JP6893886B2 - 凝縮型液体洗濯洗剤組成物 - Google Patents
凝縮型液体洗濯洗剤組成物 Download PDFInfo
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- JP6893886B2 JP6893886B2 JP2017563041A JP2017563041A JP6893886B2 JP 6893886 B2 JP6893886 B2 JP 6893886B2 JP 2017563041 A JP2017563041 A JP 2017563041A JP 2017563041 A JP2017563041 A JP 2017563041A JP 6893886 B2 JP6893886 B2 JP 6893886B2
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- laundry detergent
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- liquid laundry
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- 239000000203 mixture Substances 0.000 title claims description 205
- 239000007788 liquid Substances 0.000 title claims description 80
- 239000003599 detergent Substances 0.000 title claims description 73
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 60
- 239000000463 material Substances 0.000 claims description 49
- 150000001412 amines Chemical class 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- 239000003945 anionic surfactant Substances 0.000 claims description 31
- 239000002386 air freshener Substances 0.000 claims description 27
- 150000001299 aldehydes Chemical class 0.000 claims description 25
- 150000002576 ketones Chemical class 0.000 claims description 25
- 239000003205 fragrance Substances 0.000 claims description 24
- 230000003472 neutralizing effect Effects 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000002736 nonionic surfactant Substances 0.000 claims description 15
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 8
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229940077388 benzenesulfonate Drugs 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- CRIGTVCBMUKRSL-FNORWQNLSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone Chemical compound C\C=C\C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-FNORWQNLSA-N 0.000 claims description 4
- YJRODKCOICMRBO-UHFFFAOYSA-N 4-(2,2,6-trimethylcyclohexyl)but-3-en-2-one Chemical compound CC1CCCC(C)(C)C1C=CC(C)=O YJRODKCOICMRBO-UHFFFAOYSA-N 0.000 claims description 4
- BCLVKHGKEGFPJV-UHFFFAOYSA-N 4-ethoxy-3-hydroxybenzaldehyde Chemical compound CCOC1=CC=C(C=O)C=C1O BCLVKHGKEGFPJV-UHFFFAOYSA-N 0.000 claims description 4
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 4
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- MLUCVPSAIODCQM-UHFFFAOYSA-N but-2-enal Chemical compound CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 claims description 4
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 4
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 claims description 4
- DKZBBWMURDFHNE-UHFFFAOYSA-N trans-coniferylaldehyde Natural products COC1=CC(C=CC=O)=CC=C1O DKZBBWMURDFHNE-UHFFFAOYSA-N 0.000 claims description 4
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims description 4
- 239000001414 (2E)-2-(phenylmethylidene)octanal Substances 0.000 claims description 3
- OEVIJAZJVZDBQL-UHFFFAOYSA-N 1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one Chemical compound CC1(C)CCC=C(C(=O)CCC=C)C1 OEVIJAZJVZDBQL-UHFFFAOYSA-N 0.000 claims description 3
- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 claims description 3
- HQQPOVNESMNPNH-UHFFFAOYSA-N 3-(4-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=C(C(C)CC=O)C=C1 HQQPOVNESMNPNH-UHFFFAOYSA-N 0.000 claims description 3
- GBOYWPAUISQQSW-UHFFFAOYSA-N CCC1=C(CC(C)(C)CO)C=CC=C1 Chemical compound CCC1=C(CC(C)(C)CO)C=CC=C1 GBOYWPAUISQQSW-UHFFFAOYSA-N 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 3
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 claims description 3
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 claims description 3
- HZYHMHHBBBSGHB-DYWGDJMRSA-N (2e,6e)-nona-2,6-dienal Chemical compound CC\C=C\CC\C=C\C=O HZYHMHHBBBSGHB-DYWGDJMRSA-N 0.000 claims description 2
- NELDPSDYTZADSA-AATRIKPKSA-N (e)-1-(2,4,4-trimethylcyclohex-2-en-1-yl)but-2-en-1-one Chemical compound C\C=C\C(=O)C1CCC(C)(C)C=C1C NELDPSDYTZADSA-AATRIKPKSA-N 0.000 claims description 2
- YGFGZTXGYTUXBA-UHFFFAOYSA-N (±)-2,6-dimethyl-5-heptenal Chemical compound O=CC(C)CCC=C(C)C YGFGZTXGYTUXBA-UHFFFAOYSA-N 0.000 claims description 2
- XEJGJTYRUWUFFD-UHFFFAOYSA-N 1-(2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one Chemical compound CC=CC(=O)C1C(C)C=CCC1(C)C XEJGJTYRUWUFFD-UHFFFAOYSA-N 0.000 claims description 2
- UEGBWDUVDAKUGA-UHFFFAOYSA-N 2,6,10-trimethylundec-9-enal Chemical compound CC(C)=CCCC(C)CCCC(C)C=O UEGBWDUVDAKUGA-UHFFFAOYSA-N 0.000 claims description 2
- KNHGOYVXAHUDHP-UHFFFAOYSA-N 2-[2-(4-methylcyclohex-3-en-1-yl)propyl]cyclopentan-1-one Chemical compound C1CC(C)=CCC1C(C)CC1CCCC1=O KNHGOYVXAHUDHP-UHFFFAOYSA-N 0.000 claims description 2
- MXVLFOMMAUNPJY-UHFFFAOYSA-N 3-(1,3-benzodioxol-5-yl)-2-methylpropan-1-ol Chemical compound OCC(C)CC1=CC=C2OCOC2=C1 MXVLFOMMAUNPJY-UHFFFAOYSA-N 0.000 claims description 2
- OHRBQTOZYGEWCJ-UHFFFAOYSA-N 3-(3-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=CC(C(C)CC=O)=C1 OHRBQTOZYGEWCJ-UHFFFAOYSA-N 0.000 claims description 2
- RLEFOSDUWZYGOS-UHFFFAOYSA-N 3-(4-Isopropylphenyl)propanal Chemical compound CC(C)C1=CC=C(CCC=O)C=C1 RLEFOSDUWZYGOS-UHFFFAOYSA-N 0.000 claims description 2
- VLFBSPUPYFTTNF-UHFFFAOYSA-N 3-(4-methoxyphenyl)-2-methylpropanal Chemical compound COC1=CC=C(CC(C)C=O)C=C1 VLFBSPUPYFTTNF-UHFFFAOYSA-N 0.000 claims description 2
- ARJWAURHQDJJAC-UHFFFAOYSA-N 5-methylhept-2-en-4-one Chemical compound CCC(C)C(=O)C=CC ARJWAURHQDJJAC-UHFFFAOYSA-N 0.000 claims description 2
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 claims description 2
- UZFLPKAIBPNNCA-BQYQJAHWSA-N alpha-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 claims description 2
- 238000004061 bleaching Methods 0.000 claims description 2
- 239000007844 bleaching agent Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000002738 chelating agent Substances 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- UHEPJGULSIKKTP-UHFFFAOYSA-N sulcatone Chemical compound CC(C)=CCCC(C)=O UHEPJGULSIKKTP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 239000001489 (2E)-2-benzylidenehexanal Substances 0.000 claims 1
- XTCMQAVNRXZBRH-UHFFFAOYSA-N 1,3-dimethylcyclohexene Chemical compound CC1CCCC(C)=C1 XTCMQAVNRXZBRH-UHFFFAOYSA-N 0.000 claims 1
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 claims 1
- GFBCBQNBXRPRQD-RAXLEYEMSA-N 2-Butyl-3-phenyl-2-propen-1-al Chemical compound CCCC\C(C=O)=C\C1=CC=CC=C1 GFBCBQNBXRPRQD-RAXLEYEMSA-N 0.000 claims 1
- BGTBFNDXYDYBEY-FNORWQNLSA-N 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one Chemical compound C\C=C\C(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-FNORWQNLSA-N 0.000 claims 1
- QUMSUJWRUHPEEJ-UHFFFAOYSA-N 4-Pentenal Chemical compound C=CCCC=O QUMSUJWRUHPEEJ-UHFFFAOYSA-N 0.000 claims 1
- LMETVDMCIJNNKH-UHFFFAOYSA-N [(3,7-Dimethyl-6-octenyl)oxy]acetaldehyde Chemical compound CC(C)=CCCC(C)CCOCC=O LMETVDMCIJNNKH-UHFFFAOYSA-N 0.000 claims 1
- FZJUFJKVIYFBSY-UHFFFAOYSA-N bourgeonal Chemical compound CC(C)(C)C1=CC=C(CCC=O)C=C1 FZJUFJKVIYFBSY-UHFFFAOYSA-N 0.000 claims 1
- 125000002100 cyclohexa-1,3-dienyl group Chemical group [H]C1([*])C([H])=C([H])C([H])=C([H])C1([H])[H] 0.000 claims 1
- 125000006038 hexenyl group Chemical group 0.000 claims 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 10
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- 238000012360 testing method Methods 0.000 description 8
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- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 6
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- DRLIOHVXDBLHQM-UHFFFAOYSA-N 1-amino-3-(2-methoxyethoxy)propan-2-ol Chemical compound COCCOCC(O)CN DRLIOHVXDBLHQM-UHFFFAOYSA-N 0.000 description 1
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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- ZULPATVQDRLYAC-UHFFFAOYSA-N 2-methyl-4-(methylamino)butan-2-ol Chemical compound CNCCC(C)(C)O ZULPATVQDRLYAC-UHFFFAOYSA-N 0.000 description 1
- ITJHALDCYCTNNJ-UHFFFAOYSA-N 3-(2-ethylphenyl)-2,2-dimethylpropanal Chemical compound CCC1=CC=CC=C1CC(C)(C)C=O ITJHALDCYCTNNJ-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- LREQLEBVOXIEOM-UHFFFAOYSA-N 6-amino-2-methyl-2-heptanol Chemical compound CC(N)CCCC(C)(C)O LREQLEBVOXIEOM-UHFFFAOYSA-N 0.000 description 1
- 239000001606 7-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5-hydroxy-2-(4-hydroxyphenyl)chroman-4-one Substances 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
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- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 229920002749 Bacterial cellulose Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000298479 Cichorium intybus Species 0.000 description 1
- 235000007542 Cichorium intybus Nutrition 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 101000864678 Homo sapiens Probable ATP-dependent RNA helicase DHX37 Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000005913 Maltodextrin Substances 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical class CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 description 1
- 102100030093 Probable ATP-dependent RNA helicase DHX37 Human genes 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ZIJKGAXBCRWEOL-SAXBRCJISA-N Sucrose octaacetate Chemical compound CC(=O)O[C@H]1[C@H](OC(C)=O)[C@@H](COC(=O)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1 ZIJKGAXBCRWEOL-SAXBRCJISA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000001344 [(2S,3S,4R,5R)-4-acetyloxy-2,5-bis(acetyloxymethyl)-2-[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxolan-3-yl] acetate Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000005016 bacterial cellulose Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- VWTINHYPRWEBQY-UHFFFAOYSA-N denatonium Chemical compound [O-]C(=O)C1=CC=CC=C1.C=1C=CC=CC=1C[N+](CC)(CC)CC(=O)NC1=C(C)C=CC=C1C VWTINHYPRWEBQY-UHFFFAOYSA-N 0.000 description 1
- 229960001610 denatonium benzoate Drugs 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- DLNKOYKMWOXYQA-UHFFFAOYSA-N dl-pseudophenylpropanolamine Natural products CC(N)C(O)C1=CC=CC=C1 DLNKOYKMWOXYQA-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229960005402 heptaminol Drugs 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229940035034 maltodextrin Drugs 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- DFPMSGMNTNDNHN-ZPHOTFPESA-N naringin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1O[C@H]1[C@H](OC=2C=C3O[C@@H](CC(=O)C3=C(O)C=2)C=2C=CC(O)=CC=2)O[C@H](CO)[C@@H](O)[C@@H]1O DFPMSGMNTNDNHN-ZPHOTFPESA-N 0.000 description 1
- 229940052490 naringin Drugs 0.000 description 1
- 229930019673 naringin Natural products 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229960002748 norepinephrine Drugs 0.000 description 1
- SFLSHLFXELFNJZ-UHFFFAOYSA-N norepinephrine Natural products NCC(O)C1=CC=C(O)C(O)=C1 SFLSHLFXELFNJZ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- DLNKOYKMWOXYQA-APPZFPTMSA-N phenylpropanolamine Chemical compound C[C@@H](N)[C@H](O)C1=CC=CC=C1 DLNKOYKMWOXYQA-APPZFPTMSA-N 0.000 description 1
- 229960000395 phenylpropanolamine Drugs 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001308 poly(aminoacid) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229960001811 quinine hydrochloride Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- WWUZIQQURGPMPG-KRWOKUGFSA-N sphingosine Chemical compound CCCCCCCCCCCCC\C=C\[C@@H](O)[C@@H](N)CO WWUZIQQURGPMPG-KRWOKUGFSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229940013883 sucrose octaacetate Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 229940057400 trihydroxystearin Drugs 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Description
−当該組成物の0.001重量%〜5重量%の、アルデヒド含有芳香材料、ケトン含有芳香剤材料、又はこれらの混合物と、
−当該組成物の5重量%〜40重量%の、20〜400の分子量を有し、かつ本明細書に記載されたアルコールeRH試験を介して測定したときに20℃で50%〜80%のeRHを有するアルコールと、
−当該組成物の10重量%〜30重量%の非アミン中和直鎖アルキルベンゼンスルホネートと、
−当該組成物の5重量%未満のヒドロキシル含有アミンと、
−当該組成物の0.5重量%〜15重量%の水と、を含む、液体洗濯洗剤組成物。
−当該組成物の0.001重量%〜2重量%の、アルデヒド芳香剤材料、ケトン芳香剤材料、又はこれらの混合物と、
−当該組成物の5重量%〜40重量%の、エチレングリコール、1,3プロパンジオール、1,2プロパンジオール、テトラメチレングリコール、ペンタメチレングリコール、ヘキサメチレングリコール、2,3−ブタンジオール、1,3ブタンジオール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、グリセロールホルマルジプロピレングリコール、ポリプロポレングリコール、ジプロピレングリコールn−ブチルエーテル、及びこれらの混合物を含む群から選択されるアルコール、好ましくは、1,2プロパンジオール、ジプロピレングリコール、ポリプロポレングリコール、2,3−ブタンジオール、ジプロピレングリコールn−ブチルエーテル、及びこれらの混合物を含む群から選択される溶媒と、
−当該組成物の10重量%〜30重量%の非アミン中和直鎖アルキルベンゼンスルホネートと、
−当該組成物の5重量%未満のヒドロキシル含有アミンと、
−当該組成物の0.5重量%〜15重量%の水と、を含む、液体洗濯洗剤組成物。
本発明の組成物は、当該組成物の0.01重量%〜5重量%、又は更には0.002重量%〜4重量%、又は更には0.005重量%〜3重量%、又は更には0.1重量%〜2重量%の、アルデヒド含有芳香剤材料、ケトン含有芳香剤材料、又はこれらの混合物を含む。
液体洗濯洗剤組成物は、当該組成物の10重量%〜30重量%の非アミン中和直鎖アルキルベンゼンスルホネートを含む。好ましくは、直鎖アルキルベンゼンスルホネートは、層状液晶アルキルベンゼンスルホネートである。「層状液晶」とは、本明細書では、界面活性剤分子が、溶媒の薄層によって分離されている溶融状態の界面活性剤の二層の積層体に構築されている状態である系を意味する。この構造は、流動体の観点における液体特性及び構造化の観点における固体特性の両方を有する。この構造は、そのd−スペーシング、二層の厚さの合計、及びシート間の溶媒層によって特徴付けられる。この構造の繰り返し及び周期性によって、結晶相に特徴的な急峻なx線回折ピークが得られる。
液相は、当該組成物の5重量%〜40重量%、又は更には5重量%〜20重量%、又は更には5重量%〜15重量%のアルコールを含み、当該アルコールは、20〜400の分子量を有し、かつアルコールeRH試験を介して測定したときに20℃で50%〜80%、又は更には52%〜75%のeRHを有する。
洗剤組成物は、当該組成物の5重量%未満のヒドロキシル含有アミン化合物、又は更には当該組成物の0.1重量%〜5重量%、又は更には0.1重量%〜4重量%のヒドロキシル含有アミン化合物を含む。「ヒドロキシル含有アミン化合物」とは、本明細書では、アルコール(OH)基及びアミン基を含む化合物を意味する。ヒドロキシル含有アミン化合物は、モノエタノールアミン、トリエタノールアミン、ジイソプロパノールアミン、トリイソプロパノールアミン、モノアミノヘキサノール、2−[(2−メトキシエチル)メチルアミノ]−エタノール、プロパノールアミン、N−メチルエタノールアミン、ジエタノールアミン、モノブタノールアミン、イソブタノールアミン、モノペンタノールアミン、1−アミノ−3−(2−メトキシエトキシ)−2−プロパノール、2−メチル−4−(メチルアミノ)−2−ブタノール、6−アミノ−1−ヘキサノール、ヘプタミノール、イソエタリン、ノルエピネフリン、スフィンゴシン、フェニルプロパノールアミン、及びこれらの混合物から選択され得る。
液体洗濯洗剤組成物は、他の非アミン中和アニオン性界面活性剤、好ましくは、非アミン中和アルキルサルフェート、より好ましくは、非アミン中和エトキシ化アルキルサルフェートを含み得る。非アミン中和アニオン性界面活性剤は、非アミン中和アルキルサルフェート、非アミン中和エトキシ化アルキルサルフェート、又はこれらの混合物を含み得る。好ましくは、非アミン中和アルキルサルフェートアニオン性界面活性剤は、層状液晶アルキルサルフェートアニオン性界面活性剤である。非アミン中和アニオン性界面活性剤は、層状液晶アルキルサルフェート、層状液晶エトキシ化アルキルサルフェート、又はこれらの混合物を含み得る。
液体洗濯洗剤組成物は、非イオン性界面活性剤を含み得る。
本発明の組成物は、当該組成物の2重量%未満の構造化剤を含み得る。構造化剤が存在する場合、好ましくは、当該組成物は、0.05重量%〜2重量%、好ましくは0.1重量%〜1重量%の構造化剤を含む。構造化剤は、非ポリマー構造化剤又はポリマー構造化剤から選択され得る。構造化剤は、非ポリマー構造化剤、好ましくは、結晶化可能なグリセリドであり得る。構造化剤は、ポリマー構造化剤、好ましくは、繊維系ポリマー構造化剤、より好ましくは、セルロース繊維系構造化剤であり得る。構造化剤は、結晶化可能なグリセリド、セルロース繊維系構造化剤、TiO2、シリカ、及びこれらの混合物から選択され得る。
液体洗濯洗剤組成物は、当該組成物の0.5重量%〜15重量%の水を含む。液体洗濯洗剤組成物は、当該組成物の0.5重量%〜12重量%、又は更には0.5重量%〜10重量%の水を含み得る。
液体洗濯洗剤組成物は、当該組成物の20重量%〜40重量%の補助成分を含む。補助成分は、漂白剤、漂白触媒、染料、色調染料、アルコキシル化ポリアミン及びポリエチレンイミンを含む洗浄ポリマー、汚れ放出ポリマー、界面活性剤、溶媒、移染抑制剤、キレート剤、酵素、香料、カプセル化香料、ポリカルボキシレートポリマー、セルロースポリマー、及びこれらの混合物を含む群から選択され得る。
液体洗濯洗剤組成物は、水溶性単位用量物品中に存在していてよい。このような実施形態では、水溶性単位用量物品は、単位用量物品が水溶性フィルムによって包囲された少なくとも1つの内部区画を含むような形状の少なくとも1枚の水溶性フィルムを含む。少なくとも1つの区画は、液体洗濯洗剤組成物を含む。水溶性フィルムは、保管中に液体洗濯洗剤組成物が区画から漏れ出さないように封止される。しかし、水溶性単位用量物品を水に添加すると、水溶性フィルムが溶解して、内部区画の内容物が洗浄液中へと放出される。
本発明の液体洗濯洗剤組成物は、当該技術分野において既知の任意の好適な製造技術を使用して製造され得る。当業者であれば、本発明に係る組成物を製造するのに適切な方法及び機器を理解するであろう。
本発明の組成物又は単位用量物品は、洗濯物が既に存在しているか、又は洗濯物が加えられる洗浄液に添加してよい。上記の組成物又は物品は、洗濯機の稼働中に使用してよく、ドラムに直接添加しても、引き出し式ディスペンサー(dispenser drawer)に添加してもよい。洗濯機は、自動洗濯機であっても、半自動洗濯機であってもよい。布地柔軟剤又はしみ除去剤などの他の洗濯洗剤組成物と組み合わせて使用してもよい。洗浄液に添加する前に、前処理組成物として、しみに使用してもよい。
Claims (17)
- 液体洗濯洗剤組成物であって、
−前記組成物の0.001重量%〜5重量%の、アルデヒド含有芳香剤材料、ケトン含有芳香剤材料、又はこれらの混合物から選択される芳香剤材料と、
−前記組成物の5重量%〜40重量%のジプロピレングリコールと、
−前記組成物の10重量%〜30重量%の非アミン中和直鎖アルキルベンゼンスルホネートと、
−前記組成物の0重量%のヒドロキシル含有アミンと、
−前記組成物の0.5重量%〜15重量%の水と、
を含む、液体洗濯洗剤組成物。 - 液体洗濯洗剤組成物であって、
−前記組成物の0.001重量%〜2重量%の、アルデヒド芳香剤材料、ケトン芳香剤材料、又はこれらの混合物から選択される芳香剤材料と、
−前記組成物の5重量%〜40重量%のジプロピレングリコールと、
−前記組成物の10重量%〜30重量%の非アミン中和直鎖アルキルベンゼンスルホネートと、
−前記組成物の0重量%のヒドロキシル含有アミンと、
−前記組成物の0.5重量%〜15重量%の水と、
を含む、液体洗濯洗剤組成物。 - 前記芳香剤材料が、(2E,6E)−ノナ−2,6−ジエナール、2,6,10−トリメチルウンデカ−9−エナール;1−メチル−4−(4−メチルペンタ−3−エニル)シクロヘキサ−3−エン−1−カルバルデヒド;(E)−1−(2,6,6−トリメチル−1−シクロヘキサ−2−エニル)ブタ−2−エン−1−オン;(E)−4−(2,6,6−トリメチル−1−シクロヘキサ−2−エニル)ブタ−3−エン−2−オン;2−ベンジリデンヘプタナール;(E)−1−(2,6,6−トリメチル−1−シクロヘキセニル)ブタ−2−エン−1−オン;4−(2,6,6−トリメチルシクロヘキサン−1−イル)ブタ−3−エン−2−オン;3−(4−tert−ブチルフェニル)プロパナール、(2Z)−2−ベンジリデンヘキサナール;3−(4−メトキシフェニル)−2−メチルプロパナール;3,7−ジメチルオクタ−2,6−ジエナール;2−(3,7−ジメチルオクタ−6−エノキシ)アセトアルデヒド;3−(4−プロパン−2−イルフェニル)プロパナール;3−(4−プロパン−2−イルフェニル)ブタナール;(E)−1−(2,6,6−トリメチル−1−シクロヘキサ−1,3−ジエニル)ブタ−2−エン−1−オン;1−(2,6,6−トリメチル−1−シクロヘキサ−3−エニル)ブタ−2−エン−1−オン;4−エトキシ−3−ヒドロキシベンズアルデヒド;5−メチルヘプタ−2−エン−4−オン;3−(2−エチルフェニル)−2,2−ジメチルプロパナール;3−(3−イソプロピルフェニル)ブタナール;1−(5,5−ジメチル−1−シクロヘキセニル)ペンタ−4−エン−1−オン;(E)−3−メチル−4−(2,6,6−トリメチル−1−シクロヘキサ−2−エニル)ブタ−3−エン−2−オン;3−(1,3−ベンゾジオキソール−5−イル)−2−メチルプロパナール;1,3−ベンゾジオキソール−5−カルバルデヒド;2−(フェニルメチリデン)オクタナール;(E)−1−(2,4,4−トリメチルシクロヘキサ−2−エン−1−イル)ブタ−2−エン−1−オン;3−(4−メチル−1−シクロヘキサ−3−エニル)ブタナール;2,6−ジメチルヘプタ−5−エナール;6−メチルヘプタ−5−エン−2−オン;メチルフェニル)メチリデン]ヘプタナール;5,5−ジメチル−2,3,4,4a,6,7−ヘキサヒドロ−1H−ナフタレン−2−カルバルデヒド;2−[2−(4−メチル−1−シクロヘキサ−3−エニル)プロピル]シクロペンタン−1−オン;2,4−ジメチルシクロヘキサ−3−エン−1−カルバルデヒド;ウンデカ−10−エナール;4−ヒドロキシ−3−メトキシベンズアルデヒド;4−メトキシベンズアルデヒド、及びこれらの混合物を含む群から選択される、請求項1又は2に記載の液体洗濯洗剤組成物。
- 前記芳香剤材料が、(E)−1−(2,6,6−トリメチル−1−シクロヘキサ−2−エニル)ブタ−2−エン−1−オン;(E)−4−(2,6,6−トリメチル−1−シクロヘキサ−2−エニル)ブタ−3−エン−2−オン;(E)−1−(2,6,6−トリメチル−1−シクロヘキセニル)ブタ−2−エン−1−オン;4−(2,6,6−トリメチルシクロヘキサン−1−イル)ブタ−3−エン−2−オン;3,7−ジメチルオクタ−2,6−ジエナール;3−(4−プロパン−2−イルフェニル)ブタナール;(E)−1−(2,6,6−トリメチル−1−シクロヘキサ−1,3−ジエニル)ブタ−2−エン−1−オン;1−(2,6,6−トリメチル−1−シクロヘキサ−3−エニル)ブタ−2−エン−1−オン;4−エトキシ−3−ヒドロキシベンズアルデヒド;3−(2−エチルフェニル)−2,2−ジメチルプロパナール;3−(3−イソプロピルフェニル)ブタナール;1−(5,5−ジメチル−1−シクロヘキセニル)ペンタ−4−エン−1−オン;(E)−3−メチル−4−(2,6,6−トリメチル−1−シクロヘキサ−2−エニル)ブタ−3−エン−2−オン;1,3−ベンゾジオキソール−5−カルバルデヒド;2−(フェニルメチリデン)オクタナール;2,4−ジメチルシクロヘキサ−3−エン−1−カルバルデヒド;ウンデカ−10−エナール;4−ヒドロキシ−3−メトキシベンズアルデヒド;4−メトキシベンズアルデヒド、及びこれらの混合物を含む群から選択される、請求項3に記載の液体洗濯洗剤組成物。
- 前記アルデヒド含有芳香剤材料、ケトン含有芳香剤材料、又はこれらの混合物が、75〜450の分子量を有する、請求項1〜4のいずれか一項に記載の液体洗濯洗剤組成物。
- 前記アルデヒド含有芳香剤材料、ケトン含有芳香剤材料、又はこれらの混合物が、0.25〜7のlogPを有する、請求項1〜5のいずれか一項に記載の液体洗濯洗剤組成物。
- 前記アルデヒド含有芳香剤材料、ケトン含有芳香剤材料、又はこれらの混合物が、3.3×10−3Pa〜1.3×104Pa(2.5×10−5mmHg〜9.5×101mmHg)の25℃における蒸気圧を有する、請求項1〜6のいずれか一項に記載の液体洗濯洗剤組成物。
- 前記組成物の15重量%〜25重量%の前記非アミン中和直鎖アルキルベンゼンスルホネートを含む、請求項1〜7のいずれか一項に記載の液体洗濯洗剤組成物。
- 前記非アミン中和直鎖アルキルベンゼンスルホネートが、C10〜C16直鎖アルキルベンゼンスルホネート若しくはC11〜C14直鎖アルキルベンゼンスルホネート、又はこれらの混合物である、請求項4に記載の液体洗濯洗剤組成物。
- 前記非アミン中和直鎖アルキルベンゼンスルホネートが、直鎖アルキルベンゼンスルホン酸ナトリウム、直鎖アルキルベンゼンスルホン酸カリウム、直鎖アルキルベンゼンスルホン酸マグネシウム、又はこれらの混合物を含む、請求項1〜9のいずれか一項に記載の液体洗濯洗剤組成物。
- 他の非アミン中和アニオン性界面活性剤を含む、請求項1〜10のいずれか一項に記載の液体洗濯洗剤組成物。
- 前記組成物が、前記組成物の5重量%〜20重量%の前記ジプロピレングリコールを含む、請求項1〜11のいずれか一項に記載の液体洗濯洗剤組成物。
- 前記組成物の0重量%〜30重量%の非イオン性界面活性剤を含む、請求項1〜12のいずれか一項に記載の液体洗濯洗剤組成物。
- 構造化剤を含む、請求項1〜13のいずれか一項に記載の液体洗濯洗剤組成物。
- 補助成分を含み、前記補助成分が、漂白剤、漂白触媒、染料、色調染料、アルコキシル化ポリアミン及びポリエチレンイミンを含む洗浄ポリマー、汚れ放出ポリマー、界面活性剤、溶媒、移染抑制剤、キレート剤、酵素、香料、カプセル化香料、ポリカルボキシレートポリマー、セルロースポリマー、及びこれらの混合物を含む群から選択される、請求項1〜14のいずれか一項に記載の液体洗濯洗剤組成物。
- 水溶性フィルムと、請求項1〜15のいずれか一項に記載の洗剤組成物とを含む、水溶性単位用量物品。
- 前記単位用量物品が、少なくとも2つの区画を含む、請求項16に記載の単位用量物品。
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CA2986246C (en) | 2021-05-18 |
JP2018517040A (ja) | 2018-06-28 |
EP3101100B1 (en) | 2018-02-07 |
CA2986246A1 (en) | 2016-12-08 |
AR104886A1 (es) | 2017-08-23 |
HUE036591T2 (hu) | 2018-08-28 |
EP3101100A1 (en) | 2016-12-07 |
RU2663480C1 (ru) | 2018-08-06 |
WO2016196696A1 (en) | 2016-12-08 |
ES2666186T3 (es) | 2018-05-03 |
US20160355762A1 (en) | 2016-12-08 |
CN107690474A (zh) | 2018-02-13 |
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