JP6816269B2 - ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 - Google Patents
ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 Download PDFInfo
- Publication number
- JP6816269B2 JP6816269B2 JP2019520054A JP2019520054A JP6816269B2 JP 6816269 B2 JP6816269 B2 JP 6816269B2 JP 2019520054 A JP2019520054 A JP 2019520054A JP 2019520054 A JP2019520054 A JP 2019520054A JP 6816269 B2 JP6816269 B2 JP 6816269B2
- Authority
- JP
- Japan
- Prior art keywords
- gas
- membrane
- liquid
- nanoporous
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000012528 membrane Substances 0.000 title claims description 82
- 238000000034 method Methods 0.000 title claims description 69
- 239000000203 mixture Substances 0.000 title claims description 35
- 239000007789 gas Substances 0.000 claims description 86
- 239000007788 liquid Substances 0.000 claims description 34
- 230000002745 absorbent Effects 0.000 claims description 29
- 239000002250 absorbent Substances 0.000 claims description 29
- 239000011148 porous material Substances 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 24
- 239000006096 absorbing agent Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 21
- 238000000605 extraction Methods 0.000 claims description 20
- 239000012071 phase Substances 0.000 claims description 19
- 239000007791 liquid phase Substances 0.000 claims description 18
- 239000012510 hollow fiber Substances 0.000 claims description 17
- 238000005187 foaming Methods 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 230000008929 regeneration Effects 0.000 claims description 6
- 238000011069 regeneration method Methods 0.000 claims description 6
- 239000002033 PVDF binder Substances 0.000 claims description 5
- -1 polytetrafluoroethylene Polymers 0.000 claims description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 5
- 239000003345 natural gas Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000003209 petroleum derivative Substances 0.000 claims description 4
- 239000004695 Polyether sulfone Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920006393 polyether sulfone Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 239000004696 Poly ether ether ketone Substances 0.000 claims 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims 1
- 229920002530 polyetherether ketone Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- 230000002378 acidificating effect Effects 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 238000009736 wetting Methods 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- 238000005192 partition Methods 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/24—Dialysis ; Membrane extraction
- B01D61/246—Membrane extraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0093—Chemical modification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
- B01D71/261—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
- B01D71/262—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/52—Polyethers
- B01D71/522—Aromatic polyethers
- B01D71/5222—Polyetherketone, polyetheretherketone, or polyaryletherketone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/104—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D2053/221—Devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2313/00—Details relating to membrane modules or apparatus
- B01D2313/40—Adsorbents within the flow path
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/0283—Pore size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/025—Aluminium oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/34—Polyvinylidene fluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
- B01D71/68—Polysulfones; Polyethersulfones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/103—Sulfur containing contaminants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Urology & Nephrology (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Gas Separation By Absorption (AREA)
Description
酸性成分の抽出のプロセスは次のようにして実施される。供給ガスは、パートラクションモジュールの酸性ガス吸収体に供給される。吸収材とガスとの間の接触は、〜30℃の温度で起こり、吸収材溶液の再生は80から130℃で起こる。再生のために、吸収材溶液は、吸収したCO2およびH2Sの脱着が起こる再生器に周期的に供給される。
Claims (9)
- 天然ガスおよびプロセスガス混合物の成分をパートラクションにより抽出する方法であって、
膜の一方の側に、気相にある供給混合物を通過させ、および前記膜の反対の側に、液体吸収材を通過させるステップと、
孔を介したガス成分の拡散および液体吸収材の流れを用いたそれらの吸収を提供するステップとを含み、
ナノ多孔性膜が使用され、同時に前記気相と前記液体吸収材との間に、前記天然ガスおよびプロセスガスを前記液体吸収材の液相の中へ、および前記液体吸収材の液相を前記気相の中へ浸透させることを防ぐように前記膜の泡立ち点圧力より低い圧力差を生じさせ、
前記ナノ多孔性膜の平均孔径は5から500nmの範囲であり、孔径分布は50%を超えないことを特徴としており、
前記ナノ多孔性膜の充填密度が、1000から3200m 2 /m 3 の間であることを特徴とする、方法。 - 前記膜の泡立ち点圧力は、最大で10バールまでであることを特徴とする、請求項1に記載の方法。
- 前記ナノ多孔性膜は、平坦なシート形状もしくは管状形状、または中空繊維の形態で作られることを特徴とする、請求項1に記載の方法。
- 前記ナノ多孔性膜の外面は、化学的に修飾されて前記液体吸収材に対してより高い親和性を提供することを特徴とする、請求項3に記載の方法。
- 前記ナノ多孔性膜は、多孔性基板上に配置されたナノ多孔性層の形態で作られることを特徴とする、請求項3に記載の方法。
- 抽出される前記成分は、CO2、H2S、SO2、CH3SH、C2H5SHおよび(CH3)2Sからなる群から選択され、天然ガス、プロセスガス、または随伴石油ガスが前記供給混合物として使用されることを特徴とする請求項1に記載の方法。
- モノエタノールアミン、ジエタノールアミンおよびメチルジエタノールアミンからなる群から選択されるアミンの溶液が前記液体吸収材として使用されることを特徴とする、請求項1に記載の方法。
- ポリテトラフルオロエチレン、ポリプロピレン、ポリスルホン、ポリエーテルスルホン、ポリエーテルエーテルケトン、ポリフッ化ビニリデンおよびアルミナからなる群から選択される材料が前記ナノ多孔性膜の材料として使用されることを特徴とする、請求項6に記載の方法。
- 前記膜を通過した前記液体吸収材の再生はさらに、前記液体吸収材を別のナノ多孔性膜に通過させることにより、前記膜の泡立ち点圧力未満で前記気相と前記液体吸収材との間に圧力差を与えることにより、および吸着した成分を含有していないストリッピングガスを使用することにより、実施され、浄化された液体吸収材は、天然ガスおよびプロセスガス混合物の成分の抽出のために再使用されることを特徴とする、請求項1に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2016140487 | 2016-10-14 | ||
RU2016140487A RU2626645C1 (ru) | 2016-10-14 | 2016-10-14 | Способ извлечения компонентов из природных и технологических газовых смесей пертракцией на нанопористых мембранах |
PCT/RU2017/050100 WO2018070904A1 (ru) | 2016-10-14 | 2017-10-03 | Способ извлечения компонентов газовых смесей пертракцией на нанопористых мембранах |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020176624A Division JP2021006346A (ja) | 2016-10-14 | 2020-10-21 | ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2019534785A JP2019534785A (ja) | 2019-12-05 |
JP6816269B2 true JP6816269B2 (ja) | 2021-01-20 |
Family
ID=59632407
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019520054A Active JP6816269B2 (ja) | 2016-10-14 | 2017-10-03 | ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 |
JP2020176624A Pending JP2021006346A (ja) | 2016-10-14 | 2020-10-21 | ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020176624A Pending JP2021006346A (ja) | 2016-10-14 | 2020-10-21 | ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US10828599B2 (ja) |
JP (2) | JP6816269B2 (ja) |
CN (1) | CN109952143A (ja) |
DE (1) | DE112017005224B4 (ja) |
NO (1) | NO345261B1 (ja) |
RU (1) | RU2626645C1 (ja) |
WO (1) | WO2018070904A1 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2626645C1 (ru) | 2016-10-14 | 2017-07-31 | Публичное акционерное общество "Нефтяная компания "Роснефть" | Способ извлечения компонентов из природных и технологических газовых смесей пертракцией на нанопористых мембранах |
US10702826B2 (en) * | 2017-12-12 | 2020-07-07 | University Of Kentucky Research Foundtion | Method and apparatus for increasing mass transfer in aqueous gas adsorption processes |
RU2718928C1 (ru) * | 2018-12-27 | 2020-04-15 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Модифицированная нанопористая полимерная мембрана с улучшенными водоотталкивающими свойствами для мембранных контакторов и способ ее получения |
WO2020206148A1 (en) * | 2019-04-03 | 2020-10-08 | Arizona Board Of Regents On Behalf Of Arizona State University | System and method for carbon dioxide capture through membrane conduits |
WO2021022535A1 (en) * | 2019-08-08 | 2021-02-11 | Petroliam Nasional Berhad (Petronas) | Improved gas exchange system and method |
CN112933879B (zh) * | 2019-12-10 | 2022-11-08 | 中国科学院大连化学物理研究所 | 一种用于烟道气中co2分离的膜吸收/膜解吸耦合方法 |
RU2768147C1 (ru) * | 2020-12-23 | 2022-03-23 | федеральное государственное бюджетное образовательное учреждение высшего образования "Нижегородский государственный технический университет им. Р.Е. Алексеева" (НГТУ) | Способ удаления диоксида углерода и сероводорода из метансодержащих газовых смесей |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5358975A (en) * | 1976-11-09 | 1978-05-27 | Kanegafuchi Chem Ind Co Ltd | Gas separator |
NL9401233A (nl) * | 1994-03-25 | 1995-11-01 | Tno | Werkwijze voor membraangasabsorptie. |
US6165253A (en) * | 1994-05-23 | 2000-12-26 | New Jersey Institute Of Technology | Apparatus for removal of volatile organic compounds from gaseous mixtures |
US5637224A (en) * | 1994-09-14 | 1997-06-10 | New Jersey Institute Of Technology | Hollow fiber contained liquid membrane pervaporation for removal of volatile organic compounds from aqueous solutions |
US5954858A (en) * | 1995-11-22 | 1999-09-21 | North Carolina State University | Bioreactor process for the continuous removal of organic compounds from a vapor phase process stream |
NO302454B1 (no) | 1996-07-31 | 1998-03-09 | Kvaerner Asa | Fremgangsmåte til fjerning av karbondioksid fra gasser |
JPH1099665A (ja) * | 1996-09-27 | 1998-04-21 | Japan Gore Tex Inc | 気体分離膜および気体分離法 |
JPH10272333A (ja) * | 1997-01-31 | 1998-10-13 | Japan Organo Co Ltd | ガス精製方法、空気浄化方法、及びそれらの装置 |
JP3929723B2 (ja) * | 2001-06-06 | 2007-06-13 | 月島機械株式会社 | メタン濃縮装置 |
NL1026537C2 (nl) | 2004-07-01 | 2006-01-03 | Tno | Membraangasscheiding. |
JP5061328B2 (ja) * | 2006-04-04 | 2012-10-31 | 大陽日酸株式会社 | メタン分離方法、メタン分離装置及びメタン利用システム |
JP5361117B2 (ja) * | 2006-04-28 | 2013-12-04 | 旭化成ケミカルズ株式会社 | 気体分離膜 |
WO2007134994A2 (de) * | 2006-05-18 | 2007-11-29 | Basf Se | Kohlendioxid-absorptionsmittel mit verringertem regenerations-energiebedarf |
JP2008200589A (ja) * | 2007-02-19 | 2008-09-04 | Kansai Electric Power Co Inc:The | ガス分離方法及びガス分離装置 |
GB0704003D0 (en) | 2007-03-01 | 2007-04-11 | Oxford Catalysts | Promoted carbide-based fischer-tropsch catalyst, method for its preparation and uses thereof |
US7544340B2 (en) * | 2007-03-13 | 2009-06-09 | Gas Technology Institute | Method for creating a gas-liquid contact area |
AU2009203714B2 (en) * | 2008-01-08 | 2011-11-17 | Shell Internationale Research Maatschappij B.V. | Multi - stage membrane separation process |
RU2392038C1 (ru) | 2008-12-01 | 2010-06-20 | Федеральное государственное образовательное учреждение высшего профессионального образования Санкт-Петербургский государственный университет | Устройство для осуществления массообмена между жидкой и газовой фазами |
JP2013505824A (ja) * | 2009-09-24 | 2013-02-21 | ゴア エンタープライズ ホールディングス,インコーポレイティド | 多孔質フィルターのための完全性試験方法 |
US20120247327A1 (en) * | 2010-09-27 | 2012-10-04 | Conocophillips Company | Hollow-fiber membrane contactors |
KR101783794B1 (ko) | 2010-10-18 | 2017-11-06 | 벨로시스, 인코포레이티드 | 용접된 마이크로채널 프로세서 |
RU2011101428A (ru) * | 2011-01-14 | 2012-07-20 | Недерландсе Органисати Вор Тугепаст-Натюрветенсхаппелейк Ондерзук (Тно) (Nl) | Способ и устройство для разделения газовой смеси |
US8702844B2 (en) | 2011-04-18 | 2014-04-22 | Phillips 66 Company | Particle doped hollow-fiber contactor |
EP2537576A1 (en) * | 2011-06-24 | 2012-12-26 | Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO | Pertraction process |
RU113670U1 (ru) * | 2011-09-23 | 2012-02-27 | Учреждение Научно-исследовательский институт строительной физики Российской академии архитектуры и строительных наук (НИИСФ РААСН) | Установка для мембранно-абсорбционной очистки газовых смесей от кислых компонентов |
RU128515U1 (ru) | 2012-10-10 | 2013-05-27 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Мембранный контактор высокого давления и абсорбционно-десорбционное устройство на его основе для разделения и выделения диоксида углерода из попутных и дымовых газов процессов нефтехимии и энергетики |
US9072987B2 (en) * | 2013-03-15 | 2015-07-07 | Gas Technology Institute | Method and apparatus for desorption using a microporous membrane operated in wetted mode |
CN103342623A (zh) * | 2013-05-07 | 2013-10-09 | 石河子大学 | 一种中空纤维膜接触器分离纯化等离子体裂解煤混合气中乙炔的方法及系统 |
US9751042B2 (en) * | 2014-07-18 | 2017-09-05 | New Jersey Institute Of Technology | Systems and methods for CO2 removal from flue gas by temperature swing absorption |
EP3227005B1 (en) * | 2014-12-05 | 2019-02-06 | VLAAMSE INSTELLING VOOR TECHNOLOGISCH ONDERZOEK, afgekort V.I.T.O., onderneming van openbaar nut onder de vorm van een n.v. | Membrane cartridge with integrated functions |
GB2534383A (en) * | 2015-01-21 | 2016-07-27 | Deng Liyuan | Process |
CN105597553A (zh) * | 2016-03-17 | 2016-05-25 | 江苏久吾高科技股份有限公司 | 一种用于膜吸收过程的陶瓷膜制备方法 |
RU2626645C1 (ru) | 2016-10-14 | 2017-07-31 | Публичное акционерное общество "Нефтяная компания "Роснефть" | Способ извлечения компонентов из природных и технологических газовых смесей пертракцией на нанопористых мембранах |
-
2016
- 2016-10-14 RU RU2016140487A patent/RU2626645C1/ru active
-
2017
- 2017-10-03 CN CN201780063174.4A patent/CN109952143A/zh active Pending
- 2017-10-03 WO PCT/RU2017/050100 patent/WO2018070904A1/ru active Application Filing
- 2017-10-03 JP JP2019520054A patent/JP6816269B2/ja active Active
- 2017-10-03 DE DE112017005224.6T patent/DE112017005224B4/de active Active
- 2017-10-03 US US16/341,867 patent/US10828599B2/en active Active
-
2019
- 2019-05-07 NO NO20190580A patent/NO345261B1/en unknown
-
2020
- 2020-10-21 JP JP2020176624A patent/JP2021006346A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JP2019534785A (ja) | 2019-12-05 |
RU2626645C1 (ru) | 2017-07-31 |
US20190240616A1 (en) | 2019-08-08 |
US10828599B2 (en) | 2020-11-10 |
NO20190580A1 (en) | 2019-05-07 |
JP2021006346A (ja) | 2021-01-21 |
WO2018070904A1 (ru) | 2018-04-19 |
CN109952143A (zh) | 2019-06-28 |
NO345261B1 (en) | 2020-11-23 |
DE112017005224T5 (de) | 2019-07-11 |
DE112017005224B4 (de) | 2021-11-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6816269B2 (ja) | ナノ多孔性膜上でのパートラクションによるガス混合物の成分を抽出する方法 | |
Lin et al. | Absorption of carbon dioxide by mixed piperazine–alkanolamine absorbent in a plasma-modified polypropylene hollow fiber contactor | |
Lin et al. | Absorption of carbon dioxide by the absorbent composed of piperazine and 2-amino-2-methyl-1-propanol in PVDF membrane contactor | |
Wongchitphimon et al. | Polymer-fluorinated silica composite hollow fiber membranes for the recovery of biogas dissolved in anaerobic effluent | |
US8317906B2 (en) | Membrane contactor systems for gas-liquid contact | |
AU2014254377B2 (en) | Sweetening of natural gas by membrane contactor | |
AU2014238156B2 (en) | Method and apparatus for desorption using microporous membrane operated in wetted mode | |
Lin et al. | Determination of mass transfer resistance during absorption of carbon dioxide by mixed absorbents in PVDF and PP membrane contactor | |
CN105084466B (zh) | 一种含硫气体的脱硫剂净化工艺及装置 | |
Shutova et al. | Regeneration of alkanolamine solutions in membrane contactor based on novel polynorbornene | |
Ward et al. | Chemical absorption—amine absorption/stripping technology for biogas upgrading | |
RU2672452C1 (ru) | Мембранный контактор для очистки природных и технологических газов от кислых компонентов | |
CN204918092U (zh) | 一种含硫气体的脱硫剂净化装置 | |
JP2019205966A (ja) | Co2膜分離方法 | |
Mohammed et al. | CO2 Absorption in Membrane Contactor using Piperazine, Monoethanolamine and Diethanolamine: A Mass Transfer and Performance Study | |
AU2018256480B2 (en) | Process and system for treating natural gas feedstock | |
CN111068461B (zh) | 一种苯乙烯废气的处理方法 | |
Siagian et al. | Transversal Submerged Membrane Contactor for Simultaneous Absorption and Desorption of CO2 During Natural Gas Sweetening Process | |
KR20090041491A (ko) | 기액 접촉기용 이산화탄소 흡수제 | |
Lu | Membrane Contactor | |
Pavel et al. | The Basic Technologies of Mass Transfer and Their Progress in the Field of Upgrading Biogas | |
CN111068462A (zh) | 一种苯乙烯废气的处理方法 | |
Ratman | THE CHARACTERIZATION AND REMOVAL OF FOAM PROMOTING IMPURITIES FROM THE BLENDED METHYLDIETHANOLAMINE-PIPERAZINE SOLUTION USING MEMBRANE | |
Amaral et al. | INTEGRATION OF MEMBRANE TECHNOLOGIES FOR CO2 REMOVAL FROM NATURAL GAS IN OFFSHORE PLATFORMS | |
PL216277B1 (pl) | Sposób i układ do kondycjonowania surowego gazu ziemnego |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20190611 |
|
A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20190611 |
|
A975 | Report on accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A971005 Effective date: 20190828 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20191015 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20200115 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200414 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20200629 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20201021 |
|
C60 | Trial request (containing other claim documents, opposition documents) |
Free format text: JAPANESE INTERMEDIATE CODE: C60 Effective date: 20201021 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20201030 |
|
C21 | Notice of transfer of a case for reconsideration by examiners before appeal proceedings |
Free format text: JAPANESE INTERMEDIATE CODE: C21 Effective date: 20201102 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20201207 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20201223 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6816269 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |