JP7071925B2 - 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルム、液晶パネル、及び、画像表示装置 - Google Patents
粘着剤組成物、粘着剤層、粘着剤層付偏光フィルム、液晶パネル、及び、画像表示装置 Download PDFInfo
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- JP7071925B2 JP7071925B2 JP2018542651A JP2018542651A JP7071925B2 JP 7071925 B2 JP7071925 B2 JP 7071925B2 JP 2018542651 A JP2018542651 A JP 2018542651A JP 2018542651 A JP2018542651 A JP 2018542651A JP 7071925 B2 JP7071925 B2 JP 7071925B2
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- sensitive adhesive
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- SLVJUZOHXPZVLR-UHFFFAOYSA-N naphthalen-2-yl prop-2-enoate Chemical class C1=CC=CC2=CC(OC(=O)C=C)=CC=C21 SLVJUZOHXPZVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000005151 nonafluorobutanesulfonyl group Chemical group FC(C(C(S(=O)(=O)*)(F)F)(F)F)(C(F)(F)F)F 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000004193 piperazinyl group Chemical group 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
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- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
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- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
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- 229920002635 polyurethane Polymers 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- KRWRHQQOGIYTNX-UHFFFAOYSA-N prop-2-enamide pyrrolidine-2,5-dione Chemical compound C1(CCC(N1)=O)=O.C(C=C)(=O)N KRWRHQQOGIYTNX-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 108010033683 von Willebrand factor drug combination factor VIII Proteins 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
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- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8022—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with polyols having at least three hydroxy groups
- C08G18/8025—Masked aliphatic or cycloaliphatic polyisocyanates
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- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
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- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
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- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
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- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
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- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
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Description
(CnF2n+1SO2)2N- (1)
(一般式(1)中、nは2~10の整数)、及び、下記一般式(2):
CF2(CmF2mSO2)2N- (2)
(一般式(2)中、mは2~10の整数)、から選択される少なくとも1種で表されることを特徴とする。
本発明の粘着剤組成物は、(メタ)アクリル系ポリマー、並びに、アニオン成分及びカチオン成分を有するイオン性化合物を含有することを特徴とする。
前記粘着剤組成物は、(メタ)アクリル系ポリマーを含有することを特徴とする。前記(メタ)アクリル系ポリマーを用いることで、透明性や耐熱性に優れ、好ましい態様となる。(メタ)アクリル系ポリマーは、通常、モノマー単位として、アルキル(メタ)アクリレートを主成分として含有する。なお、(メタ)アクリレートは、アクリレート、及び/又は、メタクリレートをいい、本発明の(メタ)とは同様の意味である。
前記粘着剤組成物は、アニオン成分及びカチオン成分を有するイオン性化合物(導電剤)を含有し、前記アニオン成分の総炭素数が4以上であり、前記アニオン成分が、下記一般式(1):
(CnF2n+1SO2)2N- (1)
(一般式(1)中、nは2~10の整数)、及び、下記一般式(2):
CF2(CmF2mSO2)2N- (2)
(一般式(2)中、mは2~10の整数)、から選択される少なくとも1種で表されることを特徴とする。前記イオン性化合物を使用することにより、粘着剤層の帯電防止機能を確保できる。なお、粘着剤層中にイオン性化合物を含有することで、前記粘着剤層を接触する透明導電層(特に金属メッシュを含む透明導電層)が腐食する恐れがあり、特に湿熱環境下では、粘着剤層中のイオン性化合物が金属メッシュを含む透明導電層と接触側に偏析(偏在)し、腐食される恐れがある。このため、イオン性化合物を構成するアニオン成分として、総炭素数が4以上であり、総炭素数5以上が好ましく、総炭素数6以上がより好ましく、総炭素数7以上が更に好ましい。また、アニオン成分の総炭素数の上限値は特に限定されるものではないが、16以下であることが好ましく、10以下であることがより好ましい。総炭素数が4以上の高分子量のアニオン成分を使用することで、イオン性化合物の分子量(モル分子量)が大きくなり、イオン性化合物を含む粘着剤層の吸水率が低くなり、かつ、粘着剤層と透明導電層が接触する界面での前記イオン性化合物の偏析(偏在)が起こりにくくなり、イオン性化合物が均一に分散した状態を保持しやすいため、結果として、透明導電層(特に金属メッシュを含む透明導電層)の腐食を抑制することができ、かつ、粘着剤層表面の表面抵抗の上昇を抑え、ひいては、透明導電層の表面抵抗上昇などを抑制できる。
本発明においては、イオン性化合物を構成するアニオン成分として、総炭素数が4以上であることで、イオン性化合物自体の疎水性が高くなるため、粘着剤層中に水分を含みにくくなり、その結果、透明導電層(特に、金属メッシュを含む透明導電層)の腐食が抑制できるため好ましい。
(CnF2n+1SO2)2N- (1)
(一般式(1)中、nは2~10の整数(好ましくはnは4~10の整数))、及び、下記一般式(2):
CF2(CmF2mSO2)2N- (2)
(一般式(2)中、mは2~10の整数(好ましくはnは3~10の整数))、から選択される少なくとも1種で表されるアニオン成分であることが、腐食抑制の観点から好ましい。
本発明においては、カチオン成分としては、有機カチオンが好ましい。カチオンの炭素数は6以上であることが好ましく、8以上であることがより好ましく、10以上であることがさらに好ましい。また、カチオンの炭素数の上限値は特に限定されないが、40以下であることが好ましく、30以下であることがより好ましい。カチオン成分の炭素数が6以上であることで、イオン性化合物自体の疎水性が高くなるため、粘着剤層中に水分を含みにくくなり、その結果、透明導電層(特に、金属メッシュを含む透明導電層)の腐食が抑制できるため好ましい。
本発明の粘着剤組成物には、架橋剤を含有することができる。架橋剤を使用することで、粘着剤の耐久性に関係する凝集力を付与できるため好ましい。架橋剤としては、有機系架橋剤や多官能性金属キレートを用いることができる。有機系架橋剤としては、イソシアネート系架橋剤、過酸化物系架橋剤、エポキシ系架橋剤、イミン系架橋剤等が挙げられる。多官能性金属キレートは、多価金属が有機化合物と共有結合または配位結合しているものである。多価金属原子としては、Al、Cr、Zr、Co、Cu、Fe、Ni、V、Zn、In、Ca、Mg、Mn、Y、Ce、Sr、Ba、Mo、La、Sn、Ti等が挙げられる。共有結合または配位結合する有機化合物中の原子としては酸素原子等が挙げられ、有機化合物としてはアルキルエステル、アルコール化合物、カルボン酸化合物、エーテル化合物、ケトン化合物等が挙げられる。
本発明の粘着剤組成物には、シランカップリング剤を含有することができる。シランカップリング剤を用いることにより、耐久性を向上させることができる。シランカップリング剤としては、具体的には、たとえば、3-グリシドキシプロピルトリメトキシシラン、3-グリシドキシプロピルトリエトキシシラン、3-グリシドキシプロピルメチルジエトキシシラン、2-(3,4-エポキシシクロヘキシル)エチルトリメトキシシラン等のエポキシ基含有シランカップリング剤、3-アミノプロピルトリメトキシシラン、N-2-(アミノエチル)-3-アミノプロピルメチルジメトキシシラン、3-トリエトキシシリル-N-(1,3-ジメチルブチリデン)プロピルアミン、N-フェニル-γ-アミノプロピルトリメトキシシラン等のアミノ基含有シランカップリング剤、3-アクリロキシプロピルトリメトキシシラン、3-メタクリロキシプロピルトリエトキシシラン等の(メタ)アクリル基含有シランカップリング剤、3-イソシアネートプロピルトリエトキシシラン等のイソシアネート基含有シランカップリング剤等が挙げられる。前記例示のシランカップリング剤としては、エポキシ基含有シランカップリング剤が好ましい。
さらに本発明の粘着剤組成物には、その他の公知の添加剤を含有していてもよく、たとえば、ポリプロピレングリコール等のポリアルキレングリコールのポリエーテル化合物、着色剤、顔料等の粉体、染料、界面活性剤、可塑剤、粘着性付与剤、表面潤滑剤、レベリング剤、軟化剤、酸化防止剤、老化防止剤、光安定剤、紫外線吸収剤、重合禁止剤、無機又は有機の充填剤、金属粉、粒子状、箔状物等を使用する用途に応じて適宜添加することができる。
本発明の粘着剤層は、前記粘着剤組成物から形成されることを特徴とする。
本発明に用いられる粘着剤層付偏光フィルムは、偏光子及び前記偏光子の少なくとも片面に透明保護フィルムを有する偏光フィルム、及び、前記偏光フィルムの少なくとも片面に(前記粘着剤組成物より形成される)前記粘着剤層を有する粘着剤層付偏光フィルムを有することが好ましい。例えば、図1に示すように、本発明で用いられる粘着剤層付偏光フィルム3は、偏光フィルム1と粘着剤層2が積層されたものである。また、図2~4に示すように、本発明で用いられる粘着剤層付偏光フィルム3は、透明導電層付きの液晶セル(ガラス基板5+液晶層6+ガラス基板5)の透明導電層4に貼り合わされて用いられる。
本発明の液晶パネルは、偏光子及び前記偏光子の少なくとも片面に透明保護フィルムを有する偏光フィルム、及び、前記偏光フィルムの少なくとも片面に(前記粘着剤組成物より形成される)前記粘着剤層を有する粘着剤層付偏光フィルムを有し、かつ、前記粘着剤層を介して、前記偏光フィルムが、金属メッシュを含む透明導電層付液晶セルに貼り合わされていることが好ましい。なお、その他の構成については特に限定されるものではない。本発明においては、特定の粘着剤層を用いることで、液晶パネル全体としての耐久性の向上などを図ることができる。
本発明の画像表示装置は、前記液晶パネルを含むことが好ましい。以下、一例として、液晶表示装置について説明するが、本発明は、液晶パネルを必要とするあらゆる表示装置に適用され得るものである。
厚さ80μmのポリビニルアルコールフィルムを、速度比の異なるロール間において、30℃、0.3%濃度のヨウ素溶液中で1分間染色しながら、3倍まで延伸した。その後、60℃、4%濃度のホウ酸、10%濃度のヨウ化カリウムを含む水溶液中に0.5分間浸漬しながら総合延伸倍率が6倍になるように延伸した。次いで、30℃、1.5%濃度のヨウ化カリウムを含む水溶液中に10秒間浸漬することで洗浄した後、50℃で4分間乾燥を行い、厚さ20μmの偏光子を得た。当該偏光子の両面に、けん化処理した厚さ40μmのトリアセチルセルロースフィルム(コニカミノルタオプト(株)社製)を、それぞれ、ポリビニルアルコール系接着剤により貼り合せて偏光フィルムを作製した。
(アクリル系ポリマーの調製)
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた4つ口フラスコに、ブチルアクリレート80.3部、フェノキシエチルアクリレート16部、N-ビニルピロリドン3部、アクリル酸0.3部、及び、アクリル酸4-ヒドロキシブチル0.4部を含有するモノマー混合物を仕込んだ。さらに、前記モノマー混合物(固形分)100部に対して、重合開始剤として2,2´-アゾビスイソブチロニトリル0.2部を酢酸エチルと共に仕込み、緩やかに攪拌しながら窒素ガスを導入して窒素置換した後、フラスコ内の液温を55℃付近に保って8時間重合反応を行って、重量平均分子量160万のアクリル系ポリマー溶液を調製した。
得られた前記アクリル系ポリマー溶液の固形分100部に対して、イオン性化合物として、リチウムビス(ノナフルオロブタンスルホニル)イミド(三菱マテリアル電子化成(株)社製)1部、イソシアネート系架橋剤(D160N、三井化学社製のタケネートD160N、トリメチロールプロパンのヘキサメチレンジイソシアネートのアダクト体)0.1部、過酸化物系架橋剤(BPO、日本油脂社製のナイパーBMT、ベンゾイルパーオキサイド)0.3部、及び、シランカップリング剤(X-41-1810、信越化学工業社製のX-41-1810、チオール基含有シリケートオリゴマー)0.1部を配合して、アクリル系粘着剤組成物の溶液を調製した。
次いで、上記アクリル系粘着剤溶液を、シリコーン系剥離剤で処理されたポリエチレンテレフタレートフィルム(セパレータフィルム)の表面に、ファウンテンコータで均一に塗工し、155℃の空気循環式恒温オーブンで2分間乾燥し、セパレータフィルムの表面に厚さ20μmの粘着剤層を形成した。次いで、作製した偏光フィルムに、セパレータフィルム上に形成した粘着剤層を転写して、粘着剤層付偏光フィルムを作製した。
実施例1に対して、アクリル系ポリマー、粘着剤組成物、偏光フィルム、及び、粘着剤層付偏光フィルムの調製にあたり、表1に示すように変更したこと以外は、実施例1と同様にして、粘着剤層付偏光フィルムを作製した。なお、反応条件や配合量などは、実施例1と同じ加熱条件やモル濃度となる量等に調整・添加した。
得られた(メタ)アクリル系ポリマーの重量平均分子量(Mw)は、以下の方法により測定した。
(メタ)アクリル系ポリマーの重量平均分子量(Mw)は、GPC(ゲル・パーミエーション・クロマトグラフィー)により測定した。
・分析装置:東ソー社製、HLC-8120GPC
・カラム:東ソー社製、G7000HXL+GMHXL+GMHXL
・カラムサイズ:各7.8mmφ×30cm 計90cm
・カラム温度:40℃
・流量:0.8ml/min
・注入量:100μl
・溶離液:テトラヒドロフラン
・検出器:示差屈折計(RI)
・標準試料:ポリスチレン
実施例、比較例で得られた粘着剤層付偏光フィルムのセパレータフィルムを剥がし、室温放置条件にて、1分間放置した後、粘着剤層表面の表面抵抗値(初期)を測定した。また、更に、前記粘着剤層付偏光フィルムを60℃×95%RHの環境に500時間投入した後、40℃で1時間乾燥させてから、セパレータフィルムを剥がした後、粘着剤表面の表面抵抗値(湿熱後)を測定した。測定は、三菱化学アナリテック社製MCP-HT450を用いて行った。
なお、初期値と湿熱後の表面抵抗値の差は小さければ小さいほど、粘着剤中の導電剤の偏析が抑制されるため、耐腐食性が好ましい。また、表2中の1.0E+12とは、表面抵抗値1.0×1012(Ω/□)を指す。
ガラス(無アルカリガラス)表面に、スパッタリング法にて形成された厚さ0.1μmのアルミニウム系金属層を形成した導電性ガラスに、実施例及び比較例で得られた粘着剤層付偏光フィルムを15mm×15mmに切断し、セパレータフィルムを剥がして貼り合わせた後、50℃、5atmで15分間オートクレーブにかけたものを耐腐食性の測定サンプル(透明導電層付液晶セルに相当する導電性ガラスに粘着剤層付偏光フィルムを貼り合わせたサンプル)とした。得られた測定用サンプルを60℃×95%RHの環境に、500時間投入した後に、目視及び光学顕微鏡にて金属層の外観を評価した。なお、欠陥の大きさは、欠陥の一番長い部分を測定した。
(評価基準)
◎:欠陥なし
○:周辺の一部に僅かに欠陥(欠陥の大きさは0.5mm未満)あるが、内部には欠陥がなく、実用上問題なし。
△:周辺部に断続的な欠陥(欠陥の大きさは0.5mm以上、1mm未満)があるが、内部には欠陥がなく、実用上問題なし。
×:周辺部に連続的な欠陥(欠陥の大きさは1mm以上)があるか、又は内部に欠陥があり、実用上問題あり。
実施例、比較例で得られた粘着剤層付偏光フィルムを15インチサイズに切断したものをサンプルとした。当該サンプルからセパレータフィルムを剥がした後、厚さ0.7mmの無アルカリガラス(コーニング社製、EG-XG)にラミネーターを用いて貼着した。次いで、50℃、0.5MPaで15分間オートクレーブ処理して、上記サンプルを完全に無アクリルガラスに密着させた。かかる処理の施されたサンプルに、60℃×95%RHの各雰囲気下で500時間処理を施した後(加湿試験)、偏光フィルムとガラスの間の外観を下記基準で目視にて評価した。
(評価基準)
◎:発泡、剥がれ等の外観上の変化が全くなし。
○:わずかながら端部に剥がれ、または発泡があるが、実用上問題なし。
△:端部に剥がれ、または発泡があるが、特別な用途でなければ、実用上問題なし。
×:端部に著しい剥がれあり、実用上問題あり。
<モノマー成分>
BA:ブチルアクリレート
PEA:フェノキシエチルアクリレート
NVP:N-ビニル-ピロリドン
DMAEA:N,N-ジメチルアミノエチルアクリレート
AA:アクリル酸
HBA:4-ヒドロキシブチルアクリレート
D160N:イソシアネート系架橋剤、三井化学社製のタケネートD160N(トリメチロールプロパンのヘキサメチレンジイソシアネートのアダクト体)
BPO:過酸化物系架橋剤、ベンゾイルパーオキサイド(日本油脂社製、ナイパーBMT)
Li-NFSI:リチウムビス(ノナフルオロブタンスルホニル)イミド(三菱マテリアル電子化成(株)社製)
Li-HFSI:リチウムビス(ヘプタフルオロプロパンスルホニル)イミド(和光純薬社製)
Li-PFSI:ビス(ペンタフルオロエタンスルホニル)イミドリチウム(東京化成社製)
MTOA-NFSI:メチルトリオクチルアンモニウムビス(ノナフルオロブタンスルホニル)イミド(三菱マテリアル電子化成(株)社製)
BMI-NFSI:ブチルメチルイミダゾリウムビス(ノナフルオロブタンスルホニル)イミド(三菱マテリアル電子化成(株)社製)
Li-TFSI:リチウムビス(トリフルオロメタンスルホニル)イミド(三菱マテリアル電子化成(株)社製)
Li-CTFSI:リチウム N,N-ヘキサフルオロプロパン-1,3‐ジスルホニルイミド(三菱マテリアル電子化成(株)社製)
EMI-FSI:1‐エチル‐3‐メチルイミダゾリウムビス(フルオロスルホニル)イミド(第一工業製薬(株)社製)
4MOPy-FSI:1‐オクチル‐4‐メチルピリジニウムビス(フルオロスルホニル)イミド(第一工業製薬(株)社製)
X-41-1810:チオール基含有シリケートオリゴマー(信越化学工業社製)
KBM403:エポキシ基含有シランカップリング剤(信越化学工業社製)
2 粘着剤層
3 粘着剤層付偏光フィルム
4 金属メッシュを含む透明導電層
5 ガラス基板
6 液晶層
7 駆動電極
8 粘着剤層
9 偏光フィルム
10 駆動電極兼センサー層
11 センサー層
Claims (4)
- 偏光子及び前記偏光子の少なくとも片面に透明保護フィルムを有する偏光フィルム、及び、前記偏光フィルムの少なくとも片面に粘着剤組成物により形成される粘着剤層を有する粘着剤層付偏光フィルムであって、
前記粘着剤組成物が、(メタ)アクリル系ポリマー、並びに、アニオン成分及びカチオン成分を有するイオン性化合物を含有し、
前記(メタ)アクリル系ポリマーが、モノマー単位として、窒素含有モノマーを0.6重量%以上含有し、
前記アニオン成分の総炭素数が4以上であり、
前記アニオン成分が、下記一般式(1):
(CnF2n+1SO2)2N- (1)
(一般式(1)中、nは2~10の整数)、及び、下記一般式(2):
CF2(CmF2mSO2)2N- (2)
(一般式(2)中、mは2~10の整数)、から選択される少なくとも1種で表されることを特徴とする粘着剤層付偏光フィルム。 - 前記粘着剤組成物が、架橋剤を含有し、
前記架橋剤が、イソシアネート系架橋剤、及び/又は、過酸化物系架橋剤を含有することを特徴とする請求項1に記載の粘着剤層付偏光フィルム。 - 請求項1又は2に記載の粘着剤層付偏光フィルムを有し、かつ、前記粘着剤層を介して、前記偏光フィルムが、金属メッシュを含む透明導電層付液晶セルに貼り合わされていることを特徴とする液晶パネル。
- 請求項3に記載の液晶パネルを含むことを特徴とする画像表示装置。
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PCT/JP2017/034987 WO2018062283A1 (ja) | 2016-09-30 | 2017-09-27 | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルム、液晶パネル、及び、画像表示装置 |
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JP (1) | JP7071925B2 (ja) |
KR (1) | KR102391675B1 (ja) |
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JP2021189259A (ja) * | 2020-05-28 | 2021-12-13 | 日東電工株式会社 | 位相差層および粘着剤層付偏光板およびそれを用いた有機エレクトロルミネセンス表示装置 |
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JP2008517138A (ja) | 2005-06-10 | 2008-05-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
JP2008174739A (ja) | 2006-12-20 | 2008-07-31 | Toyo Ink Mfg Co Ltd | 制電性アクリル系樹脂組成物 |
JP2010525098A (ja) | 2007-04-19 | 2010-07-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
JP2012177022A (ja) | 2011-02-25 | 2012-09-13 | Fujikura Kasei Co Ltd | 粘着剤組成物、粘着フィルム、および光学部品 |
JP2013221067A (ja) | 2012-04-16 | 2013-10-28 | Nitto Denko Corp | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルムおよび画像形成装置 |
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JP5552271B2 (ja) | 2009-07-08 | 2014-07-16 | 日東電工株式会社 | 粘着剤層付き透明導電性フィルム、透明導電性積層体及びタッチパネル |
WO2012056774A1 (ja) * | 2010-10-29 | 2012-05-03 | リンテック株式会社 | 透明導電性フィルム、電子デバイス及び電子デバイスの製造方法 |
JP5913809B2 (ja) * | 2011-01-05 | 2016-04-27 | リンテック株式会社 | 透明電極基板、その製造方法、該透明電極基板を有する電子デバイス及び太陽電池 |
WO2012128597A2 (ko) * | 2011-03-23 | 2012-09-27 | 주식회사 엘지화학 | 점착제 조성물 |
JP5860673B2 (ja) * | 2011-11-07 | 2016-02-16 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、粘着剤層付偏光板および画像形成装置 |
JP6195707B2 (ja) * | 2011-11-24 | 2017-09-13 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルムおよび画像形成装置 |
KR20140086658A (ko) * | 2012-12-28 | 2014-07-08 | 동우 화인켐 주식회사 | 공중합체 및 이를 포함하는 점착제 조성물 |
KR102044900B1 (ko) * | 2013-03-07 | 2019-11-15 | 삼성디스플레이 주식회사 | 터치 스크린 패널 |
JP6472172B2 (ja) | 2013-06-28 | 2019-02-20 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付き光学フィルム、液晶表示装置、及び、積層体 |
JP6404707B2 (ja) * | 2014-01-06 | 2018-10-10 | 日東電工株式会社 | アクリル系粘着剤組成物、アクリル系粘着剤層、粘着剤層付き基材フィルム、積層体、及び画像表示装置 |
KR102341436B1 (ko) * | 2014-08-06 | 2021-12-23 | 삼성디스플레이 주식회사 | 터치 스크린 패널의 제조 방법 및 터치 스크린 패널 |
US11090902B2 (en) * | 2015-03-30 | 2021-08-17 | Nitto Denko Corporation | Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive-layer—attached polarizing film, and image display device |
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2017
- 2017-09-27 CN CN201780059444.4A patent/CN109790433A/zh active Pending
- 2017-09-27 KR KR1020197011994A patent/KR102391675B1/ko active IP Right Grant
- 2017-09-27 JP JP2018542651A patent/JP7071925B2/ja active Active
- 2017-09-27 US US16/337,108 patent/US20190218427A1/en not_active Abandoned
- 2017-09-27 WO PCT/JP2017/034987 patent/WO2018062283A1/ja active Application Filing
- 2017-09-29 TW TW106133668A patent/TW201827542A/zh unknown
Patent Citations (5)
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JP2008517138A (ja) | 2005-06-10 | 2008-05-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
JP2008174739A (ja) | 2006-12-20 | 2008-07-31 | Toyo Ink Mfg Co Ltd | 制電性アクリル系樹脂組成物 |
JP2010525098A (ja) | 2007-04-19 | 2010-07-22 | エルジー・ケム・リミテッド | アクリル系粘着剤組成物 |
JP2012177022A (ja) | 2011-02-25 | 2012-09-13 | Fujikura Kasei Co Ltd | 粘着剤組成物、粘着フィルム、および光学部品 |
JP2013221067A (ja) | 2012-04-16 | 2013-10-28 | Nitto Denko Corp | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルムおよび画像形成装置 |
Also Published As
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CN109790433A (zh) | 2019-05-21 |
WO2018062283A1 (ja) | 2018-04-05 |
KR102391675B1 (ko) | 2022-04-29 |
KR20190055211A (ko) | 2019-05-22 |
US20190218427A1 (en) | 2019-07-18 |
JPWO2018062283A1 (ja) | 2019-08-22 |
TW201827542A (zh) | 2018-08-01 |
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