JP2012154157A - Utilization method of sea bottom improver replacing oil treatment - Google Patents
Utilization method of sea bottom improver replacing oil treatment Download PDFInfo
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- JP2012154157A JP2012154157A JP2011025424A JP2011025424A JP2012154157A JP 2012154157 A JP2012154157 A JP 2012154157A JP 2011025424 A JP2011025424 A JP 2011025424A JP 2011025424 A JP2011025424 A JP 2011025424A JP 2012154157 A JP2012154157 A JP 2012154157A
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
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- 235000007164 Oryza sativa Nutrition 0.000 claims description 4
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
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- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- 239000000292 calcium oxide Substances 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 6
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract description 4
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- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
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- Treatment Of Biological Wastes In General (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
本発明は油流失事故に係る海洋、河川、港湾、湖沼の水面の油拡散を防止し、油を固めて沈めて、回収時間と手間をはぶき自然分解に不可欠な鉄分、リン、窒素分を補い微生物分解効果を高めたものである。また、環境汚染への影響を少なくすとともに、動植物への付着及び自然環境保護の観点からも利用価値の高いものである。The present invention prevents the spread of oil on the surface of oceans, rivers, harbors, lakes and marshes in oil spill accidents, solidifies and sinks the oil, eliminates recovery time and labor, and supplements iron, phosphorus, and nitrogen that are essential for natural decomposition. It has enhanced microbial degradation effect. Moreover, it has a high utility value from the viewpoints of reducing the influence on environmental pollution, and attaching to animals and plants and protecting the natural environment.
油を吸着マットで固形にして、ごみとして捨てるタイプは回収、焼却の手間と二酸化炭素削減に寄与していない問題があった。また、鳥及び魚貝類及び海岸砂浜に付着し環境汚染の問題があり、薬剤処理にするタイプは、陸上及び海面に使用した場合、油の拡散及び流失し自然環境及び水質、沈殿した溶剤は土壌問題があった。The type in which oil is solidified with an adsorption mat and discarded as garbage has problems that it does not contribute to recovery, incineration, and carbon dioxide reduction. In addition, there is a problem of environmental pollution that adheres to birds, fish and shellfish and coastal beaches. When used on land and on the sea surface, the type treated with chemicals diffuses and drains oil and the natural environment and water quality. There was a problem.
［特許文献１］特許第６０４３２９号の海底改良剤マリンアース、［特許文献２］特開２００８−２３１８９７号は、各材料及び骨材と水で混合及び混練する行程と、型枠に取り出し養成し、型枠から取り出し成型物にする行程を要した上で、成型物ブロックを水中に沈めていた。[Patent Document 1] Marine Seafloor improver Marine Earth of Patent No. 604329, [Patent Document 2] Japanese Patent Application Laid-Open No. 2008-231897, a process of mixing and kneading each material and aggregate with water, taking out in a mold and nurturing After taking the process of taking it out of the mold and making it into a molded product, the molded product block was submerged in water.
従来の海洋汚染の原因である廃油処理剤は、陸上及び海面に拡散して鳥及び魚貝類及び海岸砂浜に付着し環境汚染の問題があった。また油を吸着マットで固形にして、ごみとして捨てるタイプは回収、焼却の手間と二酸化炭素削減に寄与していない問題があった。薬剤処理にするタイプは、水中の自然環境及び土壌改良効果に問題があった。Conventional waste oil treatment agents that are the cause of marine pollution diffuse to land and sea surface and adhere to birds, fish and shellfish, and coastal sand beaches, resulting in environmental pollution problems. In addition, the type in which oil is solidified with an adsorption mat and discarded as garbage has problems that it does not contribute to recovery, incineration, and carbon dioxide reduction. The type used for the chemical treatment has a problem in the natural environment in water and the soil improvement effect.
また、溶剤処理費が高額で実施し難くコスト高となる問題を有している。In addition, there is a problem that the solvent treatment cost is high and it is difficult to carry out, and the cost is high.
油処理海底改良剤の原料は石炭灰、フライアッシュ、焼却灰、磁性体原料、活性炭、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、ゼオライト、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、セメント混合物の海底改良剤に澱粉、海藻とクラゲを粉砕した乾燥パウダーにカーバイド混練物を油処理目的に散布して、油処理海底改良剤の主成分である可溶性けい酸が油分を浸透吸収し固め、気泡を含む泡を取込んだ固形成型物にする。また、混練物を袋詰めにし、土豪、土豪堰堤を構築した漏水隙間を泡で固める。また、油処理目的に混練物を海水又は水で攪拌し、ポンプで放水散布することで、原料と海水が反応し気泡及び泡で油を包み込み、外部流出及び拡散を防止し固形成型物にして海底に沈めて固定させる。また、原料及び混練物を散布、固形成型物内外に気泡を含む泡を取込み接着成型物にする。The raw materials for oil treatment seabed improver are coal ash, fly ash, incinerated ash, magnetic material, activated carbon, charcoal, gypsum, lime, slug, clay, iron powder, aluminum powder, rice husk, zeolite, sand, wood chips, salt or caustic soda Dissolve the main component of oil-treated seabed improver by spraying carbide kneaded product to dry powder obtained by pulverizing starch, seaweed and jellyfish for the purpose of oil treatment. Silicic acid penetrates and absorbs the oil and solidifies it to form a solid molded product containing bubbles. In addition, the kneaded product is packed in a bag, and the water leakage gap that built the Toha and Toha dam is solidified with foam. In addition, the kneaded product is stirred with seawater or water for the purpose of oil treatment and sprinkled with a pump, and the raw material reacts with seawater to wrap the oil in bubbles and bubbles, preventing outflow and diffusion to form a solid molded product. Sink into the seabed and fix. In addition, the raw material and the kneaded product are sprayed, and bubbles containing bubbles are taken into and out of the solid molded product to form an adhesive molded product.
また、環境汚染への影響を完全になくすとともに油の回収時間と手間を少なくし、自然分解に不可欠な鉄分、リン、窒素分を補い微生物分解効果及び肥料効果を高めたものである。自然環境保護の観点からも動植物への影響を少なくし、利用価値の高いものである。本発明は河川及び護岸の形成材として、水質浄化及び藻場及び植生コンクリートブロック機能と、自然災害時及び緊急時の油処理機能と藻場修復再生を含む土壌改良の活用を目的としている。In addition, it completely eliminates the impact on environmental pollution, reduces oil recovery time and labor, supplements iron, phosphorus, and nitrogen essential for natural degradation, and enhances microbial degradation and fertilizer effects. From the viewpoint of the protection of the natural environment, it has little impact on animals and plants and has high utility value. The object of the present invention is to utilize the soil improvement including water purification, algae beds and vegetation concrete block functions, oil treatment functions during natural disasters and emergencies, and alga bed restoration and regeneration as materials for forming rivers and revetments.
他例として、浸水油流出時に海底改良剤を袋詰めに填めたものを設置し、該、袋の外側表面及び、該、袋の外側裏面に、上下凸状の連結金具を配置し、連結金具の上に袋を重ねて、連結構築した袋の上から、凹連結金具又は、杭を挿入し防護壁、土豪壁として一体構築する。As another example, when a flooding oil spills, a seabed improver filled in a bag is installed, and the upper and lower convex connecting metal fittings are arranged on the outer surface of the bag and the outer rear surface of the bag. A bag is stacked on top of each other, and a concave connection fitting or a pile is inserted from above the connected and constructed bag to construct it as a protective wall and a topo wall.
他例として、海底改良剤材料と酒類系アールコール廃液水を混練りし、生コンクリート敷設及びポンプ圧打設時に、浸透性布袋に填めた混合物袋を投入及び、敷設又は積み重ねた袋のうえから、金属製の金具を差込み土壌に固定し固める。また袋を複数連結及び構築させることで、一体成形物コンクリートブロックを構築し、自然再生多孔質性コンクリート構造物にし、電極及び磁極電位作用により、水質浄化機能、植生機能を適切に発揮させる。As another example, the seabed improver material and liquor-based alcoholic wastewater are kneaded, and when laying the ready-mixed concrete and pumping, the mixture bag filled in the permeable cloth bag is put in, and from the laid or stacked bag Insert metal fittings and fix them in the soil. Moreover, by integrally connecting and constructing a plurality of bags, an integrally molded concrete block is constructed to form a naturally regenerated porous concrete structure, and the water purification function and the vegetation function are appropriately exhibited by the electrode and magnetic pole potential action.
他例として、最終処分場の防水シートと組み合わせて、海底改良剤材料に石綿、アスベスト、石膏ボードをケイ酸化カルシウム原料に加工して、酒類アールコール廃液混合物を混練りした、生コンクリートシールド層を敷設したのうえに、ゴムシートを張れば重金属の保水性機能と重金属吸着機能を備える二重構造物になる。As another example, in combination with a tarpaulin at the final disposal site, an asbestos, asbestos, gypsum board is processed into calcium silicate raw material as a seabed improver material, and a ready-mixed concrete shield layer kneaded with an alcoholic alcohol waste liquid mixture. If a rubber sheet is stretched after laying, it becomes a double structure having a heavy metal water retention function and a heavy metal adsorption function.
各材料を混練りさせた混合物を袋詰めされたものを、水中及び湿潤場所に投入及び敷設するのみで容易に一体成形し、護岸ブロック、自然再生ブロック、土豪構築物機能を保持させつつ、適切に油処理、防災機能を発揮させて製造が容易で安価である。A bag-blended mixture of each material is easily formed into a single piece by simply putting it in and placing it in water or in a wet place, while maintaining the functions of the revetment block, natural regeneration block, and earth-moving structure. The oil treatment and disaster prevention functions are demonstrated and manufacturing is easy and inexpensive.
油処理海底改良剤の原料は石炭灰、フライアッシュ、焼却灰、磁性体原料、活性炭、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、ゼオライト、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、セメント混合物の海底改良剤に澱粉、海藻とクラゲを粉砕した乾燥パウダーにカーバイド混練物を油処理目的に散布し、固形成型物内外に気泡を含む泡を取込み接着固形成型物にする。The raw materials for oil treatment seabed improver are coal ash, fly ash, incinerated ash, magnetic material, activated carbon, charcoal, gypsum, lime, slug, clay, iron powder, aluminum powder, rice husk, zeolite, sand, wood chips, salt or caustic soda , Phosphorus, Sulfur, Calcium silicate, Cement mixture, Seabed improver, Starch, Seaweed and jellyfish are dried powder, Carbide kneaded material is sprayed for oil treatment purpose Make a solid molding.
油処理海底改良剤の原料は石炭灰、フライアッシュ、焼却灰、磁性体原料、活性炭、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、ゼオライト、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、セメント混合物の海底改良剤混合物に澱粉、海藻とクラゲを粉砕した乾燥パウダーにカーバイド混練物を填めて海水又は水で混ぜて攪拌、流動性泡混練物を動力ポンプで散布する製造利用方法。The raw materials for oil treatment seabed improver are coal ash, fly ash, incinerated ash, magnetic material, activated carbon, charcoal, gypsum, lime, slug, clay, iron powder, aluminum powder, rice husk, zeolite, sand, wood chips, salt or caustic soda , Phosphorus, sulfur, calcium silicate, cement mixture seabed improver mixture starch, seaweed and jellyfish dried powder pulverized with carbide kneaded material, mixed with seawater or water, stirred, fluid foam kneaded material power pump Manufacturing use method to spread by.
使用目的強度に応じ、各混合物材料を適正割合配合調整したセメント混合物の海底改良剤混合物に澱粉、海藻とクラゲを粉砕した乾燥パウダーにカーバイド填めた混練物に海水又は水で混ぜて攪拌、混練物に振動と回転させて、遠心力磁場圧を約１０００万ガウスかけた容器に充填し後蓋をして、タンク圧力で流動性泡混練物を散布する製造利用方法。According to the intended strength of use, each mixture material is mixed and mixed in the proper proportions. Cement mixture is mixed with sea bottom improver mixture, starch, seaweed and jellyfish are crushed in dry powder and mixed with carbide or sea water, and stirred and kneaded. A manufacturing and utilization method in which the container is filled with a centrifugal magnetic field pressure of about 10 million gauss, covered with a lid, and the fluid foam kneaded material is sprayed at tank pressure.
混合物袋を、該、浸透性袋に填め蓋をし、該袋に填めた袋の外側表面と該別袋の外側裏面に、上下凸状の連結金具を配置し、連結金具の上に袋を重ねて、袋重量で内部に凸分を押し込み固定する製造利用方法。Cover the mixture bag with the permeable bag, place the lid on the outer surface of the bag and the outer back surface of the separate bag, and place the bag on the connector. A method of manufacturing and use that piles up and pushes and fixes the convex part inside with the bag weight.
混合物袋を詰めた該袋を、油流失現場及び軟弱土壌又は、水中に設置又は敷設及び構築させた袋の上部から土砂及び生コンクリートを敷設する製造利用方法。The manufacturing and utilization method of laying earth and sand and ready-mixed concrete from the top of the bag where the bag filled with the mixture bag is installed or laid and constructed in the field of oil loss and soft soil or water.
油処理目的、土砂及び生コンクリートを敷設した湿潤コンクリート内に、混合物を袋詰めた袋を投入及び置敷きする製造利用方法。A manufacturing and utilization method in which a bag filled with a mixture is put in and placed in wet concrete laid with earth and sand and ready-mixed concrete for oil treatment purposes.
混合物材料と酒類系廃液水及び醤油又は味噌廃液水を混練り使用し、生コンクリートを敷設したうえに、混合物袋を投入及び置き敷きし、セメント溶液及び各廃液が袋に染みこみ混合物内部に浸透させて、気泡及び泡一体多孔質体構築物及び植生構築物にする製造利用方法。Kneading the mixture material with liquor waste water and soy sauce or miso waste water, laying the ready-mixed concrete, placing and placing the mixture bag, the cement solution and each waste liquid soak into the bag and penetrate into the mixture The manufacturing and utilization method of making a porous body structure and a vegetation structure integrated with bubbles and bubbles.
構築した袋の上部から杭又は、金属棒を挿入し又、凹連結金具で横縦方向に打ち込み構築物を固定し、土壌に成型物を一体連結固定構築物にする利用方法。A method of using a pile or metal rod inserted from the upper part of the constructed bag and driving it in a horizontal and vertical direction with a concave connecting bracket to fix the structure, thereby converting the molded product into an integrally connected fixed structure on the soil.
また使用目的に応じて、海底改良剤材料と汚泥、酒類（焼酎、麦酒、日本酒、ウィスキー）廃液適水量を混練りした生コンクリートで散布又は、置敷きし生コンクリートシールド保水層にする製造利用方法。In addition, depending on the purpose of use, a method of manufacturing and using a sea floor improver material, sludge, and alcoholic beverages (shochu, barley, sake, whiskey), or sprayed with ready-mixed concrete mixed with a suitable amount of waste liquid to make a fresh concrete shield water-retaining layer .
本発明は、緊急時の油流失時の散布油処理剤であり、海底改良剤の主成分である可溶性けい酸が油分を浸透吸収し固める。また、原料の澱粉、海藻とクラゲを粉砕した乾燥パウダーにカーバイド混練物と海水が反応し泡を発生させて、油を泡内に閉じ込め外部流出及び油拡散を防止し、油を吸着し固形成型物にし海底に沈めて微生物分解の手伝いをする。また、泡を固めた成型物による土豪提の役目を果たし、油の回収及び取扱い処理が簡単になる。尚、各材料を混練りさせた混合物を袋詰めされたものを、油水面及び湿潤場所に投入及び敷設するのみで容易に一体成形し、護岸ブロック、自然再生ブロック、土豪構築物機能オイルフェンス機能を保持させつつ、水質浄化及び植生ブロック機能をプラスしながら、適切に緊急防災機能を発揮させて製造設置が容易で安価である。また、そのまま海底に沈めて固定させて、自然再生及び自然分解できる優れものである。The present invention is a sprayed oil treatment agent in the event of oil loss in an emergency, and soluble silicic acid, which is the main component of the seabed improver, permeates and absorbs oil and hardens. Carbide kneaded material and seawater react with dry powder obtained by pulverizing raw starch, seaweed and jellyfish to generate bubbles, trapping the oil in the bubbles, preventing external spillage and oil diffusion, adsorbing the oil and solid molding Helps microbial degradation by sinking to the bottom of the sea. In addition, it plays the role of a dough maker with foamed moldings, making it easy to collect and handle oil. In addition, a bag-packed mixture of each material is easily formed into a single piece by simply putting it in and laying it on the oily water surface and a moist place. While maintaining it, water purification and vegetation blocking functions are added, and the emergency disaster prevention function is properly exerted to make manufacture and installation easy and inexpensive. Moreover, it is excellent in that it can be submerged and fixed on the sea floor as it is, and can be naturally regenerated and decomposed.
１．沈船 ２．油水面 ３．空中散布する海底改良剤混練物
４．ヘリコプター ５．油 ６．成型物 ７．海底1. Shipwreck 2. Oil /
Claims (5)
海底改良剤Raw materials are coal ash, fly ash, incinerated ash, magnetic material, activated carbon, charcoal, gypsum, lime, slug, clay, iron powder, aluminum powder, rice husk, zeolite, sand, wood chips, salt or caustic soda, phosphorus, sulfur, silica Powdered soap, starch, seaweed, jellyfish, and carbide kneaded material are sprayed onto a calcium oxide / cement mixture to form a solid molded product incorporating bubbles containing bubbles.
Seabed improver
海底改良剤The raw material kneaded material is sprayed for the purpose of oil treatment, and bubbles containing bubbles are taken into and out of the solid molded product to form an adhesive molded product.
Seabed improver
海底改良剤The above-mentioned raw material kneaded product can be formed into an adhesive molded product in a gap between a bagged soil gob and a soil go dam.
Seabed improver
海底改良剤The raw material kneaded product can be made into a foamed product by stirring with water and spraying.
Seabed improver
海底改良剤The raw material kneaded product is stirred with water to form a solid molded product incorporating bubbles and bubbles.
Seabed improver
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