JP6927112B2 - 半導体装置の製造方法 - Google Patents
半導体装置の製造方法 Download PDFInfo
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- JP6927112B2 JP6927112B2 JP2018059629A JP2018059629A JP6927112B2 JP 6927112 B2 JP6927112 B2 JP 6927112B2 JP 2018059629 A JP2018059629 A JP 2018059629A JP 2018059629 A JP2018059629 A JP 2018059629A JP 6927112 B2 JP6927112 B2 JP 6927112B2
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Description
図1は、半導体装置100の断面の一部を示す模式図である。なお、図1及び以降の模式図は、半導体装置100の技術的特徴をわかりやすく示すための図であり、各部の寸法を正確に示すものではない。図1には、説明を容易にするために、相互に略直交するXYZ軸が図示されている。図1のXYZ軸は、他の図のXYZ軸に対応する。なお、以降の説明では、+Z軸方向側を「上」又は「上側」とも呼ぶ。
・イオン電流:1μA〜10μA
・注入エネルギー:150keV〜250keV
・注入角度(オフ角):基板表面の(0001)面の法線方向に対し、7度
図13は、第2実施形態の半導体装置200の断面の一部を示す模式図である。半導体装置200は、p型不純物堆積領域115上に積層された、p型半導体層116を備える。p型半導体層116は、p型不純物堆積領域115上への窒化ガリウム(GaN)系半導体の選択成長によって形成された構造である。本実施形態では、p型半導体層116は、マグネシウム(Mg)をアクセプタ元素として含有する。本実施形態では、p型半導体層116に含まれるマグネシウム(Mg)濃度は、4E18cm−3以下である。本実施形態では、p型半導体層116の厚さは、1nm以上10nm以下である。半導体装置200のその他の構成は、第1実施形態の半導体装置100と同様であるため説明を省略する。
図16は、第3実施形態の半導体装置300の断面の一部を示す模式図である。図16には、半導体装置300のうち、MOSFETとして機能する素子領域R1と、素子領域R1を囲うようにして設けられた終端領域R2と、が示されている。
上記実施形態では、第1溝部121の側部s及び底部bにデルタドーピングによりp型不純物が堆積されているが、第1溝部121の側部s及び底部bへのp型不純物の堆積は、スパッタ法や、蒸着法を用いて行われてもよく、p型不純物を含有する酸化膜を第1溝部121の側部s及び底部bに形成することにより行われてもよい。
イオン注入工程(図2、図14、ステップS40)において、2価のp型不純物を用いてイオン注入が行われてもよい。同じイオン注入濃度であっても、1価のp型不純物を用いる場合と比較して、注入エネルギーを低減することができ、イオン電流を低減することができる。そのため、イオン注入によって半導体に与えられるダメージをより低減することができ、ホール濃度をより高めることができる。
イオン注入工程(図2、図14、ステップS40)では、1回のイオン注入工程における合計のイオン注入濃度が1E19cm−3以下となればよく、注入エネルギーを異ならせて複数回イオン注入を行う多重注入法によりイオン注入が行われてもよい。注入エネルギーは、20keV、80keV、200keV・・・のように次第に大きくしてもよいし、各エネルギーにおけるイオン注入濃度を異ならせてもよい。多重注入を行うことにより、p型半導体領域117のZ方向における、p型不純物の濃度分布を均一にすることができる。すなわち、イオン注入されたp型不純物の濃度分布を、ボックスプロファイルにすることができる。
イオン注入工程(図2、図14、ステップS40)では、イオンの入射方向を第1溝部121の底部bの結晶面に対し垂直にイオン注入する、チャネリング条件でイオン注入が行われてもよいし、非チャネリング条件でイオン注入が行われてもよい。チャネリング条件でイオン注入を行うことにより、イオン注入深さを増加させることができる。非チャネリング条件でイオン注入を行うことにより、イオン注入深さがばらつくことを抑制することができ、複数の半導体装置を製造する場合において、半導体装置間でのイオン注入深さがばらつくことを抑制することができる。
第1溝部121は、第1半導体層111内に底部bが位置していれば、第3半導体層113を貫通していなくともよい。第1溝部121は、第2半導体層112上に第3半導体層113が積層されていない部位に形成されてもよい。この場合には、第1溝部121内に、第2半導体層112にオーミック接触する第1電極としてのpボディ電極が形成されてもよい。半導体装置100は、第2半導体層112にオーミック接触する電極と、第3半導体層113にオーミック接触する電極と、を別の電極として備えていてもよい。
第1溝部121内に、第1電極141が形成されなくともよい。この場合には、第1溝部121内は、例えば絶縁膜130で覆われてもよい。また、第1溝部121と異なる他の部位に、第2半導体層112に接触する電極が形成されてもよい。
第1実施形態において、イオン注入工程(図2、ステップS40)が行われた後に、p型不純物の堆積工程(図2、ステップS30)が行われてもよい。また、第2実施形態において、イオン注入工程(図14、ステップS40)が行われた後に、p型不純物の堆積工程(図14、ステップS30)及び選択成長工程(図14、ステップS35)が行われてもよい。このようにしても、第1溝部121の側部s及び底部bにp型不純物を堆積することによって、高濃度n型不純物領域を補償することができる。また、第1溝部121を介したイオン注入によって、第1半導体層111内にp型半導体領域117を形成することができる。また、第1溝部121の側部sの一部は第2半導体層112内に位置しているため、第1溝部121の側部sの一部における第2半導体層112とイオン注入によって形成されたp型半導体領域117とで、高濃度n型不純物領域を補償することができる。その結果、第1溝部121近傍に電圧が印加された場合に空乏層が広がるので、半導体装置100の耐圧を向上させることができる。
第2溝部形成工程(図2,14、ステップS80)は、第1溝部形成工程(図2、図14、ステップS20)の前に行われてもよい。また、上記実施形態において、ウエットエッチングが用いられた工程では、ウエットエッチングに代えてドライエッチングが行われてもよい。また、保護膜形成工程(図2、図14、ステップS50)は省略されてもよい。熱処理工程(図2、図14、ステップS60)は、第2溝部形成工程(図2、ステップS80)の後に行われてもよい。
イオン注入工程(図2、図14、ステップS40)では、第1溝部121上に、窒化アルミニウム(AlN)、窒化インジウム(InN)、窒化アルミニウムガリウム(AlGaN)、窒化インジウムアルミニウム(InAlN)、窒化インジウムアルミニウムガリウム(InAlGaN)、ダイヤモンドライクカーボン等のスルー膜が形成されてもよい。このようにすれば、イオン注入により、第1溝部121の表面(側部s及び底部b)が汚染されることを抑制することができる。
本開示が適用される半導体装置は、上述の実施形態で説明したトレンチMOSFETに限られず、イオン注入によってp型半導体領域が形成された半導体装置であればよく、例えば、ショットキーバリアダイオード、接合型トランジスタ、バイポーラトランジスタ、絶縁ゲートバイポーラトランジスタ(IGBT:Insulated Gate Bipolar Transistor)、MESFET(metal-semiconductor field effect transistor)及びサイリスタなどであってもよい。
100a、100b、100c、100d、100e、100f、100g、100h、100i、100j、200a…中間製品
110…基板
111…第1半導体層
112…第2半導体層
113…第3半導体層
115…p型不純物堆積領域
116…p型半導体層
117…p型半導体領域
118a…p型オーミック電極
118b…n型オーミック電極
119…積層体
121…第1溝部
121p…第1溝部形成領域
122…第2溝部
122p…第2溝部形成領域
123…第3溝部
130…絶縁膜
141…第1電極
142…第2電極
143…第3電極
310…第1マスク
310p…絶縁膜
315…第2マスク
315p…絶縁膜
320、325…レジストパターン
335…保護膜
b…第1溝部の底部
b1…第2溝部底部
s…第1溝部の側部
s1…第2溝部の側部
Claims (8)
- 半導体装置の製造方法であって、
n型不純物を含有する窒化ガリウム(GaN)系の第1半導体層と、前記第1半導体層に積層され、p型不純物を含有する窒化ガリウム(GaN)系の第2半導体層とを含む積層体に対し、前記第1半導体層内に底部が位置する第1溝部を形成する、第1溝部形成工程と、
前記第1溝部の側部及び前記底部にp型不純物を堆積させる堆積工程と、
前記第1溝部を介して、p型不純物を前記第1半導体層にイオン注入する、イオン注入工程と、を備える、半導体装置の製造方法。 - 請求項1に記載の半導体装置の製造方法であって、
前記堆積工程では、デルタドーピングにより、前記第1溝部の前記側部及び前記底部にp型不純物を堆積させる、半導体装置の製造方法。 - 請求項1又は請求項2に記載の半導体装置の製造方法であって、
前記堆積工程の後に、前記イオン注入工程を行う、半導体装置の製造方法。 - 請求項1から請求項3までのいずれか一項に記載の半導体装置の製造方法であって、
前記堆積工程の後、前記第1溝部上にp型不純物を含有する窒化ガリウム(GaN)系の半導体層を成長させる、成長工程をさらに備える、半導体装置の製造方法。 - 請求項1から請求項4までのいずれか一項に記載の半導体装置の製造方法であって、
前記第1溝部形成工程では、前記第1溝部を形成する領域が開口したマスクを用いて前記第1溝部を形成し、
前記イオン注入工程では、前記マスクを用いて、前記イオン注入を行う、半導体装置の製造方法。 - 請求項1から請求項5までのいずれか一項に記載の半導体装置の製造方法であって、
前記堆積工程及び前記イオン注入工程が行われた後の前記第1溝部に第1電極を形成する、第1電極形成工程をさらに備える、半導体装置の製造方法。 - 請求項1から請求項6までのいずれか一項に記載の半導体装置の製造方法であって、
前記積層体に対し、前記第2半導体層を貫通し前記第1半導体層内に底部が位置する、第2溝部を形成する、第2溝部形成工程と、
前記第2溝部に第2電極を形成する工程であって、前記第2電極はゲート電極である、第2電極形成工程と、をさらに備える、半導体装置の製造方法。 - 請求項7に記載の半導体装置の製造方法であって、
前記第2溝部形成工程では、前記第1溝部又は前記第1溝部に積層された構造をアライメントマークとして用いて、前記第2溝部を形成する、半導体装置の製造方法。
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JP3494880B2 (ja) * | 1998-03-26 | 2004-02-09 | 株式会社東芝 | 窒化物系半導体発光素子のp側電極及び窒化物系半導体発光素子 |
JP5196980B2 (ja) | 2007-12-10 | 2013-05-15 | 株式会社東芝 | 半導体装置 |
US8519438B2 (en) * | 2008-04-23 | 2013-08-27 | Transphorm Inc. | Enhancement mode III-N HEMTs |
JP2014099670A (ja) * | 2011-02-02 | 2014-05-29 | Rohm Co Ltd | 半導体装置およびその製造方法 |
JP6290526B2 (ja) * | 2011-08-24 | 2018-03-07 | ローム株式会社 | 半導体装置およびその製造方法 |
KR101997020B1 (ko) * | 2012-03-29 | 2019-07-08 | 서울바이오시스 주식회사 | 근자외선 발광 소자 |
JP6179409B2 (ja) | 2014-01-24 | 2017-08-16 | 株式会社デンソー | 炭化珪素半導体装置の製造方法 |
JP6330705B2 (ja) * | 2015-03-24 | 2018-05-30 | 豊田合成株式会社 | 半導体装置およびその製造方法ならびに電力変換装置 |
JP6485299B2 (ja) * | 2015-06-05 | 2019-03-20 | 豊田合成株式会社 | 半導体装置およびその製造方法ならびに電力変換装置 |
JP6233539B1 (ja) * | 2016-12-21 | 2017-11-22 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
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