JP6722496B2 - Water repellent inhibitor and culture soil using it - Google Patents
Water repellent inhibitor and culture soil using it Download PDFInfo
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- JP6722496B2 JP6722496B2 JP2016082442A JP2016082442A JP6722496B2 JP 6722496 B2 JP6722496 B2 JP 6722496B2 JP 2016082442 A JP2016082442 A JP 2016082442A JP 2016082442 A JP2016082442 A JP 2016082442A JP 6722496 B2 JP6722496 B2 JP 6722496B2
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- Prior art keywords
- culture soil
- water
- water repellent
- alcohol
- soil
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Landscapes
- Cultivation Of Plants (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Description
本発明は、培養土や土壌の撥水抑制に使用される撥水抑制剤とそれを用いた培養土に関する。 The present invention relates to a water repellent inhibitor used for suppressing water repellency of culture soil and soil, and culture soil using the same.
野菜、果樹、花卉等の栽培に使用される多くの苗床や培土など各種土壌は、栽培の経過とともに給水、乾燥を繰り返すことによって、土壌の密度が高くなり、水の浸透性が低下する。さらに、有機物質や無機物質の土壌改良材、肥料、土等をブレンドした培養土、特にピートモス等の有機物質は、乾燥した植物性の繊維状物質に特有の撥水性を有しており、なおさら植物に十分に水が行きわたらなくなる。その結果、植物の生育が抑制され、十分に発育しなくなる場合があった。 For various soils such as many nurseries and soils used for cultivation of vegetables, fruit trees, flowers and the like, the density of the soil increases and the water permeability decreases by repeating water supply and drying with the progress of cultivation. Furthermore, soil soil improvers of organic and inorganic substances, fertilizers, culture soils blended with soil, especially organic substances such as peat moss have the water repellency peculiar to dried plant fibrous substances, If the plants are not fully watered, they will run out. As a result, the growth of plants was suppressed, and there were cases where the plants did not grow sufficiently.
培養土は、通常50質量%程度の水分を含有しているが、培養土中に化学肥料が配合されていると、変質して肥料本来の機能を発揮しない虞があり、また高齢者作業時の負担軽減、輸送の効率化を図るべく軽量化するために、含水率を低減することが望まれている。 The culture soil usually contains about 50% by mass of water, but if a chemical fertilizer is mixed in the culture soil, there is a possibility that the soil may be altered and the original function of the fertilizer may not be exerted. It is desired to reduce the water content in order to reduce the weight in order to reduce the burden on the vehicle and improve the efficiency of transportation.
従来、培養土の撥水抑制のために、界面活性剤を配合する方法が提案されている(特許文献1〜18)。これらの従来技術においては、アニオン界面活性剤もしくはノニオン界面活性剤のいずれか1種を単独で使用したものについて撥水抑制作用が具体的に検証されている。アニオン界面活性剤としては、ジアルキルスルホコハク酸塩、アルキルナフタレンスルホン酸ナトリウム、アルキルベンゼンスルホン酸ナトリウム等が実施例において検証され、ノニオン界面活性剤としては、ポリオキシエチレンポリオキシプロピレンブロックコポリマー、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル等のエーテル型、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル等のエステル型、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル等のエステルエーテル型等が実施例において検証されている。 Conventionally, in order to suppress water repellency of the culture soil, a method of incorporating a surfactant has been proposed (Patent Documents 1 to 18). In these prior arts, the water-repellent effect is specifically verified for those using either an anionic surfactant or a nonionic surfactant alone. As the anionic surfactant, dialkyl sulfosuccinate, sodium alkylnaphthalene sulfonate, sodium alkylbenzene sulfonate, etc. were verified in the examples, and as the nonionic surfactant, polyoxyethylene polyoxypropylene block copolymer, polyoxyalkylene alkyl were used. Examples include ether type such as ether and polyoxyethylene alkylphenyl ether, ester type such as glycerin fatty acid ester, sorbitan fatty acid ester and sucrose fatty acid ester, and ester ether type such as polyethylene glycol fatty acid ester and polyoxyethylene sorbitan fatty acid ester. Has been verified in.
しかしながら、通常培養土は製造後に輸送や保存されるため、培養土を製造してから実際に使用されるまでの間にはタイムラグが生ずるが、培養土の製造場所からの輸送や倉庫での保管の期間を経て使用されると、製造直後のような撥水抑制能を示さない場合があった。 However, since the culture soil is usually transported or stored after production, there is a time lag between the production of the culture soil and its actual use. When used after a period of, the water repellency-inhibiting ability as immediately after production may not be exhibited.
また、アニオン界面活性剤のみで撥水を抑制しようとすると、泡立ちによってハンドリング性が悪くなり、また植害や根腐れなど、植物の生育に悪影響を及ぼす虞があった。一方、ノニオン界面活性剤のみでは、撥水抑制能を長期間維持させることが難しく、また脂肪酸エステル型ノニオン界面活性剤では分解しやすく、分解により生じた脂肪酸により培養土が撥水する虞があった。 Further, if it is attempted to suppress the water repellency only by using the anionic surfactant, the handling property is deteriorated due to foaming, and there is a possibility that the plant growth such as plant damage and root rot is adversely affected. On the other hand, it is difficult to maintain the water repellency suppressing ability for a long time only with the nonionic surfactant, and it is easy to decompose with the fatty acid ester type nonionic surfactant, and the fatty acid generated by the decomposition may cause the culture soil to be water repellent. It was
上記特許文献1〜18には、各イオン性の界面活性剤として種々の化合物が挙げられているが、具体的に開示されたものはいずれもアニオン界面活性剤もしくはノニオン界面活性剤を単独で使用したもので、異なるイオン性を持つ界面活性剤の併用系については検証されていない。さらに、培養土の含水率低減については、十分な水の浸透性が得られず、実現に至っていない状況である。 The above-mentioned Patent Documents 1 to 18 list various compounds as the ionic surfactants, but all of the specifically disclosed compounds use the anionic surfactant or the nonionic surfactant alone. However, a combination system of surfactants having different ionic properties has not been verified. Furthermore, the reduction of the water content of the culture soil has not been realized because sufficient water permeability has not been obtained.
なお、特許文献1〜18のうち、例えば特許文献1には、繊維系素材および界面活性剤とともに接着剤としてポリエチレン樹脂や尿素樹脂を配合し、これらの樹脂の融点以上の温度で加熱成形しマットにする技術が提案されているが、水分量20〜60質量%の培養土については記載されていない。特許文献14、15には、PET樹脂やポリ乳酸樹脂等の人工合成品である化学繊維を培養土成分に用いて界面活性剤を配合した人工培養土が記載されているが、ピートモス等の植物性の繊維状物質や、その他天然の無機物質を培養土成分に用いた場合については記載されていない。 In addition, among Patent Documents 1 to 18, for example, in Patent Document 1, a polyethylene resin or a urea resin is mixed as an adhesive together with a fiber-based material and a surfactant, and the mat is formed by heating at a temperature equal to or higher than the melting point of these resins. However, the culture soil having a water content of 20 to 60% by mass is not described. Patent Documents 14 and 15 describe artificial culture soil in which a synthetic fiber such as PET resin or polylactic acid resin is used as a culture soil component and a surfactant is mixed, but plants such as peat moss are described. No mention is made of the case of using a fibrous substance having a sex property or other natural inorganic substance as a component of the culture soil.
本発明は、以上の通りの事情に鑑みてなされたものであり、ハンドリング性が良好で、これを付着させた培養土や土壌は、使用されるまでにタイムラグが生じても、素早く均一に水を浸透させることができ、透水性を有し、長期間にわたって安定した撥水抑制能を維持させることができ、植物の生育を促進することができる撥水抑制剤とそれを用いた培養土を提供することを課題としている。また、培養土の含水率の低減化を図っても浸透性を有する撥水抑制剤とそれを用いた培養土を提供することを課題としている。 The present invention has been made in view of the circumstances as described above, has good handleability, and the culture soil and the soil to which this is adhered can be quickly and uniformly watered even if a time lag occurs until it is used. A water repellent inhibitor capable of permeating water, having water permeability, maintaining stable water repellent inhibiting ability for a long period of time, and promoting plant growth, and a culture soil using the same. The challenge is to provide. Another object is to provide a water-repellent inhibitor having permeability and a culture soil using the same, even if the water content of the culture soil is reduced.
上記の課題を解決するために、本発明の撥水抑制剤は、水分量が20〜60質量%である培養土、または土壌の撥水抑制に使用される撥水抑制剤であって、次のアニオン界面活性剤(A)およびノニオン界面活性剤(B)を含有し、(A)/(B)で表される質量比が0.01〜5.00であることを特徴としている:
(A)スルホン酸塩型および硫酸塩型から選ばれる少なくとも1種のアニオン界面活性剤;および
(B)ポリオキシアルキレングリコール、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンスチレン化フェニルエーテル、ポリオキシエチレン(硬化)ヒマシ油、ポリオキシエチレンアルキルアミン、および脂肪酸アルカノールアミドから選ばれる少なくとも1種のノニオン界面活性剤。
In order to solve the above problems, the water repellent inhibitor of the present invention is a water repellent inhibitor used for suppressing water repellent of a culture soil having a water content of 20 to 60% by mass, or soil, Of the anionic surfactant (A) and the nonionic surfactant (B), and the mass ratio represented by (A)/(B) is 0.01 to 5.00:
(A) at least one anionic surfactant selected from sulfonate type and sulfate type; and (B) polyoxyalkylene glycol, polyoxyalkylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene styrenated At least one nonionic surfactant selected from phenyl ether, polyoxyethylene (hardened) castor oil, polyoxyethylene alkylamine, and fatty acid alkanolamide.
本発明の培養土は、上記撥水抑制剤を培養土成分に付着させた、水分量が20〜60質量%のものであることを特徴としている。 The culture soil of the present invention is characterized in that the water repellent inhibitor is attached to the culture soil component and has a water content of 20 to 60% by mass.
本発明の撥水抑制剤によれば、ハンドリング性が良好で、これを付着させた培養土や土壌は、使用されるまでにタイムラグが生じても、素早く均一に水を浸透させることができ、透水性を有し、長期間にわたって安定した撥水抑制能を維持させることができ、植物の生育を促進する。さらに、培養土の含水率を低減しても浸透性を有する。 According to the water repellent inhibitor of the present invention, the handling property is good, the culture soil and the soil to which it is attached can be quickly and uniformly permeated with water even if a time lag occurs before it is used, It has water permeability and can maintain stable water repellency suppressing ability for a long period of time, and promotes plant growth. Furthermore, it has permeability even if the water content of the culture soil is reduced.
また、本発明の培養土によれば、使用されるまでにタイムラグが生じても、素早く均一に水を浸透させることができ、透水性を有し、長期間にわたって安定した撥水抑制能を維持させることができ、植物の生育を促進する。さらに、含水率を低減しても浸透性を有する。 Further, according to the culture soil of the present invention, even if there is a time lag before use, water can be quickly and uniformly permeated, has water permeability, and maintains stable water repellent suppression ability for a long period of time. Can promote the growth of plants. Furthermore, it has permeability even if the water content is reduced.
以下に、本発明を詳細に説明する。
(撥水抑制剤)
本発明の撥水抑制剤に使用されるアニオン界面活性剤(A)は、スルホン酸塩型および硫酸塩型から選ばれる少なくとも1種のアニオン界面活性剤である。
The present invention will be described in detail below.
(Water repellent inhibitor)
The anionic surfactant (A) used in the water repellent inhibitor of the present invention is at least one anionic surfactant selected from a sulfonate type and a sulfate type.
スルホン酸塩型のアニオン界面活性剤としては、例えば、アルキルスルホコハク酸塩、アルキルベンゼンスルホン酸塩、アルファオレフィンスルホン酸塩等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the sulfonate-type anionic surfactant include alkyl sulfosuccinate, alkylbenzene sulfonate, and alpha olefin sulfonate. These may be used alone or in combination of two or more.
アルキルスルホコハク酸塩としては、例えば、アルキル基がイソブチル基、ペンチル基、ヘキシル基、オクチル基、2−エチルヘキシル基、デシル等の炭素数4〜10のものであり、カチオン種がナトリウム、カリウム等である、モノまたはジアルキルスルホコハク酸塩等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the alkyl sulfosuccinate include an alkyl group having an isobutyl group, a pentyl group, a hexyl group, an octyl group, a 2-ethylhexyl group, a decyl group and the like having 4 to 10 carbon atoms, and a cation species such as sodium and potassium. There are certain mono- or dialkyl sulfosuccinates and the like. These may be used alone or in combination of two or more.
アルキルベンゼンスルホン酸塩としては、例えば、アルキル基が炭素数10〜18の直鎖状であり、カチオン種がナトリウム、カリウム等であるもの等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the alkylbenzene sulfonate include those in which the alkyl group is a linear chain having 10 to 18 carbon atoms and the cation species are sodium, potassium and the like. These may be used alone or in combination of two or more.
アルファオレフィンスルホン酸塩としては、例えば、アルケニル基が炭素数12〜18であり、カチオン種がナトリウム、カリウム等であるもの等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the alpha olefin sulfonate include those having an alkenyl group having 12 to 18 carbon atoms and a cation species of sodium, potassium and the like. These may be used alone or in combination of two or more.
硫酸塩型のアニオン界面活性剤としては、例えば、アルキル硫酸エステル塩、アルキルエーテル硫酸エステル塩等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of sulfate type anionic surfactants include alkyl sulfate ester salts and alkyl ether sulfate ester salts. These may be used alone or in combination of two or more.
アルキル硫酸エステル塩としては、例えば、アルキル基が炭素数12〜18であり、カチオン種がナトリウム、カリウム等であるもの等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the alkyl sulfate ester salt include those in which the alkyl group has 12 to 18 carbon atoms and the cation species are sodium, potassium and the like. These may be used alone or in combination of two or more.
アルキルエーテル硫酸エステル塩としては、例えば、炭素数12〜18の高級アルコールにエチレンオキシド(EO)を付加させたものを硫酸エステル化して得られるポリオキシエチレンアルキルエーテル硫酸の塩であり、カチオン種がナトリウム、カリウム等であるもの等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 The alkyl ether sulfuric acid ester salt is, for example, a salt of polyoxyethylene alkyl ether sulfuric acid obtained by sulfuric acid esterification of a higher alcohol having 12 to 18 carbon atoms with ethylene oxide (EO), and the cationic species is sodium. , Potassium and the like. These may be used alone or in combination of two or more.
本発明の撥水抑制剤に使用されるノニオン界面活性剤(B)は、ポリオキシアルキレングリコール、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンスチレン化フェニルエーテル、ポリオキシエチレン(硬化)ヒマシ油、ポリオキシエチレンアルキルアミン、および脂肪酸アルカノールアミドから選ばれる少なくとも1種のノニオン界面活性剤である。 The nonionic surfactant (B) used in the water repellent inhibitor of the present invention is polyoxyalkylene glycol, polyoxyalkylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene styrenated phenyl ether, polyoxyethylene ( Hardened) At least one nonionic surfactant selected from castor oil, polyoxyethylene alkylamine, and fatty acid alkanolamide.
ポリオキシアルキレングリコールとしては、例えば、ポリエチレングリコール、ポリプロピレングリコール、ポリプロピレングリコールエチレンオキサイド付加物等が挙げられる。これらの中でも、ポリプロピレングリコールエチレンオキサイド付加物が好ましく、エチレンオキサイド含有率が40%以下であることがより好ましく、例えば、プロピレンオキシド25〜35モル付加物であるポリプロピレングリコールのエチレンオキサイド3〜30モル付加物等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of polyoxyalkylene glycols include polyethylene glycol, polypropylene glycol, and polypropylene glycol ethylene oxide adducts. Among these, polypropylene glycol ethylene oxide adduct is preferable, and the ethylene oxide content is more preferably 40% or less, and for example, ethylene glycol 3 to 30 mol addition of polypropylene glycol, which is a propylene oxide 25 to 35 mol adduct. Things etc. are mentioned. These may be used alone or in combination of two or more.
ポリオキシアルキレンアルキルエーテルとしては、例えば、炭素数12〜18の直鎖状もしくは分岐鎖状アルコールのプロピレンオキサイドおよび/またはエチレンオキサイド付加物等が挙げられる。これらの中でも、炭素数12〜18の直鎖状もしくは分岐鎖状アルコールのプロピレンオキサイド2〜10モル付加物、炭素数12〜18の直鎖状もしくは分岐鎖状アルコールのエチレンオキサイド2〜10モル付加物、炭素数12〜18の直鎖状もしくは分岐鎖状アルコールのエチレンオキサイド2〜15モル、プロピレンオキサイド2〜15モルのランダムもしくはブロック付加物が好ましい。ブロック付加物の場合は、乳化分散効果の点で末端エチレンオキサイド付加物が好ましい。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of polyoxyalkylene alkyl ethers include propylene oxide and/or ethylene oxide adducts of linear or branched alcohols having 12 to 18 carbon atoms. Among these, a propylene oxide 2 to 10 mol addition product of a straight or branched chain alcohol having 12 to 18 carbon atoms, and an ethylene oxide 2 to 10 mol addition product of a straight or branched chain alcohol having 12 to 18 carbon atoms And random or block adducts of 2 to 15 mol of ethylene oxide and 2 to 15 mol of propylene oxide of a linear or branched alcohol having 12 to 18 carbon atoms are preferable. In the case of a block addition product, a terminal ethylene oxide addition product is preferable from the viewpoint of the effect of emulsification and dispersion. These may be used alone or in combination of two or more.
特に、ノニオン界面活性剤(B)である上記ポリオキシアルキレングリコール、上記ポリオキシアルキレンアルキルエーテルは、泡立ち等のハンドリング性や撥水抑制能の点から、HLB8以下のものが好ましい。 In particular, the polyoxyalkylene glycol and the polyoxyalkylene alkyl ether, which are the nonionic surfactant (B), are preferably those having an HLB of 8 or less from the viewpoint of handling property such as foaming and water repellency suppressing ability.
ここで、HLB(親水性親油性バランス)は、界面活性剤の全分子量に占める親水基部分の分子量を示すものであり、ポリオキシアルキレン系ノニオン界面活性剤のHLBは、次に示すグリフィン(Griffin)の式により求められる。なお、プロピレンオキサイド単独付加物の場合はHLB値が0となる。
HLB値 = E/5
E:界面活性剤分子中に含まれるポリオキシエチレン部分の質量%
ポリオキシエチレンアルキルフェニルエーテルとしては、炭素数8〜12のアルキルフェノールの3〜50モルのエチレンオキサイド付加物が好ましく、オクチルフェノールのエチレンオキサイド5〜20モル付加物、ノニルフェノールのエチレンオキサイド5〜20モル付加物がより好ましい。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。
Here, HLB (hydrophilic/lipophilic balance) indicates the molecular weight of the hydrophilic group portion in the total molecular weight of the surfactant, and HLB of the polyoxyalkylene nonionic surfactant is the following griffin (Griffin). ) Is obtained. In addition, in the case of a propylene oxide single adduct, the HLB value is 0.
HLB value = E/5
E:% by mass of polyoxyethylene portion contained in the surfactant molecule
As the polyoxyethylene alkylphenyl ether, an ethylene oxide adduct of 3 to 50 mol of an alkylphenol having 8 to 12 carbon atoms is preferable, an ethylene oxide 5 to 20 mol adduct of octylphenol, and an ethylene oxide 5 to 20 mol adduct of nonylphenol. Is more preferable. These may be used alone or in combination of two or more.
ポリオキシエチレンスチレン化フェニルエーテルとしては、(モノ、ジ、トリ)スチレン化フェノールの3〜50モルのエチレンオキサイド付加物等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of polyoxyethylene styrenated phenyl ethers include (mono, di, tri) styrenated phenol of 3 to 50 mol of ethylene oxide adduct. These may be used alone or in combination of two or more.
ポリオキシエチレン(硬化)ヒマシ油としては、ヒマシ油もしくは硬化ヒマシ油のエチレンオキサイド10〜60モル付加物が好ましい。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 The polyoxyethylene (hardened) castor oil is preferably castor oil or a hydrogenated castor oil with 10 to 60 mol of ethylene oxide adduct. These may be used alone or in combination of two or more.
ポリオキシエチレンアルキルアミンとしては、例えば、脂肪族一級アミン(炭素数12〜18の直鎖状もしくは分岐状)のエチレンオキシド2〜20モル付加体等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the polyoxyethylene alkylamine include aliphatic primary amine (linear or branched C12-18 carbon chain) ethylene oxide 2-20 mol adduct. These may be used alone or in combination of two or more.
脂肪酸アルカノールアミドとしては、例えば、ラウリン酸ジエタノールアミド、パルミチン酸ジエタノールアミド、ミリスチン酸ジエタノールアミド、ステアリン酸ジエタノールアミド、オレイン酸ジエタノールアミド、パーム油脂肪酸ジエタノールアミド、ヤシ油脂肪酸ジエタノールアミド等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the fatty acid alkanolamide include lauric acid diethanolamide, palmitic acid diethanolamide, myristic acid diethanolamide, stearic acid diethanolamide, oleic acid diethanolamide, palm oil fatty acid diethanolamide, and coconut oil fatty acid diethanolamide. These may be used alone or in combination of two or more.
本発明の撥水抑制剤は、アニオン界面活性剤(A)およびノニオン界面活性剤(B)に加えて、さらに、炭素数1〜8の1価アルコール、炭素数1〜8の2価アルコール、炭素数1〜8の3価アルコール、および炭素数2〜8のアルコキシアルコールから選ばれる少なくとも1種のアルコール(C)を含有することが好ましい。 The water-repellent inhibitor of the present invention contains, in addition to the anionic surfactant (A) and the nonionic surfactant (B), a monohydric alcohol having 1 to 8 carbon atoms, a dihydric alcohol having 1 to 8 carbon atoms, It is preferable to contain at least one alcohol (C) selected from a trihydric alcohol having 1 to 8 carbon atoms and an alkoxy alcohol having 2 to 8 carbon atoms.
上記アルコール(C)のうち、炭素数1〜8の1価アルコールとしては、例えば、メタノール、エタノール、プロパノール、ブタノール、イソプロパノール、イソブタノール、ペンタノール、2−メチル−2−ブタノール、ヘキサノール、メチルペンタノール、ジメチルブタノール、2−エチルブタノール、ヘプタノール、オクタノール、2−エチルヘキサノール等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Of the above alcohols (C), examples of monohydric alcohols having 1 to 8 carbon atoms include methanol, ethanol, propanol, butanol, isopropanol, isobutanol, pentanol, 2-methyl-2-butanol, hexanol, and methyl pen. Examples thereof include tanol, dimethylbutanol, 2-ethylbutanol, heptanol, octanol and 2-ethylhexanol. These may be used alone or in combination of two or more.
炭素数1〜8の2価アルコールとしては、例えば、メタンジオール、エチレングリコール、1,3−プロパンジオール、1,4−ブタンジオール、1,2−ペンタンジオール、1,4−ペンタンジオール、1,5−ペンタンジオール、3−メチル−1,3−ブタンジオール、2,2−ジメチル−1,3−プロパンジオール、1,2−ヘキサンジオール、1,6−ヘキサンジオール、1,2−オクタンジオール、1,8−オクタンジオール、ジエチレングリコール、トリエチレングリコール、テトラエチレングリコール、プロピレングリコール、ジプロピレングリコール、トリプロピレングリコール等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the dihydric alcohol having 1 to 8 carbon atoms include methanediol, ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,2-pentanediol, 1,4-pentanediol and 1,2. 5-pentanediol, 3-methyl-1,3-butanediol, 2,2-dimethyl-1,3-propanediol, 1,2-hexanediol, 1,6-hexanediol, 1,2-octanediol, 1,8-octanediol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol and the like can be mentioned. These may be used alone or in combination of two or more.
炭素数1〜8の3価アルコールとしては、例えば、グリセリン等が挙げられる。 Examples of the trihydric alcohol having 1 to 8 carbon atoms include glycerin and the like.
炭素数2〜8のアルコキシアルコールとしては、例えば、2−メトキシエタノール、2−エトキシエタノール、2−(n−プロポキシ)エタノール、2−イソプロポキシ−1−エタノール、3−(n−プロポキシ)エタノール、2−(n−ブトキシ)エタノール、2−(2−メトキシエトキシ)エタノール、1−メトキシ−2−プロパノール、1−メトキシ−2−ブタノール、3−メトキシ−1−ブタノール、4−メトキシ−1−ブタノール、1−エトキシ−2−プロパノール、3−メトキシ−3−メチル−1−ブタノール等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the alkoxy alcohol having 2 to 8 carbon atoms include 2-methoxyethanol, 2-ethoxyethanol, 2-(n-propoxy)ethanol, 2-isopropoxy-1-ethanol, 3-(n-propoxy)ethanol, 2-(n-butoxy)ethanol, 2-(2-methoxyethoxy)ethanol, 1-methoxy-2-propanol, 1-methoxy-2-butanol, 3-methoxy-1-butanol, 4-methoxy-1-butanol , 1-ethoxy-2-propanol, 3-methoxy-3-methyl-1-butanol and the like. These may be used alone or in combination of two or more.
本発明の撥水抑制剤においては、上記に例示したアルコール(C)の中でも、炭素数2〜8のアルコキシアルコールが好ましい。 Among the alcohols (C) exemplified above, the water-repellent inhibitor of the present invention is preferably an alkoxy alcohol having 2 to 8 carbon atoms.
本発明の撥水抑制剤は、アニオン界面活性剤(A)とノニオン界面活性剤(B)の(A)/(B)で表される質量比が0.01〜5.00であり、好ましくは0.1〜0.8である。本発明の撥水抑制剤にアルコール(C)を配合する場合には、アニオン界面活性剤(A)とノニオン界面活性剤(B)とアルコール(C)の(C)/((A)+(B))で表される質量比が0.01〜0.25であることが好ましく、より好ましくは0.03〜0.20である。 In the water repellent inhibitor of the present invention, the mass ratio represented by (A)/(B) of the anionic surfactant (A) and the nonionic surfactant (B) is 0.01 to 5.00, and preferably Is 0.1 to 0.8. When an alcohol (C) is added to the water repellent inhibitor of the present invention, the anionic surfactant (A), the nonionic surfactant (B) and the alcohol (C) (C)/((A)+( The mass ratio represented by B)) is preferably 0.01 to 0.25, and more preferably 0.03 to 0.20.
アニオン界面活性剤(A)とノニオン界面活性剤(B)とアルコール(C)をこのような質量比で配合することによって、所望の効果を有する撥水抑制剤が得られる。アニオン界面活性剤(A)は、透水性が良好であるため、撥水抑制能を長期間維持させることができ、ノニオン界面活性剤(B)は、透水性が良好であり、アニオン界面活性剤(A)と併用することで透水性が飛躍的に向上するため、植物の根深くまで水が行き渡り、生育を助長することができ、アルコール(C)は、培養土への浸水スピードを促進させることができる。 By blending the anionic surfactant (A), the nonionic surfactant (B) and the alcohol (C) in such a mass ratio, a water repellent inhibitor having a desired effect can be obtained. Since the anionic surfactant (A) has good water permeability, it can maintain the water repellency suppressing ability for a long time, and the nonionic surfactant (B) has good water permeability, Since water permeability is dramatically improved when used in combination with (A), water can reach deep into the roots of plants and promote growth, and alcohol (C) promotes the speed of inundation of the culture soil. You can
また、本発明の撥水抑制剤は、アニオン界面活性剤(A)とノニオン界面活性剤(B)の質量比(A)/(B)を上記の範囲内とすることにより、アニオン界面活性剤(A)が水に混合、溶解する際に泡立ちが抑制される。また、アニオン界面活性剤(A)、ノニオン界面活性剤(B)が水に混合、溶解する際に増粘、ゲル形成することがあり得ることから、培養土に対して良好に付着し得ると考えられる。そのため透水性に優れ、撥水抑制能を長期間維持させることができ、アニオン界面活性剤(A)による生育阻害をも抑制すると考えられる。 Further, the water repellent inhibitor of the present invention is obtained by adjusting the mass ratio (A)/(B) of the anionic surfactant (A) and the nonionic surfactant (B) within the above range. Foaming is suppressed when (A) is mixed and dissolved in water. Further, when the anionic surfactant (A) and the nonionic surfactant (B) are mixed and dissolved in water, thickening and gel formation may occur, so that they can adhere well to the culture soil. Conceivable. Therefore, it is considered that it has excellent water permeability, can maintain the ability to suppress water repellency for a long period of time, and suppresses growth inhibition due to the anionic surfactant (A).
本発明の撥水抑制剤におけるアニオン界面活性剤(A)とノニオン界面活性剤(B)とアルコール(C)の含有量は、特に限定されるものではないが、アニオン界面活性剤(A)の含有量は、1〜50質量%が好ましく、5〜20質量%がより好ましい。ノニオン界面活性剤(B)の含有量は、10〜90質量%が好ましく、25〜75質量%がより好ましい。アルコール(C)を配合する場合には、その含有量は、1〜20質量%が好ましく、5〜15質量%がより好ましい。 The content of the anionic surfactant (A), the nonionic surfactant (B) and the alcohol (C) in the water repellent inhibitor of the present invention is not particularly limited, but the content of the anionic surfactant (A) is not limited. 1-50 mass% is preferable, and, as for content, 5-20 mass% is more preferable. The content of the nonionic surfactant (B) is preferably 10 to 90% by mass, more preferably 25 to 75% by mass. When the alcohol (C) is added, its content is preferably 1 to 20% by mass, more preferably 5 to 15% by mass.
本発明の撥水抑制剤には、アニオン界面活性剤(A)、ノニオン界面活性剤(B)、アルコール(C)の他、水を配合し希釈して使用することができる。水を配合する場合、本発明の撥水抑制剤にアルコール(C)を配合すると、アニオン界面活性剤(A)、ノニオン界面活性剤(B)が水に混合、溶解する際、増粘、ゲル化することを抑制する状態調整剤としても機能し、良好なハンドリング性を付与することができる。 The water repellent inhibitor of the present invention can be used by adding water in addition to the anionic surfactant (A), the nonionic surfactant (B) and the alcohol (C). When water (B) is blended with the water repellent inhibitor of the present invention, an alcohol (C) is blended, and when the anionic surfactant (A) and the nonionic surfactant (B) are mixed and dissolved in water, thickening and gelation occur. It also functions as a state-conditioning agent that suppresses the occurrence of oxidization, and can impart good handleability.
本発明の撥水抑制剤には、本発明の効果を損なわない範囲内において、上記(A)以外のアニオン界面活性剤、上記(B)以外のノニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、塩類、消泡剤、増粘剤、減粘剤、殺菌剤、溶剤、香料、着色料、pH調整剤、栄養源やミネラル等の肥料分等を配合することができる。 The water repellent inhibitor of the present invention includes an anionic surfactant other than (A) above, a nonionic surfactant other than (B) above, a cationic surfactant, and an amphoteric interface within a range that does not impair the effects of the present invention. Activators, salts, defoamers, thickeners, thickeners, bactericides, solvents, fragrances, colorants, pH adjustors, fertilizers such as nutrient sources and minerals can be added.
本発明の撥水抑制剤は、水分量が20〜60質量%である培養土の撥水抑制に使用することができ、これを付着させた培養土や土壌は、使用されるまでにタイムラグが生じても、素早く均一に水を浸透させることができ、透水性を有し、長期間にわたって安定した撥水抑制能を維持させることができ、植物の生育を促進することができる。培養土の水分量が20質量%より少ないと撥水抑制が困難になり、60質量%より多いと菌の発生や腐敗の虞がある。さらに、本発明の撥水抑制剤は、培養土の含水率を低減しても浸透性を有することを発揮させることができる。すなわち、培養土は、通常50質量%程度の水分を含有しているが、本発明の撥水抑制剤を配合することで、20質量%以上〜40質量%未満に低減しても水の浸透性を有する培養土が得られる。そのため、培養土に化学肥料を配合しても、変質せず肥料本来の機能を発揮させることができ、また軽量化することができるため高齢者作業時の負担軽減や輸送の効率化を図ることができる。 The water-repellent inhibitor of the present invention can be used for water-repellent inhibition of a culture soil having a water content of 20 to 60% by mass, and the culture soil and the soil to which the water-repellent agent is attached have a time lag before being used. Even if it occurs, it can quickly and uniformly permeate water, has water permeability, can maintain a stable water repellency suppressing ability for a long period of time, and can promote the growth of plants. If the water content of the culture soil is less than 20% by mass, it becomes difficult to suppress water repellency, and if it is more than 60% by mass, there is a risk of generation of bacteria and spoilage. Furthermore, the water repellent inhibitor of the present invention can exhibit permeability even if the water content of the culture soil is reduced. That is, the culture soil usually contains about 50% by mass of water, but by incorporating the water repellent inhibitor of the present invention, water permeation can be achieved even if the content is reduced to 20% by mass or more and less than 40% by mass. A culture soil having a property is obtained. Therefore, even if a chemical fertilizer is added to the culture soil, the original function of the fertilizer can be exerted without deterioration and the weight can be reduced, so that the burden on the elderly work and the efficiency of transportation can be improved. You can
さらに本発明の撥水抑制剤は、土壌の撥水抑制にも使用することができ、植栽する土地(土壌)の表面に直接散布し、あるいは土壌中に少量混合するだけでも撥水抑制効果を発揮し得るものである。 Furthermore, the water-repellent inhibitor of the present invention can be used also for water-repellent inhibition of soil, and can be sprayed directly on the surface of the land (soil) to be planted, or can be mixed in the soil in a small amount to have a water-repellent inhibitory effect. Can be demonstrated.
(培養土)
本発明の培養土は、本発明の撥水抑制剤を培養土成分に付着させた、水分量が20〜60質量%のものである。本発明の撥水抑制剤を培養土成分に付着させることにより、使用されるまでにタイムラグが生じても、素早く均一に水を浸透させることができ、透水性を有し、長期間にわたって安定した撥水抑制能を維持させることができ、植物の生育を促進する。さらに、含水率を低減しても浸透性を有する。
(Culture soil)
The culture soil of the present invention is one in which the water repellent inhibitor of the present invention is attached to the culture soil component and has a water content of 20 to 60 mass %. By attaching the water repellent inhibitor of the present invention to the culture soil component, water can be quickly and uniformly permeated even if there is a time lag before use, and it has water permeability and is stable for a long period of time. The ability to suppress water repellency can be maintained and the growth of plants can be promoted. Furthermore, it has permeability even if the water content is reduced.
本発明の培養土において、本発明の撥水抑制剤の付着量は、有効分換算(アニオン界面活性剤(A)とノニオン界面活性剤(B)とアルコール(C)の合計量)で、培養土成分100質量部に対して0.01〜10質量部であることが好ましく、より好ましくは0.01〜5質量部である。 In the culture soil of the present invention, the adhesion amount of the water repellent inhibitor of the present invention is calculated by converting the effective content (the total amount of the anionic surfactant (A), the nonionic surfactant (B) and the alcohol (C)). It is preferably 0.01 to 10 parts by mass, and more preferably 0.01 to 5 parts by mass, relative to 100 parts by mass of the soil component.
培養土成分に本発明の撥水抑制剤を付着させる方法としては、撥水抑制のための添加剤を培養土成分に付着させるために通常用いられる方法を適宜に採用することができる。すなわち、本発明の撥水抑制剤が室温で液状である場合には原液のまま、室温で固体またはペースト状である場合には加温溶融し液状として使用することができ、あるいは水が配合された本発明の撥水抑制剤を、水溶液として使用することができる。これらの形態の本発明の撥水抑制剤を培養土成分にスプレー等で塗布し、あるいは培養土成分を本発明の撥水抑制剤に浸漬するなどして、培養土成分に本発明の撥水抑制剤を付着させることができる。本発明の撥水抑制剤は、ハンドリング性や培養土成分への均一付着性の点から、水が配合された水溶液を使用することが好ましく、培養土成分への処理後に乾燥処理を施して過剰の水分を取り除いてもよい。 As a method for attaching the water repellent inhibitor of the present invention to the culture soil component, a method usually used for attaching an additive for suppressing water repellency to the culture soil component can be appropriately adopted. That is, when the water repellent inhibitor of the present invention is a liquid at room temperature, it can be used as a stock solution, and when it is a solid or paste at room temperature, it can be heated and melted to be used as a liquid, or it can be mixed with water. Further, the water repellent inhibitor of the present invention can be used as an aqueous solution. The water repellent of the present invention is applied to the culture soil component by applying the water repellent inhibitor of the present invention in these forms to the culture soil component by spraying or by immersing the culture soil component in the water repellent inhibitor of the present invention. Inhibitors can be attached. As the water repellent inhibitor of the present invention, it is preferable to use an aqueous solution mixed with water from the viewpoints of handling property and uniform adhesion to the culture soil component, and an excess amount obtained by performing a drying treatment after the treatment to the culture soil component. You may remove the water.
本発明の培養土において、使用する培養土成分は、通常培養土として使用されるものであれば、特に限定されるものではなく、例えば、植物性の繊維状物質、多孔性構造の無機物質、非多孔性構造の無機物質、肥料、土等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 In the culture soil of the present invention, the culture soil component to be used is not particularly limited as long as it is usually used as culture soil, for example, a plant fibrous substance, an inorganic substance having a porous structure, Inorganic substances having a non-porous structure, fertilizers, soil and the like can be mentioned. These may be used alone or in combination of two or more.
本発明の培養土は、本発明の効果が顕著に発揮される点から、培養土成分として、次の(i)〜(iii)から選ばれる少なくとも1種を含有することが好ましい:
(i)ピートモス、ヤシガラ、モミガラ、オガクズ、竹粉、バガス、泥炭、および草炭から選ばれる少なくとも1種の植物性の繊維状物質;
(ii)バーミキュライト、アタパルジャイト、ケイソウ土、セピオライト、ゼオライト、およびパーライトから選ばれる少なくとも1種の多孔性構造の無機物質;
(iii)珪砂、海砂、アルミナサンド、タルク、および炭酸カルシウムから選ばれる少なくとも1種の非多孔性構造の無機物質。
The culture soil of the present invention preferably contains at least one selected from the following (i) to (iii) as a component of the culture soil from the viewpoint that the effect of the present invention is remarkably exhibited:
(I) at least one plant fibrous substance selected from peat moss, coconut husk, chaff, sawdust, bamboo powder, bagasse, peat, and grass peat;
(Ii) at least one inorganic substance having a porous structure selected from vermiculite, attapulgite, diatomaceous earth, sepiolite, zeolite, and perlite;
(Iii) At least one inorganic substance having a non-porous structure selected from silica sand, sea sand, alumina sand, talc, and calcium carbonate.
培養土成分の肥料としては、例えば、窒素肥料、リン酸肥料、カリ肥料、水酸化カルシウム等のカルシウム化合物、水酸化マグネシウム等のマグネシウム化合物、酸化亜鉛等の亜鉛化合物等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of fertilizers for culture soil components include nitrogen fertilizers, phosphate fertilizers, potassium fertilizers, calcium compounds such as calcium hydroxide, magnesium compounds such as magnesium hydroxide, zinc compounds such as zinc oxide, and the like. These may be used alone or in combination of two or more.
培養土成分の土としては、例えば、黒ボク土、赤玉土、鹿沼土、日向土、田土等の天然土壌等が挙げられる。これらは1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Examples of the soil of the culture soil component include natural soils such as Kuroboku soil, Akatama soil, Kanuma soil, Hyuga soil, and rice soil. These may be used alone or in combination of two or more.
本発明の培養土は、培養土成分のうち少なくとも1種に本発明の撥水抑制剤を付着させたものであり、培養土成分の中でも、植物性の繊維状物質、多孔性構造の無機物質、および非多孔性構造の無機物質から選ばれる少なくとも1種に本発明の撥水抑制剤を付着させた培養土であることが好ましい。例えば、植物性の繊維状物質に本発明の撥水抑制剤を付着させたものに、多孔性構造の無機物質、非多孔性構造の無機物質、肥料、土などを混合して培養土とするような、培養土成分のうち1種に本発明の撥水抑制剤を付着させたものと、本発明の撥水抑制剤を付着させていない他の培養土成分とを混合して、本発明の培養土として使用しても撥水抑制効果を発揮し得るものである。 The culture soil of the present invention is obtained by adhering the water repellent inhibitor of the present invention to at least one of the culture soil components, and among the culture soil components, a vegetable fibrous substance, an inorganic substance having a porous structure. It is preferable that the culture soil has the water repellent inhibitor of the present invention adhered to at least one selected from the following, and an inorganic substance having a non-porous structure. For example, a plant fibrous substance to which the water repellent inhibitor of the present invention is attached is mixed with an inorganic substance having a porous structure, an inorganic substance having a non-porous structure, a fertilizer, soil or the like to prepare a culture soil. One of such culture soil components, to which the water repellent inhibitor of the present invention is attached, is mixed with another culture soil component to which the water repellent inhibitor of the present invention is not attached, and the present invention Even if it is used as a culture soil, the water-repellent effect can be exhibited.
以下に、実施例により本発明をさらに詳しく説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、表1および表2に示す配合量は質量部を表す。
<撥水抑制剤の調製>
撥水抑制剤は表1および表2に示す各種成分を室温にて混合攪拌して得た。
Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples. The blending amounts shown in Tables 1 and 2 are parts by mass.
<Preparation of water repellent inhibitor>
The water repellent inhibitor was obtained by mixing and stirring various components shown in Tables 1 and 2 at room temperature.
<培養土の製造>
表1および表2に示す培養土成分、質量比で混合攪拌した培養土100質量部に対して、表1および表2に示す撥水抑制剤の有効分換算付着量(質量部)および培養土中の水分量となるように、撥水抑制剤を水で適宜溶解あるいは希釈して、スプレーしながら混合撹拌し、撥水抑制剤が付着した培養土を製造した。
<Production of culture soil>
With respect to the culture soil components shown in Tables 1 and 2, and 100 parts by weight of the culture soil mixed and stirred in the mass ratio, the effective amount of the water repellent inhibitor shown in Tables 1 and 2 (mass parts) and the culture soil. The water-repellent inhibitor was appropriately dissolved or diluted with water so that the water content was moderate, and the mixture was stirred while spraying to produce a culture soil to which the water-repellent inhibitor was attached.
撥水抑制剤を水で溶解あるいは希釈する際、希釈水溶液の増粘・ゲル化および泡立ちのハンドリング性について、○:良、△:やや不良、×:不良、の3段階で観察評価した。結果を表1および表2に示す。 When the water repellent inhibitor was dissolved or diluted with water, the handling properties of thickening/gelling and foaming of the diluted aqueous solution were observed and evaluated in three grades of ◯: good, Δ: rather poor, and x: poor. The results are shown in Tables 1 and 2.
なお、製造120日後の培養土は、製造後、ポリ袋に培養土を充填、密閉し、30℃で保管したものである。また、表2中の(後)の表記は、当該培養土成分には撥水抑制剤を付着せず、製造120日後に培養土成分を混合したものを用いた。 In addition, the culture soil after 120 days of production was obtained by filling a plastic bag with the culture soil after the production, sealing it, and storing it at 30°C. In addition, the notation (after) in Table 2 was used as a mixture of the culture soil component after 120 days of production without attaching the water repellent inhibitor to the culture soil component.
<浸水スピード>
農水省規格セルトレイ(30角、128穴)に播種機を用いて一定量の培養土を充填し、展圧した後、一定量を灌水した。該水が培養土中へ浸水するまで(水浮きがない状態)の時間について、◎:3秒以内、○:5秒以内、△:10秒以内、×:20秒以上、の4段階で観察評価した。結果を表1および表2に示す。
なお、50回目とは、1日1回一定量を灌水して50日目の評価結果である。
<Inundation speed>
A cell tray (30 squares, 128 holes) standardized by the Ministry of Agriculture was filled with a fixed amount of culture soil using a seeding machine, spread, and then a fixed amount of water was irrigated. Regarding the time until the water is submerged in the culture soil (the state where the water does not float), it is observed in four stages of ◎: within 3 seconds, ○: within 5 seconds, △: within 10 seconds, ×: over 20 seconds. evaluated. The results are shown in Tables 1 and 2.
The 50th time is the evaluation result on the 50th day after irrigating a fixed amount once a day.
<透水性>
農水省規格セルトレイ(30角、128穴)に播種機を用いて一定量の培養土を充填し、展圧した後、一定量を灌水した。灌水1分後、スパチュラで培養土を掘り起し、全体に対する透水性について、◎:90%以上、○:70%以上、△:50%以上、×:30%以下、の4段階で観察評価した。結果を表1および表2に示す。
なお、50回目とは、1日1回一定量を灌水して50日目の評価結果である。
<Water permeability>
A cell tray (30 squares, 128 holes) standardized by the Ministry of Agriculture was filled with a fixed amount of culture soil using a seeding machine, spread, and then a fixed amount of water was irrigated. After 1 minute of irrigation, excavate the culture soil with a spatula, and observe the water permeability of the whole in four stages: ◎: 90% or more, ○: 70% or more, △: 50% or more, ×: 30% or less. did. The results are shown in Tables 1 and 2.
The 50th time is the evaluation result on the 50th day after irrigating a fixed amount once a day.
<生育性>
農水省規格セルトレイ(30角、128穴)に播種機を用いて一定量の培養土を充填し、展圧した後、小松菜の種子を1ポットにつき1粒ずつ再度播種機を用いて播種し、一定量の培養土で覆土し、一定量を灌水して播種作業を完了した。播種後、1日1回一定量を灌水して育苗し、7日後、発芽率、発根状況、子葉の展開状況について、○:良、△:やや不良、×:不良、の3段階で観察評価した。結果を表1および表2に示す。
<Growth>
A Ministry of Agriculture, Forestry and Fisheries standard cell tray (30 squares, 128 holes) is filled with a certain amount of culture soil using a seeding machine, and after spreading, one seed of Komatsuna seeds is sown again using the seeding machine, one seed at a time, and fixed. The soil was covered with a certain amount of culture soil, and a certain amount was irrigated to complete the seeding work. After sowing, a certain amount of water is irrigated once a day to raise seedlings, and after 7 days, the germination rate, rooting status, and cotyledon development status are observed in three stages: ○: good, △: somewhat poor, ×: poor. evaluated. The results are shown in Tables 1 and 2.
Claims (3)
前記アルコール(C)は、炭素数1〜8の1価アルコール、炭素数1〜8の2価アルコール、炭素数1〜8の3価アルコール、および炭素数2〜8のアルコキシアルコールから選ばれる少なくとも1種であり、
(A)/(B)で表される質量比が0.01〜5.00である撥水抑制剤:
(A)スルホン酸塩型および硫酸塩型から選ばれる少なくとも1種のアニオン界面活性剤;および
(B)ポリオキシアルキレングリコール、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンスチレン化フェニルエーテル、ポリオキシエチレン(硬化)ヒマシ油、ポリオキシエチレンアルキルアミン、および脂肪酸アルカノールアミドから選ばれる少なくとも1種のノニオン界面活性剤。 A water repellent inhibitor used so that the water content of the culture soil or soil after treatment with the water repellent treatment agent is 20 to 60% by mass , which comprises the following anionic surfactant (A) and nonionic surfactant: Containing an agent (B) and an alcohol (C) ,
The alcohol (C) is at least selected from a monohydric alcohol having 1 to 8 carbon atoms, a dihydric alcohol having 1 to 8 carbon atoms, a trihydric alcohol having 1 to 8 carbon atoms, and an alkoxy alcohol having 2 to 8 carbon atoms. One kind,
Water repellent inhibitor having a mass ratio represented by (A)/(B) of 0.01 to 5.00:
(A) at least one anionic surfactant selected from sulfonate type and sulfate type; and (B) polyoxyalkylene glycol, polyoxyalkylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene styrenated At least one nonionic surfactant selected from phenyl ether, polyoxyethylene (hardened) castor oil, polyoxyethylene alkylamine, and fatty acid alkanolamide.
(i)ピートモス、ヤシガラ、モミガラ、オガクズ、竹粉、バガス、泥炭、および草炭から選ばれる少なくとも1種の植物性の繊維状物質;
(ii)バーミキュライト、アタパルジャイト、ケイソウ土、セピオライト、ゼオライト、およびパーライトから選ばれる少なくとも1種の多孔性構造の無機物質;
(iii)珪砂、海砂、アルミナサンド、タルク、および炭酸カルシウムから選ばれる少なくとも1種の非多孔性構造の無機物質。
The culture soil according to claim 2, containing at least one selected from the following (i) to (iii) as a culture soil component:
(I) at least one plant fibrous substance selected from peat moss, coconut husk, chaff, sawdust, bamboo powder, bagasse, peat, and grass peat;
(Ii) at least one inorganic substance having a porous structure selected from vermiculite, attapulgite, diatomaceous earth, sepiolite, zeolite, and perlite;
(Iii) At least one inorganic substance having a non-porous structure selected from silica sand, sea sand, alumina sand, talc, and calcium carbonate .
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