JP6915099B2 - 異相ポリマー組成物を作製するための方法 - Google Patents
異相ポリマー組成物を作製するための方法 Download PDFInfo
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- JP6915099B2 JP6915099B2 JP2019566565A JP2019566565A JP6915099B2 JP 6915099 B2 JP6915099 B2 JP 6915099B2 JP 2019566565 A JP2019566565 A JP 2019566565A JP 2019566565 A JP2019566565 A JP 2019566565A JP 6915099 B2 JP6915099 B2 JP 6915099B2
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- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
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Description
背景
[0002]熱可塑性ポリマーは、日常生活において遍在するようになってきた。例えば、熱可塑性ポリマーは、様々な耐久消費財(例えば、家庭用具、家電製品、家具、および自動車)、消費財、およびこのような品物のための包装材料において使用される。熱可塑性ポリマーの遍在はリサイクル率の増加と組み合わさって、樹脂製造業者が、相当量のリサイクル材料、例えばポストコンシューマーリサイクル(PCR)材料(例えば、PCR含有量25〜50%)を含有する樹脂グレードを導入することを可能にした。これらのリサイクル樹脂は持続可能性の観点から有益であるが、100%未使用樹脂に比べて減退した物理的特性を頻繁に示す。例えば、リサイクル樹脂は通常、より低い衝撃強さおよび剛性を示す。さらに、多くのリサイクル樹脂は通常、比較的低いメルトフローレート(MFR)を示し、これにより、MFRを加工に望ましい範囲に増加させるために過酸化物の使用を必要とすることがある。しかし、過酸化物を用いてMFRを増加させると通常、リサイクル樹脂の耐衝撃性および剛性がさらに低減することになる。したがって、現存の技術をリサイクル樹脂と共に使用するときには、PCR含有量の増加と得られたポリマー組成物の耐衝撃性および剛性の望ましくない低減との妥協点に達しなければならない。
発明の簡単な概要
[0004]第1の態様では、本発明は、ポリマー組成物を製造するための方法であって、
(a)ラジカル付加反応においてフリーラジカルと反応できる官能基を2個以上含む相溶化剤を用意する工程;
(b)プロピレンポリマー相およびエチレンポリマー相を含む異相ポリマー組成物を用意する工程;
(c)リサイクルポリマーを含む第2のポリマー組成物を用意する工程;
(d)相溶化剤、異相ポリマー組成物および第2のポリマー組成物を混合する工程;ならびに
(e)異相ポリマー組成物のプロピレンポリマー相およびエチレンポリマー相中、ならびに第2のポリマー組成物のポリマー中でフリーラジカルを生成する工程
を含み、相溶化剤の少なくとも一部が、フリーラジカルと反応する、方法を提供する。
詳細な説明
[0001]以下の定義は、本出願を通して使用されるいくつかの用語を定義するために提供されている。
この定義では、用語「置換アレーン」は、単環式および多環芳香族炭化水素から誘導された化合物を意味し、その炭化水素の1種以上の水素原子は、非水素原子(例えば、ハロゲン原子)または非アルキル官能基(例えば、ヒドロキシ基)で置きかえられている。
この定義では、用語「ヘテロアレーン」は、単環式および多環芳香族炭化水素から誘導された化合物を意味し、その炭化水素の少なくとも1種のメチン基(−C=)は、3価のヘテロ原子と置きかえられており、ならびに/または炭化水素の少なくとも1種のビニリデン基(−CH=CH−)は、2価のヘテロ原子と置きかえられている。
の構造に一致する基からなる群から選択される。
分子M中の第3級炭素−水素結合の結合−解離エネルギー(ΔH°(C−H))は、以下の式1
Dmol3プログラムを使用しているとき、計算のための入力パラメーターは、分子Mについては表A、ラジカルM・およびH・については表Bに示す。H°(H・)の値は、−0.496344ハートリー(1ハートリー(Ha)=627.51kcal/mol)で計算される。
プロピレンポリマー相は、好ましくはポリプロピレンホモポリマーおよびプロピレンと50重量%以下のエチレンおよび/またはC4〜C10α−オレフィンとのコポリマーからなる群から選択されるプロピレンポリマーを含む。エチレンポリマー相は、好ましくはエチレンホモポリマーおよびエチレンとC3〜C10α−オレフィンとのコポリマーからなる群から選択されるエチレンポリマーを含む。エチレンポリマー相のエチレン含有量は、好ましくは少なくとも8重量%である。エチレン相がエチレンとC3〜C10α−オレフィンとのコポリマーである場合、エチレン相のエチレン含有量は、8〜90重量%の範囲であってもよい。一態様では、エチレン相のエチレン含有量は、好ましくは少なくとも50重量%である。プロピレンポリマー相またはエチレンポリマー相のいずれかは、組成物の連続相を形成していてもよく、もう一方は、組成物の離散または分散相を形成することになる。例えば、エチレンポリマー相は、不連続相であってもよく、ポリプロピレンポリマー相は、連続相であってもよい。本発明の一態様では、プロピレンポリマー相のプロピレン含有量は、好ましくはエチレンポリマー相のプロピレン含有量よりも多い。
異相ポリマー組成物の例は、米国特許第8,207,272 B2号および欧州特許第1
391 482 B1号に見出すことができる。
このようなアゾ化合物は、例えば2,2’−アゾビスイソブチロニトリル、2,2’−アゾビス(2−メチルブチロニトリル)、2,2’−アゾビス(2,4−ジメチルバレロニトリル)、2,2’−アゾビス(4−メトキシ−2,4−ジメチルバレロニトリル)、1,1’−アゾビス(1−シクロヘキサンカルボニトリル)、2,2’−アゾビス(イソブチルアミド)ジハイドレート、2−フェニルアゾ−2,4−ジメチル−4−メトキシバレロニトリル、ジメチル 2,2’−アゾビスイソブチレート、2−(カルバモイルアゾ)イソブチロニトリル、2,2’−アゾビス(2,4,4−トリメチルペンタン)、2,2’−アゾビス(2−メチル−プロパン)、遊離塩基または塩酸塩としての2,2’−アゾビス(N,N’−ジメチレンイソブチルアミジン)を、遊離塩基または塩酸塩としての2,2’−アゾビス(2−アミジノプロパン)、2,2’−アゾビス{2−メチル−N−[1,1−ビス(ヒドロキシメチル)エチル]プロピオンアミド}および2,2’−アゾビス{2−メチル−N−[1,1−ビス(ヒドロキシメチル)−2−ヒドロキシエチル]プロピオンアミド}を含む。
Ss=((Vbo/vb1*(W2−W1))/W0)*100
この方程式において、Ssは、百分率として表される試料の可溶性画分であり;Vboは、溶媒の元の体積(単位ミリリットル)であり;Vb1は、可溶性画分決定に使用される一定分量の体積(単位ミリリットル)であり;W2は、パンおよび可溶性画分の質量(単位グラム)であり;W1は、パンの質量(単位グラム)であり;Woは、元の試料の質量(単位グラム)である。
[0091]この例は、本発明によるいくつかのポリマー組成物の生成およびこれらのポリマー組成物によって示された物理的特性の向上を示す。
[0095]この例は、本発明によるいくつかのポリマー組成物の生成およびこれらのポリマー組成物によって示された物理的特性の向上を示す。
[0099]この例は、本発明によるいくつかのポリマー組成物の生成およびこれらのポリマー組成物によって示された物理的特性の向上を示す。
[0103]この例は、本発明によるいくつかのポリマー組成物の生成およびこれらのポリマー組成物によって示された物理的特性の向上を示す。
記載されている。それらの好ましい態様の変形形態は、前述の説明を読むことにより、当業者に明らかになり得る。発明者らは、当業者がこのような変形形態を適宜使用することを期待し、また発明者らは、ここに具体的に記載されている以外の方法でここに記載されている主題が実施されることを意図している。したがって、この開示は、準拠法によって許可されるようにここに添付された特許請求の範囲で列挙された主題の全ての変更形態および相当物を含む。さらに、その全ての可能な変形形態における前述の要素の任意の組合せは、ここで特に指示がない、または明らかに文脈と矛盾しない限り、本開示によって包含される。
Claims (12)
- ポリマー組成物を製造するための方法であって、
(a)ラジカル付加反応においてフリーラジカルと反応できる官能基を2個以上含む相溶化剤を用意する工程;
(b)プロピレンポリマー相およびエチレンポリマー相を含む異相ポリマー組成物を用意する工程;
ここで、異相ポリマー組成物が、(i)ポリプロピレンホモポリマーおよびプロピレンと50重量%以下のエチレンおよび/またはC 4 〜C 10 α−オレフィンとのコポリマーからなる群から選択されるポリプロピレンポリマーを含む連続相、ならびに(ii)エチレンとC 3 〜C 10 α−オレフィンモノマーとのコポリマーからなる群から選択されるエラストマーエチレンポリマーを含む不連続相を含むポリプロピレンインパクトコポリマーであり、前記不連続相が、前記組成物中のプロピレンポリマーおよびエチレンポリマーの合計の5重量%〜35重量%である、
(c)50重量%以上のリサイクルポリオレフィンポリマーを含む第2のポリマー組成物を用意する工程;
(d)前記相溶化剤、前記異相ポリマー組成物および前記第2のポリマー組成物を混合する工程;ならびに
(e)前記異相ポリマー組成物の前記プロピレンポリマー相および前記エチレンポリマー相中、ならびに前記第2のポリマー組成物のポリマー中でフリーラジカルを生成する工程を含み、前記相溶化剤の少なくとも一部が、前記フリーラジカルと反応する、方法。 - 前記相溶化剤が、前記相溶化剤、前記異相ポリマー組成物および前記第2のポリマー組成物の混合物中に200ppm〜5,000ppmの量で存在する、請求項1に記載の方法。
- 前記相溶化剤が、230℃以下の融点を有する、請求項1または請求項2に記載の方法。
- 前記相溶化剤が、式(EX)の構造
と一致する化合物である、請求項1〜3の何れかに記載の方法。 - 前記不連続相のエチレン含有量が、8重量%〜80重量%である、請求項1に記載の方法。
- 前記異相組成物のエチレン含有量が、前記組成物中のプロピレンポリマーおよびエチレンポリマーの合計に基づいて、5重量%〜30重量%である、請求項1に記載の方法。
- 前記連続相のプロピレン含有量が、80重量%以上である、請求項1に記載の方法。
- リサイクルポリオレフィンポリマーが、ポストコンシューマーリサイクル(PCR)ポリマーである、請求項1〜7の何れかに記載の方法。
- 前記第2のポリマー組成物が、75重量%以上のPCRポリマーを含む、請求項8に記載の方法。
- 前記フリーラジカルが、工程(e)において有機過酸化物の添加により生成される、請求項1〜9の何れかに記載の方法。
- 前記有機過酸化物が、前記相溶化剤、前記異相ポリマー組成物および前記第2のポリマー組成物の前記混合物中に100ppm〜2,000ppmの量で存在する、請求項10に記載の方法。
- 前記相溶化剤が、前記組成物中に、相溶化剤のモル数対過酸化物結合のモル当量の比が1:10〜10:1で存在する、請求項10に記載の方法。
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JP2020508388A (ja) | 2020-03-19 |
US10590270B2 (en) | 2020-03-17 |
EP3585835A1 (en) | 2020-01-01 |
WO2018156278A1 (en) | 2018-08-30 |
BR112019017013B1 (pt) | 2023-01-17 |
BR112019017013A2 (pt) | 2020-04-14 |
KR102327465B1 (ko) | 2021-11-17 |
TW201837059A (zh) | 2018-10-16 |
SA519402477B1 (ar) | 2022-06-23 |
CN110536926A (zh) | 2019-12-03 |
KR20190112823A (ko) | 2019-10-07 |
CA3052790C (en) | 2021-09-21 |
US20180237625A1 (en) | 2018-08-23 |
MX2019009773A (es) | 2019-10-14 |
TWI826366B (zh) | 2023-12-21 |
CN110536926B (zh) | 2022-05-31 |
CA3052790A1 (en) | 2018-08-30 |
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