JP7403931B2 - Resin molded bodies and fiber reinforced resin molded bodies - Google Patents

Resin molded bodies and fiber reinforced resin molded bodies Download PDF

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JP7403931B2
JP7403931B2 JP2022149936A JP2022149936A JP7403931B2 JP 7403931 B2 JP7403931 B2 JP 7403931B2 JP 2022149936 A JP2022149936 A JP 2022149936A JP 2022149936 A JP2022149936 A JP 2022149936A JP 7403931 B2 JP7403931 B2 JP 7403931B2
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sheet
base material
fiber
thermosetting resin
surface layer
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JP2022171921A (en
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淳 大藪
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Inoac Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/20Making multilayered or multicoloured articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/04Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material

Description

本開示は、樹脂成形体に関する。 The present disclosure relates to a resin molded article.

従来、基材としてのプリプレグにシートモールディングコンパウンドが積層されてなる繊維強化樹脂成形体が知られている(例えば、特許文献1参照)。このような繊維強化樹脂成形体では、シートモールディングコンパウンドによって、繊維強化樹脂成形体の表面に補強リブやボスのような局所的な突部等が形成される。 BACKGROUND ART Conventionally, a fiber-reinforced resin molded body is known in which a sheet molding compound is laminated on a prepreg as a base material (for example, see Patent Document 1). In such a fiber-reinforced resin molded product, local protrusions such as reinforcing ribs and bosses are formed on the surface of the fiber-reinforced resin molded product using a sheet molding compound.

特許第4015584号公報(段落[0020])Patent No. 4015584 (paragraph [0020])

従来の樹脂成形体において、シートモールディングコンパウンドからなる部位と基材との固定の安定化が望まれている。 In conventional resin molded articles , it is desired to stabilize the fixation between the portion made of the sheet molding compound and the base material.

上記課題を解決するためになされた発明の第1態様は、板状の基材の表裏のうち少なくとも一方の面に、第1の熱硬化性樹脂を含むシートモールディングコンパウンドからなる表層構成部が部分的に積層されてなり、前記基材は、前記シートモールディングコンパウンドに含まれる繊維よりも繊維長の長い補強繊維と第2の熱硬化性樹脂とを含み、前記第1の熱硬化性樹脂と前記第2の熱硬化性樹脂とが硬化することにより、前記基材と前記表層構成部とが一体化した繊維強化樹脂成形体であって、前記表層構成部は、前記基材に埋め込まれ、前記基材と反対側を向く面に、突部又は凹部からなる賦形部を有し、前記表層構成部のうち前記賦形部以外の部分は、前記基材と略面一に配置され、前記第2の熱硬化性樹脂は、前記第1の熱硬化性樹脂に比べて、硬化温度が高い、又は、硬化時間が長い、繊維強化樹脂成形体である。 A first aspect of the invention made to solve the above problem is that a surface layer component made of a sheet molding compound containing a first thermosetting resin is partially formed on at least one of the front and back surfaces of a plate-shaped base material. The base material includes reinforcing fibers having a longer fiber length than the fibers contained in the sheet molding compound, and a second thermosetting resin, and the first thermosetting resin and the A fiber-reinforced resin molded article in which the base material and the surface layer component are integrated by curing the second thermosetting resin, wherein the surface layer component is embedded in the base material and the surface layer component is embedded in the base material. a shaped part consisting of a protrusion or a recess on a surface facing opposite to the base material, a portion of the surface layer component other than the shaped part is arranged substantially flush with the base material; The second thermosetting resin is a fiber-reinforced resin molded article having a higher curing temperature or a longer curing time than the first thermosetting resin.

ここで、硬化温度が高いとは、熱硬化性樹脂を一定時間で硬化させるために必要な温度が高い、という意味である。また、硬化時間が長いとは、熱硬化性樹脂を一定の温度で硬化させるために必要な時間が長い、という意味である。 Here, a high curing temperature means that the temperature required to cure the thermosetting resin in a certain period of time is high. Moreover, a long curing time means that the time required to cure the thermosetting resin at a constant temperature is long.

発明の第2態様は、前記基材は、熱硬化性樹脂発泡体からなり連続気泡を有する発泡シートの表裏のうち少なくとも一方の面に、前記補強繊維からなる1対の繊維シートが積層されると共に、前記発泡シートと前記1対の繊維シートとに前記第2の熱硬化性樹脂が含浸してなり、前記発泡シートのうち、厚み方向で前記表層構成部と重なる部分は、厚み方向で前記表層構成部と重ならない部分に比べて、厚み方向に圧縮されている、第1態様に記載の繊維強化樹脂成形体である。 A second aspect of the invention is that the base material is made of a thermosetting resin foam and a pair of fiber sheets made of the reinforcing fibers are laminated on at least one of the front and back surfaces of a foam sheet having open cells. In addition, the foamed sheet and the pair of fiber sheets are impregnated with the second thermosetting resin, and the portion of the foamed sheet that overlaps with the surface layer component in the thickness direction is impregnated with the second thermosetting resin. The fiber-reinforced resin molded article according to the first aspect is compressed in the thickness direction compared to a portion that does not overlap with the surface layer constituent portion.

発明の第3態様は、前記基材の前記少なくとも一方の面には、複数の前記表層構成部が互いに離れて設けられ、各表層構成部に前記賦形部が設けられている、第1態様又は第2態様に記載の繊維強化樹脂成形体である。 A third aspect of the invention is the first aspect, wherein a plurality of the surface layer constituent parts are provided on the at least one surface of the base material at a distance from each other, and each surface layer constituent part is provided with the shaping part . Or the fiber-reinforced resin molded article according to the second aspect .

発明の第4態様は、第1の熱硬化性樹脂を含むシートモールディングコンパウンドと、前記シートモールディングコンパウンドに含まれる繊維よりも繊維長の長い補強繊維と第2の熱硬化性樹脂とを含む基材用シートと、を用意し、前記シートモールディングコンパウンドを前記基材用シートの表裏のうち少なくとも一方の面に部分的に重ね、加熱プレス成形により、前記第1の熱硬化性樹脂と前記第2の熱硬化性樹脂とを硬化させて、前記基材用シートから形成した基材と、前記シートモールディングコンパウンドから形成した表層構成部と、を一体化する繊維強化樹脂成形体の製造方法であって、前記表層構成部を形成する際に、前記表層構成部のうち前記基材と反対側を向く面に、突部又は凹部からなる賦形部を形成し、前記第2の熱硬化性樹脂として、前記第1の熱硬化性樹脂に比べて、前記加熱プレス成形の温度において硬化時間が長いものを用いる、繊維強化樹脂成形体の製造方法である。 A fourth aspect of the invention is a base material comprising a sheet molding compound containing a first thermosetting resin, reinforcing fibers having a longer fiber length than the fibers contained in the sheet molding compound, and a second thermosetting resin. The sheet molding compound is partially overlapped on at least one surface of the front and back surfaces of the base sheet, and the first thermosetting resin and the second thermosetting resin are heated and press-molded. A method for producing a fiber-reinforced resin molded article, which comprises curing a thermosetting resin to integrate a base material formed from the base material sheet and a surface layer component formed from the sheet molding compound, When forming the surface layer component, a shaped portion consisting of a protrusion or a recess is formed on the surface of the surface layer component facing opposite to the base material, and as the second thermosetting resin, This is a method for producing a fiber reinforced resin molded body, using a thermosetting resin that takes a longer time to harden at the temperature of the hot press molding than the first thermosetting resin.

発明の第5態様は、前記基材用シートとして、熱硬化性樹脂発泡体からなり連続気泡を有する発泡シートの表裏のうち少なくとも一方の面に、前記補強繊維からなる繊維シートが積層され、前記第2の熱硬化性樹脂が含浸したものを用いる、第4態様に記載の繊維強化樹脂成形体の製造方法である。 A fifth aspect of the invention is that, as the base material sheet, a fiber sheet made of the reinforcing fiber is laminated on at least one of the front and back surfaces of a foamed sheet made of a thermosetting resin foam and having open cells, and This is a method for producing a fiber-reinforced resin molded article according to the fourth aspect , using a fiber-reinforced resin molded article impregnated with the second thermosetting resin.

発明の第6態様は、前記加熱プレス成形を行うための成形金型の成形面に、前記表層構成部の前記賦形部を形成するための表面形成部を複数設けておき、前記加熱プレス成形を行うにあたって、前記シートモールディングコンパウンドを複数枚用意し、それら複数枚のシートモールディングコンパウンドを、互いに離して前記成形面の前記表面形成部に重ねる、第4態様又は第5態様に記載の繊維強化樹脂成形体の製造方法である。 A sixth aspect of the invention is that a plurality of surface forming portions for forming the shaping portion of the surface layer forming portion are provided on the molding surface of the molding die for performing the hot press molding, and the hot press molding The fiber-reinforced resin according to the fourth aspect or the fifth aspect , wherein a plurality of sheet molding compounds are prepared, and the plurality of sheet molding compounds are separated from each other and stacked on the surface forming portion of the molding surface. This is a method for manufacturing a molded object.

発明の第1態様、第4態様では、基材に含まれる第2の熱硬化性樹脂が、シートモールディングコンパウンドに含まれる第1の熱硬化性樹脂よりも、硬化温度が高いか、又は、硬化時間が長くなっている。従って、繊維強化樹脂成形体の製造時に、第1の熱硬化性樹脂を硬化させてから、第2の熱硬化性樹脂を硬化させることができ、第1の熱硬化性樹脂が硬化して硬くなった表層構成部の形状に、基材を追従させた状態に形成することが容易となる。これにより、表層構成部が基材に埋め込まれて、シートモールディングコンパウンドからなる表層構成部と基材との固定の安定を図ることが可能となる。また、表層構成部のうち突部又は凹部からなる賦形部以外の部分を、基材と略面一に配置することで、突部の突出量又は凹部の深さについて寸法精度の安定化を図ることが可能となる。 In the first and fourth aspects of the invention , the second thermosetting resin contained in the base material has a higher curing temperature than the first thermosetting resin contained in the sheet molding compound, or Time is getting longer. Therefore, when manufacturing a fiber-reinforced resin molded article, the first thermosetting resin can be cured and then the second thermosetting resin can be cured, and the first thermosetting resin can be cured and hardened. It becomes easy to form the base material in a state that follows the shape of the surface layer component. Thereby, the surface layer component is embedded in the base material, and it becomes possible to stabilize the fixation between the surface layer component made of the sheet molding compound and the base material. In addition, by arranging the portion of the surface layer component other than the shaped portion consisting of protrusions or recesses substantially flush with the base material, the dimensional accuracy of the protrusion amount of the protrusion or the depth of the recess can be stabilized. It becomes possible to achieve this goal.

発明の第2態様では、基材には、連続気泡を有する発泡シートが設けられる。そして、発泡シートのうち厚み方向で表層構成部と重なる部分は、厚み方向で表層構成部と重ならない部分に比べて、厚み方向に圧縮されている。本発明によれば、発泡シートのうち厚み方向で表層構成部と重なる部分が圧縮されることによって、表層構成部を基材に埋め込まれた状態に形成し易くすることができる。また、発明の第5態様によっても、発泡シートのうち厚み方向でシートモールディングコンパウンドと重なる部分を圧縮することにより、表層構成部を基材に埋め込まれた状態に形成し易くすることができる。 In the second aspect of the invention , the base material is provided with a foam sheet having open cells. The portion of the foam sheet that overlaps with the surface layer component in the thickness direction is compressed in the thickness direction compared to the portion that does not overlap with the surface layer component in the thickness direction. According to the present invention, by compressing the portion of the foam sheet that overlaps with the surface layer component in the thickness direction, it is possible to easily form the surface layer component in a state embedded in the base material. Also, according to the fifth aspect of the invention , by compressing the portion of the foam sheet that overlaps with the sheet molding compound in the thickness direction, it is possible to easily form the surface layer component in a state embedded in the base material.

発明の第3態様、第6態様では、突部又は凹部からなる賦形部が複数設けられる。本発明によれば、複数の賦形部全てに亘って1つのシートモールディングコンパウンドからなる表層構成部が形成される場合に比べて、表層構成部を形成するためのシートモールディングコンパウンドの使用量を少なくすることが可能となる。 In the third and sixth aspects of the invention , a plurality of shaped parts each consisting of a protrusion or a recess are provided. According to the present invention, the amount of sheet molding compound used to form the surface layer component can be reduced compared to the case where the surface layer component made of one sheet molding compound is formed over all of the plurality of shaped parts. It becomes possible to do so.

本開示の一実施形態に係る繊維強化樹脂成形体の斜視図A perspective view of a fiber reinforced resin molded article according to an embodiment of the present disclosure 繊維強化樹脂成形体の側断面図Side sectional view of fiber reinforced resin molded body 繊維強化樹脂成形体のボス周辺の拡大側断面図Enlarged side sectional view around the boss of the fiber-reinforced resin molded body 成形金型で加熱プレス成形する前の基材用シートとシートモールディングコンパウンドとの側断面図Side sectional view of the base material sheet and sheet molding compound before hot press molding with a molding die 成形金型で加熱プレス成形された後の基材と表層構成部との側断面図Side cross-sectional view of the base material and surface layer components after hot press molding with a molding die (A)加熱プレス成形される前の基材用シートとシートモールディングコンパウンドの拡大側断面図、(B)成形金型内で第1の熱硬化樹脂が硬化したときの基材用シートと表層構成部の拡大側断面図、(A) Enlarged side sectional view of the base sheet and sheet molding compound before hot press molding, (B) Base sheet and surface layer configuration when the first thermosetting resin is cured in the molding die. Enlarged side sectional view of (A)成形金型内で変形した基材用シートの拡大側面図、(B)成形金型内で形成された基材の拡大側断面図(A) Enlarged side view of the base material sheet deformed within the mold, (B) Enlarged side sectional view of the base material formed within the mold. 第1と第2の熱硬化性樹脂の加熱時間と硬化度の関係を概念的に示すグラフGraph conceptually showing the relationship between heating time and degree of curing of the first and second thermosetting resins 他の実施形態に係る繊維強化樹脂成形体の斜視図A perspective view of a fiber-reinforced resin molded body according to another embodiment 他の実施形態に係る繊維強化樹脂成形体の側断面図Side sectional view of a fiber-reinforced resin molded article according to another embodiment 他の実施形態に係る繊維強化樹脂成形体の側断面図Side sectional view of a fiber-reinforced resin molded body according to another embodiment

図1には、本開示の一実施形態に係る繊維強化樹脂成形体10が示されている。本実施形態の繊維強化樹脂成形体10は、例えば、自転車の部品等に用いられる。繊維強化樹脂成形体10は、板状の基材20を有し、その基材20の表裏の一方の面である第1面20Aから、突部(具体的には、補強リブ13とボス14)が突出した構成となっている。なお、本実施形態では、基材20の他方の面である第2面20B(図2参照)は、平坦面となっているが、第2面20Bは、凹凸を有していてもよいし、湾曲面であってもよい。 FIG. 1 shows a fiber-reinforced resin molded article 10 according to an embodiment of the present disclosure. The fiber-reinforced resin molded body 10 of this embodiment is used for, for example, bicycle parts. The fiber-reinforced resin molded body 10 has a plate-shaped base material 20, and protrusions (specifically, reinforcing ribs 13 and bosses 14) are formed from a first surface 20A, which is one of the front and back surfaces of the base material 20. ) has a prominent structure. Note that in this embodiment, the second surface 20B (see FIG. 2), which is the other surface of the base material 20, is a flat surface, but the second surface 20B may have unevenness. , it may be a curved surface.

具体的には、図2に示されるように、繊維強化樹脂成形体10は、基材20の第1面20Aに、補強リブ13とボス14を構成する表層構成部30が部分的に積層されてなる。表層構成部30は、繊維と第1の熱硬化性樹脂を含むシートモールディングコンパウンド(以下、SMCということとする。)からなる。 Specifically, as shown in FIG. 2, the fiber-reinforced resin molded body 10 includes a surface layer component 30 that constitutes the reinforcing ribs 13 and the bosses 14 that are partially laminated on the first surface 20A of the base material 20. It becomes. The surface layer component 30 is made of a sheet molding compound (hereinafter referred to as SMC) containing fibers and a first thermosetting resin.

図2及び図3に示されるように、表層構成部30は、基材20と反対側を向く面に、賦形部を有する構成となっている。具体的には、表層構成部30は、薄板状をなして基材20に重ねられるベース部31と、そのベース部31のうち基材20と反対側を向く露出面31Aから突出する上述の賦形部としての表面突部32と、からなる。また、本実施形態では、補強リブ13を構成する表層構成部30と、ボス14を構成する表層構成部30とが、別に設けられ、互いに離れて配置されている。そして、各表層構成部30の表面突部32が、それぞれ補強リブ13とボス14を構成している。 As shown in FIGS. 2 and 3, the surface layer component 30 has a shaped portion on the surface facing away from the base material 20. As shown in FIGS. Specifically, the surface layer forming portion 30 includes a base portion 31 having a thin plate shape and stacked on the base material 20, and the above-mentioned features protruding from an exposed surface 31A of the base portion 31 facing opposite to the base material 20. It consists of a surface protrusion 32 as a shaped part. Moreover, in this embodiment, the surface layer structure part 30 which forms the reinforcing rib 13 and the surface layer structure part 30 which forms the boss 14 are provided separately and arranged apart from each other. The surface protrusions 32 of each surface layer component 30 constitute reinforcing ribs 13 and bosses 14, respectively.

基材20は、発泡シート21の表裏の両面に、1対の繊維シート22,22が積層された構成を有する。発泡シート21は、熱硬化性樹脂からなる連続気泡発泡体で構成され、発泡シート21には第2の熱硬化性樹脂が含浸している。また、本実施形態では、繊維シート22は、表層構成部30を構成するSMCの繊維よりも繊維長が長い補強繊維から構成されていると共に、繊維シート22にも第2の熱硬化性樹脂が含浸している。そして、発泡シート21と1対の繊維シート22,22に含浸した第2の熱硬化性樹脂が硬化することによって発泡シート21と1対の繊維シート22,22とが一体化されている。 The base material 20 has a structure in which a pair of fiber sheets 22, 22 are laminated on both the front and back surfaces of a foamed sheet 21. The foamed sheet 21 is made of open-cell foam made of a thermosetting resin, and the foamed sheet 21 is impregnated with a second thermosetting resin. Further, in this embodiment, the fiber sheet 22 is made of reinforcing fibers having a longer fiber length than the SMC fibers constituting the surface layer component 30, and the fiber sheet 22 also includes a second thermosetting resin. Impregnated. Then, the second thermosetting resin impregnated into the foam sheet 21 and the pair of fiber sheets 22, 22 is cured, so that the foam sheet 21 and the pair of fiber sheets 22, 22 are integrated.

ここで、表層構成部30のベース部31は、基材20に埋め込まれていて、基材20に密着している。表層構成部30のうち表面突部32以外の部分は、基材20と略面一に配置されている。具体的には、表層構成部30のベース部31の露出面31Aと基材20の第1面20Aとが略面一となっている。 Here, the base portion 31 of the surface layer forming portion 30 is embedded in the base material 20 and is in close contact with the base material 20. The portions of the surface layer forming portion 30 other than the surface protrusions 32 are arranged substantially flush with the base material 20. Specifically, the exposed surface 31A of the base portion 31 of the surface layer component 30 and the first surface 20A of the base material 20 are substantially flush with each other.

また、基材20の発泡シート21のうち、厚み方向で表層構成部30と重なる部分は、厚み方向で表層構成部30と重ならない部分に比べて、ベース部31の厚みと略同じ分だけ圧縮されて薄くなっている。 In addition, the portion of the foamed sheet 21 of the base material 20 that overlaps with the surface layer component 30 in the thickness direction is compressed by approximately the same amount as the thickness of the base portion 31, compared to the portion that does not overlap with the surface layer component 30 in the thickness direction. It has become thinner.

繊維強化樹脂成形体10では、表層構成部30に含まれる第1の熱硬化性樹脂と、基材20に含浸された第2の熱硬化性樹脂とが硬化することにより、表層構成部30と基材20とが一体化している。ここで、第2の熱硬化性樹脂は、第1の熱硬化性樹脂よりも、熱硬化し難くなっている。即ち、第2の熱硬化性樹脂は、第1の熱硬化性樹脂よりも、一定の温度で硬化するために必要な時間である硬化時間が長いか、又は、一定時間で硬化するために必要な温度である硬化温度が高くなっている。 In the fiber-reinforced resin molded body 10, the first thermosetting resin contained in the surface layer component 30 and the second thermosetting resin impregnated into the base material 20 are cured, so that the surface layer component 30 and the second thermosetting resin are hardened. The base material 20 is integrated. Here, the second thermosetting resin is more difficult to thermoset than the first thermosetting resin. That is, the second thermosetting resin has a longer curing time than the first thermosetting resin, which is the time required for curing at a constant temperature, or a longer curing time than the first thermosetting resin. The curing temperature is increasing.

繊維強化樹脂成形体10の各構成要素、即ち、発泡シート21、繊維シート22、第1の熱硬化性樹脂、第2の熱硬化性樹脂、及び、SMCの詳細については、以下のようになっている。 Details of each component of the fiber-reinforced resin molded body 10, that is, the foam sheet 21, the fiber sheet 22, the first thermosetting resin, the second thermosetting resin, and the SMC, are as follows. ing.

発泡シート21を構成する発泡体としては、例えば、ウレタン樹脂発泡体、メラミン樹脂発泡体等が挙げられる。また、発泡シート21の厚みは、例えば、基材20の厚み0.5~30mmに対して、0.1~29.5mmとなっている。 Examples of the foam forming the foam sheet 21 include urethane resin foam, melamine resin foam, and the like. Further, the thickness of the foamed sheet 21 is, for example, 0.1 to 29.5 mm, while the thickness of the base material 20 is 0.5 to 30 mm.

繊維シート22としては、例えば、炭素繊維、ガラス繊維、アラミド繊維等の繊維によって構成されたものを用いることができる。また、繊維シート22は、例えば、織物、編み物、不織布等の形態であってもよい。織物の織り方としては、平織、綾織、朱子織、三軸織等が挙げられる。また、繊維シート22は、一方向又は複数方向に配向した繊維から構成されていてもよい。なお、軽量化と剛性向上の観点から、繊維シート22を構成する繊維としては、炭素繊維が好ましい。また、剛性向上の観点から、繊維シート22は、繊維織物から構成されることが好ましい。熱硬化性樹脂が含浸した繊維シート22としては、例えば、プリプレグが挙げられる。 As the fiber sheet 22, for example, one made of fibers such as carbon fiber, glass fiber, aramid fiber, etc. can be used. Further, the fiber sheet 22 may be in the form of, for example, a woven fabric, a knitted fabric, a nonwoven fabric, or the like. Examples of weaving methods for the fabric include plain weave, twill weave, satin weave, and triaxial weave. Further, the fiber sheet 22 may be composed of fibers oriented in one direction or in multiple directions. Note that carbon fiber is preferable as the fiber constituting the fiber sheet 22 from the viewpoint of reducing weight and improving rigidity. Moreover, from the viewpoint of improving rigidity, it is preferable that the fiber sheet 22 is made of a fiber fabric. Examples of the fiber sheet 22 impregnated with a thermosetting resin include prepreg.

また、繊維シート22を構成する繊維としては、SMCの繊維より繊維長が長いものが好ましく、例えば、SMCの繊維よりも数平均繊維長が長いものが挙げられる。また、繊維シート22としては、例えば、連続繊維又は不連続繊維からなるものが挙げられる。繊維シート22は、剛性の観点から、5mm以上の繊維長のものが好ましい。また、繊維シート22は、剛性、第2の熱硬化性樹脂の含浸性、軽量性の観点から、目付量が90~400g/mのものが好ましい。 Further, the fibers constituting the fiber sheet 22 preferably have longer fiber lengths than SMC fibers, such as fibers having a longer number average fiber length than SMC fibers. Furthermore, examples of the fiber sheet 22 include those made of continuous fibers or discontinuous fibers. From the viewpoint of rigidity, the fiber sheet 22 preferably has a fiber length of 5 mm or more. Further, the fiber sheet 22 preferably has a basis weight of 90 to 400 g/m 2 from the viewpoints of rigidity, impregnability with the second thermosetting resin, and light weight.

SMCとしては、例えば、炭素繊維、ガラス繊維等の繊維を含むものを用いることができる。なお、軽量化と剛性向上の観点から、SMCを構成する繊維としては、炭素繊維が好ましい。SMCを構成する繊維としては、30mm以下の繊維長のものが好ましい。 As the SMC, for example, one containing fibers such as carbon fibers and glass fibers can be used. In addition, from the viewpoint of weight reduction and rigidity improvement, carbon fiber is preferable as the fiber constituting the SMC. The fibers constituting the SMC preferably have a fiber length of 30 mm or less.

SMCの第1の熱硬化性樹脂としては、例えば、エポキシ樹脂、ビニールエステル樹脂、不飽和ポリエステル樹脂、フェノール樹脂、エポキシアクリレート樹脂、又は、これらの樹脂のうち2種類以上の樹脂の混合樹脂、等が挙げられる。 Examples of the first thermosetting resin of SMC include epoxy resin, vinyl ester resin, unsaturated polyester resin, phenol resin, epoxy acrylate resin, or a mixed resin of two or more of these resins. can be mentioned.

なお、表層構成部30に設けられる補強リブ13としては、例えば、突出量が0.1~30mmで、最小幅が0.5~10mmであるものが挙げられる。また、ボス14としては、例えば、突出量が0.1~30mmで、内径と外径の差が0.5~10.0mmのものが挙げられる。 The reinforcing ribs 13 provided on the surface layer component 30 may have a protrusion amount of 0.1 to 30 mm and a minimum width of 0.5 to 10 mm, for example. Further, as the boss 14, for example, one having a protrusion amount of 0.1 to 30 mm and a difference between the inner diameter and the outer diameter of 0.5 to 10.0 mm can be mentioned.

基材20の第2の熱硬化性樹脂としては、例えば、エポキシ樹脂、フェノール樹脂、又は、これらの樹脂の混合樹脂、等が挙げられる。これらの樹脂を用いることにより、剛性の向上が図られる。 Examples of the second thermosetting resin of the base material 20 include epoxy resin, phenol resin, or a mixed resin of these resins. By using these resins, rigidity can be improved.

繊維強化樹脂成形体10は、以下のようにして製造される。まず、複数のシートが用意される。具体的には、連続気泡を有する発泡シート21、1対の繊維シート22,22、及び、第1の熱硬化性樹脂を含むSMC30S、が用意される。発泡シート21と各繊維シート22には、第2の熱硬化性樹脂を含浸させておく。第2の硬化性樹脂としては、第1の硬化性樹脂に比べて、硬化温度が高いか、又は、硬化時間が長いものを用いればよい。なお、第2の熱硬化性樹脂は、発泡シート21と繊維シート22のうち一方にのみ含浸させておいてもよい。また、発泡シート21としては、後述する加熱プレス成形での圧縮容易性、第2の熱硬化性樹脂の含浸性、軽量性、剛性の観点から、密度が5~80kg/mのものを用いるのが好ましい。 The fiber-reinforced resin molded body 10 is manufactured as follows. First, multiple sheets are prepared. Specifically, a foamed sheet 21 having open cells, a pair of fiber sheets 22, 22, and an SMC 30S containing a first thermosetting resin are prepared. The foam sheet 21 and each fiber sheet 22 are impregnated with a second thermosetting resin. The second curable resin may have a higher curing temperature or a longer curing time than the first curable resin. Note that only one of the foam sheet 21 and the fiber sheet 22 may be impregnated with the second thermosetting resin. Further, as the foamed sheet 21, one with a density of 5 to 80 kg/m 3 is used from the viewpoints of ease of compression in hot press molding, impregnation with the second thermosetting resin, lightness, and rigidity, which will be described later. is preferable.

本実施形態の例では、第1の熱硬化性樹脂としてビニールエステル樹脂とエポキシアクリレート樹脂との混合樹脂を用い、第2の熱硬化性樹脂として第1の熱硬化性樹脂よりも硬化時間が高く且つ硬化時間も長いフェノール樹脂を用いた。また、発泡シート21としてウレタン樹脂発泡体からなるものを用い、繊維シート22として炭素繊維織物からなるプリプレグ、SMCとして炭素繊維を有するものを用いた。 In the example of this embodiment, a mixed resin of vinyl ester resin and epoxy acrylate resin is used as the first thermosetting resin, and the curing time is longer than that of the first thermosetting resin as the second thermosetting resin. In addition, a phenolic resin that takes a long time to cure was used. Further, the foam sheet 21 was made of urethane resin foam, the fiber sheet 22 was a prepreg made of carbon fiber fabric, and the SMC was made of carbon fiber.

次いで、発泡シート21と繊維シート22とSMC30Sとが重ねられて、成形金型70によって加熱プレス成形される。 Next, the foamed sheet 21, the fiber sheet 22, and the SMC 30S are stacked on top of each other and heated and press-molded using the molding die 70.

図4には、成形金型70が示されている。同図に示されるように、成形金型70は、上型71と下型72とから構成される。本実施形態では、上型71の成形面は、平坦となっている一方、下型72の成形面には、補強リブ13とボス14をそれぞれ形成するための表面形成部として成形凹部73,74が設けられている。詳細には、成形凹部73は、溝状となっていると共に、成形凹部74は、円筒状の凹部となっている。なお、下型72の成形面のうち成形凹部73,74が設けられた部分以外は、平坦になっている。 In FIG. 4, a molding die 70 is shown. As shown in the figure, the molding die 70 is composed of an upper die 71 and a lower die 72. In this embodiment, the molding surface of the upper mold 71 is flat, while the molding surface of the lower mold 72 has molding recesses 73 and 74 as surface forming parts for forming the reinforcing ribs 13 and the bosses 14, respectively. is provided. Specifically, the molding recess 73 is groove-shaped, and the molding recess 74 is a cylindrical recess. Note that the molding surface of the lower mold 72 is flat except for the portions where the molding recesses 73 and 74 are provided.

加熱プレス成形を行うにあたっては、まず、成形金型70が型開き状態にされて、SMC30Sが、下型72の成形凹部73,74を覆うように下型72の成形面に部分的に重ねられる(図4及び図6(A)参照)。本実施形態では、成形凹部73を覆うSMC30Sと成形凹部74を覆うSMC30Sとは、別に設けられ、互いに離れて配置される。また、各SMC30Sは、各成形凹部73,74を満たすのに必要な量、即ち、補強リブ13、ボス14の形成に必要な量、よりも多い量となっている。 To perform hot press molding, first, the molding die 70 is opened, and the SMC30S is partially overlapped on the molding surface of the lower mold 72 so as to cover the molding recesses 73 and 74 of the lower mold 72. (See FIGS. 4 and 6(A)). In this embodiment, the SMC 30S that covers the molded recess 73 and the SMC 30S that covers the molded recess 74 are provided separately and arranged apart from each other. Furthermore, the amount of each SMC 30S is greater than the amount required to fill each molding recess 73, 74, that is, the amount required to form the reinforcing ribs 13 and bosses 14.

そして、発泡シート21の両面に1対の繊維シート22,22が重ねられた基材用シート20Sが、SMC30Sの上に重ねられ、成形金型70が型閉じされる。すると、図5及び図6(B)に示されるように、加熱されて流動性が生じたSMC30Sが、成形凹部73,74に流れ込む。また、SMC30Sのうち成形凹部73,74に入りきれなかった余剰部分は、薄板状となって成形凹部73,74の上に残る。一方、基材用シート20S(特に、発泡シート21)は、成形金型70に加熱プレスされることにより圧縮される。 Then, the base sheet 20S, in which a pair of fiber sheets 22, 22 are stacked on both sides of the foamed sheet 21, is stacked on the SMC 30S, and the molding die 70 is closed. Then, as shown in FIGS. 5 and 6(B), the heated and fluidized SMC 30S flows into the molding recesses 73 and 74. Further, the surplus portion of the SMC 30S that cannot fit into the molding recesses 73 and 74 remains on the molding recesses 73 and 74 in the form of a thin plate. On the other hand, the base material sheet 20S (especially the foamed sheet 21) is compressed by being heated and pressed into the molding die 70.

ここで、上述のように、基材用シート20Sの第2の熱硬化性樹脂は、SMC30Sの第1の熱硬化性樹脂よりも、硬化時間が長くなっている。従って、図6(B)に示されるように、成形金型70内で、SMC30Sの第1の熱硬化性樹脂が、第2の熱硬化性樹脂よりも先に硬化することとなる(図6(B)、図7(A)及び図7(B)では、第1と第2の熱硬化性樹脂のうち硬化しきった熱硬化性樹脂を含む部分が灰色で示されている)。なお、ここで、図8には、成形金型70内での一定の加熱温度における、第1及び第2の熱硬化性樹脂の硬化度と加熱時間との関係が概念的に示されていて、図7において第1と第2の熱硬化性樹脂がそれぞれ硬化しきったタイミングT1、T2のときが、それぞれ図6(B)、図7(B)に示す状態である。 Here, as described above, the second thermosetting resin of the base sheet 20S has a longer curing time than the first thermosetting resin of the SMC 30S. Therefore, as shown in FIG. 6B, the first thermosetting resin of SMC30S is cured before the second thermosetting resin in the molding die 70 (FIG. (B), FIG. 7(A), and FIG. 7(B), the portions of the first and second thermosetting resins that include the fully cured thermosetting resin are shown in gray). Here, FIG. 8 conceptually shows the relationship between the degree of curing of the first and second thermosetting resins and the heating time at a constant heating temperature within the molding die 70. In FIG. 7, timings T1 and T2 when the first and second thermosetting resins are completely cured are the states shown in FIGS. 6(B) and 7(B), respectively.

第1の熱硬化性樹脂が硬化すると、SMC30Sから表層構成部30が形成される。このとき、SMC30Sのうち成形凹部73,74に入り込んだ部分により、それぞれ補強リブ13とボス14(即ち、各表面突部32)が形成されると共に、SMC30Sのうち成形凹部73,74に入りきらなかった薄板状の余剰部分により、ベース部31が形成される。 When the first thermosetting resin hardens, the surface layer component 30 is formed from the SMC 30S. At this time, the reinforcing ribs 13 and bosses 14 (i.e., the respective surface protrusions 32) are formed by the portions of the SMC 30S that have entered the molding recesses 73 and 74, and the portions of the SMC 30S that have entered the molding recesses 73 and 74 form the reinforcing ribs 13 and bosses 14, respectively. The base portion 31 is formed by the thin plate-like surplus portion that was not present.

ここで、図8に示されるように、第1の熱硬化性樹脂が硬化しきってからもタイミングT2までは、第2の熱硬化性樹脂は硬化しきっていないので、基材用シート20Sが硬化しきっておらず、図6(B)から図7(A)への変化に示されるように、基材用シート20Sを変形させて表層構成部30の形状に追従させることができる。これにより、ベース部31を基材用シート20Sに埋め込んで、ベース部31と基材用シート20Sとのうち下型72と対向する部分同士を略面一にすることができる。また、このとき、基材用シート20Sの発泡シート21のうち、厚み方向で表層構成部30のベース部31と重なる部分は、厚み方向でベース部31と重ならない部分に比べて、ベース部31の厚みと略同じ分だけ圧縮されることとなる。 Here, as shown in FIG. 8, even after the first thermosetting resin is completely cured, the second thermosetting resin is not completely cured until timing T2, so that the base sheet 20S is cured. As shown in the change from FIG. 6(B) to FIG. 7(A), the base sheet 20S can be deformed to follow the shape of the surface layer component 30. Thereby, the base part 31 can be embedded in the base material sheet 20S, and the parts of the base part 31 and the base material sheet 20S that face the lower mold 72 can be made substantially flush with each other. In addition, at this time, the portion of the foamed sheet 21 of the base material sheet 20S that overlaps with the base portion 31 of the surface layer component 30 in the thickness direction is smaller than the portion that does not overlap with the base portion 31 in the thickness direction. It will be compressed by approximately the same amount as the thickness.

図7(B)に示されるように、基材用シート20Sの第2の熱硬化性樹脂が硬化しきると、基材用シート20Sが硬化する。このとき、発泡シート21と1対の繊維シート22,22とが一体化して基材20が形成されると共に、基材20と表層構成部30とが一体化する(図5参照)。 As shown in FIG. 7(B), when the second thermosetting resin of the base sheet 20S is completely cured, the base sheet 20S is cured. At this time, the foam sheet 21 and the pair of fiber sheets 22, 22 are integrated to form the base material 20, and the base material 20 and the surface layer component 30 are integrated (see FIG. 5).

次いで、成形金型70が型開きされて、基材20と表層構成部30が成形金型70から外され、図2に示される繊維強化樹脂成形体10が完成する。 Next, the molding die 70 is opened, the base material 20 and the surface layer component 30 are removed from the molding die 70, and the fiber-reinforced resin molded article 10 shown in FIG. 2 is completed.

本実施形態に係る繊維強化樹脂成形体10の構成及び繊維強化樹脂成形体10の製造方法に関する説明は以上である。次に、繊維強化樹脂成形体10及びその製造方法の作用効果について説明する。 The configuration of the fiber-reinforced resin molded body 10 and the method for manufacturing the fiber-reinforced resin molded body 10 according to the present embodiment have been described above. Next, the effects of the fiber-reinforced resin molded body 10 and its manufacturing method will be explained.

本実施形態の繊維強化樹脂成形体10及びその製造方法では、基材20に含まれる第2の熱硬化性樹脂が、SMCに含まれる第1の熱硬化性樹脂よりも、硬化温度が高いか、又は、硬化時間が長くなっている。従って、繊維強化樹脂成形体10の製造時に、SMCの第1の熱硬化性樹脂を硬化させてから、基材用シート20Sの第2の熱硬化性樹脂を硬化させることができ、第1の熱硬化性樹脂が硬化して硬くなった表層構成部30の形状に、基材20を追従させた状態に形成することが容易となる。これにより、表層構成部30が基材20に埋め込まれて、SMCからなる表層構成部30と基材20との固定の安定を図ることが可能となる。また、表層構成部30のベース部31を、基材と略面一に配置することで、表面突部32の突出量について寸法精度の安定化を図ることが可能となる。しかも、ベース部31が基材20の第1面20Aと略面一になることにより、下型72と基材用シート20Sとの間に、ベース部31の略厚み分のスペースが生じることを防ぐことができ、基材20の厚み精度の向上が図られると共に、基材20の設計において設計自由度の向上を図ることができる。 In the fiber-reinforced resin molded article 10 and the manufacturing method thereof of the present embodiment, the second thermosetting resin contained in the base material 20 has a higher curing temperature than the first thermosetting resin contained in the SMC. , or the curing time is longer. Therefore, when manufacturing the fiber-reinforced resin molded body 10, the first thermosetting resin of the SMC can be cured, and then the second thermosetting resin of the base sheet 20S can be cured, and the first thermosetting resin can be cured. It becomes easy to form the base material 20 in a state that follows the shape of the surface layer component 30 which has become hard due to hardening of the thermosetting resin. Thereby, the surface layer component 30 is embedded in the base material 20, and it becomes possible to stabilize the fixation between the surface layer component 30 made of SMC and the base material 20. Further, by arranging the base portion 31 of the surface layer forming portion 30 substantially flush with the base material, it is possible to stabilize the dimensional accuracy of the amount of protrusion of the surface protrusion 32. Furthermore, since the base portion 31 is substantially flush with the first surface 20A of the base material 20, a space approximately equal to the thickness of the base portion 31 is created between the lower mold 72 and the base material sheet 20S. This makes it possible to improve the thickness accuracy of the base material 20 and to improve the degree of freedom in designing the base material 20.

本実施形態の繊維強化樹脂成形体10では、基材20には、連続気泡を有する発泡シート21が設けられる。そして、発泡シート21のうち厚み方向で表層構成部30と重なる部分は、厚み方向で表層構成部30と重ならない部分に比べて、厚み方向に圧縮されている。本実施形態の繊維強化樹脂成形体10によれば、発泡シート21のうち厚み方向で表層構成部30と重なる部分を圧縮することによって、表層構成部30を基材20に埋め込まれた状態に形成し易くすることができ、ベース部31と基材20の第1面20Aとを略面一に配置し易くすることができる。また、本実施形態の繊維強化樹脂成形体10の製造方法によっても、発泡シート21のうち厚み方向でSMC30Sと重なる部分を圧縮することにより、表層構成部30を基材20に埋め込まれた状態に形成し易くすることができる。しかも、本実施形態によれば、発泡シート21によって加熱プレス成形時の歪みを吸収し、基材20の第2面20Bにおいて厚み方向で表層構成部30と重なる部分に、ヒケ等が発生することを抑制可能となり、第2面20Bが不均一な外観になることを抑制可能となる。 In the fiber-reinforced resin molded article 10 of this embodiment, the base material 20 is provided with a foamed sheet 21 having open cells. The portion of the foamed sheet 21 that overlaps with the surface layer component 30 in the thickness direction is compressed in the thickness direction compared to the portion that does not overlap with the surface layer component 30 in the thickness direction. According to the fiber-reinforced resin molded article 10 of the present embodiment, the surface layer component 30 is formed in a state embedded in the base material 20 by compressing the portion of the foam sheet 21 that overlaps with the surface layer component 30 in the thickness direction. The base portion 31 and the first surface 20A of the base material 20 can be easily disposed substantially flush with each other. Also, according to the method for manufacturing the fiber-reinforced resin molded body 10 of the present embodiment, by compressing the portion of the foamed sheet 21 that overlaps with the SMC 30S in the thickness direction, the surface layer component 30 is embedded in the base material 20. It can be made easier to form. Moreover, according to the present embodiment, the foamed sheet 21 absorbs distortion during hot press molding, and sink marks and the like do not occur in the portion of the second surface 20B of the base material 20 that overlaps with the surface layer component 30 in the thickness direction. This makes it possible to prevent the second surface 20B from having an uneven appearance.

本実施形態では、表面突部32が設けられる表層構成部30が複数設けられ、それら複数の表層構成部30が互いに離れて配置される。本実施形態によれば、複数の表面突部32全てに亘って1つのSMCからなる表層構成部30が形成される場合に比べて、表層構成部30を形成するためのSMCの使用量を少なくすることが可能となる。 In this embodiment, a plurality of surface layer constituent parts 30 are provided with surface protrusions 32, and the plurality of surface layer constituent parts 30 are arranged apart from each other. According to the present embodiment, the amount of SMC used to form the surface layer component 30 is reduced compared to the case where the surface layer component 30 made of one SMC is formed over all the plurality of surface protrusions 32. It becomes possible to do so.

[確認実験]
以下、繊維強化樹脂成形体10を上述の製造方法で製造した実験例について説明する。
[Confirmation experiment]
Hereinafter, an experimental example in which the fiber-reinforced resin molded body 10 was manufactured by the above-mentioned manufacturing method will be described.

<材料>
本実験例では、繊維強化樹脂成形体10を構成する各構成要素について、以下の材料を用いた。
発泡シート21:株式会社イノアックコーポレーション製の「バソテクト(登録商標)G+」(密度:9.2kg/m、厚み5.0mmで、200mm×200mmのサイズにカットしたものを用いた。)
繊維シート22:東邦テナックス株式会社製の「W-3161-L」(連続繊維からなる炭素繊維織物で、目付量が200g/m。発泡シート21と同様のサイズにカットしたものを用いた。)
第2の熱硬化性樹脂:住友ベークライト株式会社製の「スミライトレジン(登録商標)PR-55791」(フェノール樹脂。ガラス転移温度:151℃)
シートモールディングコンパウンド(SMC):三菱ケミカル株式会社製の「パイロフィル(登録商標) STR120N131」(厚み2.0mm、繊維長25.4mm。第1の熱硬化性樹脂としてビニールエステル樹脂とエポキシアクリレート樹脂の混合樹脂を含有。ガラス転移温度:130℃)
<Materials>
In this experimental example, the following materials were used for each component constituting the fiber-reinforced resin molded body 10.
Foam sheet 21: "Basotect (registered trademark) G+" manufactured by INOAC Corporation (density: 9.2 kg/m 3 , thickness 5.0 mm, cut into a size of 200 mm x 200 mm was used.)
Fiber sheet 22: "W-3161-L" manufactured by Toho Tenax Co., Ltd. (a carbon fiber fabric made of continuous fibers, with a basis weight of 200 g/m 2 . A sheet cut to the same size as the foam sheet 21 was used. )
Second thermosetting resin: “Sumilite Resin (registered trademark) PR-55791” manufactured by Sumitomo Bakelite Co., Ltd. (phenolic resin. Glass transition temperature: 151°C)
Sheet molding compound (SMC): "Pyrofil (registered trademark) STR120N131" manufactured by Mitsubishi Chemical Corporation (thickness 2.0 mm, fiber length 25.4 mm. A mixture of vinyl ester resin and epoxy acrylate resin as the first thermosetting resin) Contains resin.Glass transition temperature: 130℃)

<成形条件>
本実験例の加熱プレス成形の成形条件としては、成形温度を150℃、成形圧力を20MPa、成形時間を10分とした。
<Molding conditions>
The molding conditions for hot press molding in this experimental example were a molding temperature of 150° C., a molding pressure of 20 MPa, and a molding time of 10 minutes.

<実験結果>
上記の材料及び成形条件で、加熱プレス成形を行ったところ、補強リブ13とボス14が形成される共に、表層構成部30のベース部31と基材20の第1面20Aとが面一となった繊維強化樹脂成形体10が得られた。具体的には、繊維強化樹脂成形体10において、補強リブ13とボス14(即ち、表面突部32)を除いた部分の厚みは、1.0mmとなった。詳細には、繊維強化樹脂成形体10において基材20と表層構成部30が厚み方向で重なっていない部分では、発泡シート21が0.50mm、各繊維シート22が0.25mmであった。また、繊維強化樹脂成形体10において基材20と表層構成部30が厚み方向で重なっている部分では、発泡シート21が0.10mm、各繊維シート22が0.25mm、表層構成部30のベース部31が0.40mmであった。
<Experiment results>
When hot press molding was performed using the above materials and molding conditions, the reinforcing ribs 13 and bosses 14 were formed, and the base portion 31 of the surface layer component 30 and the first surface 20A of the base material 20 were flush with each other. A fiber-reinforced resin molded article 10 was obtained. Specifically, in the fiber-reinforced resin molded body 10, the thickness of the portion excluding the reinforcing ribs 13 and the bosses 14 (namely, the surface protrusions 32) was 1.0 mm. Specifically, in the portion of the fiber-reinforced resin molded article 10 where the base material 20 and the surface layer component 30 did not overlap in the thickness direction, the foam sheet 21 had a thickness of 0.50 mm, and each fiber sheet 22 had a thickness of 0.25 mm. In addition, in the portion where the base material 20 and the surface layer component 30 overlap in the thickness direction in the fiber-reinforced resin molded product 10, the foam sheet 21 has a thickness of 0.10 mm, each fiber sheet 22 has a thickness of 0.25 mm, and the base layer of the surface layer component 30 has a thickness of 0.10 mm. The portion 31 was 0.40 mm.

この繊維強化樹脂成形体10では、基材20とSMCからなる表層構成部30とが十分に固定されていることが確認できたと共に、寸法精度が良好であった。さらに、基材20の第2面20Bにおいて厚み方向で表層構成部30と重なる部分は、ヒケ等が生じて不均一な外観になることもなく、良好な外観であった。 In this fiber-reinforced resin molded article 10, it was confirmed that the base material 20 and the surface layer component 30 made of SMC were sufficiently fixed, and the dimensional accuracy was good. Furthermore, the portion of the second surface 20B of the base material 20 that overlapped with the surface layer component 30 in the thickness direction had a good appearance without any sink marks or the like resulting in an uneven appearance.

なお、上記同様の成形温度及び成形圧で、加熱プレス成形の成形時間を3分とした場合、SMCの第1の熱硬化性樹脂が硬化していることが確認できた一方で、第2の熱硬化性樹脂が硬化しきっておらず、成形金型70から基材20を外す際に、基材20が変形した。即ち、成形時間が3分経ったタイミングは、図8に示すタイミングT1以降で、タイミングT2の前であると考えられる。成形時間が10分の場合、図8に示すタイミングT2を経過するため、SMCの第1の熱硬化性樹脂と、発泡シート21及び繊維シート22に含浸した第2の熱硬化性樹脂と、の両方が硬化しきり、上述のような良好な状態の繊維強化樹脂成形体10を製造することができる。 In addition, when the molding temperature and molding pressure were the same as above, and the molding time of hot press molding was 3 minutes, it was confirmed that the first thermosetting resin of SMC was cured, while the second thermosetting resin was confirmed to be cured. The thermosetting resin was not completely cured, and when the base material 20 was removed from the molding die 70, the base material 20 was deformed. That is, the timing at which three minutes of molding time have elapsed is considered to be after timing T1 shown in FIG. 8 and before timing T2. When the molding time is 10 minutes, timing T2 shown in FIG. Both are completely cured, and the fiber-reinforced resin molded article 10 in good condition as described above can be manufactured.

[他の実施形態]
(1)上記実施形態では、表層構成部30のうち基材20と反対側を向く面に、賦形部として、表面突部32が設けられていたが、図9及び図10に示されるように、凹部32Vが設けられていてもよい。この場合においても、表層構成部30のベース部31を、基材20と略面一に配置することで、凹部32Vの深さについて寸法精度の安定化を図ることが可能となる。なお、このような凹部32Vは、溝であってもよいし、穴であってもよい。
[Other embodiments]
(1) In the above embodiment, the surface protrusion 32 was provided as a shaping portion on the surface of the surface layer component 30 facing away from the base material 20, but as shown in FIGS. 9 and 10, A recessed portion 32V may be provided in the recessed portion 32V. Also in this case, by arranging the base portion 31 of the surface layer forming portion 30 substantially flush with the base material 20, it is possible to stabilize the dimensional accuracy regarding the depth of the recessed portion 32V. Note that such a recess 32V may be a groove or a hole.

(2)上記実施形態において、補強リブ13とボス14とをそれぞれ構成する2つの表面突部32,32同士が、1つの表層構成部30に設けられていてもよい(即ち、1枚のSMCから形成されてもよい)。 (2) In the above embodiment, the two surface protrusions 32, 32 that constitute the reinforcing rib 13 and the boss 14, respectively, may be provided in one surface layer component 30 (i.e., in one SMC may be formed from).

(3)上記実施形態では、基材20が、繊維シート22を発泡シート21の表裏の両面に積層した構成であったが、繊維シート22を発泡シート21の表裏の一方の面のみに積層した構成であってもよい。この場合、表層構成部30は、基材20に対して、繊維シート22側から積層されていてもよいし、図11に示されるように発泡シート21側から積層されていてもよい。 (3) In the above embodiment, the base material 20 has a structure in which the fiber sheet 22 is laminated on both the front and back surfaces of the foam sheet 21, but the fiber sheet 22 is laminated only on one of the front and back surfaces of the foam sheet 21. It may be a configuration. In this case, the surface layer component 30 may be laminated on the base material 20 from the fiber sheet 22 side, or may be laminated from the foam sheet 21 side as shown in FIG.

(4)上記実施形態において、発泡シート21と繊維シート22が積層された基材20の構成として、発泡シート21が2枚以上設けられる構成であってもよいし、繊維シート22が3枚以上設けられる構成であってもよい。これらの場合、基材20が、発泡シート21と繊維シート22を一枚ずつ交互に積層した構成であってもよいし、隣り合う発泡シート21同士又は隣り合う繊維シート22同士を含む構成であってもよい。また、これらの場合、基材20のうち表層構成部30が積層される最外層は、発泡シート21によって構成されていてもよいし、繊維シート22によって構成されていてもよい。 (4) In the above embodiment, the structure of the base material 20 in which the foam sheet 21 and the fiber sheet 22 are laminated may be a structure in which two or more foam sheets 21 are provided, or a structure in which three or more fiber sheets 22 are provided. The structure may be provided. In these cases, the base material 20 may have a structure in which foam sheets 21 and fiber sheets 22 are alternately laminated one by one, or may have a structure including adjacent foam sheets 21 or adjacent fiber sheets 22. It's okay. Moreover, in these cases, the outermost layer of the base material 20 on which the surface layer component 30 is laminated may be configured by the foam sheet 21 or the fiber sheet 22.

(5)上記実施形態では、基材20を構成するシートが、発泡シート21と繊維シート22であったが、繊維シート22のみであってもよい。この構成として、例えば、基材20がプリプレグからなる構成が挙げられる。 (5) In the above embodiment, the sheets constituting the base material 20 were the foam sheet 21 and the fiber sheet 22, but the fiber sheet 22 alone may be used. An example of this configuration is a configuration in which the base material 20 is made of prepreg.

(6)上記実施形態において、表層構成部30が、基材20の表裏の両面に設けられていてもよい。この場合、繊維強化樹脂成形体10を製造する際に、基材用シート20Sの表裏の両面にSMC30Sが重ねられる。 (6) In the above embodiment, the surface layer forming portion 30 may be provided on both the front and back sides of the base material 20. In this case, when manufacturing the fiber-reinforced resin molded body 10, the SMC 30S is stacked on both the front and back sides of the base sheet 20S.

(7)上記実施形態では、発泡シート21と繊維シート22とに含浸する熱硬化性樹脂が同じであったが、異なっていてもよい。この場合、発泡シート21に含浸する熱硬化性樹脂と、繊維シート22に含浸する熱硬化性樹脂とは、それぞれ、SMCを構成する第1の熱硬化性樹脂に比べて、硬化温度が高いか、又は、硬化時間が長いものが用いられる。 (7) In the above embodiment, the foamed sheet 21 and the fiber sheet 22 are impregnated with the same thermosetting resin, but they may be different. In this case, the thermosetting resin impregnated into the foam sheet 21 and the thermosetting resin impregnated into the fiber sheet 22 each have a higher curing temperature than the first thermosetting resin constituting the SMC. Or, a material with a long curing time is used.

(8)上記実施形態において、表層構成部30の表面突部32は、例えば、突条、突壁、棒状の突部であってもよい。 (8) In the embodiment described above, the surface protrusion 32 of the surface layer forming portion 30 may be, for example, a protrusion, a protrusion wall, or a bar-shaped protrusion.

10 繊維強化樹脂成形体
20 基材
30 表層構成部
10 Fiber-reinforced resin molded body 20 Base material 30 Surface layer constituent part

Claims (4)

第1の熱硬化性樹脂を含むシートモールディングコンパウンドからなる表層構成部と、a surface layer component made of a sheet molding compound containing a first thermosetting resin;
前記第1の熱硬化性樹脂に比べて硬化温度が高い又は硬化時間が長い第2の熱硬化性樹脂が含浸した発泡シートを備える基材と、を備え、A base material comprising a foam sheet impregnated with a second thermosetting resin having a higher curing temperature or a longer curing time than the first thermosetting resin,
前記表層構成部は、前記発泡シートに配置されており、前記発泡シートと反対側を向く面に、突部又は凹部からなる賦形部を有する、樹脂成形体。The surface layer component is arranged on the foamed sheet, and the resin molded article has a shaped portion consisting of a protrusion or a recess on a surface facing opposite to the foamed sheet.
前記基材には、前記第2の熱硬化性樹脂が含浸した繊維シートが、前記繊維シートと前記表層構成部とが前記発泡シートを挟むように配置して積層されている請求項1に記載の樹脂成形体。2. A fiber sheet impregnated with the second thermosetting resin is laminated on the base material such that the fiber sheet and the surface layer component sandwich the foam sheet. resin molded body. 発泡シートを備える基材に、第1の熱硬化性樹脂を含むシートモールディングコンパウンドからなる表層構成部が積層されてなり、A surface layer component made of a sheet molding compound containing a first thermosetting resin is laminated on a base material including a foamed sheet,
前記基材は、前記シートモールディングコンパウンドに含まれる繊維よりも繊維長の長い補強繊維と、前記第1の熱硬化性樹脂に比べて硬化温度が高い又は硬化時間が長い第2の熱硬化性樹脂を含み、The base material includes reinforcing fibers having a longer fiber length than the fibers contained in the sheet molding compound, and a second thermosetting resin that has a higher curing temperature or a longer curing time than the first thermosetting resin. including;
前記表層構成部は、前記基材と反対側を向く面に、突部又は凹部からなる賦形部を有する、繊維強化樹脂成形体。The surface layer forming part is a fiber-reinforced resin molded article having a shaped part consisting of a protrusion or a recess on a surface facing opposite to the base material.
基材に、第1の熱硬化性樹脂を含むシートモールディングコンパウンドからなる表層構成部が積層されてなり、A surface layer component made of a sheet molding compound containing a first thermosetting resin is laminated on the base material,
前記基材は、前記シートモールディングコンパウンドに含まれる繊維よりも繊維長の長い補強繊維と、前記第1の熱硬化性樹脂に比べて硬化温度が高い又は硬化時間が長い第2の熱硬化性樹脂とを含み、The base material includes reinforcing fibers having a longer fiber length than the fibers contained in the sheet molding compound, and a second thermosetting resin that has a higher curing temperature or a longer curing time than the first thermosetting resin. including
前記表層構成部は、前記基材と反対側を向く面に、凹部からなる賦形部を有する、繊維強化樹脂成形体。The surface layer forming part is a fiber-reinforced resin molded article having a shaped part consisting of a recessed part on a surface facing opposite to the base material.
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