JP7233364B2 - ディーゼル車用ｈ２－ｓｃｒを使用する低温ｎｏｘ還元 - Google Patents

ディーゼル車用ｈ２－ｓｃｒを使用する低温ｎｏｘ還元 Download PDF

Info

Publication number
JP7233364B2
JP7233364B2 JP2019520827A JP2019520827A JP7233364B2 JP 7233364 B2 JP7233364 B2 JP 7233364B2 JP 2019520827 A JP2019520827 A JP 2019520827A JP 2019520827 A JP2019520827 A JP 2019520827A JP 7233364 B2 JP7233364 B2 JP 7233364B2
Authority
JP
Japan
Prior art keywords
catalyst
composition
article
doc
scr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2019520827A
Other languages
English (en)
Japanese (ja)
Other versions
JP2020501060A5 (enExample
JP2020501060A (ja
Inventor
リー，ユエチン
Original Assignee
ビーエーエスエフ コーポレーション
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ビーエーエスエフ コーポレーション filed Critical ビーエーエスエフ コーポレーション
Publication of JP2020501060A publication Critical patent/JP2020501060A/ja
Publication of JP2020501060A5 publication Critical patent/JP2020501060A5/ja
Application granted granted Critical
Publication of JP7233364B2 publication Critical patent/JP7233364B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/90—Injecting reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9422—Processes characterised by a specific catalyst for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9427—Processes characterised by a specific catalyst for removing nitrous oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105—General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • F01N3/106—Auxiliary oxidation catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/202—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions
    • B01D2255/9205—Porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions
    • B01D2255/9207—Specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9436—Ammonia
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/30—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel reformer
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2250/00—Combinations of different methods of purification
    • F01N2250/02—Combinations of different methods of purification filtering and catalytic conversion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
    • F01N2510/068—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings
    • F01N2510/0684—Surface coverings for exhaust purification, e.g. catalytic reaction characterised by the distribution of the catalytic coatings having more than one coating layer, e.g. multi-layered coatings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/04—Adding substances to exhaust gases the substance being hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)
JP2019520827A 2016-10-18 2017-10-17 ディーゼル車用ｈ２－ｓｃｒを使用する低温ｎｏｘ還元 Active JP7233364B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662409413P 2016-10-18 2016-10-18
US62/409,413 2016-10-18
PCT/IB2017/056452 WO2018073750A1 (en) 2016-10-18 2017-10-17 Low temperature nox reduction using h2-scr for diesel vehicles

Publications (3)

Publication Number Publication Date
JP2020501060A JP2020501060A (ja) 2020-01-16
JP2020501060A5 JP2020501060A5 (enExample) 2020-11-26
JP7233364B2 true JP7233364B2 (ja) 2023-03-06

Family

ID=62018298

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2019520827A Active JP7233364B2 (ja) 2016-10-18 2017-10-17 ディーゼル車用ｈ２－ｓｃｒを使用する低温ｎｏｘ還元

Country Status (7)

Country Link
US (2) US11732625B2 (enExample)
EP (2) EP4252891A3 (enExample)
JP (1) JP7233364B2 (enExample)
KR (1) KR102567604B1 (enExample)
CN (1) CN110072609A (enExample)
PL (1) PL3528929T3 (enExample)
WO (1) WO2018073750A1 (enExample)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3041422A1 (en) * 2016-10-24 2018-05-03 Basf Corporation Integrated scr catalyst and lnt for nox abatement
BR112019020825A2 (pt) * 2017-04-04 2020-04-28 Basf Corporation sistema de controle de emissão para tratamento de uma corrente de gás de exaustão e método para tratar uma corrente de gás de exaustão
PL3607177T3 (pl) * 2017-04-04 2024-07-08 Basf Corporation Zintegrowany system kontroli emisji
JP2020515765A (ja) * 2017-04-04 2020-05-28 ビーエーエスエフ コーポレーション 触媒的汚染除去のための水素還元剤
CN110505694A (zh) * 2018-05-17 2019-11-26 索尼公司 用于无线通信的电子设备和方法、计算机可读存储介质
JP7676151B2 (ja) * 2018-05-29 2025-05-14 ビーエーエスエフ モバイル エミッションズ カタリスツ エルエルシー 超低ＮＯｘ制御のためのディーゼル酸化触媒
KR20210034783A (ko) * 2019-09-23 2021-03-31 희성촉매 주식회사 저온 NOx 흡장 조성물 및 이를 함유한 디젤산화촉매
CN116194192A (zh) * 2020-09-30 2023-05-30 巴斯夫公司 用于处理内燃机废气的催化系统
DE102020006451A1 (de) * 2020-10-20 2021-03-18 FEV Group GmbH Steuergerät zum Steuern eines Wasserstoffgehalts eines Abgases eines Verbrennungsmotors
CN112943418B (zh) * 2021-01-27 2023-07-18 江苏大学 一种稀燃发动机的高效脱硝尾气后处理系统及控制方法
EP4279175A1 (en) 2022-05-17 2023-11-22 Basf Corporation Hydrogen oxidation catalysts for hydrogen-internal combustion engine systems
EP4282513A1 (en) 2022-05-23 2023-11-29 Basf Corporation Improved catalysts for selective nox reduction using hydrogen
EP4293207B1 (en) * 2022-06-14 2025-02-26 Volvo Truck Corporation An engine system comprising a hydrogen combustion engine and an exhaust aftertreatment system
EP4551804B1 (en) 2022-07-04 2026-06-03 Volvo Truck Corporation A method for controlling the operation of a hydrogen combustion engine system of a vehicle
US12540568B2 (en) 2022-07-04 2026-02-03 Volvo Truck Corporation Method for controlling the operation of a hydrogen combustion engine system
CN115400787B (zh) * 2022-09-28 2024-02-23 无锡威孚环保催化剂有限公司 一种氢内燃机催化剂及其制备方法
CN115555044B (zh) * 2022-10-10 2024-02-09 无锡威孚环保催化剂有限公司 一种催化剂在氢内燃机NOx污染物去除中的应用
WO2024161111A1 (en) * 2023-01-30 2024-08-08 Johnson Matthey Public Limited Company System comprising h2-internal combustion engine and exhaust system therefor
US12655818B2 (en) * 2023-07-12 2026-06-16 MöbiVolt Defense LLC Hydrogen generator for internal combusion engines
US12163451B1 (en) 2023-10-30 2024-12-10 Caterpillar Inc. Selective catalytic reduction for hydrogen engines
CN117703570A (zh) * 2024-01-11 2024-03-15 无锡威孚力达催化净化器有限责任公司 一种氢内燃机用尾气后处理装置及其控制方法
FR3166555A1 (fr) * 2024-09-25 2026-03-27 IFP Energies Nouvelles Catalyseur de PdNi pour la réduction catalytique des oxydes d’azote (NOx) en présence d’hydrogène
FR3166553A1 (fr) * 2024-09-25 2026-03-27 IFP Energies Nouvelles Procédé de réduction catalytique des oxydes d’azote (NOx) en présence d’hydrogène

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001079402A (ja) 1999-07-09 2001-03-27 Nissan Motor Co Ltd 排ガス浄化触媒及びその製造方法
US20100050604A1 (en) 2008-08-28 2010-03-04 John William Hoard SCR-LNT CATALYST COMBINATION FOR IMPROVED NOx CONTROL OF LEAN GASOLINE AND DIESEL ENGINES
JP2013096347A (ja) 2011-11-04 2013-05-20 Hino Motors Ltd 排ガス浄化装置
JP2015164729A (ja) 2009-04-17 2015-09-17 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ リーン／リッチエージングに対する耐久性を有する窒素酸化物の還元のための小細孔分子篩担持銅触媒

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3027057B2 (ja) * 1992-11-09 2000-03-27 アイシン精機株式会社 車載用水素供給装置
EP1066874B1 (en) 1999-07-09 2009-09-23 Nissan Motor Company, Limited Exhaust gas purifying catalyst and method of producing same
DE10219799A1 (de) 2002-05-03 2003-11-13 Bosch Gmbh Robert Verbrennungsvorrichtung mit einer Abgasreinigungsvorrichtung
US7332135B2 (en) * 2002-10-22 2008-02-19 Ford Global Technologies, Llc Catalyst system for the reduction of NOx and NH3 emissions
DE60326602D1 (de) * 2003-12-08 2009-04-23 Ford Global Tech Llc Verfahren zur Entfernung von NOx und teilchenförmigem Material
US7481983B2 (en) * 2004-08-23 2009-01-27 Basf Catalysts Llc Zone coated catalyst to simultaneously reduce NOx and unreacted ammonia
US20070012032A1 (en) * 2005-07-12 2007-01-18 Eaton Corporation Hybrid system comprising HC-SCR, NOx-trapping, and NH3-SCR for exhaust emission reduction
US7861517B2 (en) * 2005-11-09 2011-01-04 Delphi Technologies, Inc. Method and system for controlling catalyst temperature
US7669408B2 (en) * 2005-12-02 2010-03-02 Eaton Corporation LNT desulfation strategy with reformer temperature management
US7759280B2 (en) 2006-09-20 2010-07-20 Basf Corporation Catalysts, systems and methods to reduce NOX in an exhaust gas stream
US9863297B2 (en) 2007-12-12 2018-01-09 Basf Corporation Emission treatment system
JP5081635B2 (ja) * 2008-01-08 2012-11-28 本田技研工業株式会社 内燃機関の排気浄化装置
US7744840B2 (en) * 2008-05-16 2010-06-29 Siemens Energy, Inc. Selective catalytic reduction system and process using a pre-sulfated zirconia binder
EP2177256A1 (en) * 2008-10-15 2010-04-21 Linde AG Catalyst containing platinum and palladium for the selective reduction of NOx with hydrogen (H2-SCR)
EP2177257A1 (en) * 2008-10-15 2010-04-21 Linde AG Catalyst containing platinum on a support consisting of nano-crystal magnesium oxide and cerium dioxide towards H2-SCR
WO2010108083A1 (en) * 2009-03-20 2010-09-23 Basf Catalysts Llc EMISSIONS TREATMENT SYSTEM WITH LEAN NOx TRAP
EP2269729A1 (en) 2009-06-16 2011-01-05 Linde AG Catalyst consisting of platinum supported on chemically promoted magnesium oxide and cerium dioxide towards H2-SCR
EP2301650B1 (en) * 2009-09-24 2016-11-02 Haldor Topsøe A/S Process and catalyst system for scr of nox
US8293182B2 (en) 2010-05-05 2012-10-23 Basf Corporation Integrated SCR and AMOx catalyst systems
DE102012209852A1 (de) * 2012-06-12 2013-12-12 Robert Bosch Gmbh Abgasreinigungssystem zur Anordnung in einem Abgasstrang eines Kraftfahrzeuges, insbesondere eines Dieselkraftfahrzeugs
US9333490B2 (en) * 2013-03-14 2016-05-10 Basf Corporation Zoned catalyst for diesel applications
EP2875856A1 (en) * 2013-11-25 2015-05-27 Air Products And Chemicals, Inc. NOx reduction using a Zn- and/or Ga-containing catalyst
US8877151B1 (en) * 2013-11-25 2014-11-04 Air Products And Chemicals, Inc. NOx reduction using a Zn- and/or Ga-containing catalyst
US10145281B2 (en) * 2015-01-29 2018-12-04 GM Global Technology Operations LLC Synergistic combinations of low temperature NOx adsorbers
CN107371373A (zh) * 2015-03-26 2017-11-21 巴斯夫公司 排气处理系统
CN105840227A (zh) 2016-04-27 2016-08-10 山西东华机械有限公司 道轨上吊式单轨吊牵引移动式道轨装置
CN105840277B (zh) * 2016-05-11 2018-06-19 王东亮 乙醇水蒸汽重整成氢气制h2-scr系统

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001079402A (ja) 1999-07-09 2001-03-27 Nissan Motor Co Ltd 排ガス浄化触媒及びその製造方法
US20100050604A1 (en) 2008-08-28 2010-03-04 John William Hoard SCR-LNT CATALYST COMBINATION FOR IMPROVED NOx CONTROL OF LEAN GASOLINE AND DIESEL ENGINES
JP2015164729A (ja) 2009-04-17 2015-09-17 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ リーン／リッチエージングに対する耐久性を有する窒素酸化物の還元のための小細孔分子篩担持銅触媒
JP2013096347A (ja) 2011-11-04 2013-05-20 Hino Motors Ltd 排ガス浄化装置

Also Published As

Publication number Publication date
PL3528929T3 (pl) 2023-12-04
WO2018073750A1 (en) 2018-04-26
EP3528929A1 (en) 2019-08-28
EP3528929A4 (en) 2020-03-25
EP4252891A3 (en) 2023-12-20
JP2020501060A (ja) 2020-01-16
EP4252891A2 (en) 2023-10-04
US20190242282A1 (en) 2019-08-08
US12071882B2 (en) 2024-08-27
EP3528929B1 (en) 2023-08-16
KR20190058658A (ko) 2019-05-29
CN110072609A (zh) 2019-07-30
US11732625B2 (en) 2023-08-22
KR102567604B1 (ko) 2023-08-17
US20230340898A1 (en) 2023-10-26

Similar Documents

Publication Publication Date Title
US12071882B2 (en) Low temperature NOx reduction using H2-SCR for diesel vehicles
US9656209B2 (en) Three-way catalyst and its use in exhaust systems
US11185854B2 (en) Cold start catalyst and its use in exhaust systems
CN105813745B (zh) 包含两种不同贵金属-分子筛催化剂的废气催化剂
CN109414649B (zh) 用于氧化催化剂组合的分区配置
GB2551936B (en) Passive NOx Adsorber
KR102641284B1 (ko) 백금족 금속을 비귀금속 산화물과 조합한 디젤 산화 촉매
US11179706B2 (en) Lean NOx trap catalyst
JP7676151B2 (ja) 超低ＮＯｘ制御のためのディーゼル酸化触媒
CN105682792B (zh) 包含含银挤出沸石基材的三元催化剂及其在排气系统中的用途
EP3532198A1 (en) Catalytic and sorptive articles comprising metal fiber felt substrates
US11207641B2 (en) Oxidation catalyst for a diesel engine exhaust
JP7700050B2 (ja) ディーゼル酸化触媒および低温ｎｏｘ吸着剤を含む統合排出制御システム
JP2023509349A (ja) ＣｕおよびＰｄを含む、複合材中の共交換されたゼオライト

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20201016

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20201016

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20211129

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20211130

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20220218

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220322

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20220426

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20220708

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220913

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20230124

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20230221

R150 Certificate of patent or registration of utility model

Ref document number: 7233364

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: R3D02