JP6886916B2 - ポリマー鎖延長のための組成物 - Google Patents
ポリマー鎖延長のための組成物 Download PDFInfo
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- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
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- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/916—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/42—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
従って、本発明は、逐次ポリマーの分子量の改変に有用な組成物であって、アルコキシ官能化トリメリテートおよび少なくとも1種のキャリアー樹脂を含む組成物に向けられる。
R1、R2およびR3は、同一であるかまたは異なっており、C1−C10−アルキル、好ましくはC1−C6−アルキル、より好ましくはC1−C4−アルキル、最も好ましくはC1−C2−アルキルを表す]、
および少なくとも1種のキャリアー樹脂を含む組成物に向けられる。
6つの調製物A〜Fを、Leistritz MASS technology(27mm/40D)を用いて、通常の工業的手順に従って押出した。そのために、キャリア系としてのポリカーボネートに10%の鎖延長剤を含有するマスターバッチを押出した。200〜300℃の温度における35〜40sの平均滞留時間での押出により、このマスターバッチをPETに組み入れた(表1に示した量)。固有粘度(I.V.)をneat PETに対して測定した。
9つの調製物A〜Iを、Leistritz MASS technology(27mm/40D)を用いて、通常の工業的手順に従って押出した。そのために、キャリアー系としてのポリカーボネートに10%の鎖延長剤を含有するマスターバッチを調製した。200〜300℃の温度における押出により、このマスターバッチをPETに組み入れた(表2に示した量)。このトライアルでは、押出機内の材料の滞留時間を変動させた。
4つの調製物A〜Dを、Leistritz MASS technology(27mm/40D)を用いて、通常の工業的手順に従って押出した。そのために、異なるキャリア系に10%の鎖延長剤を含有するマスターバッチを調製した。このマスターバッチを、200〜300℃の温度での押出によりPETに組み入れた。
なお、本願は、特許請求の範囲に記載の発明に関するものであるが、他の態様として以下も包含し得る。
1.少なくとも1種の式(1)の化合物
および少なくとも1種のキャリアー樹脂、
を含む組成物。
2.R 1 、R 2 およびR 3 が、同一であるかまたは異なっており、C 1 −C 2 −アルキルを示す、上記1に記載の組成物。
3.R 1 、R 2 およびR 3 がメチルである、上記1または2に記載の組成物。
4.上記キャリアー樹脂が、ポリエチレン、ポリエチレン−ノルボルネンコポリマー、ポリプロピレン、ポリブチレン、ポリメチルペンテン、ポリエチレン−ビニルアセテートコポリマー、ポリカーボネート、ポリスチレン、ポリスチレンブロックコポリマー、ポリブタジエン、ポリイソプレン、ポリエチレン−ブチレン、ポリアクリレート、ポリビニルクロリド、塩素化ポリエチレン、ポリビニリデンクロリド、ポリエチレン−アクリレートコポリマー、アクリルニトリル−ブタジエン−スチレン−コポリマーおよびそれらの混合物からなる群から選択される、上記1〜3のいずれか1つに記載の組成物。
5.上記キャリアー樹脂が、アクリルニトリル−ブタジエン−スチレン−コポリマー、ポリスチレンまたはポリカーボネートである、上記1〜4のいずれか1つに記載の組成物。
6.上記キャリアー樹脂が、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンテレフタレートグリコール、無水マレイン酸グラフトポリエチレンまたはそれらの混合物である、上記1〜3のいずれか1つに記載の組成物。
7.式(1)の化合物が、濃厚物組成物の全重量に対して、0.01〜99.9重量%の量で存在する、上記1〜6のいずれか1つに記載の組成物。
8.式(1)の化合物が、濃厚物組成物の全重量に対して、5.0〜50.0重量%の量で存在する、上記1〜7のいずれか1つに記載の組成物。
9.式(1)の化合物およびキャリアー樹脂が分散もしくは分配混合により組み合わされる、上記1〜8のいずれか1つに記載の組成物を製造するための方法。
10.逐次重縮合物のための鎖延長剤としての上記1〜9のいずれか1つに記載の組成物の使用。
11.重縮合物が、ポリアミド類、ポリエステル類、ポリカーボネート類、ポリウレタン類、ポリスチレン−コ−無水マレイン酸またはポリエチレン−コ−アクリル酸である、上記10に記載の使用。
12.上記組成物および重縮合物の全重量に対して、0.1〜50重量%、より好ましくは1〜30重量%、最も好ましくは5〜25重量%の量での、上記10または11に記載の使用。
13.重縮合物がポリマー製物品に製造される、上記10〜12のいずれか1つに記載の使用。
14.ポリマー製物品がシート、フィルム、容器または繊維である、上記10〜13のいずれか1つに記載の使用。
Claims (14)
- R1、R2およびR3がメチルである、請求項1に記載の組成物。
- 上記キャリアー樹脂がポリカーボネートである、請求項1または2に記載の組成物。
- 上記キャリアー樹脂が無水マレイン酸グラフトポリエチレンである、請求項1または2に記載の組成物。
- 式(1)の化合物が、組成物の全重量に対して、0.01〜99.9重量%の量で存在する、請求項1〜4のいずれか1つに記載の組成物。
- 式(1)の化合物が、組成物の全重量に対して、5.0〜50.0重量%の量で存在する、請求項1〜5のいずれか1つに記載の組成物。
- 式(1)の化合物およびキャリアー樹脂が分散もしくは分配混合により組み合わされる、請求項1〜6のいずれか1つに記載の組成物を製造するための方法。
- 逐次重縮合物のための鎖延長剤としての請求項1〜6のいずれか1つに記載の組成物の使用。
- 重縮合物が、ポリアミド類、ポリエステル類、ポリカーボネート類、ポリウレタン類、ポリスチレン−コ−無水マレイン酸またはポリエチレン−コ−アクリル酸である、請求項8に記載の使用。
- 上記組成物および重縮合物の全重量に対して、0.1〜50重量%の量での、請求項8または9に記載の使用。
- 上記組成物および重縮合物の全重量に対して、1〜30重量%の量での、請求項8または9に記載の使用。
- 上記組成物および重縮合物の全重量に対して、5〜25重量%の量での、請求項8または9に記載の使用。
- 重縮合物がポリマー製物品に製造される、請求項8〜12のいずれか1つに記載の使用。
- ポリマー製物品がシート、フィルム、容器または繊維である、請求項8〜13のいずれか1つに記載の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP14003779.7 | 2014-11-05 | ||
EP14003779.7A EP3018169A1 (en) | 2014-11-05 | 2014-11-05 | Composition for polymeric chain extension |
PCT/EP2015/074630 WO2016071126A1 (en) | 2014-11-05 | 2015-10-23 | Composition for polymeric chain extension |
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JP2017532427A JP2017532427A (ja) | 2017-11-02 |
JP6886916B2 true JP6886916B2 (ja) | 2021-06-16 |
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US (1) | US10273334B2 (ja) |
EP (2) | EP3018169A1 (ja) |
JP (1) | JP6886916B2 (ja) |
KR (1) | KR102601295B1 (ja) |
CN (1) | CN107108872B (ja) |
AU (1) | AU2015342120A1 (ja) |
BR (1) | BR112017008379B1 (ja) |
CA (1) | CA2966427C (ja) |
ES (1) | ES2745224T3 (ja) |
MX (1) | MX2017005905A (ja) |
PL (1) | PL3215560T3 (ja) |
SG (1) | SG11201703347QA (ja) |
TW (1) | TWI762437B (ja) |
WO (1) | WO2016071126A1 (ja) |
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WO2020229857A1 (en) | 2019-05-15 | 2020-11-19 | Ecole Polytechnique Federale De Lausanne (Epfl) | Composition and method for the preparation of sheets, films, fibers, and molded parts |
JP2023512771A (ja) * | 2020-02-05 | 2023-03-29 | カネカ アメリカズ ホールディング,インコーポレイティド | 溶融粘度を改善するポリエステル用の調整剤 |
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US3186961A (en) * | 1962-10-08 | 1965-06-01 | Monsanto Co | Plasticized polycarbonate resins |
JPS5128311B2 (ja) * | 1972-12-05 | 1976-08-18 | ||
DE3538527A1 (de) * | 1984-11-27 | 1986-06-05 | Showa Electric Wire & Cable Co., Ltd., Kawasaki, Kanagawa | Verfahren zur herstellung eines mit vernetzten polyolefinen isolierten kabels |
JPS6270419A (ja) * | 1985-09-25 | 1987-03-31 | Polyplastics Co | 液晶構造を保持した三次元架橋ポリエステルの製造方法 |
US4698382A (en) * | 1986-09-30 | 1987-10-06 | E. I. Du Pont De Nemours And Company | Plasticized poly(vinyl fluoride) |
IL110514A0 (en) * | 1993-10-04 | 1994-10-21 | Eastman Chem Co | Concentrates for improving polyester compositions and a method for preparing such compositions |
US5830982A (en) * | 1995-01-20 | 1998-11-03 | E. I. Du Pont De Nemours And Company | Production of poly (ethylene terephthalate) |
IT1283590B1 (it) * | 1996-04-12 | 1998-04-22 | Sinco Eng Spa | Resine poliesteri aventi migliorate proprieta' reologiche (mg-18) |
JP4024437B2 (ja) * | 1999-03-24 | 2007-12-19 | ポリプラスチックス株式会社 | インサート成形品 |
JP2000336259A (ja) * | 1999-03-24 | 2000-12-05 | Polyplastics Co | 難燃性ポリエステル樹脂組成物 |
JP2001019851A (ja) * | 1999-07-06 | 2001-01-23 | New Japan Chem Co Ltd | 熱可塑性樹脂用添加剤及びそれを用いた樹脂組成物 |
WO2002004719A1 (en) * | 2000-07-10 | 2002-01-17 | E. I. Du Pont De Nemours And Company | Method of producing polymeric filaments |
EP1756211A1 (en) * | 2004-06-17 | 2007-02-28 | Ciba Specialty Chemicals Holding Inc. | Polystyrene containing masterbatch composition for polyester modification |
CN103228711A (zh) * | 2010-12-03 | 2013-07-31 | 普立万公司 | 用于喷射模塑的塑料制品的塑料溶胶 |
JP5892734B2 (ja) * | 2011-05-02 | 2016-03-23 | スリーエム イノベイティブ プロパティズ カンパニー | 熱伝導性シート |
PL2980148T3 (pl) * | 2013-03-28 | 2018-03-30 | Denka Company Limited | Mieszanka kauczukowa, kompozycja mieszanki kauczukowej i wulkanizat |
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- 2015-10-23 KR KR1020177015018A patent/KR102601295B1/ko active IP Right Grant
- 2015-10-23 US US15/524,554 patent/US10273334B2/en active Active
- 2015-10-23 SG SG11201703347QA patent/SG11201703347QA/en unknown
- 2015-10-23 EP EP15790056.4A patent/EP3215560B1/en active Active
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- 2015-10-23 AU AU2015342120A patent/AU2015342120A1/en not_active Abandoned
- 2015-10-23 CN CN201580058082.8A patent/CN107108872B/zh active Active
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JP2017532427A (ja) | 2017-11-02 |
KR102601295B1 (ko) | 2023-11-14 |
TW201634549A (zh) | 2016-10-01 |
EP3215560A1 (en) | 2017-09-13 |
BR112017008379B1 (pt) | 2022-05-03 |
CA2966427C (en) | 2023-10-03 |
PL3215560T3 (pl) | 2020-03-31 |
CN107108872A (zh) | 2017-08-29 |
KR20170082564A (ko) | 2017-07-14 |
CA2966427A1 (en) | 2016-05-12 |
US10273334B2 (en) | 2019-04-30 |
ES2745224T3 (es) | 2020-02-28 |
AU2015342120A1 (en) | 2017-05-04 |
EP3215560B1 (en) | 2019-07-24 |
WO2016071126A1 (en) | 2016-05-12 |
MX2017005905A (es) | 2017-11-17 |
US20170313813A1 (en) | 2017-11-02 |
TWI762437B (zh) | 2022-05-01 |
EP3018169A1 (en) | 2016-05-11 |
BR112017008379A2 (pt) | 2017-12-19 |
SG11201703347QA (en) | 2017-05-30 |
CN107108872B (zh) | 2021-05-28 |
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