JP6960879B2 - Hair cosmetics - Google Patents

Description

The present invention relates to a hair cosmetic having an excellent feeling of use and finishing effect when applied to hair, and more specifically, behenyl PG trimonium chloride, a linear alkyl group having 14 to 24 carbon atoms. Higher alcohol having, higher alcohol having an alkyl group of 14 to 24 carbon atoms, hydrogenated palm oil, hydrogenated palm oil, hydrogenated castor oil, one or more selected from hydrogenated rapeseed oil, carbon By containing a specific amount of each of an ester of a fatty acid of several 10 to 22 and a monovalent alcohol having 1 to 2 carbon atoms, it is excellent in a rich feeling at the time of application, a familiar feeling at the time of application, and a suppleness at the time of application. As a finishing effect, it relates to a hair cosmetic having excellent moistness and smoothness and good stability over time at low temperature.

Hair cosmetics include various items such as hair shampoos, hair rinses, hair treatments, and hair styling products, and have a wide range of required functions. For example, when applying hair cosmetics, it is important to have a feeling of spreading and spreading on the hair, a feeling of familiarity, richness, and softness, and the finishing effect given to the hair is moisturizing and moisturizing. Feeling, smoothness, finger passage, suppleness, firmness, gloss, etc. can be mentioned.
In order to obtain these excellent usability and finish effects, various oil agents, moisturizing components, polymer components, and other various substances have been studied for formulation.

Among the feelings of use at the time of application, the feeling of richness and familiarity are important items when the hair cosmetic is uniformly applied to the entire hair. For example, there is a technique (see, for example, Patent Document 1) containing a specific higher alcohol or a specific polyoxypropylene derivative in order to obtain a rich feeling.
Further, there is a technique (see, for example, Patent Document 2) containing a specific vesicle structure in order to obtain a familiar feeling at the time of application.

On the other hand, moist feeling, finger passage, and smoothness are also important items as the required quality as the finishing effect given to the hair. For example, a technique containing an organic acid or a specific polyhydric alcohol (see, for example, Patent Document 3), a technique containing a specific amidamine salt (see, for example, Patent Document 4), and smoothness in order to improve the moist feeling. In order to improve the moist feeling, there is a technique containing a specific organomodified silicone (see, for example, Patent Document 5).

Japanese Unexamined Patent Publication No. 2016-52298 Japanese Unexamined Patent Publication No. 2014-374403 Japanese Unexamined Patent Publication No. 2016-216432 Japanese Unexamined Patent Publication No. 2015-140303 Japanese Unexamined Patent Publication No. 2015-40250

The hair cosmetic described in Patent Document 1 contains a specific linear alcohol and a specific polyoxypropylene derivative to impart an excellent effect of richness and stretchability at the time of application. Due to the influence of certain linear alcohols, stability over time at low temperatures may deteriorate. Further, the hair cosmetics described in Patent Document 2 give a familiar feeling at the time of application by containing a vesicle structure containing a specific branched fatty acid, a tertiary amine and a specific organic acid. , There was a case that the richness at the time of use was impaired.
The hair cosmetics described in Patent Document 3 contain succinic acid, naphthalene sulfonic acid and dipropylene glycol as specific organic acids to improve the moist feeling at the time of finishing. Due to the influence, the smoothness at the time of finishing may be impaired. The hair cosmetic described in Patent Document 4 contains a specific condensed hydroxy fatty acid amidoamine acid to impart familiarity to the hair and a long-lasting moist feeling, but it has a rich feeling at the time of application and a low temperature aging. In some cases, stability was impaired. The organomodified silicone described in Patent Document 5, a method for producing the same, and a hair cosmetic containing the same include a specific organomodified silicone to give the hair a smooth and moist feeling, but at the time of application. In some cases, it was not possible to obtain a sufficient feeling of richness and familiarity at the time of application.

Although such problems exist, when using hair cosmetics, they are excellent in usability such as richness and familiarity at the time of application, and as a hair finishing effect, they are excellent in moistness and smoothness. There has never been a product that satisfies all of the stability over time at low temperature, and the development of such a hair cosmetic has been desired.

In view of such circumstances, as a result of diligent studies to solve the above problems, the present inventors have conducted a specific amount of behenyl PG trimonium as a surfactant that imparts a moist feeling and softness at the time of finishing in hair cosmetics. Chloride is effective, and by using a higher alcohol having a specific amount of a linear alkyl group having 14 to 24 carbon atoms and a higher alcohol having a branched alkyl group having 14 to 24 carbon atoms in combination, the richness at the time of application is achieved. It was found that it gives a feeling and is excellent in stability over time at low temperature. Furthermore, by using an ester of a specific amount of fatty acid having 10 to 22 carbon atoms and a monohydric alcohol having 1 to 2 carbon atoms in combination, a hair cosmetic having an excellent familiar feeling at the time of application can be obtained without impairing the finishing effect. I found that it was possible.
Furthermore, by using one or more of hydrogenated palm oil, hydrogenated palm oil, hydrogenated castor oil, and hydrogenated rapeseed oil in combination, the finish effect is not impaired and the suppleness at the time of application is achieved. We found that a new effect of coconut oil can be obtained.
As described above, behenyl PG trimonium chloride, a higher alcohol having a linear alkyl group having 14 to 24 carbon atoms, a higher alcohol having a branched alkyl group having 14 to 24 carbon atoms, a hydrogenated palm oil, and a hydrogenated palm. By containing one or more selected from oil, hydrogenated palm oil, and hydrogenated rapeseed oil, a specific amount of an ester of a fatty acid having 10 to 22 carbon atoms and a monovalent alcohol having 1 to 2 carbon atoms, respectively. The product of the present invention has been completed by finding that it is excellent in richness at the time of application, familiarity at the time of application, excellent moistness and smoothness as a hair finishing effect, and excellent stability over time at low temperature.

In the present invention, the following components (A) to (E);
(A) Behenyl PG Trimonium Chloride 0.1 to 5.0% by mass
(B) Higher alcohol having a linear alkyl group having 14 to 24 carbon atoms 0.5 to 15.0% by mass
(C) Higher alcohol having an alkyl group of a branched chain having 14 to 24 carbon atoms 0.1 to 10.0% by mass
(D) One or more selected from hydrogenated coconut oil, hydrogenated palm oil, hydrogenated castor oil, hydrogenated rapeseed oil 0.1 to 10.0% by mass
(E) Ester of fatty acid having 10 to 22 carbon atoms and monohydric alcohol having 1 to 2 carbon atoms 0.05 to 5.0% by mass
To provide a hair cosmetic containing.

The present invention further provides a hair cosmetic containing silicone oil as a component (F).

The present invention provides a hair cosmetic in which the component (D) is one or more selected from hydrogenated coconut oil and hydrogenated palm oil.

The present invention provides a hair cosmetic in which the component (E) is one or more selected from ethyl oleate and ethyl olive fatty acid.

The present invention provides a hair cosmetic that is excellent in richness at the time of application, familiarity at the time of application, suppleness at the time of application, and as a hair finishing effect, excellent in moistness and smoothness, and excellent in stability over time at low temperature. do.

Hereinafter, the present invention will be described in detail. In this specification, when a numerical range is expressed by using "~", the range includes the numerical values at both ends.

Component (A): Behenyl PG Trimonium Chloride The behenyl PG trimonium chloride of the component (A) used in the present invention is composed of a hydrophilic group capable of exhibiting cationic properties by chlorine ion dissociation in water and an alkyl group having 22 carbon atoms. It is a hydroxyether-type cationic surfactant having a certain hydrophobic group and a hydroxypropyl moiety and having a structure represented by the following general formula (1).

_{C 22 H 45 -OCH 2 CH (} OH) CH 2 -N + (CH 3) 3 · Cl - ··· (1)

In the present invention, the component (A) is preferable in that it has good affinity and adsorptivity for hair, and is excellent in hair finish (moist feeling) and hair finish (smoothness). Although not particularly limited, as the component (A), Katinal BHC-60BE (Toho Chemical Industry Co., Ltd.) or the like can be used.

The content of the component (A) in the hair cosmetic of the present invention is 0.1 to 5.0% by mass (hereinafter, "mass%" is simply abbreviated as "%"). If the content of the component (A) is less than 0.1%, the suppleness at the time of application and the finish (moist feeling) of the hair may not be excellent. If the content of the component (A) exceeds 5.0%, the familiar feeling at the time of application may not be excellent. The content of the component (A) is preferably 0.2 to 3.0%, more preferably 0.5 to 2.0%, from the viewpoint of excellent hair finish (moist feeling) and hair finish (smoothness). preferable.

Component (B): Higher alcohol having a linear alkyl group having 14 to 24 carbon atoms The higher alcohol having a linear alkyl group having 14 to 24 carbon atoms of the component (B) used in the present invention is generally described below. The one represented by the formula (2) can be used.

R ¹ -OH ・ ・ ・ (2)
[In the formula, R ¹ represents a linear alkyl group having 14 to 24 carbon atoms. ]

The component (B) is not particularly limited, and specific examples thereof include myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, and cetostearyl alcohol. These can be used alone or in combination of two or more.
In the present invention, it is preferable to use the component (B) in that an excellent feeling of use is imparted without impairing the finishing effect. Among these, behenyl alcohol and cetostearyl alcohol are particularly preferable for obtaining an excellent usability.

The content of the component (B) in the hair cosmetic of the present invention is 0.5 to 15.0%. If the content of the component (B) is less than 0.5%, the richness at the time of application may not be excellent, and if the content of the component (B) exceeds 15.0%, the feeling of familiarity at the time of application may not be excellent. , It may not be excellent in stability over time at low temperature. The content of the component (B) is preferably 1.0 to 10.0%, more preferably 2.0 to 8.0%, from the viewpoint of excellent richness at the time of application and suppleness at the time of application.

Component (C): Higher alcohol having an alkyl group of a branched chain having 14 to 24 carbon atoms The higher alcohol having an alkyl group of a branched chain having 14 to 24 carbon atoms of the component (C) used in the present invention is generally described below. The one represented by the formula (3) can be used.

R ^2- OH ... (3)
[In the formula, R ² represents an alkyl group of a branched chain having 14 to 24 carbon atoms. ]

The component (C) is not particularly limited, and specific examples thereof include isostearyl alcohol, octyldodecanol, decyltetradecanol, and isocetyl alcohol. These can be used alone or in combination of two or more.
In the present invention, it is preferable to use the component (C) in that the stability at low temperature is improved without impairing the usability of the component (B). Among these, octyldodecanol and decyltetradecanol are particularly preferable in that they improve excellent low temperature stability.

The content of the component (C) in the hair cosmetic of the present invention is 0.1 to 10.0%. If the content of the component (C) is less than 0.1%, the finish (moist feeling) of the hair and the stability over time at low temperature may not be excellent, and the content of the component (C) exceeds 10.0%. In some cases, the suppleness at the time of application is not excellent. The content of the component (C) is preferably 0.2 to 5.0%, more preferably 0.3 to 4.0%, from the viewpoint of excellent stability over time at low temperatures.

Ingredient (D): One or more selected from coconut oil, coconut palm oil, coconut oil, rapeseed oil, coconut oil, coconut oil of the component (D) used in the present invention. One or more selected from palm oil, hydrogenated castor oil, and hydrogenated rapeseed oil are not particularly limited in origin, and can be obtained by watering an oil agent obtained from palm, palm, castor, and rapeseed. One or more selected from the ones.
The origin of the palm oil is not particularly limited, and may include those obtained from the flesh of oil palm and those obtained from the core in the inner pericarp (palm kernel oil).
The rapeseed oil is not particularly limited in origin, but may include rapeseed seed oil obtained from rapeseed seeds.
As for ingredient (D), "hydrangea palm oil", "hydrogen palm oil", and "hydrogen palm kernel oil" are listed in the "ingredient labeling name list" created by the Japan Cosmetic Industry Association. , "Hydrolified castor oil", "Hydrolified rapeseed seed oil" and the like can be used.
Among the components (D), one or more selected from hydrogenated coconut oil and hydrogenated palm oil are particularly preferable because they are excellent in familiarity at the time of application and stability over time at low temperature.

The content of the component (D) in the hair cosmetic of the present invention is 0.1 to 10.0%. If the content of the component (D) is less than 0.1%, the suppleness at the time of application may not be excellent, and if the content of the component (D) exceeds 10.0%, the hair finish (Smoothness) may not be excellent. The content of the component (D) is preferably 0.2% to 5.0%, more preferably 0.3% to 4%, from the viewpoint of excellent flexibility at the time of application.

Component (E): Ester of fatty acid having 10 to 22 carbon atoms and monovalent alcohol having 1 to 2 carbon atoms The component (E) used in the present invention is a fatty acid having 10 to 22 carbon atoms and 1 to 2 carbon atoms. It is an ester with a valent alcohol.
The component (E) used in the present invention is not particularly limited, but specifically, methyl laurate, ethyl laurate, methyl myristate, ethyl myristate, methyl palmitate, ethyl palmitate, methyl stearate, Ethyl stearate, methyl oleate, ethyl oleate, methyl isostearate, ethyl isostearate, methyl behenate, ethyl behenate and the like, as well as plant-derived esters containing these fatty acid chains can also be used and are specific. Examples thereof include avocado fatty acid ethyl, olive fatty acid ethyl, soybean oil fatty acid methyl, palm nucleus fatty acid ethyl, coconut oil fatty acid methyl and the like. These can be used alone or in combination of two or more.
Among these, one or more selected from ethyl oleate and ethyl olive fatty acid are particularly preferable because they are excellent in familiarity at the time of application.

The content of the component (E) in the hair cosmetic of the present invention is 0.05 to 5.0%. If the content of the component (E) is less than 0.05%, the familiar feeling at the time of application and the finish (smoothness) of the hair may not be excellent, and the content of the component (E) is 5.0%. If it exceeds, the richness at the time of application may not be excellent. Familiarity at the time of application From the viewpoint of excellent hair finish (smoothness), 0.1 to 2.5% is preferable, and 0.2 to 2.0% is more preferable.

The hair cosmetic of the present invention can further contain silicone oil as the component (F).
The silicone oil as the component (F) is not particularly limited, but specifically, low polymerization degree dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, Tetramethyltetrahydrogencyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alkoxy-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, amino-modified polysiloxane , Aminophenyl-modified polysiloxane, glycerin-modified polysiloxane, acrylic-modified polysiloxane, higher alkoxy-modified polysiloxane, higher fatty acid-modified polysiloxane, and the like. These can be used alone or in combination of two or more.
In the present invention, it is preferable to use the component (F) in combination because the hair finish (smoothness) and the hair finish (smoothness) are excellent without impairing the richness during use. Among these, dimethylpolysiloxane, methylphenylpolysiloxane, and amino-modified polysiloxane having a low degree of polymerization are particularly preferable because they are excellent in hair finish (smoothness) and hair finish (smoothness).

The content of the component (F) in the hair cosmetic of the present invention is not particularly limited, but is 0.1 to 20 from the viewpoint of excellent hair finish (moist feeling) and hair finish (smoothness). .0% is preferable, and 0.2 to 15.0% is more preferable.

Further, the hair cosmetic of the present invention is not particularly limited as long as it is used as a normal hair cosmetic, and can be used. In-bath products such as hair rinses, hair conditioners, hair masks, and scalp massagers, as well as non-rinse out baths such as hair milk, hair cream, hair essence, hair protectants, and hair styling products, for excellent usability and finish. Products and the like are preferred.

Further, the hair cosmetic of the present invention is preferably an O / W type emulsifier type, although the dosage form is not particularly limited as long as the constituent requirements are satisfied. The container form is not particularly limited as long as it is an ordinary hair cosmetic, but it can be used in a bottle container, a dispenser container, a tube container, a jar container, and an aerosol container from the viewpoint of usability to be applied to hair. .. When used as an aerosol container, the gas (propellant) to be filled is not particularly limited, but for example, a hydrocarbon, a halogenated hydrocarbon, or the like is usually used for cosmetics. can. Specifically, propane, isobutane, normal butane, isopentan, liquefied petroleum gas (hereinafter abbreviated as "LPG"), dimethyl ether (hereinafter abbreviated as "DME"), dichlorodifluorethane, trichloromonofluorethane, Examples thereof include nitrogen and carbon dioxide. Among them, LPG and DME can be uniformly applied on the skin, and preferably one or two or more of these propellants can be appropriately selected and used.

In addition to the above-mentioned ingredients, the hair cosmetics of the present invention include ordinary cosmetics, non-pharmaceutical products, external pharmaceuticals, etc. within the quantitative and qualitative range that does not impair the effects of the present invention according to the purpose. Ingredients used in the formulation of, for example, purified water, hot spring water, water such as deep water, alcohols, higher alcohols other than ingredients (B) and (C), ingredients other than ingredients (D), (E) and (F). General-purpose ingredients such as oils, powders for texture adjustment or coloring, surfactants other than component (A), water-soluble polymers, film-forming agents, oil-based gelling agents, resins, inclusion compounds, moisturizers , Antibacterial / preservatives, deodorants, salts, UV absorbers, antioxidants, chelating agents, anti-fading agents, defoaming agents, refreshing agents, propellants, fragrances, pigments, etc. It can contain propane, butane, isobutane, isopentan, dimethyl ether, carbon dioxide, nitrogen and the like.

The method for producing the hair cosmetic of the present invention is not particularly limited, and is prepared by a conventional method. For example, it can be prepared by uniformly emulsifying the components (A) to (E) and other components as needed.

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

Below, hair cosmetics were manufactured and evaluated.
Examples 1 to 30 and Comparative Examples 1 to 12; Hair cosmetics Hair cosmetics are prepared by the compositions shown in Tables 1 to 4 and the following production methods, and by the methods shown below, <1> richness at the time of application. , <2> Familiarity when applied, <3> Suppleness when applied, <4> Hair finish (moist feeling), <5> Hair finish (smoothness), <6> Stability over time at low temperature The items were evaluated and judged by the evaluation method and judgment criteria shown below. The results are also shown in Tables 1 to 4. Further, in the following, unless otherwise specified, the component corresponding to the component (D) is indicated by the display name listed in the "component display name list" prepared by the Japan Cosmetic Industry Association.

(Production method)
A: No. 1 to 14 were uniformly heated, mixed and dissolved.
B: No. 15, 16 and 18 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled to room temperature, and No. 17 was added to obtain a hair cosmetic.

[Evaluation method 1]: <1> Rich feeling at the time of application, <2> Familiar feeling at the time of application, <3> Suppleness at the time of application, <4> Hair finish (moist feeling), <5> Hair finish (Smoothness)
We asked 20 cosmetics specialist panels to use the hair cosmetics shown in Tables 1 to 4, and <1> the richness of the application, <2> the familiarity of the application, and <3> the suppleness of the application. Was evaluated on a 5-point scale according to the evaluation criteria of (a), (b), and (c) below. In addition, <4> hair finish (moist feeling) and <5> hair finish (smoothness) were evaluated on a 5-point scale according to the following evaluation criteria (d) and (e). After that, each evaluation was judged according to the following (f) judgment criteria.

(A) [Evaluation Criteria] <1> Rich feeling at the time of application The richness was evaluated as the feeling of use when the hair cosmetic was picked up and applied to the hair.
Five-level evaluation criteria:
[Score]: [Evaluation result]
5 points: Sufficient richness at the time of application 4 points: Almost sufficient richness at the time of application 3 points: Slightly insufficient richness at the time of application 2 points: Very insufficient richness at the time of application 1 point: Insufficient richness at the time of application (b) [Evaluation criteria] <2> Familiar feeling at the time of application The familiar feeling at the time of application was evaluated as the feeling of use when the hair cosmetic was picked up and applied to the hair.
Five-level evaluation criteria:
[Score]: [Evaluation result]
5 points: Sufficient familiarity at the time of application 4 points: Almost sufficient familiarity at the time of application 3 points: Familiarity at the time of application is a little insufficient 2 points: Familiarity at the time of application is not enough 1 point: Insufficient familiarity during application (c) [Evaluation criteria] <3> Flexibility during application 5 grades Evaluation criteria:
The suppleness of the hair was evaluated as a feeling of use when the hair cosmetic was picked up and applied to the hair.
[Score]: [Evaluation result]
5 points: Sufficient hair suppleness at the time of application 4 points: Almost sufficient hair suppleness at the time of application 3 points: Hair suppleness at the time of application is slightly insufficient 2 points: Hair at the time of application Insufficient suppleness 1 point: Insufficient suppleness of hair at the time of application (d) [Evaluation criteria] <4> Hair finish (moist feeling)
Five-level evaluation criteria:
The finish (moist feeling) of the hair after picking up the hair cosmetic, applying it to the hair, rinsing it, and air-drying it was evaluated.
[Score]: [Evaluation result]
5 points: Sufficient moist feeling of the finished hair 4 points: Almost enough moist feeling of the finished hair 3 points: Moist feeling of the finished hair Slightly insufficient 2 points: Moist feeling of the finished hair Not enough 1 point: Insufficient moist feeling of hair at the time of finish (e) [Evaluation criteria] <4> Hair finish (smoothness)
Five-level evaluation criteria:
The finish (smoothness) of the hair after picking up the hair cosmetic, applying it to the hair, rinsing it, and air-drying it was evaluated.
[Score]: [Evaluation result]
5 points: Sufficient smoothness of the finished hair 4 points: Almost sufficient smoothness of the finished hair 3 points: Slightly insufficient smoothness of the finished hair 2 points: Smoothness of the finished hair Not enough 1 point: The smoothness of the hair at the time of finishing is insufficient (to) Judgment criteria [Judgment]: [Average score]
◎: 4.5 or more ○: 3.5 or more and less than 4.5 Δ: 1.5 or more and less than 3.5 ×: less than 1.5

[Evaluation method 2]: <6> Stability over time at low temperature A sample when the produced sample is filled in a transparent glass bottle, placed in a constant temperature bath set at 0 ° C., allowed to stand for 1 month, and then returned to room temperature. The condition of was visually confirmed, and (g) the judgment was made according to the judgment criteria.
(G) Judgment criteria [Judgment]: [Evaluation result]
◎: No lumps or deterioration of texture is seen.
◯: There is a slight deterioration in texture and texture.
Δ: There are many cases of lumps and deterioration of texture.
×: Poor texture is observed throughout

As is clear from the results of Tables 1 to 4, the hair cosmetics of Examples 1 to 30 have "richness at the time of application", "familiarity at the time of application", "suppleness at the time of application", and "hair". The results were good for each item of "finish (moist feeling)", "hair finish (smoothness)", and "stability over time at low temperature".
Comparative Example 1 containing no component (A) is inferior in "suppleness at the time of application", "hair finish (moist feeling)", "hair finish (smoothness)", and "low temperature stability over time". rice field.
Comparative Example 2 containing no component (D) was inferior in "richness at the time of application", "suppleness at the time of application", "hair finish (smoothness)", and "stability over time at low temperature".
In Comparative Example 3 in which the content of the component (A) is less than 0.1%, "suppleness at the time of application", "hair finish (moist feeling)", and "hair finish (smoothness)" are inferior. Was there.
In Comparative Example 4 in which the content of the component (A) exceeded 5.0%, "familiarity at the time of application", "hair finish (smoothness)", and "stability over time at low temperature" were inferior.
In Comparative Example 5 in which the content of the component (B) was less than 0.5%, "richness at the time of application", "suppleness at the time of application", and "hair finish (moist feeling)" were inferior. ..
In Comparative Example 6 in which the content of the component (B) exceeded 15.0%, "familiarity at the time of application", "hair finish (smoothness)", and "stability over time at low temperature" were inferior.
In Comparative Example 7 in which the content of the component (C) was less than 0.1%, "hair finish (moist feeling)" and "stability over time at low temperature" were inferior.
In Comparative Example 8 in which the content of the component (C) exceeded 10.0%, "suppleness at the time of application" and "hair finish (smoothness)" were inferior.
In Comparative Example 9 in which the content of the component (D) was less than 0.1%, "suppleness at the time of application" and "hair finish (moist feeling)" were inferior.
In Comparative Example 10 in which the content of the component (D) exceeded 10.0%, "hair finish (smoothness)" and "stability over time at low temperature" were inferior.
In Comparative Example 11 in which the content of the component (E) was less than 0.05%, "familiarity at the time of application" and "hair finish (smoothness)" were inferior.
In Comparative Example 12 in which the content of the component (E) exceeded 5.0%, "richness at the time of application" and "suppleness at the time of application" were inferior.

Example 31: Hair rinse (ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 1.5
2. Behenyl trimethylammonium chloride 0.5
3. 3. Stearyl trimethylammonium chloride 0.5
4. Distearyl Chloride Dimethyl Ammonim 0.2
5. Dicocoyl ethyl hydroxyethylmonium metosulfate 0.1
6. Setostearyl alcohol 2.0
7. Cetanol 1.0
8. Stearyl alcohol 1.0
9. Behenyl alcohol 1.0
10. Octyldodecanol 1.5
11. Decyltetradecanol 0.5
12. Isostearyl alcohol 0.5
13. Oleyl alcohol 0.3
14. Hydrogenated coconut oil 1.8
15. Hydrogenated palm oil 0.2
16. Hydrogenated castor oil 0.2
17. Hydrogenated polyisobutene 0.5
18. Cetyl ethylcaproate 1.5
19. Triethylhexanoin 2.0
20. Ethyl oleate 0.3
21. Olive fatty acid ethyl 0.2
22. Dimethicone (10 mPa · s at 25 ° C) 3.5
23. Dimethicone (1 million mPa · s at 25 ° C) 0.5
24. Dimethiconol (1 million mPa · s at 25 ° C) 0.5
25. Amodimethicone 0.8
26. Glycerin 1.5
27. Propylene glycol 3.5
28.1,3-butylene glycol 0.5
29.1,3-Propanediol 1.0
30. Tripropylene glycol 0.5
31. Citric acid 0.01
32. Na citrate 0.01
33. Glycine 0.1
34. Lysine dilauroyl glutamate Na 0.1
35. Phosphoryl choline glycol polyacrylate 0.1
36. Fragrance 0.3
37. Remaining amount of purified water (manufacturing method)
A: No. 1 to 25 were uniformly heated, mixed and dissolved.
B: No. 26 to 35 and 37 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 36 was added to obtain a hair rinse.

The hair rinse of Example 31 obtained as described above has a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), a hair finish (smoothness), and a low temperature. It was good for each item of stability over time.

Example 32: Hair mask (ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 2.5
2. Behenyl trimethylammonium chloride 1.0
3. 3. Dicocoyl chloride dimethylammonim 0.5
4. Distearyl Chloride Dimethyl Ammonim 0.2
5. Dicocoyl ethyl hydroxyethylmonium metosulfate 0.1
6. Stearyl PG Trimonium Chloride 0.4
7. Setostearyl alcohol 6.0
8. Stearyl alcohol 1.0
9. Behenyl alcohol 1.5
10. Octyldodecanol 2.0
11. Decyltetradecanol 1.0
12. Isostearyl alcohol 0.2
13. Oleic acid 0.3
14. Hydrogenated coconut oil 2.0
15. Hydrogenated palm oil 0.2
16. Vaseline 0.2
17. Heavy liquid isoparaffin 0.5
18. Polypropylene 0.4
19. Dextrin isostearate 0.5
20. Ethyl oleate 0.5
21. Olive fatty acid ethyl 0.5
22. Dimethicone (100 mPa · s at 25 ° C) 5.0
23. Dimethiconol (100,000 mPa · s at 25 ° C) 1.0
24. (Bisbutyrroxyamidimethicone / PEG-60) Copolymer 0.5
25. Amodimethicone 0.5
26. Diglycerin 1.5
27. PEG-8 2.0
28. PEG-45M 0.2
29. Dipropylene glycol 1.0
30. Ethanol 0.5
31. Lactic acid 0.01
32. Na lactate 0.01
33. Isostearoyl Hydrolyzed Collagen AMPD 0.1
34. PCA-Na 0.05
35. Polyquaternium-51 (Note 1) 0.1
36. Polyquaternium-61 (Note 2) 0.1
37. Polyquaternium-65 (Note 3) 0.3
38. Polyquaternium-104 0.1
39. Polyquaternium-64 (Note 4) 0.1
40. Fragrance 0.3
41. Remaining amount of purified water (Note 1) LIPIDURE-PMB (BG) (manufactured by NOF CORPORATION)
(Note 2) LIPIDURE-NR (manufactured by NOF CORPORATION)
(Note 3) LIPIDURE-A (manufactured by NOF CORPORATION)
(Note 4) LIPIDURE-C (manufactured by NOF CORPORATION)
(Production method)
A: No. 1 to 25 were uniformly heated, mixed and dissolved.
B: No. 26 to 39 and 41 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 40 was added to obtain a hair mask.

The hair mask of Example 32 obtained as described above has a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), a hair finish (smoothness), and a low temperature. It was good for each item of stability over time.

Example 33: Hair treatment (ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 2.0
2. Behenyl trimethylammonium chloride 0.5
3. 3. Distearyl Chloride Dimethyl Ammonim 0.5
4. Setostearyl alcohol 4.5
5. Behenyl alcohol 1.5
6. Octyldodecanol 1.0
7. Hydrogenated coconut oil 4.0
8. Ethyl oleate 1.0
9. Phytosteryl oleate 1.5
10. Daimage Reno Rail Hydrogenated Rosin Condensate 0.3
11. Dimer dilinoleic acid dimer dilinoleyl bisisostearyl 0.1
12. Dimer dilinoleate di (isostearyl / phytosteryl) 0.2
13. Phytosteryl isosterate 0.3
14. Pentaerythrityl tetraisosterate 1.0
15. Pentaerythrityl tetraethylcaproate 0.2
16. Hexa (hydroxystearic acid / stearic acid / rosin acid)
Dipentaerythrityl 0.2
17. Cyclohexane-1,4-dicarboxylic acid bisethoxydiglycol 0.2
18. (Icosanedioic acid / tetradecanedioic acid) Polyglyceryl-10 0.3
19. Isononyl isononanoate 0.5
20. Isotridecyl isononanoate 0.5
21. Phenyltrimethicone 5.0
22. Dimethicone (10 million mPa · s at 25 ° C) 0.2
23. Diphenylsiloxyphenyltrimethicone 1.0
24. (Bisisobutyl PEG-14 / Amodimethicone) Copolymer 0.5
25. Bis (Hydroxy / Methoxy) Amodimethicone 0.5
26. Methylgluces-10 1.5
27. PPG-10 Methyl Glucose 2.0
28. Glucosyl trehalose 0.2
29. PPG-52 Butyl 1.0
30. Isopropanol 0.5
31. Malic acid 0.01
32. Na malate 0.01
33. (Dihydroxymethylsilylpropoxy) Hydroxypropyl
Hydrolyzed silk 0.1
34. Diglucosyl gallic acid 0.05
35. Polyquaternium-6 (Note 5) 0.1
36. Polyquaternium-7 (Note 6) 0.1
37. Polyquaternium-22 (Note 7) 0.1
38. Polyquaternium-39 (Note 8) 0.1
39. Gua-hydroxypropyltrimonium chloride (Note 9) 0.1
40. Fragrance 0.3
41. Remaining amount of purified water (Note 5) Merquat 100 Polymer (manufactured by Japan Lubrizol)
(Note 6) Merquat 550 Polymer (manufactured by Japan Lubrizol)
(Note 7) Merquat 295 Polymer (manufactured by Japan Lubrizol)
(Note 8) Merquat 3330PR Polymer (manufactured by Japan Lubrizol)
(Note 9) JAGUAR C-14S (manufactured by Solvay SA)
(Production method)
A: No. 1 to 25 were uniformly heated, mixed and dissolved.
B: No. 26 to 39 and 41 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 40 was added to obtain a hair treatment.

The hair treatment of Example 33 obtained as described above includes a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), and a hair finish (smoothness). It was good for each item of stability over time at low temperature.

Example 34: Aerosol foam hair treatment stock solution (ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 1.0
2. Behenyl trimethylammonium chloride 0.5
3. 3. Distearyl Chloride Dimethyl Ammonim 0.5
4. Setostearyl alcohol 1.5
5. Myristyl alcohol 0.5
6. Octyldodecanol 0.8
7. Hydrogenated coconut oil 1.5
8. Ethyl oleate 0.3
9. Isopropyl myristate 1.5
10. Ethylhexyl methoxycinnamate 0.3
11. Tocopherol acetate 0.1
12. Natural Vitamin E 0.1
13. Astaxanthin 0.05
14. Ceramide 2 0.05
15. Ceramide 3 0.05
16. Cholesterol 0.1
17. Phytosterol 0.1
18. Olive squalane 0.1
19. Bisethylhexyloxyphenol methoxyphenyl triazine 0.1
20. Lauroyl sarcosine isopropyl 0.5
21. Light liquid isoparaffin 1.0
22. Dimethicone (6 mPa · s at 25 ° C) 0.2
23. (Dimethicone / Phenylvinyl Dimethicone) Cross Polymer 0.5
24. (Dimethicone / Porglycerin-3) Crosspolymer 0.5
25. (Dimethicone / (PEG-10 / 15) Cross Polymer 0.5
26. Alanine 0.1
27. Arginine 0.1
28. Aspartic acid 0.1
29. Acetyl hydroxyproline 0.1
30. Cysteine 0.1
31. Na Phosphate 0.01
32. Phosphoric acid 2Na 0.01
33. (Vinylpyrrolidone / VA) Copolymer 0.1
34. PVP 0.1
35. Hydroxypropyltrimonium hyaluronate 0.1
36. Succinic acid 0.01
37. Polyquaternium-11 0.1
38. (Acrylate / Acrylic acid (C1-18) / Alkyl (C1-8)
Acrylamide) Copolymer 0.1
39. Polyurethane-14 0.1
40. Fragrance 0.3
41. Remaining amount of purified water 42. Water-soluble collagen (Note 10) 0.01
43. Sodium hyaluronate (Note 11) 0.01
44. Sodium chondroitin sulfate (Note 12) 0.01
45. Rosemary water (Note 13) 0.01
46. Yuzu extract (Note 14) 0.01
47. Cha extract (Note 15) 0.01
48. Tea leaf extract (Note 16) 0.01
49. Deep ocean water (Note 17) 0.01
50. Resveratrol 0.001
51. Caffeine 0.001
(Note 10) PANCOGEN MARINE (manufactured by GATTEFOSSE)
(Note 11) Hyaluronic acid FCH-SU (manufactured by Kikkoman Food Chemifa)
(Note 12) Sodium chondroitin sulfate (manufactured by Maruha Nichiro Foods Co., Ltd.)
(Note 13) Rosemary water (manufactured by Koei Kogyo Co., Ltd.)
(Note 14) Yuzu extract-J (manufactured by Maruzen Pharmaceuticals Co., Ltd.)
(Note 15) Green tea extract BG (manufactured by Maruzen Pharmaceuticals Co., Ltd.)
(Note 16) Black tea liquid (manufactured by Ichimaru Falcos)
(Note 17) Deep sea water (manufactured by Kokando Co., Ltd.)
(Production method)
A: No. 1 to 25 were uniformly heated, mixed and dissolved.
B: No. 26-39, 41-51 were uniformly heated, mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 40 was added to obtain a stock solution.
E: The undiluted solution and the propellant LPG 0.45 were filled in an aerosol can with the undiluted solution: propellant = 90:10 to obtain an aerosol foam hair treatment.

The aerosol foam hair treatment of Example 34 obtained as described above has a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), and a hair finish (smoothness). ), It was good for each item of stability over time at low temperature.

Example 35: Hair cream (ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 1.0
2. Dicocoyl chloride dimethylammonim 0.3
3. 3. Stearyltrimethylammonim bromide 0.2
4. Benzalkonium chloride 0.2
5. Alkyl (C12, C14) Oxyhydroxypropyl Arginine
HCL 0.1
6. Setostearyl alcohol 1.5
7. Cetanol 1.0
8. Myristyl alcohol 1.0
9. Octyldodecanol 0.5
10. Jojoba alcohol 0.5
11. Hydrogenated coconut oil 0.5
12. Hydrogenated palm kernel oil 0.5
13. Hydrogenated rapeseed oil 0.3
14. Hydrogenated Polydecene 1.0
15. Bacil alcohol 0.2
16. Squalene 0.2
17. Microcrystalline wax 0.1
18. Rice bran 0.2
19. Candelilla Row 0.2
20. Ethyl oleate 0.3
21. Olive fatty acid ethyl 0.2
22. Carnauba wax 0.1
23. Beeswax 0.2
24. Dimethicone (10 million mPa · s at 25 ° C) 0.5
25. Light liquid isoparaffin 1.0
26. Pentylene glycol 1.5
27. Erythritol 0.5
28. Caprylyl glycol 0.5
29.1,3-Propanediol 1.0
30. Tripropylene glycol 0.5
31. Succinic acid 0.01
32. Succinic acid 2Na 0.01
33. Sorbitol 0.1
34. Fructose 0.1
35. Quotanium-33 (Note 18) 0.1
36. Fragrance 0.3
37. Remaining amount of purified water
(Note 18) Cation NH (manufactured by Nippon Fine Chemical Co., Ltd.)
(Production method)
A: No. 1 to 26 were uniformly heated, mixed and dissolved.
B: No. 27 to 35 and 37 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 36 was added to obtain a hair cream.

The hair cream of Example 35 obtained as described above has a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), and a hair finish (smoothness). It was good for each item of stability over time at low temperature.

Example 36: Hair milk (ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 0.8
2. Stearyl trimethylammonium chloride 0.2
3. 3. PEG-5 stealtrimonium chloride 0.1
4. Cocoyl Arginine Ethyl PCA 0.2
5. Stearamidopropyl dimethylamine 0.1
6. Setostearyl alcohol 1.5
7. Cetanol 0.5
8. Octyldodecanol 1.0
9. Hydrogenated coconut oil 1.0
10. Ethyl oleate 0.5
11. Isononyl isononanoate 0.3
12. Ethylhexyl palmitate 0.5
13. Polyhydroxystearic acid 0.1
14. Tridecylic isononanoate 0.3
15. Trimethylolpropane triisostearate 0.2
16. Tritridecyl trimeritoate 0.2
17. Dicapric acid PG 0.5
18. Isostearic acid PG 0.5
19. Diethylhexyl succinate 0.5
20. Di lauroyl glutamate (octyldodecyl / phytosteryl /
Behenil 0.3
21. Di (phytosteryl / octyldodecyl) lauroyl glutamate 0.2
22. Laurolyl sarcosine isopropyl 0.4
23. Methyltrimethicone 0.5
24. Dimethiconol (1000 mPa · s at 25 ° C) 0.5
25. Trimethylsiloxysilicic acid 0.2
26. Propylene glycol 1.5
27. Glucose 0.1
28. Sucrose 0.1
29. Glycylglycine 0.1
30. Citrulline 0.1
31. Threonine 0.01
32. Valine 0.01
33. Histidine 0.1
34. Phenylalanine 0.1
35. Lactic acid 0.1
36. Fragrance 0.3
37. Remaining amount of purified water
(Production method)
A: No. 1 to 25 were uniformly heated, mixed and dissolved.
B: No. 26 to 35 and 37 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 36 was added to obtain hair milk.

The hair milk of Example 36 obtained as described above has a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), a hair finish (smoothness), and a low temperature. It was good for each item of stability over time.

Example 37: Hair Essence (Ingredient) (%)
1. 1. Behenyl PG Trimonium Chloride 1.0
2. Stearyl trimethylammonium chloride 0.5
3. 3. Behentrimonium metosulfate 0.2
4. Palmamide propyltrimonium metosulfate 0.2
5. Behenamide propyl dimethylamine 0.1
6. Setostearyl alcohol 2.0
7. Octyldodecanol 1.0
8. Ethyl oleate 1.0
9. Hydrogenated coconut oil 0.5
10. Hydrogenated palm oil 0.5
11. Olive oil 0.2
12. Meadowfoam oil 0.2
13. Macadamia nut oil 0.2
14. Argania spinosa kernel oil 0.2
15. Camellia oil 0.2
16. Sage oil 0.1
17. Lavender oil 0.1
18. Jojoba seed 1.0
19. Almond oil 1.0
20. Avocado oil 0.1
21. Rice bran oil 0.2
22. Coix oil 0.1
23. Astropotassium Murmur Seed Oil 0.1
24. Dimethicone (100 mPa · s at 25 ° C) 0.5
25. Amodimethicone 0.1
26. Glycosyl trehalose 0.5
27. Trehalose 0.1
28. Hydroxypropyl Methyl Celose 0.05
29. Hydroxypropyl Methyl Cellose Stearoxy Ether 0.05
30. Xanthan gum 0.01
31. PVP 0.1
32. Hydroxyethyl cellulose 0.01
33. Hydrolyzed hyaluronic acid 0.1
34. Ectoine 0.1
35. Citric acid 0.1
36. Fragrance 0.3
37. Remaining amount of purified water
(Production method)
A: No. 1 to 25 were uniformly heated, mixed and dissolved.
B: No. 26 to 35 and 37 were uniformly heated and mixed and dissolved.
C: A was added to B and emulsified and mixed.
D: C was cooled, and No. 36 was added to obtain a hair essence.

The hair essence of Example 37 obtained as described above includes a rich feeling at the time of application, a familiar feeling at the time of application, a suppleness at the time of application, a hair finish (moist feeling), and a hair finish (smoothness). It was good for each item of stability over time at low temperature.

Claims (4)

The following components (A) to (E);
(A) Behenyl PG Trimonium Chloride 0.1 to 5.0% by mass
(B) Higher alcohol having a linear alkyl group having 14 to 24 carbon atoms 0.5 to 15.0% by mass
(C) Higher alcohol having an alkyl group of a branched chain having 14 to 24 carbon atoms 0.1 to 10.0% by mass
(D) One or more selected from hydrogenated coconut oil, hydrogenated palm oil, hydrogenated castor oil, hydrogenated rapeseed oil 0.1 to 10.0% by mass
(E) Ester of fatty acid having 10 to 22 carbon atoms and monohydric alcohol having 1 to 2 carbon atoms 0.05 to 5.0% by mass
Hair cosmetics containing. The hair cosmetic according to claim 1, further containing silicone oil as the component (F). The hair cosmetic according to claim 1 or 2, wherein the component (D) is one or more selected from hydrogenated coconut oil and hydrogenated palm oil. The hair cosmetic according to any one of claims 1 to 3, wherein the component (E) is one or more selected from ethyl oleate and ethyl olive fatty acid.