JP7357746B1 - New seabed improvement agent 3 that promotes the binding of marine plastic debris and radioactive pollutants and heavy metal substances in seawater - Google Patents

Abstract

[Problem] Conventional waste oil processing agents diffuse onto land and sea surfaces, causing environmental pollution, and oil-absorbing mats do not contribute to carbon dioxide reduction. Chemical treatment leaves oil, marine debris, plastic debris, etc. untouched, which poses a problem in improving the natural environment and soil, and increases the effect of microbial decomposition and reduces the impact on environmental pollution. [Solution] The raw materials are volcanic ash, coal ash, incineration ash, zeolite containing seed silica components, organic magnetic material and electrode raw materials, activated carbon, charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husk, A solution of inorganic mucin, starch, seaweed, jellyfish, dried natto powder, vegetable oil, animal oil, and water is sprayed onto a mixture of sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, and powdered soap. By making it into granular solids and by spreading the granulated solids, it prevents the solid raw materials from scattering and accurately penetrates and absorbs contaminated water and oil, separating the raw materials in the solids from contaminated water and oil. Foam generated by reaction with pollutants envelops contaminated water and oil and turns them into solids. [Selection diagram] Figure 2

Description

Detailed description of the invention

Details of the invention

Technical field to which the present invention pertains

The present invention prevents the spread of contaminated water and oil on the surface of oceans, rivers, ports, and lakes related to oil spill accidents, and adsorbs pollutants and oil contained in contaminated water, as well as marine debris such as wood chips, seaweed, fishing nets, plastics, and microchips. It is compacted and submerged in the ocean floor, where it is converted into carbon dioxide and chlorine, supplementing iron, phosphorus, and nitrogen, which are essential for natural decomposition, and enhancing the ionic bonding effect through electrical conduction between microorganisms and the anode and cathode. In addition, it reduces the impact on environmental pollution and has high utility value from the perspective of protecting the natural environment.

The type that solidifies the oil with an absorbent mat and throws it away as garbage has the problem of having to collect and incinerate it and not contributing to carbon dioxide reduction. In addition, there is a problem of environmental pollution due to adhesion to birds, fish and shellfish, and coastal sand, and solid treatment types, when sprayed in the air or used on land and sea surfaces, cause the natural dispersion of raw materials, oil runoff, and marine debris. There were environmental and water quality problems due to precipitation.

Patent No. 604329 JP-A No. 2008-231897 requires the steps of mixing and kneading each material and aggregate with water, taking it out into a mold, curing it, taking it out of the mold and making it into a molded product, and then turning the molded product block in water. I was sinking into it.

Problems that the invention aims to solve

Contaminated water and waste oil dispersants, which are conventional causes of marine pollution, are sprayed in the air or dropped or spread on land and sea surfaces, causing problems of environmental pollution. There is also the problem that polluted water and oil are adsorbed and solidified and disposed of as marine debris, which requires the labor and effort of collection and incineration and does not contribute to carbon dioxide reduction. The type that undergoes solidification treatment has problems with its effects on improving the natural environment in water and soil as it is used in large quantities.

Further, there is a problem in that the solvent treatment cost is high, making it difficult to implement and resulting in high costs.

Means to solve problems

Raw materials for contaminated water and oil dispersants include volcanic ash, coal ash, incinerated ash, and zeolite containing seed silica components, organic magnetic materials and electrode body raw materials, magnetic material raw materials, activated carbon, charcoal, gypsum, lime, slag, Inorganic protein mucin, starch, seaweed, jellyfish, and natto are ground into a mixture of clay, iron powder, aluminum powder, rice husks, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, cement, and carbide. Dry powder or aqueous solution is sprayed and solidified into granules, and then sprayed for the purpose of treating contaminated water and oil.The main component, soluble silicic acid, penetrates and absorbs contaminated water and oil, and the foam containing air bubbles removes the pollutants. Make it into a solid substance. In addition, granular solids will be filled inside the storage facility and tunnel, and foam will be used to seal cracks and flooded areas to create an integrated structure. In addition, we will construct a dam using granular solids packed in bags, repair cracks in the collapsed levee, and solidify leakage gaps with foam integral structures. In addition, when solids are sprinkled onto contaminated water for the purpose of treating contaminated water, oil, and marine debris, granular solids dissolve, and bubbles and bubbles are created when the solids react with water in the contaminated water or oil. The system wraps pollutants, oil, and marine plastic debris in contaminated water in foam to prevent them from leaking out and dispersing them, and transforms them into solid objects and sinks them into the seabed and fixes them. The anode, which is electrically connected to the electrode inside, elutes Fe ions and S ions, and the cathode part elutes Fe ions and S ions, and the cathode part generates 1/2 O2 + H2O + 2e- → 2OH- in seawater → OH-, and also in plastic garbage. The bottle is made of PET resin, which is mainly composed of carbon, oxygen, and hydrogen.
Approximately 1/3 of the resin is made up of oxygen derived from air, making it a resin that is less dependent on petroleum than other plastics.
2) Compared to other plastics, it contains more oxygen, which is heavier than carbon, so it sinks and decomposes into carbon, oxygen, and hydrogen, and plastic waste is converted into carbon dioxide and chlorine, while phosphorus or , combines with nitrogen, ammonia, cesium, carbon dioxide, etc., and deposits calcium carbonate on the cathode electrode surface, promoting the settlement and growth of seaweed, microorganisms, young shellfish, and young corals. , carbon dioxide is fixed on the ocean floor as calcium carbonate deposits. Additionally, electrolysis of water increases the concentration of dissolved oxygen in water.

自然環境保護の観点からも動植物への影響を少なくし、利用価値の高いものである。本発明は空中散布又は海洋及び陸上散布、河川及び護岸の形成材として、水質浄化及び藻場及び植生コンクリートブロック機能と、自然災害時及び緊急時の汚染水及び油処理、海洋ゴミとプラスチック及びマイクロチップゴミを吸着し海底に固定分解する機能並びに、核保管施設内及びトンネル内の亀裂、漏水修復及び隙間を塞ぎ、出入口の密閉すると伴に、一体構造物になる目的としている。In addition, it completely eliminates the impact on environmental pollution, reduces the time and effort required to collect contaminated water and oil, and enhances the electrolytic ion effect of microbial decomposition by supplementing iron, phosphorus, and nitrogen, which are essential for natural decomposition. . In addition, the chemical formula (molecular formula, composition formula, structural formula) of PET (polyethylene terephthalate) is as follows.

From the perspective of protecting the natural environment, it has less impact on animals and plants, and has high utility value. The present invention can be used for aerial spraying or spraying on the ocean or land, as a forming material for rivers and seawalls, for water purification, seaweed bed and vegetation concrete block functions, for the treatment of contaminated water and oil during natural disasters and emergencies, for marine debris, plastics, and microorganisms. It has the function of adsorbing chip debris and fixing it on the seabed and decomposing it, as well as repairing cracks and water leaks in nuclear storage facilities and tunnels, filling gaps, and sealing entrances and exits, as well as becoming an integrated structure.

As another example, a bag filled with granular solids is installed in the event of a flooded oil spill, and the bag is a paper bag or a bag made of a combination of carbon fiber, chemical fiber, and aluminum foil, and the outer surface of the bag and the Arrange vertically convex connecting metal fittings on the outside back of the bag, stack the bags on top of the connecting metal fittings, and insert concave connecting metal fittings or stakes from above the connected bags to form a protective wall or a landlocking wall. To construct.

Other examples include cushioning materials that seal the gaps by generating bubbles by filling the gaps in pollutant storage facilities and storage tunnels with granular solids, water leakage and corrosion prevention materials, crack repair materials, Can be used as bulkhead material for entrances and exits. A paper bag or a bag made of a combination of carbon fiber, chemical fiber, and aluminum foil. Granular solids filled in a permeable cloth bag, and bags filled with granular solitary particles in a permeable cloth bag during the laying and pumping of fresh concrete. Insert metal fittings into the soil and harden it by inserting metal fittings on top of the laid or stacked bags. In addition, by connecting and constructing multiple bags, the gap is filled with bubbles to form an integrated structure, and the integrated structure measures ionic bonding with the pollutant component of contaminated water through electrical conduction between the electrode material and the magnetic pole material.

As another example, powdered solids are filled in permeable paper bags, carbon fiber bags, synthetic fiber sheet bags, or containers in the storage facilities of nuclear final disposal sites and in the gaps between storage containers and mixed according to the intended use. Once adjusted and installed, it will become a dual structure with heavy metal water purification functions, heavy metal adsorption functions, and an integrated structure.

The solids can be easily dissolved by simply throwing and spraying a bag or dissolving container filled with granular solids made by kneading each material into contaminated water, the ocean during an oil spill, and marine debris in the water. It generates bubbles and reacts with oil, contaminated water, and pollutants, forming an integral molded product and fixing it. In addition, it can be used as a suitable material for treating contaminated water and oil, while retaining its function as a buffer material for nuclear power generation explosion accidents, damage repair of entrance/exit bulkheads in nuclear facilities, storage containers in storage facilities, and gaps within the facility. It is easy to implement and has a disaster prevention function for repairing cracks and water leaks inside and outside of facilities and tunnels.

The mixture is placed in a permeable bag, the lid is placed on the bag, and the electrode plate and the magnetic pole plate, which have connecting fittings arranged above and below the outer surface of the bag and the outer back surface of the bag, are pressed into the bag and solidified. As a manufacturing usage method,
Example 1. When an electrode plate (1) is connected to an iron material and a galvanic anode (magnesium alloy cathode) and immersed in seawater, a current is applied to the surface of the iron material, and an alkaline component OH- is generated on the surface of the iron material. Calcium ion Ca2+, hydrogen carbonate ion HCO3-, and magnesium ion Mg2+ in seawater form a precipitate shown in the following formula and adhere to the surface of the electrode steel material. This deposit is recognized as electrode material.
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH-→Mg(OH)2↓
▲3▼ Since the electrode material is close to calcium carbonate, which is the main component of the skeletons of shellfish and reef-building corals, it has the advantage that young corals can easily settle on it.
▲4▼ Utilizing this principle, the electrode-attached base is a base on which calcium carbonate is deposited on the surface of the metal base through which a magnetic current is passed to ensure electrical continuity and magnetic conduction. The purpose is to promote the epiphytic growth of microorganisms, young shellfish, and young corals.

The electrode plate and the magnetic pole plate have conductivity and magnetic polarity as described above. Electromagnetic continuity is ensured between the organic body partitioned by an inorganic substance in the center of the solid body and the seawater, and the gas generated from the electrode (anode in the above example) placed in the insulator containment vessel. teeth,
Example 1. When an electrode plate (1) is connected to an iron material and a galvanic anode (magnesium alloy cathode) and immersed in seawater, a current is applied to the surface of the iron material, and an alkaline component OH- is generated on the surface of the iron material. Calcium ion Ca2+, hydrogen carbonate ion HCO3-, and magnesium ion Mg2+ in seawater form a precipitate shown in the following formula and adhere to the surface of the electrode steel material. This deposit is recognized as electrode material.
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH-→Mg(OH)2↓
▲3▼ Since the electrode material is close to calcium carbonate, which is the main component of the skeletons of shellfish and reef-building corals, it has the advantage that young corals can easily settle on it.
▲4▼ Utilizing this principle, the electrode-attached base is a base on which calcium carbonate is deposited on the surface of the metal base through which a magnetic current is passed to ensure electrical continuity and magnetic conduction. The purpose is to promote the epiphytic growth of microorganisms, young shellfish, and young corals.
An electrode plate and a magnetic pole plate of a device in which a mixture is placed in a permeable bag and a lid is placed on the bag, and connecting fittings are placed above and below the outside surface of the bag and the outside back surface of the bag, and a reflective device is provided in the center. Example 1. When an electrode plate (1) is connected to an iron material and a galvanic anode (magnesium alloy cathode) and immersed in seawater, a current is applied to the surface of the iron material, and an alkaline component OH- is generated on the surface of the iron material. Calcium ion Ca2+, hydrogen carbonate ion HCO3-, and magnesium ion Mg2+ in seawater form a precipitate shown in the following formula and adhere to the surface of the electrode steel material. This deposit is recognized as electrode material.
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH-→Mg(OH)2↓
▲3▼ Since the electrode material is close to calcium carbonate, which is the main component of the skeletons of shellfish and reef-building corals, it has the advantage that young corals can easily settle on it.
▲4▼ Utilizing this principle, the electrode-attached base is a base on which calcium carbonate is deposited on the surface of the metal base through which a magnetic current is passed to ensure electrical continuity and magnetic conduction. The purpose is to promote the epiphytic growth of microorganisms, young shellfish, and young corals. The reaction at the electrode part of the magnetic material that has absorbed ionized water is expressed by equations [Equation 1] and [Equation 2].

Next, in the hollow part of the aerated concrete body, we installed a steel plate (potential in seawater -06 to -0.7V VS SCE) and a metal with a higher potential than iron, such as an aluminum plate (potential in seawater +02 to 0.3V VS SCE). ), when filled with a mixture of activated carbon, etc. and immersed in seawater, a current flows from the aluminum plate with a high potential to the iron with a low potential, forming an electrode, the iron plate becomes an anode, and Fe ions are generated as in equation [1]. The aluminum, zinc, and magnesium plates become cathodes and generate OH- as shown in equation [2]. When filled with iron and a mixture of metals with a higher potential than iron, the amount of Fe ions eluted increases at an accelerated rate compared to when only iron is filled, resulting in the proliferation of diatoms, plankton, and seaweed This further improves the proliferation of other species, and indirectly increases the collection effect compared to when only iron is used. Note that the elution of Fe ions from the iron plate serving as the anode increases as the area of the cathode increases, so the amount of Fe ions eluted can be adjusted by changing the area (i.e., weight) components of the aluminum, zinc, and magnesium plates. By filling a hollow part of the main body with iron and immersing it in seawater, parts with different potentials mix on the iron surface to form a local electrode, and iron ions and hydrogen ions are eluted. As a result, Fe and S ion molecules combine with phosphorus, nitrogen, ammonia, cesium, etc., and are absorbed by seaweed, producing the effect of promoting the reproduction of seaweed.
(4) Iron components (potential in seawater -0.6 to -0.7V) and metals with a higher potential than iron, such as aluminum, zinc, and magnesium components (potential in seawater -0.6 to -0.7V), are placed in the hollow space of the solid material containing air bubbles. By filling the mixture with activated carbon, etc. and immersing it in seawater, a current flows from the aluminum, zinc, or magnesium plate with a high potential to the iron ion component with a low potential, forming an electrode. The iron component becomes an anode and elutes as Fe ions as in (3) above, and the aluminum, zinc, and magnesium components become a cathode and generate OH-. When filled with a mixture of iron powder and magnetic metal that has a higher potential than the iron plate, the amount of Fe ions eluted increases at an accelerated rate compared to when only iron powder is filled, so diatoms and plankton Breeding, seawater and algae growth are further improved, and indirectly the collection effect is further enhanced than when only iron is filled. By taking advantage of these properties, we have developed a method for producing and using solid materials of mixtures and kneaded products in which bags are placed and placed for the purpose of nuclear power generation explosion accidents, nuclear contaminated water treatment, and diffusion prevention.

The raw materials for the contaminated water and oil and marine debris treatment agent are 35 g of volcanic ash, coal ash, fly ash, or zeolite containing seed silica, and magnetic material raw materials, activated carbon, charcoal, gypsum, lime, slag, clay, and iron. In the kneading process, 50 g of a mixture of powder, aluminum powder, rice husks, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, and powdered soap are mixed into dry powders of inorganic mucin, starch, seaweed, jellyfish, and natto. While spraying 100 mL of a kneaded product of 15 g of an aqueous solution of There are two methods: a method in which a solid material coated on the surface of an object is directly sprayed for the purpose of treating contaminated water and oil, and a method in which it is filled in a permeable bag or a dissolvable container and covered with a lid, and then sprayed in the air or dropped.
In addition, the solid substance reacts with water and generates bubbles containing air bubbles, and the bubbles also contain contaminated water, pollutants, and oil, and within the solid substance, electrical conduction between the anode and cathode and electrolytic ion effects occur. increases and forms ionic bonds with pollutants in contaminated water.

The essential raw materials for contaminated water, oil, and marine debris treatment agents are volcanic ash, coal ash, or fly ash containing silica components, electrode materials, magnetic material materials, and activated carbon, depending on the purpose and place of use. A mixture of 10 to 12 types of charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husk, zeolite, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, and powdered soap. In the process of mixing and adjusting the mixture, a mixed aqueous solution of inorganic mucin, starch, seaweed, jellyfish, dried powder of crushed natto, and vegetable oil is sprayed and solidified into particles of 10 to 20 mm.

Depending on the purpose of use, organic raw materials include volcanic ash containing silica components, coal ash, fly ash, or zeolite, 35 g, magnetic material raw materials, activated carbon, charcoal, gypsum, lime, slag, clay, iron powder, aluminum. Knead 50g of a mixture of flour, rice husk, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, and powdered soap, and add inorganic mucin and starch to the kneaded product during the vibration and rotation process in a rotating pan. , by spraying an aqueous solution containing 15 g of dried powder of seaweed, jellyfish, and natto, and applying a centrifugal magnetic field pressure of about 10 million gauss to the granular solids, producing a magnetic electrode from the solids under centrifugal pressure. How to Use.

Fill granular solids in permeable and dissolvable bags or containers and close the lids. A usage method in which the bags and containers are stacked and arranged, and the convex part is pushed into the bag or container by the weight of the container to form an integrated structure.

Spread the bag or container filled with granular solids into contaminated water, oil spill sites, soft soil, or marine debris, or throw the bag or container filled with solids into the seabed and place it firmly on the seabed. How to use things.

For the purpose of preventing radioactive gas emissions during nuclear power generation explosion accidents, nuclear contaminated water and oil disposal, oil spills, and reactor fires, solid materials are sprayed and solid materials are placed in bags and permeable containers. A method of use in which packed materials are dropped and sprayed from the air or on land, or pumped into the reactor or building for filling.

A method of production and utilization in which a bag filled with solid matter is filled with contaminated water, and contaminated water is allowed to penetrate into the solid matter, trapping the contaminant within the bubbles and bubbles to form an integral structure of foam.

How to use it to repair nuclear power generation explosion accidents, nuclear facilities, entrances and exits in tunnels, water leaks and cracks in tunnels, and to harden and fix as a cushioning material for foam in gaps and construct integrated structures.

Also, depending on the purpose of use, the solid material is mixed with an appropriate amount of sludge, alcoholic beverages (shochu, beer, sake, whiskey) waste water, and then the solid material is sprayed or used as a seawall shield water retention layer.

Effect of the invention

The present invention is a spraying material for contaminated water or oil spills in emergencies, and a contaminated water and oil treatment agent, which includes ash containing solid seed silica, soluble silicic acid as the main component, starch as an inorganic raw material, and seaweed as a main component. A mixed aqueous solution of jellyfish, dried powder obtained by crushing natto, and vegetable oil is sprayed onto the kneaded material to form a solid material, and at the same time, the contaminated water and oil are penetrated and solidified. In addition, by hardening the surface with foam, solids are prevented from dispersing during spraying, and at the same time, solids that have penetrated from the surface of contaminated water and oil to the inner layer react with moisture and generate foam, which causes the solids to rise above the sea surface. Contains oil and marine debris in the foam, prevents spillage and oil diffusion, adsorbs contaminated water and oil, as well as plastic and microchip debris from marine debris, and helps in microbial decomposition by sinking and fixing them on the seabed. do.
In addition, it becomes easier to collect and handle the molded product, which is made up of foam that has reacted with the solids and the contaminated water and oil. In addition, a mixture of various materials or solid materials packed in bags can be molded into one piece by simply placing it in a wet place with contaminated water or oily water surface, and can be used as a seawall block, natural regeneration block, or a landlocking structure function. While maintaining the oil fence function, it can be used as a buffer material to repair nuclear power generation explosion accidents, cracks and filtration in nuclear storage facilities and tunnels, and fill gaps, as well as sealing entrances and exits, bulkheads, and structures integrated with facilities. become.

Diagram Cross section Cross section Diagram

1. Shipwreck 2. Oil level 3. Aerially sprayed solid seabed improvement agent 4. Helicopter 5. Oil 6. Solids 7. Undersea 8. Rotating pan 9. Rotating pan body 10. Kneaded product 11. Kneaded material filling device 12. Reactor building 13. Conduit 14. Filling path 15. reactor core

Claims (3)

Raw materials include volcanic ash, coal ash, incineration ash, and zeolite containing seed silica components, magnetic material and electrode body materials, activated carbon, charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husks, sand, and wood chips. A mixed solution of protein mucin, starch, seaweed, jellyfish, dried natto powder, vegetable oil, animal oil, and water is sprayed onto a mixture of salt or caustic soda, phosphorus, sulfur, calcium silicate, and powdered soap to form granular solids. A method of using a seabed improvement agent, which is characterized by the fact that it has been made into a product. The granular solid material according to claim 1 described above is filled into nuclear facilities and storage facilities, tunnels, and shafts, and gaps between bulkheads and cracks in reactor buildings and facilities can be made into an integrated structure. How to use seabed improvement agents. The granular solids according to any of claims 1 and 2 above are dispersed in water, Fe ions, S ions, contaminated water and pollutants, heavy metals, phosphorus, nitrogen, ammonia, A method of using a seabed improvement agent, which is characterized in that it can be formed into an integral structure with cesium, carbon dioxide, plastic, and microchips.