google Patents
少なくとも1つのバリアコート層を有する板紙構造物 Download PDFInfo
- Publication number
- JP7424985B2 JP7424985B2 JP2020543917A JP2020543917A JP7424985B2 JP 7424985 B2 JP7424985 B2 JP 7424985B2 JP 2020543917 A JP2020543917 A JP 2020543917A JP 2020543917 A JP2020543917 A JP 2020543917A JP 7424985 B2 JP7424985 B2 JP 7424985B2
- Authority
- JP
- Japan
- Prior art keywords
- paperboard
- coat layer
- binder
- paperboard structure
- barrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000004888 barrier function Effects 0.000 title claims description 186
- 239000011087 paperboard Substances 0.000 title claims description 166
- 238000010276 construction Methods 0.000 title claims description 16
- 239000000049 pigment Substances 0.000 claims description 100
- 239000011230 binding agent Substances 0.000 claims description 96
- 239000000758 substrate Substances 0.000 claims description 66
- 230000009477 glass transition Effects 0.000 claims description 31
- 230000000903 blocking effect Effects 0.000 claims description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 28
- 238000012360 testing method Methods 0.000 claims description 24
- 239000004927 clay Substances 0.000 claims description 23
- 239000008199 coating composition Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 239000011436 cob Substances 0.000 claims description 19
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims description 15
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 14
- 238000004806 packaging method and process Methods 0.000 claims description 10
- 235000013305 food Nutrition 0.000 claims description 9
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 5
- 239000011118 polyvinyl acetate Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 3
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims 2
- 239000010410 layer Substances 0.000 description 116
- 238000000576 coating method Methods 0.000 description 34
- 239000002245 particle Substances 0.000 description 34
- 239000011248 coating agent Substances 0.000 description 27
- 239000000523 sample Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 239000000123 paper Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000835 fiber Substances 0.000 description 11
- 241000723377 Coffea Species 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 235000016213 coffee Nutrition 0.000 description 9
- 235000013353 coffee beverage Nutrition 0.000 description 9
- 238000010998 test method Methods 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 235000013361 beverage Nutrition 0.000 description 3
- 235000015243 ice cream Nutrition 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 101100386518 Caenorhabditis elegans dbl-1 gene Proteins 0.000 description 1
- 241000227999 Coffea canephora Species 0.000 description 1
- -1 Polyethylene Polymers 0.000 description 1
- 241000274582 Pycnanthus angolensis Species 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000020965 cold beverage Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 235000012171 hot beverage Nutrition 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862632265P | 2018-02-19 | 2018-02-19 | |
| US62/632,265 | 2018-02-19 | ||
| PCT/US2019/016633 WO2019160706A1 (en) | 2018-02-19 | 2019-02-05 | Paperboard structure with at least one barrier coating layer |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2021514034A JP2021514034A (ja) | 2021-06-03 |
| JP2021514034A5 JP2021514034A5 (https=) | 2022-02-03 |
| JPWO2019160706A5 JPWO2019160706A5 (https=) | 2022-02-03 |
| JP7424985B2 true JP7424985B2 (ja) | 2024-01-30 |
Family
ID=65494566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020543917A Active JP7424985B2 (ja) | 2018-02-19 | 2019-02-05 | 少なくとも1つのバリアコート層を有する板紙構造物 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US11299855B2 (https=) |
| EP (1) | EP3755841A1 (https=) |
| JP (1) | JP7424985B2 (https=) |
| CN (1) | CN112055769A (https=) |
| CA (1) | CA3102029A1 (https=) |
| MX (1) | MX2020007502A (https=) |
| WO (1) | WO2019160706A1 (https=) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2020007502A (es) * | 2018-02-19 | 2020-09-14 | Westrock Mwv Llc | Estructura de carton con por lo menos una capa de recubrimiento de barrera. |
| CN112352079A (zh) | 2018-04-27 | 2021-02-09 | 维实洛克Mwv有限责任公司 | 可热封纸板结构和相关联的基于纸板的容器 |
| SE543216C2 (en) * | 2019-01-25 | 2020-10-27 | Stora Enso Oyj | Heat-sealable paperboard |
| CA3088440A1 (en) | 2019-07-26 | 2021-01-26 | Cascades Sonoco Inc. | Heat sealable paper-based substrate coated with water-based coatings, its process of manufacturing and uses thereof |
| JP7335119B2 (ja) * | 2019-09-20 | 2023-08-29 | 北越コーポレーション株式会社 | 包装用紙 |
| WO2021150404A1 (en) * | 2020-01-22 | 2021-07-29 | Westrock Mwv, Llc | Heat-sealable paperboard structures and methods |
| CN115427632A (zh) * | 2020-03-04 | 2022-12-02 | 维实洛克Mwv有限责任公司 | 耐咖啡着色的纤维素结构及相关容器和方法 |
| KR102393249B1 (ko) * | 2020-03-16 | 2022-05-03 | 한국제지 주식회사 | 친환경 종이컵 원지 |
| KR102393254B1 (ko) * | 2020-03-16 | 2022-05-03 | 한국제지 주식회사 | 친환경 종이컵 원지 제조방법 |
| EP4121593A1 (en) * | 2020-03-20 | 2023-01-25 | WestRock MWV, LLC | Barrier recycled paperboard and method for manufacturing thereof |
| TWI847004B (zh) * | 2020-06-09 | 2024-07-01 | 新川創新股份有限公司 | 塗料組合物以及紙材 |
| TWI814014B (zh) * | 2020-06-23 | 2023-09-01 | 新川創新股份有限公司 | 紙材以及使用其的軟包裝材 |
| JP7268648B2 (ja) * | 2020-06-30 | 2023-05-08 | 王子ホールディングス株式会社 | ヒートシール紙 |
| USD980069S1 (en) | 2020-07-14 | 2023-03-07 | Ball Corporation | Metallic dispensing lid |
| US12234059B2 (en) | 2020-10-08 | 2025-02-25 | Dart Container Corporation | Method of forming a paper container and related materials |
| US12168551B2 (en) | 2021-03-01 | 2024-12-17 | Ball Corporation | Metal container and end closure with seal |
| CN114381971A (zh) * | 2021-12-15 | 2022-04-22 | 金华盛纸业(苏州工业园区)有限公司 | 一种纸袋的制备方法及环保型纸袋 |
| WO2023157217A1 (ja) * | 2022-02-18 | 2023-08-24 | 日本製紙株式会社 | ヒートシール紙 |
| WO2024044448A1 (en) * | 2022-08-26 | 2024-02-29 | Westrock Mww, Llc | Coated cellulosic substrates and coated cellulosic containers |
| WO2024167775A1 (en) * | 2023-02-06 | 2024-08-15 | Westrock Mwv, Llc | Sustainable cellulosic structures for barrier applications |
| CN116497629A (zh) * | 2023-04-20 | 2023-07-28 | 金东纸业(江苏)股份有限公司 | Cck纸的制备方法及cck纸 |
| US20240392140A1 (en) * | 2023-05-24 | 2024-11-28 | Westrock Mwv, Llc | Dual ovenable, repulpable coated paperboard for food containers and method for manufacturing thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001081695A (ja) | 1999-09-10 | 2001-03-27 | Keiwa Inc | バリア紙 |
| JP2001248097A (ja) | 1999-12-27 | 2001-09-14 | Oji Paper Co Ltd | 包装用紙 |
| JP2015500927A (ja) | 2011-12-06 | 2015-01-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | バリヤーコーティングを有する紙包装及び厚紙包装 |
| WO2017100316A1 (en) | 2015-12-09 | 2017-06-15 | Cargill, Incorporated | Barrier coatings |
| JP2018505323A (ja) | 2015-02-11 | 2018-02-22 | ウエストロック・エム・ダブリュー・ヴイ・エルエルシー | 耐油性、耐グリース性、及び耐湿性板紙 |
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| US10562659B2 (en) | 2017-09-08 | 2020-02-18 | Georgia-Pacific Bleached Board LLC | Heat sealable barrier coatings for paperboard |
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| DE102017131277A1 (de) | 2017-12-22 | 2019-06-27 | Mitsubishi Hitec Paper Europe Gmbh | Recyclingfähiges Barrierepapier |
| DE102019103343A1 (de) | 2018-02-13 | 2019-08-14 | Mitsubishi Hitec Paper Europe Gmbh | Heißsiegelfähiges Barrierepapier |
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| SE543572C2 (en) | 2018-12-10 | 2021-03-30 | Stora Enso Oyj | Repulpable and heat-sealable packaging material |
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2019
- 2019-02-05 MX MX2020007502A patent/MX2020007502A/es unknown
- 2019-02-05 CA CA3102029A patent/CA3102029A1/en active Pending
- 2019-02-05 EP EP19706126.0A patent/EP3755841A1/en not_active Withdrawn
- 2019-02-05 WO PCT/US2019/016633 patent/WO2019160706A1/en not_active Ceased
- 2019-02-05 CN CN201980014270.9A patent/CN112055769A/zh active Pending
- 2019-02-05 US US16/267,865 patent/US11299855B2/en active Active
- 2019-02-05 JP JP2020543917A patent/JP7424985B2/ja active Active
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2022
- 2022-03-08 US US17/689,041 patent/US12152346B2/en active Active
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| JP2001081695A (ja) | 1999-09-10 | 2001-03-27 | Keiwa Inc | バリア紙 |
| JP2001248097A (ja) | 1999-12-27 | 2001-09-14 | Oji Paper Co Ltd | 包装用紙 |
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| JP2018505323A (ja) | 2015-02-11 | 2018-02-22 | ウエストロック・エム・ダブリュー・ヴイ・エルエルシー | 耐油性、耐グリース性、及び耐湿性板紙 |
| WO2017100316A1 (en) | 2015-12-09 | 2017-06-15 | Cargill, Incorporated | Barrier coatings |
Also Published As
| Publication number | Publication date |
|---|---|
| CA3102029A1 (en) | 2019-08-22 |
| US11299855B2 (en) | 2022-04-12 |
| MX2020007502A (es) | 2020-09-14 |
| US20220195671A1 (en) | 2022-06-23 |
| WO2019160706A1 (en) | 2019-08-22 |
| US12152346B2 (en) | 2024-11-26 |
| JP2021514034A (ja) | 2021-06-03 |
| BR112020013660A2 (pt) | 2020-12-01 |
| CN112055769A (zh) | 2020-12-08 |
| EP3755841A1 (en) | 2020-12-30 |
| US20190257034A1 (en) | 2019-08-22 |
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