JP7179618B2 - 鉱滓綿のための改善された硬化性樹脂 - Google Patents
鉱滓綿のための改善された硬化性樹脂 Download PDFInfo
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- JP7179618B2 JP7179618B2 JP2018558478A JP2018558478A JP7179618B2 JP 7179618 B2 JP7179618 B2 JP 7179618B2 JP 2018558478 A JP2018558478 A JP 2018558478A JP 2018558478 A JP2018558478 A JP 2018558478A JP 7179618 B2 JP7179618 B2 JP 7179618B2
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- weight
- sugar
- polycarboxylic acid
- resin composition
- binder
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/04—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C08B30/18—Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
- F16L59/028—Composition or method of fixing a thermally insulating material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
- C08J2305/02—Dextran; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/162—Selection of materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Inorganic Chemistry (AREA)
- Biochemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
-糖:Tereos Syralにより提供されるDE11~15のマルトデキストリン「Maldex 120」。
-ポリカルボン酸架橋剤:Sigma-Aldrichからのクエン酸試薬グレード(参照符号251275)およびSigma-AldrichからのL-酒石酸試薬グレード(参照符号351380)。
-多価金属酸化物硬化促進剤:Sigma-AldrichからのCaO試薬グレード(参照符号248568);Sigma-AldrichからのZnO試薬グレード(参照符号96479)。
Claims (15)
- 成分a)、b)およびc)を含む、鉱滓綿製品の製造のための、硬化性樹脂組成物であって、
a)は糖であり、
b)はポリカルボン酸架橋剤であり、そして
c)は酸化カルシウム、酸化亜鉛(II)、またはそれらの混合物から選択される多価金属酸化物であり、硬化性樹脂の硬化促進剤として機能し、
糖が有するヒドロキシル基とポリカルボン酸架橋剤が有するカルボキシル基とのモル比(ヒドロキシル基/カルボキシル基)は少なくとも1である、硬化性樹脂組成物。 - ホルムアルデヒドを含まない請求項1に記載の硬化性樹脂組成物。
- 前記多価金属酸化物の量が、前記成分a)、b)およびc)の重量の合計に対して0.5~10重量%の範囲にある、請求項1または2に記載の樹脂組成物。
- 前記ポリカルボン酸架橋剤が、<5,000g/molの重量平均分子量を有するポリカルボン酸化合物である、請求項1~3のいずれか一項に記載の樹脂組成物。
- 前記ポリカルボン酸架橋剤が、クエン酸、コハク酸、酒石酸、マレイン酸、それらの対応する無水物、それらの塩、およびそれらの混合物の群から選択される、請求項1~4のいずれか一項に記載の樹脂組成物。
- 前記樹脂が、不飽和カルボン酸モノマー由来のポリマーを実質的に含まない、請求項1~5のいずれか一項に記載の樹脂組成物。
- <400g/molの分子量を有する、糖とは異なるポリオールをさらに含む、請求項1~6のいずれか一項に記載の樹脂組成物。
- 前記ポリオールが、アルケングリコール、糖アルコール、およびそれらの混合物の群から選択される、請求項7に記載の樹脂組成物。
- 前記糖が、少なくとも1,000g/mol、または少なくとも10,000g/mol、または少なくとも100,000g/molの重量平均分子量を有するオリゴ糖または多糖である、請求項1~8のいずれか一項に記載の樹脂組成物。
- 糖の量が、前記成分a)、b)およびc)の重量の合計に関して少なくとも25重量%、または少なくとも40重量%である、請求項1~9のいずれか一項に記載の樹脂組成物。
- 糖a)の量が20~80重量%の範囲にあり、ポリカルボン酸架橋剤b)の量が20~80重量%の範囲にあり、そして多価金属酸化物c)の量が0.5~10重量%の範囲にあり、全ての量が前記成分a)、b)およびc)の重量の合計に関する、請求項1~10のいずれか一項に記載の樹脂組成物。
- 糖a)を含む水性組成物を調製することと、それを任意の順序でポリカルボン酸架橋剤b)および酸化カルシウム、酸化亜鉛(II)、またはそれらの混合物から選択される多価金属酸化物c)と接触させることとを含む、請求項1~11のいずれか一項に記載の樹脂組成物の製造方法。
- 請求項1~11のいずれか一項に記載の硬化性樹脂組成物を含む、鉱滓綿製品の製造のための水性結合剤であって、前記結合剤は、4~20重量%の乾燥重量を有し、かつ前記結合剤の前記乾燥重量に関して1~5重量%のシラン化合物および/または1~20重量%の油を任意に含むことができる、水性結合剤。
- 鉱滓綿および硬化した結合剤を含む鉱滓綿製品であって、前記硬化した結合剤は、請求項13に記載の結合剤を100℃より大きい温度で硬化することにより得られるものである、鉱滓綿製品。
- 鉱滓綿製品の製造における結合剤硬化促進剤としての多価金属酸化物の使用であって、当該多価金属酸化物は酸化カルシウム、酸化亜鉛(II)、またはそれらの混合物から選択され、前記結合剤は、糖およびポリカルボン酸架橋剤を含むものであり、糖が有するヒドロキシル基とポリカルボン酸架橋剤が有するカルボキシル基とのモル比(ヒドロキシル基/カルボキシル基)は少なくとも1である、使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16153179.3 | 2016-01-28 | ||
EP16153179.3A EP3199312B1 (en) | 2016-01-28 | 2016-01-28 | Improved curable resin for mineral wool |
PCT/EP2016/081040 WO2017129311A1 (en) | 2016-01-28 | 2016-12-14 | Improved curable resin for mineral wool |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2019506522A JP2019506522A (ja) | 2019-03-07 |
JP7179618B2 true JP7179618B2 (ja) | 2022-11-29 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018558478A Active JP7179618B2 (ja) | 2016-01-28 | 2016-12-14 | 鉱滓綿のための改善された硬化性樹脂 |
Country Status (9)
Country | Link |
---|---|
US (1) | US10988588B2 (ja) |
EP (1) | EP3199312B1 (ja) |
JP (1) | JP7179618B2 (ja) |
EA (1) | EA035420B1 (ja) |
ES (1) | ES2870662T3 (ja) |
PL (1) | PL3199312T3 (ja) |
PT (1) | PT3199312T (ja) |
SI (1) | SI3199312T1 (ja) |
WO (1) | WO2017129311A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109021262B (zh) * | 2018-05-04 | 2021-03-30 | 华南农业大学 | 一种固载皮克林乳液抑菌膜及其制备方法和应用 |
US10988643B2 (en) | 2018-06-19 | 2021-04-27 | Johns Manville | Starch and carboxylic acid binder compositions and articles made therewith |
CN110713738A (zh) * | 2019-10-28 | 2020-01-21 | 深圳市广田环保涂料有限公司 | 一种新型除甲醛无机贝壳粉涂料及其制备方法 |
US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002129038A (ja) | 2000-09-20 | 2002-05-09 | Natl Starch & Chem Investment Holding Corp | モノ(ヒドロキシアルキル)ウレアおよび多糖類の架橋系 |
JP2005533145A (ja) | 2002-07-15 | 2005-11-04 | ロックウール・インターナショナル・アクティーゼルスカブ | 鉱物繊維用のホルムアルデヒドを含まない水性バインダー組成物 |
JP2011506781A (ja) | 2007-12-05 | 2011-03-03 | サン−ゴバン・イソベール | 単糖類及び/又は多糖類と有機ポリカルボン酸とを含むミネラルウール用のサイズ剤組成物、及び得られた断熱製品 |
US20110166275A1 (en) | 2010-01-06 | 2011-07-07 | Mingfu Zhang | Formaldehyde-free binder compositions containing metal-ion crosslinkers and products made there from |
JP2014515793A (ja) | 2011-03-01 | 2014-07-03 | オウェンス コーニング インテレクチュアル キャピタル リミテッド ライアビリティ カンパニー | バイオベースバインダーを有する断熱製品 |
WO2016009062A1 (en) | 2014-07-17 | 2016-01-21 | Knauf Insulation Sprl | Improved binder compositions and uses thereof |
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US5895804A (en) * | 1997-10-27 | 1999-04-20 | National Starch And Chemical Investment Holding Corporation | Thermosetting polysaccharides |
KR20240056621A (ko) * | 2005-07-26 | 2024-04-30 | 크나우프 인설레이션, 인크. | 접착제 및 이들로 만들어진 물질 |
AU2006321786B2 (en) * | 2005-12-06 | 2012-05-10 | James Hardie Technology Limited | Engineered low-density heterogeneous microparticles and methods and formulations for producing the microparticles |
CA2666749C (en) | 2006-11-03 | 2016-01-12 | Dynea Oy | Renewable binder for nonwoven materials |
DE102007051657A1 (de) | 2007-10-26 | 2009-04-30 | Robert Bosch Gmbh | Kommunikationssystem mit einem CAN-Bus und Verfahren zum Betreiben eines solchen Kommunikationssystems |
MX2010006875A (es) * | 2007-12-21 | 2010-10-05 | Akzo Nobel Nv | Polisacaridos termoestables. |
US20090275699A1 (en) | 2008-05-05 | 2009-11-05 | Mingfu Zhang | Starch containing formaldehyde-free thermoset binders for fiber products |
BR112012007961B1 (pt) | 2009-10-09 | 2019-11-19 | Owens Corning Intellectual Capital, Llc | composição de ligante aquosa para uso na formação de tapetes de não-tecido e isolantes de fibra de vidro, produto isolante fibroso, tapete não tecido e processo para formar o pr oduto isolante fibroso |
WO2012166414A1 (en) | 2011-05-27 | 2012-12-06 | Cargill, Incorporated | Bio-based binder systems |
US20170096577A1 (en) * | 2015-10-01 | 2017-04-06 | PRC-DeSoto International. Inc. | Primer-less coated substrates |
-
2016
- 2016-01-28 EP EP16153179.3A patent/EP3199312B1/en active Active
- 2016-01-28 PL PL16153179T patent/PL3199312T3/pl unknown
- 2016-01-28 ES ES16153179T patent/ES2870662T3/es active Active
- 2016-01-28 SI SI201631225T patent/SI3199312T1/sl unknown
- 2016-01-28 PT PT161531793T patent/PT3199312T/pt unknown
- 2016-12-14 JP JP2018558478A patent/JP7179618B2/ja active Active
- 2016-12-14 WO PCT/EP2016/081040 patent/WO2017129311A1/en active Application Filing
- 2016-12-14 EA EA201891705A patent/EA035420B1/ru not_active IP Right Cessation
- 2016-12-14 US US16/073,161 patent/US10988588B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002129038A (ja) | 2000-09-20 | 2002-05-09 | Natl Starch & Chem Investment Holding Corp | モノ(ヒドロキシアルキル)ウレアおよび多糖類の架橋系 |
JP2005533145A (ja) | 2002-07-15 | 2005-11-04 | ロックウール・インターナショナル・アクティーゼルスカブ | 鉱物繊維用のホルムアルデヒドを含まない水性バインダー組成物 |
JP2011506781A (ja) | 2007-12-05 | 2011-03-03 | サン−ゴバン・イソベール | 単糖類及び/又は多糖類と有機ポリカルボン酸とを含むミネラルウール用のサイズ剤組成物、及び得られた断熱製品 |
US20110166275A1 (en) | 2010-01-06 | 2011-07-07 | Mingfu Zhang | Formaldehyde-free binder compositions containing metal-ion crosslinkers and products made there from |
JP2014515793A (ja) | 2011-03-01 | 2014-07-03 | オウェンス コーニング インテレクチュアル キャピタル リミテッド ライアビリティ カンパニー | バイオベースバインダーを有する断熱製品 |
WO2016009062A1 (en) | 2014-07-17 | 2016-01-21 | Knauf Insulation Sprl | Improved binder compositions and uses thereof |
Also Published As
Publication number | Publication date |
---|---|
WO2017129311A1 (en) | 2017-08-03 |
EA201891705A1 (ru) | 2019-02-28 |
SI3199312T1 (sl) | 2021-08-31 |
PL3199312T3 (pl) | 2021-08-16 |
US20190062510A1 (en) | 2019-02-28 |
JP2019506522A (ja) | 2019-03-07 |
EP3199312B1 (en) | 2021-03-10 |
EA035420B1 (ru) | 2020-06-11 |
EP3199312A1 (en) | 2017-08-02 |
ES2870662T3 (es) | 2021-10-27 |
US10988588B2 (en) | 2021-04-27 |
PT3199312T (pt) | 2021-05-21 |
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