JP2024049267A - New seabed modifier 3 that promotes binding of marine plastic debris with radioactive contaminants and heavy metals in seawater - Google Patents
New seabed modifier 3 that promotes binding of marine plastic debris with radioactive contaminants and heavy metals in seawater Download PDFInfo
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Landscapes
- Treatment Of Sludge (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Water Treatment By Sorption (AREA)
- Treatment Of Biological Wastes In General (AREA)
- Removal Of Specific Substances (AREA)
- Removal Of Floating Material (AREA)
Abstract
Description
本発明は汚染水及び油流失事故に係る海洋、河川、港湾、湖沼の水面の油拡散を防止し、汚染水含む汚染物質及び油並びに海洋ゴミの木くず、海藻、漁網、プラスチック及びマイクロチップを吸着し固め海底に沈めて、二酸化炭素及び塩素に変えながら、自然分解に不可欠な鉄分、リン、窒素分を補い微生物及び陽極と陰極間で電気的導通によるイオン結合効果を高めたものである。また、環境汚染への影響を少なくすとともに、自然環境保護の観点からも利用価値の高いものである。This invention prevents the spread of oil on the surface of oceans, rivers, harbors, and lakes in the event of a contaminated water or oil spill, and adsorbs and solidifies contaminants and oil, including contaminated water, as well as marine debris such as wood chips, seaweed, fishing nets, plastics, and microchips, sinking them to the bottom of the sea and converting them into carbon dioxide and chlorine, while supplementing iron, phosphorus, and nitrogen, which are essential for natural decomposition, and enhancing the ionic bond effect through electrical conduction between microorganisms and the anode and cathode. It also reduces the impact on environmental pollution and is highly useful from the perspective of protecting the natural environment.
油を吸着マットで固形にして、ごみとして捨てるタイプは回収、焼却の手間と二酸化炭素削減に寄与していない問題があった。また、鳥及び魚貝類及び海岸砂浜に付着し環境汚染の問題があり、固形処理にするタイプは、空中散布又は陸上及び海面に使用した場合、原料の拡散と油の流失及び海洋ゴミとの自然環境及び水質、沈殿し問題があった。The type of product that solidifies the oil with an absorbent mat and then throws it away as garbage has problems with the effort required for collection and incineration, and does not contribute to reducing carbon dioxide emissions. In addition, it causes problems with the oil adhering to birds, fish, shellfish, and beach sand, and the type that solidifies the oil has problems with the natural environment and water quality, with the spread of raw materials, the loss of oil, and marine litter, and settling, when sprayed in the air or used on land or sea surfaces.
従来の海洋汚染の原因である汚染水及び廃油処理剤は、空中散布又は、陸上及び海面に投下又は拡散し、環境汚染の問題があった。また汚染水及び油、を吸着固形にして、海洋ゴミとして捨てるタイプの回収、焼却の手間と二酸化炭素削減に寄与していない問題があった。固化処理にするタイプは、大量に使用し水中の自然環境及び土壌改良効果に問題があった。Conventional agents for treating contaminated water and waste oil, which are the cause of marine pollution, are sprayed in the air or dropped or spread on land and sea surfaces, causing environmental pollution. In addition, agents that absorb contaminated water and oil and turn them into solids and then discard them as marine litter require the effort of collection and incineration, and do not contribute to reducing carbon dioxide. Agents that solidify the contaminated water and oil are used in large quantities, causing problems with the natural environment in the water and the effect of improving the soil.
また、溶剤処理費が高額で実施し難くコスト高となる問題を有している。Furthermore, the cost of the solvent treatment is high, making it difficult to carry out, and resulting in high costs.
汚染水及び油処理剤の原料は、種シリカ成分を含む火山灰、石炭灰、焼却灰、ゼオライトの何れかと、有機物の磁性体及び電極体原料磁性体原料、活性炭、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、セメント、カーバイドの混練物に、無機質の蛋白質ムチン及び、澱粉、海藻、クラゲ、納豆を粉砕した乾燥パウダー、水溶液を噴霧して粒状に固めて、汚染水及び油処理目的に散布して、主成分である可溶性けい酸が汚染水及び油分を浸透吸収し、気泡を含む泡で汚染物質を取込んだ固形物にする。また、粒状の固形物を、保管施設内及びトンネル内に充填し、泡で亀裂及び浸水箇所を塞ぎ一体構造物にする。また、粒状の固形物を、袋詰めにした堰堤を構築し、決壊した堤防の亀裂補修及び漏水隙間を泡の一体構築物で固める。また、汚染水及び油並びに、海洋ゴミ処理目的に固形物を汚染水に散布することで、粒状固形物が溶解するとと伴に、汚染水又は油物質の水分と固形物が反応した気泡及び泡で、汚染水内の汚染物質及び油と海洋プラスチックゴミを泡で包み込み、外部流出及び拡散を防止し、該、固形成型物にして海底に沈めて固定させると伴に、プラスチックゴミを、固形物内の電極と電気的な導通による陽極は、Feイオン、Sイオンを溶出し、陰極部は、1/2・O2+H2O+2e-→2OH-海水中では→OH-生成すると伴に、プラスチックゴミの中でもペットボトルは、PET樹脂は、主に炭素、酸素、水素から構成されて、
約1/3が空気を原料とする酸素で占められており、他のプラスチックに比べて石油依存度が低い樹脂といえます。
2)他のプラスチックに比べて炭素より重い酸素が多いことから、密度が水より重く沈み炭素、酸素、水素に分解し、また
プラスチックゴミは、二酸化炭素及び塩素に変えながら、海水中のリン又は、窒素又は、アンモニア又は、セシュウム又は、二酸化炭素等と結合する伴に、陰極電極面側に、炭酸カルシウムを析出させて、海藻、微生物、稚貝、稚サンゴの着生及び成長促進する伴に、二酸化炭素は海底に炭酸カルシウム堆積物として固定する。また、水の電気分解により、水中の溶存酸素濃度が高められる。The raw materials for the contaminated water and oil treatment agent are a mixture of volcanic ash, coal ash, incineration ash, or zeolite containing silica components, organic magnetic and electrode raw materials, activated carbon, charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husk, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, cement, and carbide, which are then sprayed with inorganic protein mucin, starch, seaweed, jellyfish, and natto (dried powder and aqueous solution) to form granules, which are then spread for the purpose of contaminated water and oil treatment. The main component, soluble silicic acid, penetrates and absorbs the contaminated water and oil, and the foam containing air bubbles captures the contaminants and turns them into a solid material. The granular solid material is then filled into storage facilities and tunnels, and the foam is used to seal cracks and water-logged areas to form an integrated structure. Also, a dam made of bags of granular solids is constructed, and cracks in the collapsed levee are repaired and the leaking gaps are solidified with a foam structure. In addition, by scattering solids into contaminated water for the purpose of treating contaminated water, oil, and marine garbage, the granular solids dissolve, and the water in the contaminated water or oil reacts with the solids to produce bubbles and foam that envelop the contaminants, oil, and marine plastic garbage in the contaminated water, preventing them from leaking out and spreading. The solids are then sunk to the bottom of the sea as solids, and the anode, which is electrically connected to the electrode in the solids, dissolves Fe ions and S ions, and the cathode part dissolves 1/2.002+H2O+2e-→2OH- in seawater→OH-. Among the plastic garbage, PET bottles, PET resin, is mainly composed of carbon, oxygen, and hydrogen,
Approximately one-third of the material is oxygen derived from the air, making this resin less dependent on petroleum than other plastics.
2) Compared to other plastics, plastic waste contains a lot of oxygen, which is heavier than carbon, so it is denser than water and sinks, breaking down into carbon, oxygen, and hydrogen. The plastic waste is converted into carbon dioxide and chlorine, and combines with phosphorus, nitrogen, ammonia, cesium, carbon dioxide, etc. in the seawater, depositing calcium carbonate on the cathode electrode surface, promoting the attachment and growth of seaweed, microorganisms, young shellfish, and young coral, while the carbon dioxide is fixed as calcium carbonate deposits on the seabed. Also, the electrolysis of water increases the concentration of dissolved oxygen in the water.
また、環境汚染への影響を完全になくすとともに、汚染水及び油の回収時間と手間を少なくし、自然分解に不可欠な鉄分、リン、窒素分を補い微生物分解電解イオン効果を高めたものである。また、PET(ポリエチレンテレフタラート)の化学式(分子式・組成式・構造式)は以下の通りです。
他例として、浸水油流出時に粒状の固形物を袋詰めにしたものを設置し、該、袋は、紙袋、又は炭素繊維、化学繊維、アルミ箔を組合わせた袋の外側表面及び、該、袋の外側裏面に、上下凸状の連結金具を配置し、連結金具の上に袋を重ねて、連結構築した袋の上から、凹連結金具又は、杭を挿入し防護壁、土豪壁として一体構築する。As another example, in the event of an oil spill, bags of granular solid material are set up, and the bags are made of paper bags or a combination of carbon fiber, chemical fiber, and aluminum foil. Connecting metal fittings with convex top and bottom are placed on the outer surface and outer back surface of the bags. The bags are then placed on top of the connecting metal fittings, and concave connecting metal fittings or stakes are inserted on top of the connected bags to construct a protective wall or earth wall.
他例として、汚染物質保管施設内及び保管トンネル内の隙間に、粒状の固形物を充填することで、泡を発生させて固め隙間を密閉する緩衝材、漏水及び腐食防止材、亀裂修復材、出入口の隔壁材になる。紙袋、又は炭素繊維、化学繊維、アルミ箔を組合わせた袋浸透性布袋に填めた粒状の固形物と、生コンクリート敷設及びポンプ圧打設時に、浸透性布袋に粒状の孤閨を填めた袋を投入及び、敷設又は積み重ねた袋のうえから、金属製の金具を差込み土壌に固定し固める。また袋を複数連結及び構築させることで、隙間を泡で塞ぎ一体構築物にし、電極材及び磁極材の電気的導通よる汚染水のセシュウ成分とのイオン結合を計る一体構築物。As another example, filling gaps in contaminated material storage facilities and storage tunnels with granular solids can be used as a buffer material that generates foam to harden and seal gaps, as a leak and corrosion prevention material, as a crack repair material, and as a bulkhead for entrances and exits. Granular solids are packed into paper bags or permeable cloth bags made of a combination of carbon fiber, chemical fiber, and aluminum foil, and when ready-mixed concrete is laid and pumped, bags filled with granular fertilizer are inserted into the permeable cloth bags, and metal fittings are inserted from above the laid or stacked bags to fix them to the soil and harden them. Also, by connecting and constructing multiple bags, gaps are filled with foam to form an integrated structure, and ionic bonds with the sesquioxane components of contaminated water are achieved through electrical conduction between the electrode material and magnetic pole material.
他例として、核最終処分場の保管施設内及び保管容器との隙間に粉状の固形物を、浸透性紙袋,炭素繊維袋、化繊シート袋、容器内に充填し使用目的場所に応じて配合調整し設置すれば、重金属の水質浄化機能と重金属吸着機能と、一体構造物を備えた二重構造物になる。As another example, if powdered solids are filled into permeable paper bags, carbon fiber bags, synthetic fiber sheet bags, or containers in the gaps between the storage facilities and storage containers at a nuclear final disposal site, and the mixture is adjusted according to the intended use, a dual structure will be created that has the functions of water purification of heavy metals and heavy metal adsorption, as well as an integrated structure.
各材料を混練りされた粒状の固形物を袋又は溶解性容器に充填したものを、汚染水及び油流出時の海洋及び水中の海洋ゴミに、投入及び散布するのみで容易に固形物が溶解し、泡を発生させて油及び汚染水並びに汚染物質と反応し、一体成形物にすると伴に固定する。また、原子力発電の爆発事故とか核施設内の出入口の隔壁及び破損補修及び保管施設内の保管容器と施設内の隙間の緩衝材機能を保持させつつ、適切に汚染水及び油処理材になり、施設及びトンネル内外の亀裂、漏水修復防災機能を発揮させて施行が容易である。By simply pouring or scattering the granular solids, which are made by mixing the various materials, into bags or dissolving containers, on the ocean or underwater marine debris during contaminated water or oil spills, the solids will dissolve easily, generating foam that reacts with the oil, contaminated water, and contaminants, forming an integral molded product and fixing it in place. It also functions as a buffer material for the bulkheads and damaged repairs of entrances and exits in nuclear facilities and storage containers and gaps within storage facilities in the event of a nuclear power plant explosion, and can be used as a contaminated water and oil treatment material, and can be used to repair cracks and leaks inside and outside facilities and tunnels, providing disaster prevention functions, making it easy to implement.
混合物を、浸透性袋に填め蓋をし、該袋に填めた袋の外側表面と該袋の外側裏面の上下に連結金具を配置した電極板と磁極板を、該袋に押し込み固めて固定する製造利用方法として、
例1.電極板を▲1▼鉄材と流電陽極(マグネシウム合金陰極)を接続し海水中に浸すと、鉄材表面に電流が通電し、鉄材表面ではアルカリ成分OH-が生成する。海水中のカルシウムイオンCa2+、炭酸水素イオンHCO3-およびマグネシウムイオンMg2+は以下の式に示す沈殿物を形成して電極鋼材表面に付着する。この付着物を電極着物と認識されている。
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH-→Mg(OH)2↓
▲3▼電極着物は貝類及び造礁サンゴの骨格の主成分である炭酸カルシウムに近いので、稚サンゴが着生しやすい特長がある。
▲4▼この原理を活用して、金属基盤に電気的な導通を確保及び磁気的な導通を確保した磁気電流を流した表面に、炭酸カルシウムを析出させた基盤が電極着基盤で、海藻、微生物、稚貝、稚サンゴの着生成長促進を目的とする。The mixture is placed in a permeable bag and closed with a lid, and the electrode plate and magnetic pole plate, which have connecting metal fittings arranged on the upper and lower outer surfaces of the outer surface and the outer back surface of the bag, are pressed into the bag and fixed therein.
Example 1. When an electrode plate (1) is connected to an iron material and a galvanic anode (magnesium alloy cathode) and immersed in seawater, a current flows through the surface of the iron material, and the alkaline component OH- is generated on the surface of the iron material. Calcium ions Ca2+, bicarbonate ions HCO3-, and magnesium ions Mg2+ in the seawater form a precipitate as shown in the following formula and adhere to the surface of the electrode steel material. This deposit is recognized as electrode deposit.
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH- → Mg(OH)2↓
(3) The electrode coating is similar to calcium carbonate, which is the main component of the skeletons of shellfish and reef-building corals, and has the characteristic that it is easy for young corals to attach to it.
(4) By utilizing this principle, a base on which calcium carbonate is precipitated on the surface of a metal base through which a magnetic current is passed to ensure electrical and magnetic conductivity is ensured is an electrode base, with the aim of promoting the attachment and growth of seaweed, microorganisms, young shellfish, and young corals.
電極板と磁極板は、上述したように導電性と磁極性を有する。固形物内中央部に、無機質体で仕切られる有機質体と、海水との間で電磁気的な導通を確保するとともに、絶縁体格納容器内に配置される電極(上記例では陽極)から発生する気体は、
例1.電極板を▲1▼鉄材と流電陽極(マグネシウム合金陰極)を接続し海水中に浸すと、鉄材表面に電流が通電し、鉄材表面ではアルカリ成分OH-が生成する。海水中のカルシウムイオンCa2+、炭酸水素イオンHCO3-およびマグネシウムイオンMg2+は以下の式に示す沈殿物を形成して電極鋼材表面に付着する。この付着物を電極着物と認識されている。
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH-→Mg(OH)2↓
▲3▼電極着物は貝類及び造礁サンゴの骨格の主成分である炭酸カルシウムに近いので、稚サンゴが着生しやすい特長がある。
▲4▼この原理を活用して、金属基盤に電気的な導通を確保及び磁気的な導通を確保した磁気電流を流した表面に、炭酸カルシウムを析出させた基盤が電極着基盤で、海藻、微生物、稚貝、稚サンゴの着生成長促進を目的とする。
混合物を、浸透性袋に填め蓋をし、該袋に填めた袋の外側表面と該袋の外側裏面の上下に連結金具を配置した中央部に反射装置を設けた装置の電極板と磁極板を、該袋に押し込み固めて固定する製造利用方法として、例1.電極板を▲1▼鉄材と流電陽極(マグネシウム合金陰極)を接続し海水中に浸すと、鉄材表面に電流が通電し、鉄材表面ではアルカリ成分OH-が生成する。海水中のカルシウムイオンCa2+、炭酸水素イオンHCO3-およびマグネシウムイオンMg2+は以下の式に示す沈殿物を形成して電極鋼材表面に付着する。この付着物を電極着物と認識されている。
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH-→Mg(OH)2↓
▲3▼電極着物は貝類及び造礁サンゴの骨格の主成分である炭酸カルシウムに近いので、稚サンゴが着生しやすい特長がある。
▲4▼この原理を活用して、金属基盤に電気的な導通を確保及び磁気的な導通を確保した磁気電流を流した表面に、炭酸カルシウムを析出させた基盤が電極着基盤で、海藻、微生物、稚貝、稚サンゴの着生成長促進を目的とする。磁性体イオン水を吸収させたものに、電極部での反応は[数1],[数2]式で示される。
Example 1. When an electrode plate (1) is connected to an iron material and a galvanic anode (magnesium alloy cathode) and immersed in seawater, a current flows through the surface of the iron material, and the alkaline component OH- is generated on the surface of the iron material. Calcium ions Ca2+, bicarbonate ions HCO3-, and magnesium ions Mg2+ in the seawater form a precipitate as shown in the following formula and adhere to the surface of the electrode steel material. This deposit is recognized as electrode deposit.
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH- → Mg(OH)2↓
(3) The electrode coating is similar to calcium carbonate, which is the main component of the skeletons of shellfish and reef-building corals, and has the characteristic that it is easy for young corals to attach to it.
(4) By utilizing this principle, a base on which calcium carbonate is precipitated on the surface of a metal base through which a magnetic current is passed to ensure electrical and magnetic conductivity is ensured is an electrode base, with the aim of promoting the attachment and growth of seaweed, microorganisms, young shellfish, and young corals.
The mixture is placed in a permeable bag and closed with a lid, and the electrode plate and magnetic pole plate of the device, which has a reflector in the center and connecting metal fittings on the top and bottom of the outer surface and the outer back surface of the bag, are pressed into the bag and fixed as a manufacturing and utilization method, Example 1. When the electrode plate is connected to an iron material and a galvanic anode (magnesium alloy cathode) and immersed in seawater, a current flows through the iron material surface, and an alkaline component OH- is generated on the iron material surface. Calcium ions Ca2+, bicarbonate ions HCO3-, and magnesium ions Mg2+ in seawater form a precipitate shown in the following formula and adhere to the surface of the electrode steel material. This deposit is recognized as an electrode deposit.
Ca2++HCO3-+OH-→CaCO3↓+H2O
Mg2++2OH- → Mg(OH)2↓
(3) The electrode coating is similar to calcium carbonate, which is the main component of the skeletons of shellfish and reef-building corals, and has the characteristic that it is easy for young corals to attach to it.
4. By utilizing this principle, a metal base is electrically and magnetically conductive, and a magnetic current is passed through the surface of the metal base, on which calcium carbonate is deposited, forming an electrode base, with the aim of promoting the attachment and growth of seaweed, microorganisms, young shellfish, and young corals. The reaction at the electrode part when magnetic ion water is absorbed is shown by the formulas [Equation 1] and [Equation 2].
次に、気泡コンクリート本体の中空部に鉄板(海水中の電位-06~-0.7V VS SCE)と鉄に比べ電位の高い金属、例えばアルミ板(海水中の電位+02~0.3V VS SCE),活性炭等との混合物を充填して海水に浸漬すると、電位の高いアルミ板から電位の低い鉄に電流が流れて電極を形成し、鉄板は陽極となり、[数1]式と同じくFeイオンとなって溶出し、アルミ、亜鉛、マグネシュウム板は陰極となり、[数2]式のようにOH-を生成する。鉄と鉄に比べて電位の高い金属の混合物とを充填した場合では、鉄のみを充填した場合に比較して、溶出するFeイオン量が加速的に増加するため、珪藻,プランクトンの繁殖,海藻類の増殖はさらに向上し、間接的に蝟集効果は鉄のみを充填した場合に比較しさらに高まる。なお陽極となる鉄板からのFeイオンの溶出は、陰極の面積が大きいほど大きくなるので、アルミ、亜鉛、マグネシュウム板の面積(すなわち重量)成分を変えることによって、Feイオンの溶出量を調節できる。本体の任意の個所に設けられた中空部に鉄を充填して海水に浸漬することにより、鉄表面に電位を異にする部分が混有して局部電極を形成し、鉄イオン水素イオンが溶出して、Fe、Sイオン分子がリン、窒素、アンモニア、セシュウム等と結合し、海藻類に吸収され海藻の繁殖を促す効果が発生する。
(4)気泡を取込んだ固形物内の中空部に鉄成分(海水中の電位-0.6~-0.7V)と鉄に比べ電位の高い金属、例えばアルミ、亜鉛、マグネシュウム成分(海水中の電位+0.2~0.3V),活性炭等との混合物を充填して海水に浸漬することにより、電位の高いアルミ、亜鉛、マグネシュウム板から電位の低い鉄イオン成分に電流が流れて電極を形成し、鉄成分は陽極となり、上記(3)と同じくFeイオンとなって溶出し、アルミ、亜鉛、マグネシュウム成分は陰極となり、OH-を生成する。鉄粉と鉄板に比べて電位の高い磁性体金属の混合物を充填した場合では、鉄粉のみを充填した場合に比較して、溶出するFeイオン量が加速的に増加するため、珪藻,プランクトンの繁殖,海、藻類の増殖はさらに向上し、間接的に蝟集効果は鉄のみを充填した場合より、さらに高まる。これらの性質を利用して、原子力発電の爆発事故とか核汚染水処理及び拡散防止目的で、混合物及び混練物の固形物を、袋詰めした袋を投入及び置敷きする製造利用方法を得た。Next, when the hollow part of the aerated concrete body is filled with a mixture of an iron plate (electric potential in seawater -0.6 to -0.7 V vs. SCE) and a metal with a higher electric potential than iron, such as an aluminum plate (electric potential in seawater +0.2 to 0.3 V vs. SCE), activated carbon, etc., and immersed in seawater, a current flows from the aluminum plate with a higher electric potential to the iron with a lower electric potential, forming electrodes, and the iron plate becomes an anode, and dissolves as Fe ions as in formula [1], while the aluminum, zinc, and magnesium plates become cathodes and generate OH- as in formula [2]. When iron and a mixture of metals with a higher electric potential than iron are filled, the amount of dissolved Fe ions increases at an accelerated rate compared to when only iron is filled, so the proliferation of diatoms, plankton, and seaweed is further improved, and the insect gathering effect is indirectly further increased compared to when only iron is filled. Since the amount of Fe ions eluted from the iron plate, which acts as the anode, increases with the area of the cathode, the amount of Fe ions eluted can be adjusted by changing the area (i.e. weight) of the aluminum, zinc, or magnesium plate. By filling the hollow space in any part of the main body with iron and immersing it in seawater, parts with different potentials are mixed on the iron surface to form local electrodes, and iron and hydrogen ions are eluted, and the Fe and S ion molecules combine with phosphorus, nitrogen, ammonia, cesium, etc., which are absorbed by seaweed and promote the proliferation of seaweed.
(4) By filling the hollow space in the solid material that has trapped the bubbles with a mixture of iron components (electric potential in seawater -0.6 to -0.7 V) and metals with a higher electric potential than iron, such as aluminum, zinc, magnesium components (electric potential in seawater +0.2 to 0.3 V), activated carbon, etc., and immersing it in seawater, a current flows from the aluminum, zinc, and magnesium plates with a higher electric potential to the iron ion components with a lower electric potential, forming electrodes, the iron components become the anode, and as in (3) above, they become Fe ions and are dissolved, while the aluminum, zinc, and magnesium components become the cathode, generating OH-. When a mixture of iron powder and a magnetic metal with a higher electric potential than an iron plate is filled, the amount of dissolved Fe ions increases at an accelerated rate compared to when only iron powder is filled, so the proliferation of diatoms and plankton and the proliferation of seaweed are further improved, and the insect gathering effect is indirectly even greater than when only iron is filled. By utilizing these properties, a manufacturing and utilization method has been obtained in which solid mixtures and kneaded materials are packed in bags and then poured and laid down for the purpose of treating nuclear contaminated water and preventing diffusion in the event of an explosion at a nuclear power plant.
汚染水及び油並びに海洋ゴミ処理剤の原料は、種シリカ成分を含む火山灰又は、石炭灰又は、フライアッシュ、又はゼオライト、35gに磁性体原料、活性炭、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、粉石鹸の混合物50gを混練物工程の中で、無機質のムチン、澱粉、海藻、クラゲ、納豆の乾燥パウダーの水溶液15gの混練物に100mLを5mL/分で噴霧しながら、約20分間、回転速度が200rpmの回転パンを用いて造粒、1ミリから10ミリの粒状固形物にすると伴に、粒状固形物の表面をコーティングした固形物を、汚染水及び油処理目的に直散布する方法と、浸透性袋又は、溶解性容器内に充填蓋をし、空中散布又は投下する方法がある。
また、固形物は水と反応し気泡を含む泡を発生させるとともに、泡内に汚染水及び汚染物質並びに、油を取込み固めた固形物内で、陽極及び陰極間の電気的導通と電解イオン効果を高めて、汚染水内の汚染物質とイオン結合する。The raw material for the agent for treating polluted water and oil, as well as marine debris, is 35g of volcanic ash, coal ash, fly ash, or zeolite containing a seed silica component, and 50g of a mixture of magnetic raw materials, activated carbon, charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husk, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, and soap powder. In the kneading process, 100mL of a kneaded mixture of 15g of an aqueous solution of dried powder of inorganic substances such as mucin, starch, seaweed, jellyfish, and natto is sprayed at 5mL/min for about 20 minutes using a rotating pan rotating at 200 rpm, and granulated into granular solids of 1 to 10 mm in size. The solids, which have their surfaces coated, can be directly sprayed for the purpose of treating polluted water and oil, or filled into a permeable bag or a dissolving container with a lid and sprayed or dropped in the air.
In addition, the solid reacts with water to generate bubbles containing air bubbles, and the bubbles trap contaminated water, contaminants, and oil, and the solid solids solidify, increasing the electrical conductivity between the anode and cathode and the electrolytic ion effect, forming ionic bonds with the contaminants in the contaminated water.
汚染水及び油並びに海洋ゴミ処理剤の必衰原料は、有機物の種シリカ成分を含む火山灰又は、石炭灰又は、フライアッシュ、又は、電極体原料、磁性体原料、活性炭とし、使用目的使用場所に応じて、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、ゼオライト、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、粉石鹸の何れか10~12種類の混合物を配合調整する混練物の工程で、無機質のムチン及び、澱粉、海藻とクラゲ、納豆を粉砕した乾燥パウダー、植物油の混合水溶液を噴霧し10ミリから20ミリの粒状に固める製造利用方法とか、The raw materials for the agent for treating polluted water and oil, as well as marine debris, are volcanic ash, coal ash, or fly ash containing organic silica components, or raw materials for electrodes, raw materials for magnetic materials, or activated carbon, and depending on the purpose and place of use, 10 to 12 types of mixtures of charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husk, zeolite, sand, wood chips, salt, or caustic soda, phosphorus, sulfur, calcium silicate, and powdered soap are mixed and adjusted to produce a kneaded product, and a mixed aqueous solution of inorganic mucin, starch, dried powder of crushed seaweed, jellyfish, and natto, and vegetable oil is sprayed onto the mixture and solidified into granules of 10 to 20 mm in size.
使用目的場所に応じ、有機質の原料は種シリカ成分を含む火山灰又は、石炭灰又は、フライアッシュ、又はゼオライト、35gに磁性体原料、活性炭、炭、石膏、石灰、スラッグ、粘土、鉄粉、アルミ粉、籾殻、砂、木屑、塩又は苛性ソーダ、リン、硫黄、ケイ酸化カルシウム、粉石鹸の混合物50gを混練物を、回転パン内で振動と回転工程の中で、混練物に無機質のムチン、澱粉、海藻、クラゲ、納豆の乾燥パウダーの水溶液15g配合の水溶液を噴霧し、粒状の固形物に、遠心力磁場圧を約1000万ガウスかけて、遠心分離圧力で固形物を磁性電極体にする製造利用方法。Depending on the intended use location, 35g of organic raw material such as volcanic ash, coal ash, fly ash, or zeolite containing silica components is mixed with 50g of a mixture of magnetic raw material, activated carbon, charcoal, gypsum, lime, slag, clay, iron powder, aluminum powder, rice husk, sand, wood chips, salt or caustic soda, phosphorus, sulfur, calcium silicate, and soap powder, and the mixture is vibrated and rotated in a rotating pan. A solution containing 15g of an aqueous solution of inorganic mucin, starch, seaweed, jellyfish, and natto dried powder is sprayed onto the mixture, and a centrifugal force magnetic field pressure of approximately 10 million gauss is applied to the granular solid material, and the centrifugal pressure turns the solid material into a magnetic electrode body.
粒状の固形物を、浸透性溶解性袋又は容器に填めて蓋をし、原子力発電の爆発事故とか核容器炉施設及び接続するトンネル施設内に、固形物又は、固形物を袋又は容器に填めた袋や容器を積み重ねて配置し、袋又は容器袋又は容器重量で内部に凸分を押し込み固定する一体構築物に成る利用方法。A method of use in which granular solids are placed in a permeable and soluble bag or container and then covered, and the solids or bags or containers containing solids are stacked and arranged in a nuclear power plant explosion accident, nuclear reactor facility, or connected tunnel facility, and the weight of the bag or container is used to push in the protruding parts inside and fix them in place, forming an integrated structure.
粒状の固形物を詰めた該袋又は容器を、汚染水及び油流失現場及び軟弱土壌又は、海洋ゴミの水中に固形物を散布又は、固形物を填めた袋を投入し海底に固定敷設する固形物の利用方法。The method of using solid materials involves scattering the bags or containers filled with granular solid materials in the water at the site of contaminated water or oil spills, or in soft soil or marine debris, or dropping the bags filled with solid materials into the seabed and fixing them thereon.
原子力発電の爆発事故とか核汚染水及び油処理、油流出及び原子炉火災時の放射能ガスの排出を防止する目的に、固形物を散布及び固形物を袋に填めた袋及び浸透性容器に詰めしたものを、上空及び陸上から、投下及び散布又は原子炉内及び建屋内にポンプ圧送し、充填する利用方法。This method involves scattering solids or packing solids into bags or permeable containers from the air or land, or pumping them into reactors and buildings to fill them, for the purpose of preventing the emission of radioactive gases in the event of a nuclear power plant explosion, the treatment of nuclear contaminated water or oil, or oil spills or reactor fires.
固形物を袋に充填した袋内に、汚染水を固形物内部に浸透させて、気泡及び泡内に汚染物質を閉じ込めて、泡の一体構築物にする製造利用方法。A manufacturing and utilization method in which a bag is filled with solid material, and contaminated water is allowed to penetrate into the solid material, trapping the contaminants within the air bubbles and foam to create an integral foam structure.
原子力発電の爆発事故とか核施設及びトンネル内の出入り口並びに、トンネル内の漏水及び亀裂の修復及び隙間の泡の緩衝材として固めて固定し、一体構造物を構築する利用方法。Uses include: at the entrances and exits of nuclear power plants, nuclear facilities, and tunnels; repairing water leaks and cracks in tunnels; and as a foam cushioning material to harden and fix gaps and to build integrated structures.
また使用目的に応じて、固形物材料と汚泥、酒類(焼酎、麦酒、日本酒、ウィスキー)廃液適水量を混練りした固形物を、散布又は、護岸シールド保水層にする製造利用方法。Depending on the purpose of use, the solid material can be mixed with sludge and an appropriate amount of alcoholic beverage (shochu, beer, sake, whiskey) wastewater and then used as a solid material to be spread or as a water-retaining layer for a bank protection shield.
本発明は、緊急時の汚染水又は油流失時の散布材及び汚染水及び油処理剤であり、固形物の種シリカを含む灰と主成分である可溶性けい酸、無機質の原料の澱粉、海藻とクラゲ、納豆を粉砕した乾燥パウダー、植物油の混合水溶液を混練物に噴霧し固形物にすると伴に、汚染水及び油分を浸透吸収し固める。また表面を泡で固めることで、散布時の固形物の拡散を防ぎ同時に、汚染水及び油の表面から内部層まで、侵入した固形物は、水分と反応し泡を発生させて、海面上の油及び海洋ゴミを泡内に閉じ込めるとともに、外部流出及び油拡散を防止し、汚染水及び油と海洋ゴミのプラスチック及びマイクロチップゴミを吸着すると伴に、海底に沈めて固定し、微生物分解の手伝いをする。
また、固形物と汚染水及び油の水分と反応した泡を固めた成型物の回収及び取扱い処理が簡単になる。尚、各材料を混練りさせた混合物又は、固形物を袋詰めされたものを、汚染水及び油水面の湿潤場所に投入敷設するのみで一体成形し、護岸ブロック、自然再生ブロック、土豪構築物機能オイルフェンス機能を保持させつつ、原子力発電の爆発事故とか核保管施設及びトンネル内の亀裂及び濾水の修復及び隙間を充填する緩衝材にすると伴に、出入口の密閉、隔壁及び施設と一体構造物になる。The present invention is a material to be spread in the event of an emergency spill of contaminated water or oil, and a treatment agent for contaminated water and oil, which is sprayed with a mixture of ash containing silica as a solid material, soluble silicic acid as the main component, starch as an inorganic raw material, dried powder of crushed seaweed, jellyfish, and natto, and a mixed aqueous solution of vegetable oil onto a kneaded material to form a solid material, and penetrates, absorbs, and solidifies the contaminated water and oil. The surface is solidified with foam to prevent the solid material from spreading when sprayed, and at the same time, the solid material that penetrates from the surface to the inner layer of the contaminated water and oil reacts with water to generate foam, which traps the oil and marine debris on the sea surface within the foam, preventing the oil from leaking out and spreading, and adsorbs the contaminated water, oil, and marine debris, including plastic and microchip debris, and sinks and fixes it to the seabed to help with microbial decomposition.
In addition, the recovery and handling of the molded product made of solidified foam that reacts with the moisture in the contaminated water and oil becomes easy.The mixture of each material or the bagged solid material can be poured into the wet area of the contaminated water or oil surface to form an integrated structure, which can be used as a buffer material to repair and fill gaps in the event of a nuclear power plant explosion, nuclear storage facilities, and tunnels, while retaining its functions as a revetment block, natural regeneration block, earthwork structure, and oil fence, and can also be used to seal entrances and exits, and to form an integrated structure with bulkheads and facilities.
1.沈船 2.油水面 3.空中散布する海底改良剤固形物
4.ヘリコプター 5.油 6.固形物 7.海底
8.回転パン 9.回転パン本体 10.混練物
11.混練物充填装置 12.原子炉建屋 13.送管 14.充填経路
15.炉心1. Sunken ship 2. Oily water surface 3. Solid seabed improver sprayed from the air 4. Helicopter 5. Oil 6. Solid 7. Seabed 8. Rotating pan 9. Rotating pan body 10. Mixture 11. Mixture filling device 12. Reactor building 13. Pipe 14. Filling route 15. Reactor core
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JP2010172882A (en) * | 2009-02-02 | 2010-08-12 | Chisui:Kk | Coagulant, and method of treating muddy effluent |
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JP2017206933A (en) * | 2016-05-20 | 2017-11-24 | 篠原 健二 | Sea bottom improver 3 promoting bonding between radioactive contaminant with heavy metal substance in sea water |
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JP2010172882A (en) * | 2009-02-02 | 2010-08-12 | Chisui:Kk | Coagulant, and method of treating muddy effluent |
JP2012154157A (en) * | 2011-01-21 | 2012-08-16 | Kenji Shinohara | Utilization method of sea bottom improver replacing oil treatment |
JP2016002530A (en) * | 2014-06-18 | 2016-01-12 | サン・アンド・シイ・コンサルタント株式会社 | Method for immobilizing contaminant |
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JP2021037503A (en) * | 2019-09-02 | 2021-03-11 | Ac‐Labo株式会社 | Rapid treatment solidification agent having hybrid double effect sludge and sludge rapid solidification method using the same |
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