JP7293466B1 - 燃料電池システムおよび燃料電池システムの運転方法 - Google Patents
燃料電池システムおよび燃料電池システムの運転方法 Download PDFInfo
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- JP7293466B1 JP7293466B1 JP2022108294A JP2022108294A JP7293466B1 JP 7293466 B1 JP7293466 B1 JP 7293466B1 JP 2022108294 A JP2022108294 A JP 2022108294A JP 2022108294 A JP2022108294 A JP 2022108294A JP 7293466 B1 JP7293466 B1 JP 7293466B1
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- Prior art keywords
- fuel
- oxidizing gas
- gas
- control valve
- line
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- 239000000446 fuel Substances 0.000 title claims abstract description 272
- 238000000034 method Methods 0.000 title claims description 22
- 239000007789 gas Substances 0.000 claims abstract description 384
- 230000001590 oxidative effect Effects 0.000 claims abstract description 351
- 239000002737 fuel gas Substances 0.000 claims abstract description 294
- 238000010248 power generation Methods 0.000 claims abstract description 101
- 238000010438 heat treatment Methods 0.000 claims abstract description 98
- 230000007423 decrease Effects 0.000 claims description 27
- 230000004044 response Effects 0.000 claims description 24
- 239000000567 combustion gas Substances 0.000 claims description 21
- 230000008859 change Effects 0.000 claims description 13
- 230000003247 decreasing effect Effects 0.000 claims description 12
- 238000007599 discharging Methods 0.000 claims description 10
- 238000011144 upstream manufacturing Methods 0.000 claims description 7
- 230000003197 catalytic effect Effects 0.000 description 41
- 239000012212 insulator Substances 0.000 description 24
- 239000000758 substrate Substances 0.000 description 21
- 239000012298 atmosphere Substances 0.000 description 17
- 230000001276 controlling effect Effects 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000012528 membrane Substances 0.000 description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000007784 solid electrolyte Substances 0.000 description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 9
- 230000001105 regulatory effect Effects 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000007084 catalytic combustion reaction Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- -1 oxygen ions Chemical class 0.000 description 5
- 230000002093 peripheral effect Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000002309 gasification Methods 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
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- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
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- 238000010926 purge Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910002367 SrTiO Inorganic materials 0.000 description 2
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- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
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- 239000002001 electrolyte material Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000015654 memory Effects 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229910018279 LaSrMnO Inorganic materials 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04111—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants using a compressor turbine assembly
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
- H01M8/04302—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0432—Temperature; Ambient temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0438—Pressure; Ambient pressure; Flow
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2022108294A JP7293466B1 (ja) | 2022-07-05 | 2022-07-05 | 燃料電池システムおよび燃料電池システムの運転方法 |
JP2023011983A JP7408855B1 (ja) | 2022-07-05 | 2023-01-30 | 燃料電池システムおよび燃料電池システムの運転方法 |
PCT/JP2023/006931 WO2024009552A1 (fr) | 2022-07-05 | 2023-02-27 | Système de pile à combustible et procédé d'exploitation d'un système de pile à combustible |
TW112110198A TW202404164A (zh) | 2022-07-05 | 2023-03-20 | 燃料電池系統及燃料電池系統之運轉方法 |
Applications Claiming Priority (1)
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---|---|---|---|
JP2022108294A JP7293466B1 (ja) | 2022-07-05 | 2022-07-05 | 燃料電池システムおよび燃料電池システムの運転方法 |
Related Child Applications (1)
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JP2023011983A Division JP7408855B1 (ja) | 2022-07-05 | 2023-01-30 | 燃料電池システムおよび燃料電池システムの運転方法 |
Publications (2)
Publication Number | Publication Date |
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JP7293466B1 true JP7293466B1 (ja) | 2023-06-19 |
JP2024007090A JP2024007090A (ja) | 2024-01-18 |
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JP2022108294A Active JP7293466B1 (ja) | 2022-07-05 | 2022-07-05 | 燃料電池システムおよび燃料電池システムの運転方法 |
JP2023011983A Active JP7408855B1 (ja) | 2022-07-05 | 2023-01-30 | 燃料電池システムおよび燃料電池システムの運転方法 |
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JP2023011983A Active JP7408855B1 (ja) | 2022-07-05 | 2023-01-30 | 燃料電池システムおよび燃料電池システムの運転方法 |
Country Status (3)
Country | Link |
---|---|
JP (2) | JP7293466B1 (fr) |
TW (1) | TW202404164A (fr) |
WO (1) | WO2024009552A1 (fr) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6591112B1 (ja) | 2019-05-31 | 2019-10-16 | 三菱日立パワーシステムズ株式会社 | 加圧空気供給システム及びこの加圧空気供給システムを備える燃料電池システム並びにこの加圧空気供給システムの起動方法 |
JP2021136175A (ja) | 2020-02-27 | 2021-09-13 | 三菱パワー株式会社 | 燃料電池システム及びその起動方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017104210A1 (fr) | 2015-12-15 | 2017-06-22 | 日産自動車株式会社 | Système de pile à combustible et son procédé de commande |
JP7383515B2 (ja) | 2020-02-14 | 2023-11-20 | 三菱重工業株式会社 | 発電システム並びにその制御装置、制御方法、及び制御プログラム |
-
2022
- 2022-07-05 JP JP2022108294A patent/JP7293466B1/ja active Active
-
2023
- 2023-01-30 JP JP2023011983A patent/JP7408855B1/ja active Active
- 2023-02-27 WO PCT/JP2023/006931 patent/WO2024009552A1/fr unknown
- 2023-03-20 TW TW112110198A patent/TW202404164A/zh unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6591112B1 (ja) | 2019-05-31 | 2019-10-16 | 三菱日立パワーシステムズ株式会社 | 加圧空気供給システム及びこの加圧空気供給システムを備える燃料電池システム並びにこの加圧空気供給システムの起動方法 |
JP2021136175A (ja) | 2020-02-27 | 2021-09-13 | 三菱パワー株式会社 | 燃料電池システム及びその起動方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2024009552A1 (fr) | 2024-01-11 |
TW202404164A (zh) | 2024-01-16 |
JP2024007311A (ja) | 2024-01-18 |
JP2024007090A (ja) | 2024-01-18 |
JP7408855B1 (ja) | 2024-01-05 |
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