JP6896796B2 - ポリイソプレン/ポリクロロプレン組成物 - Google Patents
ポリイソプレン/ポリクロロプレン組成物 Download PDFInfo
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- JP6896796B2 JP6896796B2 JP2019110293A JP2019110293A JP6896796B2 JP 6896796 B2 JP6896796 B2 JP 6896796B2 JP 2019110293 A JP2019110293 A JP 2019110293A JP 2019110293 A JP2019110293 A JP 2019110293A JP 6896796 B2 JP6896796 B2 JP 6896796B2
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- polyisoprene
- polychloroprene
- gloves
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- 239000000203 mixture Substances 0.000 title claims description 64
- 229920001084 poly(chloroprene) Polymers 0.000 title claims description 16
- 229920001195 polyisoprene Polymers 0.000 title claims description 15
- 238000000034 method Methods 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 18
- 239000005077 polysulfide Substances 0.000 claims description 18
- 229920001021 polysulfide Polymers 0.000 claims description 18
- 150000008117 polysulfides Polymers 0.000 claims description 18
- 238000000576 coating method Methods 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 10
- 239000000701 coagulant Substances 0.000 claims description 8
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 7
- CPGFMWPQXUXQRX-UHFFFAOYSA-N 3-amino-3-(4-fluorophenyl)propanoic acid Chemical compound OC(=O)CC(N)C1=CC=C(F)C=C1 CPGFMWPQXUXQRX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 229920003051 synthetic elastomer Polymers 0.000 claims description 6
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- SZRLKIKBPASKQH-UHFFFAOYSA-M dibutyldithiocarbamate Chemical compound CCCCN(C([S-])=S)CCCC SZRLKIKBPASKQH-UHFFFAOYSA-M 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000000774 hypoallergenic effect Effects 0.000 claims 2
- 230000000717 retained effect Effects 0.000 claims 2
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 229920006037 cross link polymer Polymers 0.000 claims 1
- 229920006254 polymer film Polymers 0.000 claims 1
- TYLSDQJYPYQCRK-UHFFFAOYSA-N sulfo 4-amino-4-oxobutanoate Chemical compound NC(=O)CCC(=O)OS(O)(=O)=O TYLSDQJYPYQCRK-UHFFFAOYSA-N 0.000 claims 1
- 238000001356 surgical procedure Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- 239000011593 sulfur Substances 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- 239000004816 latex Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- -1 ZMBT Chemical compound 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 229920001194 natural rubber Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 229920006132 styrene block copolymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 2
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- GIUBHMDTOCBOPA-UHFFFAOYSA-N 3h-1,3-benzothiazole-2-thione;zinc Chemical compound [Zn].C1=CC=C2SC(S)=NC2=C1 GIUBHMDTOCBOPA-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- ZUQAPLKKNAQJAU-UHFFFAOYSA-N acetylenediol Chemical compound OC#CO ZUQAPLKKNAQJAU-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- 208000030961 allergic reaction Diseases 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000003811 finger Anatomy 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- ZWWQICJTBOCQLA-UHFFFAOYSA-N o-propan-2-yl (propan-2-yloxycarbothioyldisulfanyl)methanethioate Chemical compound CC(C)OC(=S)SSC(=S)OC(C)C ZWWQICJTBOCQLA-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 231100000051 skin sensitiser Toxicity 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
- A41D19/0058—Three-dimensional gloves
- A41D19/0065—Three-dimensional gloves with a textile layer underneath
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/50—Synthetic resins or rubbers
- A41D2500/54—Synthetic resins or rubbers in coated form
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Gloves (AREA)
Description
本発明の上で記載した特徴が詳細に理解できるように、本発明のより具体的な説明(上では短くまとめたが)を、実施態様を参照して行い、そのいくつかは添付した図面において説明されている。しかし、添付した図面及び開示は、本発明の例示態様を表しており、したがって、記載した特定の形態の範囲に限定していると考えられるべきではなく、当業者は本発明の追加の態様を理解し、それは添付した特許請求の範囲によって規定される本発明の思想及び範囲内の全ての変更、均等物、及び代替物を含むことに注意すべきである。
本発明による態様は、天然及び/又は合成ポリイソプレンとポリクロロプレンのブレンド物を含む、ポリマー、エラストマー、又はラテックスの組成物を包含する。合成ポリイソプレンは高価であり、優れた触覚感度及び柔軟性を示す。そして、ポリイソプレン組成物において用いられる典型的な硬化促進剤はジフェニルグアニジン(DPG)であり、これは公知の皮膚感作物質である。ポリクロロプレンはより低価格であり、しかし比較的硬い。DPGを含まないポリイソプレンとポリクロロプレンのブレンド物は、驚くべきことに、十分に硬化され、強くかつ柔軟さを保っているコーティング及び/又はゴム層を作り出すことが示されている。このブレンド物は、1以上の多硫化硫黄供与体をさらに含み、また、いくつかの態様では、殆ど元素状硫黄を含まない。この組成物及び/又はブレンド物は、保護物品、例えば、支持部材のない(unsupported)手袋、又は布裏地を含む支持部材のある(supported)手袋のためのコーティングを作るために用いることができる。その他の保護物品、例えばコンドームも、本発明の範囲内であると考えられる。
Claims (10)
- 合成ポリイソプレン材料;
ポリクロロプレン材料;
キサントゲンポリスルフィド又はジペンタメチレンチウラムテトラスルフィドのうち少なくとも1つを含む、少なくとも1つの多硫化硫黄供与体;及び
ジブチルジチオカルバメート亜鉛、ジエチルジチオカルバメート亜鉛、又はジブチルジチオカルバメートナトリウムのうち少なくとも1つを含む、少なくとも1つの促進剤を含む、架橋化ポリマー組成物を含む非発泡層を含む、強くて柔らかい低アレルギー性の支持部材のない手袋であって、前記組成物のポリマー成分は、40%〜60%のポリイソプレン及び40%〜60%のポリクロロプレンを含み、前記組成物は、ジフェニルグアニジンを含まず、前記手袋は、1.9〜2.5MPaの量で500%伸びでの未エージング弾性率を含み、前記手袋は、少なくとも7日間の70℃でのエージングの後、少なくとも95%が保持された引張強度を有する、手袋。 - 前記組成物が活性化剤をさらに含む、請求項1に記載の手袋。
- 前記組成物がスルホスクシナメートをさらに含む、請求項1に記載の手袋。
- 診察用又は手術用手袋である、請求項1に記載の手袋。
- 前記ポリマー成分が40%〜60%のポリイソプレン及び40%〜60%のポリクロロプレンから成る、請求項1に記載の手袋。
- 以下の工程:
手袋の形状をした成形型を、凝集剤溶液でコーティングする工程;
凝集剤でコーティングされた成形型を、合成ポリイソプレン材料;ポリクロロプレン材料; キサントゲンポリスルフィド又はジペンタメチレンチウラムテトラスルフィドのうち少なくとも1つを含む、少なくとも1つの多硫化硫黄供与体;及びジブチルジチオカルバメート亜鉛、ジエチルジチオカルバメート亜鉛、又はジブチルジチオカルバメートナトリウムのうち少なくとも1つを含む、少なくとも1つの促進剤を含む、ポリマー成分が、40%〜60%のポリイソプレン及び40%〜60%のポリクロロプレンを含み、ジフェニルグアニジンを含まない組成物中に浸漬し、ポリマーコーティングを形成する工程;及び
前記ポリマーコーティングを硬化させる工程、
を含む、強くて柔らかい低アレルギー性の支持部材のない手袋の製造方法であって、前記手袋は、1.9〜2.5MPaの量で500%伸びでの未エージング弾性率を含み、前記手袋は、少なくとも7日間の70℃でのエージングの後、少なくとも95%が保持された引張強度を有する、方法。 - 前記組成物がスルホスクシナメートを含む、請求項6に記載の方法。
- 塩素化工程又はポリマーフィルム適用工程のうち少なくとも1つによって手袋のべたつきを低下させる工程をさらに含む、請求項6に記載の方法。
- 形成される手袋が診察用又は手術用手袋である、請求項6に記載の方法。
- 前記ポリマー成分が40%〜60%のポリイソプレン及び40%〜60%のポリクロロプレンから成る、請求項6に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/224,832 | 2014-03-25 | ||
US14/224,832 US10253170B2 (en) | 2014-03-25 | 2014-03-25 | Polyisoprene/polychloroprene compositions |
JP2016553515A JP2017508840A (ja) | 2014-03-25 | 2015-02-10 | ポリイソプレン/ポリクロロプレン組成物 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016553515A Division JP2017508840A (ja) | 2014-03-25 | 2015-02-10 | ポリイソプレン/ポリクロロプレン組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2019147969A JP2019147969A (ja) | 2019-09-05 |
JP6896796B2 true JP6896796B2 (ja) | 2021-06-30 |
Family
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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JP2016553515A Pending JP2017508840A (ja) | 2014-03-25 | 2015-02-10 | ポリイソプレン/ポリクロロプレン組成物 |
JP2019110293A Active JP6896796B2 (ja) | 2014-03-25 | 2019-06-13 | ポリイソプレン/ポリクロロプレン組成物 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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JP2016553515A Pending JP2017508840A (ja) | 2014-03-25 | 2015-02-10 | ポリイソプレン/ポリクロロプレン組成物 |
Country Status (6)
Country | Link |
---|---|
US (2) | US10253170B2 (ja) |
EP (1) | EP3122816B1 (ja) |
JP (2) | JP2017508840A (ja) |
CN (1) | CN106459515A (ja) |
AU (1) | AU2015234680B2 (ja) |
WO (1) | WO2015143473A1 (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015006806A1 (en) | 2013-07-16 | 2015-01-22 | Skinprotect Corporation Sdn Bhd | Elastomeric film-forming compositions and articles made from the elastomeric film |
US11925222B2 (en) | 2015-06-19 | 2024-03-12 | Summit Glove Inc. | Safety glove with fingertip protective member |
US9730477B2 (en) | 2013-12-13 | 2017-08-15 | Covco Ltd. | Ambidextrous fish scale-textured glove |
US11241051B2 (en) * | 2014-07-08 | 2022-02-08 | Covco (H.K.) Limited | Ambidextrous fish scale-textured glove |
USD930325S1 (en) * | 2016-06-09 | 2021-09-14 | Christine Stuart | Linking glove |
LT3434437T (lt) * | 2017-07-25 | 2022-01-25 | Skinprotect Corporation Sdn Bhd | Elastomerinės pirštinės ir jų gamybos būdai |
US20190191795A1 (en) * | 2017-12-21 | 2019-06-27 | Medline Industries, Inc. | Disposable gloves and methods of using and making |
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EP3122816A4 (en) | 2017-08-30 |
CN106459515A (zh) | 2017-02-22 |
AU2015234680A1 (en) | 2016-07-07 |
JP2017508840A (ja) | 2017-03-30 |
US10253170B2 (en) | 2019-04-09 |
AU2015234680B2 (en) | 2018-11-08 |
JP2019147969A (ja) | 2019-09-05 |
WO2015143473A1 (en) | 2015-10-01 |
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