JP6979023B2 - 水素またはヘリウムの精製方法、および水素またはヘリウムの精製装置 - Google Patents
水素またはヘリウムの精製方法、および水素またはヘリウムの精製装置 Download PDFInfo
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- JP6979023B2 JP6979023B2 JP2018541039A JP2018541039A JP6979023B2 JP 6979023 B2 JP6979023 B2 JP 6979023B2 JP 2018541039 A JP2018541039 A JP 2018541039A JP 2018541039 A JP2018541039 A JP 2018541039A JP 6979023 B2 JP6979023 B2 JP 6979023B2
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- gas
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 80
- 238000000034 method Methods 0.000 title claims description 73
- 239000001257 hydrogen Substances 0.000 title claims description 54
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 54
- 238000000746 purification Methods 0.000 title claims description 32
- 239000001307 helium Substances 0.000 title claims description 30
- 229910052734 helium Inorganic materials 0.000 title claims description 30
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 title claims description 30
- 239000007789 gas Substances 0.000 claims description 234
- 238000001179 sorption measurement Methods 0.000 claims description 150
- 239000003463 adsorbent Substances 0.000 claims description 143
- 229930195733 hydrocarbon Natural products 0.000 claims description 82
- 150000002430 hydrocarbons Chemical class 0.000 claims description 82
- 239000004215 Carbon black (E152) Substances 0.000 claims description 52
- 239000002994 raw material Substances 0.000 claims description 50
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 41
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 41
- 239000012535 impurity Substances 0.000 claims description 39
- 238000011049 filling Methods 0.000 claims description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- 238000004140 cleaning Methods 0.000 claims description 26
- 239000000741 silica gel Substances 0.000 claims description 21
- 229910002027 silica gel Inorganic materials 0.000 claims description 21
- 238000003795 desorption Methods 0.000 claims description 20
- 239000010457 zeolite Substances 0.000 claims description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims description 18
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 15
- 230000006837 decompression Effects 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 3
- 244000060011 Cocos nucifera Species 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 36
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 20
- 238000006477 desulfuration reaction Methods 0.000 description 12
- 230000023556 desulfurization Effects 0.000 description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000011002 quantification Methods 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 238000011282 treatment Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910001868 water Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000002912 waste gas Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000009841 combustion method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- -1 ethylene, butylene, propylene Chemical group 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 102100025674 Angiopoietin-related protein 4 Human genes 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 101000693076 Homo sapiens Angiopoietin-related protein 4 Proteins 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/053—Pressure swing adsorption with storage or buffer vessel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B23/00—Noble gases; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016186677 | 2016-09-26 | ||
| JP2016186677 | 2016-09-26 | ||
| JP2016238474 | 2016-12-08 | ||
| JP2016238474 | 2016-12-08 | ||
| PCT/JP2017/033430 WO2018056203A1 (ja) | 2016-09-26 | 2017-09-15 | 水素またはヘリウムの精製方法、および水素またはヘリウムの精製装置 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2018056203A1 JPWO2018056203A1 (ja) | 2019-07-04 |
| JP6979023B2 true JP6979023B2 (ja) | 2021-12-08 |
Family
ID=61689930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018541039A Active JP6979023B2 (ja) | 2016-09-26 | 2017-09-15 | 水素またはヘリウムの精製方法、および水素またはヘリウムの精製装置 |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6979023B2 (ko) |
| KR (1) | KR102391642B1 (ko) |
| CN (1) | CN109789368A (ko) |
| PH (1) | PH12019500649A1 (ko) |
| TW (1) | TWI734835B (ko) |
| WO (1) | WO2018056203A1 (ko) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113735078A (zh) * | 2020-05-27 | 2021-12-03 | 中国石油化工股份有限公司 | 从lng工厂的bog尾气中回收氦气的方法、系统及回收的氦气 |
| CN114950068A (zh) * | 2021-02-22 | 2022-08-30 | 国家能源投资集团有限责任公司 | 混合气变温变压吸附分离的方法和系统 |
| KR20240114120A (ko) | 2023-01-16 | 2024-07-23 | (주)금강 | Psa 공정의 사전 설계를 위한 흡착제량의 조절이 용이한 흡착탑 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3011094B2 (ja) | 1995-05-27 | 2000-02-21 | システム エンジ サービス株式会社 | 廃棄ガスに含まれるガス状炭化水素の処理・回収方法 |
| JP2925522B2 (ja) | 1997-06-17 | 1999-07-28 | システム エンジ サービス株式会社 | ガス状炭化水素を含む廃棄ガスから炭化水素を液状で回収する方法 |
| JPH119935A (ja) * | 1997-06-25 | 1999-01-19 | Nippon Steel Corp | Ｐｓａ法による製品水素ガスの品質制御方法 |
| JP3089297B2 (ja) | 1998-03-18 | 2000-09-18 | 農林水産省畜産試験場長 | 嫌気性汚水処理用後処理装置 |
| JP2000102779A (ja) | 1998-09-29 | 2000-04-11 | Kubota Corp | メタンガス発生促進方法 |
| JP2001300244A (ja) * | 2000-04-20 | 2001-10-30 | Mitsubishi Kakoki Kaisha Ltd | 水素製造用圧力変動吸着装置の吸着塔 |
| AU2002217475B2 (en) * | 2000-12-25 | 2005-02-17 | Sumitomo Seika Chemicals Co., Ltd. | Method for separating hydrogen gas |
| JP2002275482A (ja) | 2001-03-16 | 2002-09-25 | Ebara Corp | 消化ガスによる発電方法及び発電システム |
| JP3974013B2 (ja) * | 2001-12-28 | 2007-09-12 | システム エンジ サービス株式会社 | 揮発性炭化水素含有排ガスの処理方法及び該方法を実施するための装置 |
| FR2836061B1 (fr) | 2002-02-15 | 2004-11-19 | Air Liquide | Procede de traitement d'un melange gazeux comprenant de l'hydrogene et du sulfure d'hydrogene |
| CN100581645C (zh) * | 2002-12-24 | 2010-01-20 | 普莱克斯技术有限公司 | 氢气提纯用工艺和装置 |
| US7390350B2 (en) * | 2005-04-26 | 2008-06-24 | Air Products And Chemicals, Inc. | Design and operation methods for pressure swing adsorption systems |
| WO2008047828A1 (fr) * | 2006-10-20 | 2008-04-24 | Sumitomo Seika Chemicals Co., Ltd. | Procédé et appareil de séparation de gaz d'hydrogène |
| WO2008056579A1 (fr) * | 2006-11-08 | 2008-05-15 | Sumitomo Seika Chemicals Co., Ltd. | Procédé de séparation de l'hydrogène gazeux et appareil de séparation |
| CN102199433A (zh) * | 2011-03-05 | 2011-09-28 | 何巨堂 | 一种以co2为燃烧过程控温组分的煤炭化工艺 |
| JP5675505B2 (ja) * | 2011-06-07 | 2015-02-25 | 住友精化株式会社 | 目的ガス分離方法、および目的ガス分離装置 |
| US20160097013A1 (en) * | 2013-06-19 | 2016-04-07 | Kent S. Knaebel & Associates, Inc. | PSA Separation of Nitrogen from Natural Gas |
-
2017
- 2017-09-15 CN CN201780058840.5A patent/CN109789368A/zh active Pending
- 2017-09-15 JP JP2018541039A patent/JP6979023B2/ja active Active
- 2017-09-15 KR KR1020197009111A patent/KR102391642B1/ko active IP Right Grant
- 2017-09-15 WO PCT/JP2017/033430 patent/WO2018056203A1/ja active Application Filing
- 2017-09-20 TW TW106132225A patent/TWI734835B/zh active
-
2019
- 2019-03-25 PH PH12019500649A patent/PH12019500649A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2018056203A1 (ja) | 2019-07-04 |
| TWI734835B (zh) | 2021-08-01 |
| KR20190052018A (ko) | 2019-05-15 |
| KR102391642B1 (ko) | 2022-04-27 |
| TW201827335A (zh) | 2018-08-01 |
| CN109789368A (zh) | 2019-05-21 |
| PH12019500649A1 (en) | 2019-07-29 |
| WO2018056203A1 (ja) | 2018-03-29 |
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