JP7385980B1 - 扁平断面ガラス繊維、及び、ガラス再生材料を含むガラス原料からの扁平断面ガラス繊維の製造方法 - Google Patents
扁平断面ガラス繊維、及び、ガラス再生材料を含むガラス原料からの扁平断面ガラス繊維の製造方法 Download PDFInfo
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- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
- C03B37/022—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/075—Manufacture of non-optical fibres or filaments consisting of different sorts of glass or characterised by shape, e.g. undulated fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture, Treatment Of Glass Fibers (AREA)
- Glass Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
5.5 ≦ C 2 /(A×A×B) 1/2 ≦ 53.6 ・・・(a)
11.7 ≦ C2/(A×A×B)1/2 ≦ 33.4 ・・・(1)
14.0 ≦ C2/(A×A×B)1/2 ≦ 26.3 ・・・(2)
5.5 ≦ C 2 /(A×A×B) 1/2 ≦ 53.6 ・・・(a)
5.5 ≦ C 2 /(A×A×B) 1/2 ≦ 53.6 ・・・(a)
11.7 ≦ C2/(A×A×B)1/2 ≦ 33.4 ・・・(1)
14.0 ≦ C2/(A×A×B)1/2 ≦ 26.3 ・・・(2)
全量に対して5.0質量%のガラス再生材料を含むガラス原料を溶融し、得られた溶融ガラスを、200個のノズルチップを備えるブッシングから引き出して、複数の扁平断面ガラスフィラメントを得て、これらの扁平断面ガラスフィラメントを集束させて扁平断面ガラス繊維を製造した。前記ノズルチップは、所定の範囲の長さの長径と所定の範囲の長さの短径とを備える扁平な断面形状を有する孔部と、溶融ガラスを冷却する切り欠きを備えた壁部とを備えている。
実施例1~12又は比較例1~7の扁平断面ガラス繊維を8時間生産するにあたり、扁平断面ガラス繊維を構成する扁平断面ガラスフィラメントに切断が生じる回数が1.0回/時間以下の場合を「A」、1.0回超2.0回以下の場合を「B」、2.0回/時間超の場合を「C」と評価した。
実施例1~12又は比較例1~7の扁平断面ガラス繊維を生産するにあたり、前記ノズルチップ1個当たりを通過する溶融ガラスの流量が0.30g/分以上の場合を「A」、0.20g/分以上0.30g/分未満の場合を「B」、0.20g/分未満の場合を「C」と評価した。
実施例1~12又は比較例1~7の扁平断面ガラス繊維の表面をシランカップリング剤を含む組成物で被覆し、3mmの長さに切断して、チョップドストランドとした。次に、前記チョップドストランドとポリアミド6樹脂(宇部興産株式会社製、商品名:UBE1015B)とを、スクリュー回転数を100rpmとして、二軸混練機(芝浦機械株式会社製、商品名:TEM-26SS)にて270℃の温度で混練し、ガラス繊維含有率が30質量%の樹脂ペレットを作製した。
前記反り測定用試験片を成形に用いたものと同一の樹脂ペレットを用いて、射出成形機(日精樹脂工業株式会社製、商品名:NEX80)により金型温度90℃、射出温度270℃にて射出成形を行い、JIS K 7165:2008に準じたA型ダンベル試験片(厚さ4mm)を作製した。前記A型ダンベル試験片について、試験温度23℃の条件で、精密万能試験機(株式会社島津製作所製、商品名:オートグラフAG-5000B)を用いて、JIS K 7171:2016に準拠した静的引張試験により得られた測定値を、曲げ強度とした。曲げ強度が250MPa以上であるものを「A」、200MPa以上250MPa未満ものを「B」、200MPa未満のものを「C」と評価した。
表1、2から、短径の長さの変動係数Cが8.0~26.1%の範囲にある実施例1~12の扁平断面ガラス繊維は、連続生産性及び大量生産適性に優れるか、又は特に優れており、かつ、優れた、又は特に優れた樹脂成形品強化性を得ることができることが明らかである。
Claims (5)
- 所定の範囲の長さの長径と所定の範囲の長さの短径とを備える扁平な断面形状を有する扁平断面ガラスフィラメントを複数本含む扁平断面ガラス繊維であって、
短径の長さAが、3.5~10.5μmの範囲にあり、前記短径の長さに対する長径の長さの比(長径の長さ/短径の長さ)Bが1.5~9.0の範囲にあり、
前記短径の長さの変動係数Cが8.0~26.1%の範囲にあり、
前記A、B、及び、Cが、次式(a)を満たすことを特徴とする、扁平断面ガラス繊維。
5.5 ≦ C2/(A×A×B)1/2 ≦ 53.6 ・・・(a) - 請求項1記載の扁平断面ガラス繊維において、前記短径の変動係数が12.6~18.5%の範囲にあることを特徴とする、扁平断面ガラス繊維。
- 請求項1記載の扁平断面ガラス繊維において、前記A、B、及び、Cが、次式(1)を満たすことを特徴とする、扁平断面ガラス繊維。
11.7 ≦ C2/(A×A×B)1/2 ≦ 33.4 ・・・(1) - 請求項3記載の扁平断面ガラス繊維において、前記A、B、及び、Cが、次式(2)を満たすことを特徴とする、扁平断面ガラス繊維。
14.0 ≦ C2/(A×A×B)1/2 ≦ 26.3 ・・・(2) - 全量に対し、1.0~50.0質量%の範囲のガラス再生材料を含むガラス原料を用いて、
所定の範囲の長さの長径と所定の範囲の長さの短径とを備える扁平な断面形状を有し、短径の長さAが、3.5~10.5μmの範囲にあり、前記短径の長さに対する長径の長さの比(長径の長さ/短径の長さ)Bが1.5~9.0の範囲にあり、前記短径の長さの変動係数Cが8.0~26.1%の範囲にあり、
前記A、B、及び、Cが、次式(a)を満たす、複数本の扁平断面ガラスフィラメントを得て、前記複数本の扁平断面ガラスフィラメントを集束させることを特徴とする、ガラス再生材料を含むガラス原料からの扁平断面ガラス繊維の製造方法。
5.5 ≦ C 2 /(A×A×B) 1/2 ≦ 53.6 ・・・(a)
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JP2010150127A (ja) | 2008-11-20 | 2010-07-08 | Nippon Electric Glass Co Ltd | ガラス繊維製造装置およびガラス繊維製造方法 |
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