JP6697359B2 - Adhesives for flexible displays, adhesive sheets, flexible laminated members and flexible displays - Google Patents

Description

  The present invention relates to a pressure sensitive adhesive for flexible displays, a pressure sensitive adhesive sheet, a flexible laminated member and a flexible display.

  In recent years, a bendable display, a so-called flexible display, has been proposed as a display body (display) of an electronic device. The flexible display is expected to have a wide range of uses, for example, for a stationary display that is bent and installed on a columnar pillar, or for a mobile display that can be folded and rolled to be carried.

  Examples of the type of flexible display include an organic electroluminescence (organic EL) display, an electrophoretic display (electronic paper), a liquid crystal display using a plastic film as a substrate, and the like.

  In the flexible display as described above, it is general that one bendable member (flexible member) constituting the flexible display and another flexible member are bonded to each other by an adhesive layer of an adhesive sheet. Conceivable. Here, as the conventional non-flexible pressure-sensitive adhesive sheet for a display, for example, those disclosed in Patent Documents 1 and 2 are known.

  The flexible display may be repeatedly bent (folded) as described in Patent Document 3, instead of being curved once. When a conventional pressure-sensitive adhesive sheet is used for a flexible display for such an application, the pressure-sensitive adhesive layer in a repeatedly bent portion may have lines or become cloudy, resulting in poor appearance and low visibility as a display. The problem arises.

JP, 2015-174907, A JP, 2016-774, A JP, 2016-27664, A

  The present invention has been made in view of such an actual situation, and can withstand repeated bending when applied to a flexible display, an adhesive for flexible display having excellent bending resistance, an adhesive sheet, a flexible laminated member, and The purpose is to provide a flexible display.

In order to achieve the above-mentioned object, firstly, the present invention relates to a pressure-sensitive adhesive for a flexible display for laminating one flexible member and another flexible member constituting a flexible display, which is stored at -20 ° C. The elastic modulus G ′ (− 20) is 0.05 MPa or more and less than 1 MPa, and based on the storage elastic modulus G ′ (− 20) and the storage elastic modulus G ′ (40) at 40 ° C., the following equation ( A flexible display pressure-sensitive adhesive is provided, wherein the elastic modulus change rate derived in 1) is 350% or more and 10000% or less (Invention 1).
Elastic modulus change rate (%) = (G ′ (− 20) / G ′ (40)) × 100 (1)

  Since the pressure-sensitive adhesive according to the above invention (Invention 1) has the above G '(-20) and the elastic modulus change rate, it becomes a soft material having a very high stress relaxation property, and is repeatedly bent when applied to a flexible display. When this is done, the adhesive layer is suppressed from forming lines or clouding, and has excellent flex resistance.

  In the above invention (Invention 1), the gel fraction is preferably 60% or more and 100% or less (Invention 2).

  In the said invention (invention 1, 2), it is preferable that the glass transition temperature (Tg) of the main polymer of the said adhesive for flexible displays is -80 degreeC or more and -40 degreeC or less (invention 3).

  Secondly, the present invention is a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer for bonding one flexible member and another flexible member constituting a flexible display, wherein the pressure-sensitive adhesive layer is the pressure-sensitive adhesive for flexible display. A pressure-sensitive adhesive sheet comprising an agent (Inventions 1 to 3) is provided (Invention 4).

  In the above invention (Invention 4), the pressure-sensitive adhesive sheet includes two release sheets, and the pressure-sensitive adhesive layer is sandwiched between the release sheets so as to contact the release surfaces of the two release sheets. Preferably (Invention 5).

  Thirdly, the present invention provides a flexible laminated member including one flexible member and another flexible member that form a flexible display, and an adhesive layer that bonds the one flexible member and the other flexible member to each other. A pressure-sensitive adhesive layer is the pressure-sensitive adhesive layer of the pressure-sensitive adhesive sheet (Invention 4, 5), and a flexible laminated member is provided (Invention 6).

  In the above invention (invention 6), at least one of the one flexible member and the other flexible member is preferably a flexible display element (invention 7).

  In the above inventions (Inventions 6 and 7), it is preferable that the Young's modulus of each of the one flexible member and the other flexible member is 0.1 to 10 GPa (Invention 8).

  In the said invention (invention 6-8), it is preferable that the thickness of the said one flexible member and the said other flexible member is 10-3000 micrometers, respectively (invention 9).

  In the said invention (invention 6-9), it is preferable that the interlayer adhesive force between said one flexible member and said another flexible member is 1-30 N / 25 mm (invention 10).

  Fourthly, the present invention provides a flexible display including the flexible laminated member (Inventions 6 to 10) (Invention 11).

  The pressure-sensitive adhesive and pressure-sensitive adhesive sheet for a flexible display and the pressure-sensitive adhesive layer of the flexible laminated member and the flexible display according to the present invention have excellent flex resistance when repeatedly bent.

It is sectional drawing of the adhesive sheet which concerns on one Embodiment of this invention. It is sectional drawing of the flexible laminated member which concerns on one Embodiment of this invention.

Hereinafter, embodiments of the present invention will be described.
[Adhesive for flexible displays]
The adhesive for flexible display according to the present embodiment (hereinafter, may be simply referred to as “adhesive”) is an adhesive for bonding one flexible member and another flexible member constituting the flexible display. is there. The flexible display and the flexible member will be described later.

The pressure-sensitive adhesive according to this embodiment has a storage elastic modulus G ′ at −20 ° C. (which may be referred to as “G ′ (− 20)” in this specification) of 0.05 MPa or more and less than 1 MPa. , G ′ (− 20) and the storage elastic modulus G ′ at 40 ° C. (which may be referred to as “G ′ (40)” in the present specification), the elasticity derived from the following formula (1). The rate change rate is 350% or more and 10000% or less.
Elastic modulus change rate (%) = (G ′ (− 20) / G ′ (40)) × 100 (1)
In addition, G '(-20) and G' (40) are values measured by a method based on JIS K7244-6, and a specific measuring method is as shown in a test example described later.

  The pressure-sensitive adhesive according to the present embodiment has the above G ′ (− 20) and the elastic modulus change rate, and thus becomes a soft material having a very high stress relaxation property, and when applied to a flexible display and repeatedly bent. In addition, the adhesive layer is suppressed from forming lines or clouding, and has excellent bending resistance. Therefore, when the flexible display using the pressure-sensitive adhesive layer made of the pressure-sensitive adhesive according to the present embodiment is repeatedly bent at a predetermined portion, the appearance may be deteriorated or the visibility may be deteriorated at the bent portion. Is suppressed.

  From the above viewpoint, G ′ (− 20) is preferably 0.9 MPa or less, and particularly preferably 0.8 MPa or less. The lower limit of G '(-20) is not particularly limited, but is preferably 0.10 MPa or more, and particularly preferably 0.30 MPa or more.

  The elastic modulus change rate is preferably 6000% or less, and particularly preferably 3000% or less. The lower limit value of the elastic modulus change rate is preferably 500% or more, and particularly preferably 800% or more, from the viewpoint of ensuring an appropriate interlayer adhesion.

  From the viewpoint of easily satisfying the elastic modulus change rate, G ′ (40) is preferably 0.005 to 0.28 MPa, particularly preferably 0.008 to 0.18 MPa, and further 0. It is preferably 0.01 to 0.1 MPa.

  The adhesive according to the present embodiment preferably has a gel fraction of 60% or more, particularly preferably 65% or more, and further preferably 70% or more. Further, the gel fraction is preferably 100% or less, particularly preferably 95% or less, and further preferably 90% or less. Since the pressure-sensitive adhesive according to the present embodiment has a gel fraction of 60% or more, it has further excellent flex resistance while maintaining stress relaxation property. The method for measuring the gel fraction is as shown in the test example described later.

  The glass transition temperature (Tg) of the main polymer of the pressure-sensitive adhesive according to the present embodiment (polymer that constitutes the pressure-sensitive adhesive and has the highest compounding ratio) is preferably −40 ° C. or lower, and particularly −45. The temperature is preferably not higher than 0 ° C, more preferably not higher than -50 ° C. Further, the glass transition temperature (Tg) is preferably −80 ° C. or higher, particularly preferably −75 ° C. or higher, and further preferably −70 ° C. or higher. Since the glass transition temperature (Tg) of the main polymer of the pressure-sensitive adhesive according to the present embodiment is -40 ° C or lower, the elastic modulus is less likely to change in the temperature range of actual use of the pressure-sensitive adhesive, and the elastic modulus change described above is caused. The rate is easier to meet. The method for measuring the glass transition temperature (Tg) is as shown in the test example described later.

  The pressure-sensitive adhesive according to this embodiment is not particularly limited as long as it satisfies the above physical properties, and examples thereof include acrylic pressure-sensitive adhesive, polyester pressure-sensitive adhesive, polyurethane pressure-sensitive adhesive, rubber pressure-sensitive adhesive, and silicone. It may be any of a pressure-sensitive adhesive and the like. The adhesive may be emulsion type, solvent type or solventless type, and may be crosslinked type or non-crosslinked type.

  Among the above, it is preferable to use an acrylic pressure-sensitive adhesive that easily satisfies the above-mentioned physical properties and is excellent in pressure-sensitive adhesive properties and optical properties. The acrylic pressure-sensitive adhesive may contain a non-crosslinked main polymer, or may contain a main polymer crosslinked with a crosslinking agent. Considering the ease of satisfying the above-mentioned physical properties, a polymer containing a main polymer crosslinked with a crosslinking agent is preferable. Here, the main polymer of the acrylic pressure-sensitive adhesive is usually a (meth) acrylic acid ester polymer. In addition, in this specification, (meth) acrylic acid means both acrylic acid and methacrylic acid. The same applies to other similar terms. In addition, the term “polymer” also includes the concept of “copolymer”.

  The pressure-sensitive adhesive according to the present embodiment is a pressure-sensitive adhesive composition containing a (meth) acrylic acid ester polymer (A) as a main polymer and a cross-linking agent (B) described below (hereinafter, referred to as “pressure-sensitive adhesive composition”). It may be referred to as "P."). The pressure-sensitive adhesive obtained by crosslinking the pressure-sensitive adhesive composition P (hereinafter sometimes referred to as “pressure-sensitive adhesive Q”) particularly easily satisfies the above-mentioned physical properties.

(1) Component (1-1) of the adhesive composition P (meth) acrylic acid ester polymer (A)
The (meth) acrylic acid ester polymer (A) has, as a monomer unit constituting the polymer, a (meth) acrylic acid alkyl ester having an alkyl group having 2 to 20 carbon atoms and a reactive functional group in the molecule. It is preferable to contain a monomer having (reactive functional group-containing monomer).

  The (meth) acrylic acid ester polymer (A) contains a (meth) acrylic acid alkyl ester having an alkyl group having 2 to 20 carbon atoms as a monomer unit constituting the polymer, and thus has a preferable adhesive property. Can be expressed. The (meth) acrylic acid alkyl ester having an alkyl group having 2 to 20 carbon atoms has a glass transition temperature (Tg) as a homopolymer of −40 ° C. or lower (hereinafter sometimes referred to as “low Tg alkyl acrylate”). .) Is preferred. By including such a low Tg alkyl acrylate as a constituent monomer unit, it becomes easy to set the glass transition temperature (Tg) of the main polymer of the pressure-sensitive adhesive according to the present embodiment within the above-mentioned range, and thus the above-mentioned elastic modulus change rate. It becomes easy to be filled.

  Examples of the low Tg alkyl acrylate include n-butyl acrylate (Tg-55 ° C), n-octyl acrylate (Tg-65 ° C), isooctyl acrylate (Tg-58 ° C), and 2-ethylhexyl acrylate (Tg). -70 ° C), isononyl acrylate (Tg-58 ° C), isodecyl acrylate (Tg-60 ° C), isodecyl methacrylate (Tg-41 ° C), n-lauryl methacrylate (Tg-65 ° C), tridecyl acrylate. (Tg-55 ° C), tridecyl methacrylate (-40 ° C) and the like are preferable. Among them, from the viewpoint of more effectively reducing the elastic modulus change rate, it is more preferable that the Tg of the homopolymer is −45 ° C. or less, and −50 ° C. or less as the low Tg alkyl acrylate. It is particularly preferable that Specifically, n-butyl acrylate and 2-ethylhexyl acrylate are particularly preferable. These may be used alone or in combination of two or more. The alkyl group in the (meth) acrylic acid alkyl ester having 2 to 20 carbon atoms in the alkyl group refers to a linear, branched or cyclic alkyl group.

  The (meth) acrylic acid ester polymer (A) preferably contains a low Tg alkyl acrylate as a lower limit value of 60% by mass or more, particularly 80% by mass or more, as a monomer unit constituting the polymer. Is preferable, and it is more preferable to contain 90% by mass or more. By containing 60% by mass or more of the low Tg alkyl acrylate, it becomes easy to set the glass transition temperature (Tg) of the main polymer of the pressure-sensitive adhesive according to the present embodiment within the above-mentioned range.

  The (meth) acrylic acid ester polymer (A) preferably contains the low Tg alkyl acrylate as a monomer unit constituting the polymer in an amount of 99.9% by mass or less as an upper limit, and particularly 99% by mass. It is preferably contained below, and more preferably contained in an amount of 98% by mass or less. By containing 99.9% by mass or less of the low Tg alkyl acrylate, a suitable amount of another monomer component (particularly a reactive functional group-containing monomer) is introduced into the (meth) acrylic acid ester polymer (A). You can

  On the other hand, the (meth) acrylic acid ester polymer (A) is used as a homopolymer in order to easily set the glass transition temperature (Tg) of the main polymer of the pressure-sensitive adhesive according to this embodiment. It is preferable to reduce the content of a monomer having a temperature (Tg) of higher than 0 ° C. (hereinafter sometimes referred to as “hard monomer”) as much as possible. Specifically, in the (meth) acrylic acid ester polymer (A), the content of the hard monomer as a monomer unit constituting the polymer is preferably 15% by mass or less as an upper limit, and particularly 10 It is preferably not more than 5% by mass, more preferably not more than 5% by mass. The hard monomer includes a reactive functional group-containing monomer described later.

  Examples of the hard monomer include methyl acrylate (Tg10 ° C.), methyl methacrylate (Tg105 ° C.), ethyl methacrylate (Tg65 ° C.), n-butyl methacrylate (Tg20 ° C.), isobutyl methacrylate (Tg48 ° C.), T-Butyl methacrylate (Tg107 ° C), n-stearyl acrylate (Tg30 ° C), n-stearyl methacrylate (Tg38 ° C), cyclohexyl acrylate (Tg15 ° C), cyclohexyl methacrylate (Tg66 ° C), phenoxyethyl acrylate (Tg 5 ° C.), phenoxyethyl methacrylate (Tg 54 ° C.), benzyl methacrylate (Tg 54 ° C.), isobornyl acrylate (Tg 94 ° C.), isobornyl methacrylate (Tg 180 ° C.), acryloylmorpholine (Tg 145 ° C.), adamantyl acrylate (Tg 115). C.), adamantyl methacrylate (Tg 141 ° C.), acrylic acid (Tg 103 ° C.), acrylic monomers such as dimethyl acrylamide (Tg 89 ° C.), acrylamide (Tg 165 ° C.), vinyl acetate (Tg 32 ° C.), styrene (Tg 80 ° C.), etc. Can be mentioned.

  The (meth) acrylic acid ester polymer (A) contains a reactive functional group-containing monomer as a monomer unit constituting the polymer, so that the reactive functional group derived from the reactive functional group-containing monomer is introduced. Then, it reacts with a crosslinking agent (B) described later, whereby a crosslinked structure (three-dimensional network structure) is formed, and an adhesive having a desired cohesive force is obtained.

  Examples of the reactive functional group-containing monomer contained in the (meth) acrylic acid ester polymer (A) as a monomer unit constituting the polymer include a monomer having a hydroxyl group in the molecule (a hydroxyl group-containing monomer) and a carboxy group in the molecule. Preferable examples thereof include a monomer having a group (carboxy group-containing monomer) and a monomer having an amino group in the molecule (amino group-containing monomer). Among these, hydroxyl group-containing monomers are particularly preferable. Many of the hydroxyl group-containing monomers have a glass transition temperature (Tg) of 0 ° C. or lower, and it is easy to set the glass transition temperature (Tg) of the main polymer of the pressure-sensitive adhesive according to the present embodiment within the range described above.

  Examples of the hydroxyl group-containing monomer include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, and (meth ) Examples include hydroxyalkyl esters of (meth) acrylic acid such as 3-hydroxybutyl acrylate and 4-hydroxybutyl (meth) acrylate. Among them, from the viewpoint of the glass transition temperature (Tg), the reactivity of the hydroxyl group in the obtained (meth) acrylic acid ester polymer (A) with the crosslinking agent (B), and the copolymerizability with other monomers, It is preferably at least one of 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 3-hydroxypropyl acrylate, and 4-hydroxybutyl acrylate. These may be used alone or in combination of two or more.

  Examples of the carboxy group-containing monomer include ethylenically unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid and citraconic acid. Among them, acrylic acid is preferable from the viewpoint of the reactivity of the carboxy group in the obtained (meth) acrylic acid ester polymer (A) with the crosslinking agent (B) and the copolymerizability with other monomers. These may be used alone or in combination of two or more.

  Examples of the amino group-containing monomer include aminoethyl (meth) acrylate and n-butylaminoethyl (meth) acrylate. These may be used alone or in combination of two or more.

  The (meth) acrylic acid ester polymer (A) preferably contains a reactive functional group-containing monomer as a monomer unit constituting the polymer at a lower limit of 0.1% by mass or more, and particularly 0.5 The content is preferably at least mass%, more preferably at least 1 mass%. The (meth) acrylic acid ester polymer (A) preferably contains a reactive functional group-containing monomer as a monomer unit constituting the polymer in an amount of 30% by mass or less as an upper limit, and particularly 20% by mass. It is preferably contained below, and more preferably 8 mass% or less. When the (meth) acrylic acid ester polymer (A) contains the reactive functional group-containing monomer, especially the hydroxyl group-containing monomer as a monomer unit in the above amount, the gel fraction of the obtained pressure-sensitive adhesive tends to fall within the above-mentioned range. ..

  It is also preferred that the (meth) acrylic acid ester polymer (A) does not contain, as a monomer unit constituting the polymer, a carboxy group-containing monomer, particularly acrylic acid which is also a hard monomer. Since the carboxy group is an acid component, by not containing the carboxy group-containing monomer, the object to which the pressure-sensitive adhesive is attached causes a problem due to the acid, for example, a transparent conductive film such as tin-doped indium oxide (ITO) or a metal film, Even when a metal mesh or the like is present, it is possible to suppress the defects (corrosion, resistance value change, etc.) due to the acid.

  If desired, the (meth) acrylic acid ester polymer (A) may contain other monomer as a monomer unit constituting the polymer. As the other monomer, a monomer that does not contain a reactive functional group is preferable because it does not hinder the action of the reactive functional group-containing monomer. Examples of such other monomer include (meth) acrylic acid alkoxyalkyl esters such as methoxyethyl (meth) acrylate and ethoxyethyl (meth) acrylate, and a glass transition temperature (Tg) of -40 as a homopolymer. Examples thereof include monomers having a temperature higher than 0 ° C. and lower than or equal to 0 ° C. (hereinafter sometimes referred to as “medium Tg alkyl acrylate”). Examples of the medium Tg alkyl acrylate include ethyl acrylate (Tg-20 ° C), isobutyl acrylate (Tg-26 ° C), 2-ethylhexyl methacrylate (Tg-10 ° C), and n-lauryl acrylate (Tg-23). C), isostearyl acrylate (Tg-18 ° C), and the like. These may be used alone or in combination of two or more.

  The polymerization mode of the (meth) acrylic acid ester polymer (A) may be a random copolymer or a block copolymer.

  The lower limit of the weight average molecular weight of the (meth) acrylic acid ester polymer (A) is preferably 200,000 or more, particularly preferably 400,000 or more, and further preferably 600,000 or more. When the lower limit of the weight average molecular weight of the (meth) acrylic acid ester polymer (A) is at least the above, problems such as leaching of the pressure-sensitive adhesive are suppressed. In addition, the weight average molecular weight in this specification is the value of standard polystyrene conversion measured by the gel permeation chromatography (GPC) method.

  The upper limit of the weight average molecular weight of the (meth) acrylic acid ester polymer (A) is preferably 2,000,000 or less, particularly preferably 1,500,000 or less, and further preferably 900,000 or less. preferable. When the upper limit of the weight average molecular weight of the (meth) acrylic acid ester polymer (A) is not more than the above, the adhesive force between layers of the obtained pressure-sensitive adhesive is likely to fall within a suitable range described below.

  In addition, in the adhesive composition P, the (meth) acrylic acid ester polymer (A) may be used alone or in combination of two or more kinds.

(1-2) Crosslinking agent (B)
When the pressure-sensitive adhesive composition P containing the cross-linking agent (B) is heated, the cross-linking agent (B) cross-links the (meth) acrylic acid ester polymer (A) to form a three-dimensional network structure. As a result, the cohesive force of the obtained pressure-sensitive adhesive is improved, and the gel fraction of the pressure-sensitive adhesive is likely to fall within the range described above, and thus the flex resistance is further improved.

  The cross-linking agent (B) may be any as long as it reacts with the reactive group of the (meth) acrylic acid ester polymer (A), and examples thereof include an isocyanate cross-linking agent, an epoxy cross-linking agent and an amine cross-linking agent. , Melamine crosslinking agent, aziridine crosslinking agent, hydrazine crosslinking agent, aldehyde crosslinking agent, oxazoline crosslinking agent, metal alkoxide crosslinking agent, metal chelate crosslinking agent, metal salt crosslinking agent, ammonium salt crosslinking agent, etc. Is mentioned. Among the above, when the reactive group of the (meth) acrylic acid ester polymer (A) is a hydroxyl group, it is preferable to use an isocyanate cross-linking agent having excellent reactivity with the hydroxyl group, and the (meth) acrylic acid ester When the reactive group contained in the polymer (A) is a carboxy group, it is preferable to use an epoxy-based cross-linking agent having excellent reactivity with the carboxy group. The crosslinking agent (B) may be used alone or in combination of two or more.

  The isocyanate-based crosslinking agent contains at least a polyisocyanate compound. Examples of the polyisocyanate compound include tolylene diisocyanate, diphenylmethane diisocyanate, aromatic polyisocyanates such as xylylene diisocyanate, aliphatic polyisocyanates such as hexamethylene diisocyanate, isophorone diisocyanate, and alicyclic polyisocyanates such as hydrogenated diphenylmethane diisocyanate. And their biurets, isocyanurates, and adducts which are reaction products with low molecular weight active hydrogen-containing compounds such as ethylene glycol, propylene glycol, neopentyl glycol, trimethylolpropane and castor oil. Among them, trimethylolpropane-modified aromatic polyisocyanate, particularly trimethylolpropane-modified tolylene diisocyanate and trimethylolpropane-modified xylylene diisocyanate are preferable from the viewpoint of reactivity with a hydroxyl group.

  Examples of the epoxy-based cross-linking agent include 1,3-bis (N, N-diglycidylaminomethyl) cyclohexane, N, N, N ', N'-tetraglycidyl-m-xylylenediamine, ethylene glycol diglycidyl ether. , 1,6-hexanediol diglycidyl ether, trimethylolpropane diglycidyl ether, diglycidyl aniline, diglycidyl amine and the like. Among them, 1,3-bis (N, N-diglycidylaminomethyl) cyclohexane is preferable from the viewpoint of reactivity with the carboxy group.

  The content of the cross-linking agent (B) in the adhesive composition P is preferably 0.01 parts by mass or more, and particularly preferably 0.1 part by mass, relative to 100 parts by mass of the (meth) acrylic acid ester polymer (A). The amount is preferably 05 parts by mass or more, and more preferably 0.1 parts by mass or more. Further, the content is preferably 10 parts by mass or less, particularly preferably 8 parts by mass or less, and further preferably 5 parts by mass or less. When the content of the cross-linking agent (B) is within the above range, the gel fraction of the obtained pressure-sensitive adhesive becomes easier to fall within the above range.

(1-3) Various additives In the adhesive composition P, if desired, various additives usually used in acrylic adhesives, for example, silane coupling agents, ultraviolet absorbers, antistatic agents, and tackifiers. Agents, antioxidants, light stabilizers, softening agents, fillers, refractive index adjusting agents and the like can be added. In addition, the below-mentioned polymerization solvent and diluent solvent are not included in the additives constituting the adhesive composition P.

(2) Production of Adhesive Composition P Adhesive composition P was produced by producing (meth) acrylic acid ester polymer (A), and obtained (meth) acrylic acid ester polymer (A) and a crosslinking agent. It can be produced by mixing with (B) and optionally adding an additive.

  The (meth) acrylic acid ester polymer (A) can be produced by polymerizing a mixture of monomers constituting the polymer by an ordinary radical polymerization method. The polymerization of the (meth) acrylic acid ester polymer (A) is preferably carried out by a solution polymerization method, optionally using a polymerization initiator. Examples of the polymerization solvent include ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, acetone, hexane, methyl ethyl ketone, and the like, and two or more kinds may be used in combination.

  Examples of the polymerization initiator include azo compounds and organic peroxides, and two or more kinds may be used in combination. Examples of the azo compound include 2,2′-azobisisobutyronitrile, 2,2′-azobis (2-methylbutyronitrile), 1,1′-azobis (cyclohexane1-carbonitrile), and , 2'-azobis (2,4-dimethylvaleronitrile), 2,2'-azobis (2,4-dimethyl-4-methoxyvaleronitrile), dimethyl2,2'-azobis (2-methylpropionate) 4,4'-azobis (4-cyanovaleric acid), 2,2'-azobis (2-hydroxymethylpropionitrile), 2,2'-azobis [2- (2-imidazolin-2-yl) Propane] and the like.

  Examples of the organic peroxide include benzoyl peroxide, t-butyl perbenzoate, cumene hydroperoxide, diisopropyl peroxydicarbonate, di-n-propyl peroxydicarbonate, di (2-ethoxyethyl) peroxy. Dicarbonate, t-butyl peroxy neodecanoate, t-butyl peroxy vivarate, (3,5,5-trimethylhexanoyl) peroxide, dipropionyl peroxide, diacetyl peroxide and the like can be mentioned.

  In the polymerization step, the weight average molecular weight of the obtained polymer can be adjusted by adding a chain transfer agent such as 2-mercaptoethanol.

  After the (meth) acrylic acid ester polymer (A) is obtained, the crosslinking agent (B), and optionally an additive and a diluent solvent are added to the solution of the (meth) acrylic acid ester polymer (A), The adhesive composition P (coating solution) diluted with a solvent is obtained by mixing with.

  In any of the above components, when a solid one is used, or when precipitation occurs when mixed with other components in an undiluted state, the component alone is preliminarily diluted with a solvent. It may be dissolved or diluted and then mixed with other components.

  Examples of the diluent solvent include hexane, heptane, aliphatic hydrocarbons such as cyclohexane, toluene, aromatic hydrocarbons such as xylene, methylene chloride, halogenated hydrocarbons such as ethylene chloride, methanol, ethanol, propanol, butanol, Alcohols such as 1-methoxy-2-propanol, ketones such as acetone, methyl ethyl ketone, 2-pentanone, isophorone and cyclohexanone, esters such as ethyl acetate and butyl acetate, and cellosolve solvents such as ethyl cellosolve are used.

  The concentration / viscosity of the coating solution thus prepared is not particularly limited as long as it can be coated, and can be appropriately selected depending on the situation. For example, it is diluted so that the concentration of the adhesive composition P is 10 to 60% by mass. In addition, when obtaining a coating solution, addition of a diluting solvent or the like is not a necessary condition, and a diluting solvent may not be added as long as it has a viscosity such that the adhesive composition P can be coated. In this case, the adhesive composition P becomes a coating solution using the polymerization solvent of the (meth) acrylic acid ester polymer (A) as a diluting solvent.

(3) Production of pressure-sensitive adhesive Q The pressure-sensitive adhesive Q preferable as the pressure-sensitive adhesive according to the present embodiment is obtained by crosslinking the pressure-sensitive adhesive composition P. Crosslinking of the adhesive composition P can usually be performed by heat treatment. The heat treatment can also be used as a drying treatment when the diluent solvent or the like is volatilized from the coating film of the adhesive composition P applied to a desired object.

  The heating temperature of the heat treatment is preferably 50 to 150 ° C, and particularly preferably 70 to 120 ° C. Further, the heating time is preferably 10 seconds to 10 minutes, and particularly preferably 50 seconds to 2 minutes.

  After the heat treatment, a curing period of about 1 to 2 weeks may be provided at room temperature (for example, 23 ° C. and 50% RH), if necessary. When this curing period is required, the adhesive agent Q is formed after the curing period has elapsed, and when the curing period is unnecessary, after the heat treatment is completed.

  By the above heat treatment (and curing), the (meth) acrylic acid ester polymer (A) is sufficiently crosslinked through the crosslinking agent (B) to form a crosslinked structure, and the pressure-sensitive adhesive Q is obtained. The adhesive Q is particularly easy to satisfy the above-mentioned storage elastic modulus and elastic modulus change rate.

[Adhesive sheet]
The pressure-sensitive adhesive sheet according to the present embodiment has a pressure-sensitive adhesive layer for laminating one flexible member and another flexible member constituting the flexible display, and the pressure-sensitive adhesive layer is made of the above-mentioned pressure-sensitive adhesive. Is.

A specific configuration as an example of the pressure-sensitive adhesive sheet according to the present embodiment is shown in FIG.
As shown in FIG. 1, the pressure-sensitive adhesive sheet 1 according to one embodiment includes two release sheets 12a and 12b and the two release sheets 12a so as to be in contact with the release surfaces of the two release sheets 12a and 12b. , 12b sandwiched between the adhesive layers 11. In addition, the release surface of the release sheet in the present specification refers to a surface having releasability in the release sheet, and includes both a release-treated surface and a release-removable surface. ..

(1) Constituent Element (1-1) Adhesive Layer The adhesive layer 11 is composed of the adhesive according to the above-described embodiment, and is preferably composed of the adhesive Q obtained by crosslinking the adhesive composition P. It

  The thickness (value measured according to JIS K7130) of the pressure-sensitive adhesive layer 11 in the pressure-sensitive adhesive sheet 1 according to the present embodiment is preferably 5 μm or more as a lower limit value, particularly preferably 10 μm or more, and further, It is preferably 20 μm or more. The upper limit of the thickness of the pressure-sensitive adhesive layer 11 is preferably 300 μm or less, more preferably 200 μm or less, and particularly preferably 100 μm or less. When the thickness of the pressure-sensitive adhesive layer 11 is within the above range, the desired pressure-sensitive adhesive force is easily exhibited and the flex resistance is excellent. The pressure-sensitive adhesive layer 11 may be formed as a single layer, or may be formed by stacking a plurality of layers.

(1-2) Release Sheet The release sheets 12a and 12b protect the pressure-sensitive adhesive layer 11 until the pressure-sensitive adhesive sheet 1 is used, and are peeled off when the pressure-sensitive adhesive sheet 1 (pressure-sensitive adhesive layer 11) is used. In the pressure-sensitive adhesive sheet 1 according to this embodiment, one or both of the release sheets 12a and 12b are not always necessary.

  Examples of the release sheets 12a and 12b include polyethylene film, polypropylene film, polybutene film, polybutadiene film, polymethylpentene film, polyvinyl chloride film, vinyl chloride copolymer film, polyethylene terephthalate film, polyethylene naphthalate film, polybutylene. Terephthalate film, polyurethane film, ethylene vinyl acetate film, ionomer resin film, ethylene / (meth) acrylic acid copolymer film, ethylene / (meth) acrylic acid ester copolymer film, polystyrene film, polycarbonate film, polyimide film, fluorine A resin film or the like is used. Further, these crosslinked films are also used. Furthermore, these laminated films may be used.

  It is preferable that the release surface of each of the release sheets 12a and 12b (particularly the surface in contact with the pressure-sensitive adhesive layer 11) is subjected to a release treatment. Examples of the release agent used in the release treatment include alkyd-based, silicone-based, fluorine-based, unsaturated polyester-based, polyolefin-based, and wax-based release agents. It is preferable that one of the release sheets 12a and 12b is a heavy release type release sheet having a large release force and the other release sheet is a light release type release sheet having a low release force.

  The thickness of the release sheets 12a and 12b is not particularly limited, but is usually about 20 to 150 μm.

(2) Physical properties (total light transmittance)
The total light transmittance (value measured according to JIS K7361-1: 1997) of the pressure-sensitive adhesive layer 11 of the pressure-sensitive adhesive sheet 1 according to this embodiment is preferably 80% or more, and particularly 90% or more. It is preferable that it is 99% or more. When the total light transmittance is 80% or more, the transparency is high and it is suitable for optical use (for display). When the pressure-sensitive adhesive layer 11 is composed of the pressure-sensitive adhesive Q, it is easy to satisfy the above total light transmittance.

(3) Production of pressure-sensitive adhesive sheet As one production example of the pressure-sensitive adhesive sheet 1, a case of using the pressure-sensitive adhesive composition P will be described. The coating liquid of the adhesive composition P is applied to the release surface of one release sheet 12a (or 12b), and the adhesive composition P is thermally cross-linked to form a coating layer, and then the application is performed. The release surface of the other release sheet 12b (or 12a) is overlaid on the layer. When the curing period is required, the curing period is set, and when the curing period is unnecessary, the coating layer serves as the adhesive layer 11 as it is. Thereby, the adhesive sheet 1 is obtained. The heat treatment and curing conditions are as described above.

  Another example of the production of the pressure-sensitive adhesive sheet 1 is to apply a coating solution of the pressure-sensitive adhesive composition P to the release surface of one release sheet 12a and heat-treat the heat-crosslinking the pressure-sensitive adhesive composition P to form a coating layer. Is formed to obtain a release sheet 12a with a coating layer. On the other side of the release sheet 12b, a coating solution of the adhesive composition P is applied, and heat treatment is performed to thermally crosslink the adhesive composition P to form a coating layer. To obtain a release sheet 12b. Then, the release sheet 12a with the coating layer and the release sheet 12b with the coating layer are attached to each other so that both coating layers contact each other. When the curing period is required, the curing period is set, and when the curing period is not necessary, the above-mentioned laminated coating layer becomes the pressure-sensitive adhesive layer 11 as it is. Thereby, the adhesive sheet 1 is obtained. According to this manufacturing example, even if the pressure-sensitive adhesive layer 11 is thick, it is possible to manufacture it stably.

  As a method of applying the coating liquid of the adhesive composition P, for example, a bar coating method, a knife coating method, a roll coating method, a blade coating method, a die coating method, a gravure coating method, or the like can be used.

[Flexible laminated member]
As shown in FIG. 2, the flexible laminated member 2 according to the present embodiment includes a first flexible member 21 (one flexible member), a second flexible member 22 (another flexible member), and a space between them. The pressure-sensitive adhesive layer 11 is provided and is configured to bond the first flexible member 21 and the second flexible member 22 to each other.

  The pressure-sensitive adhesive layer 11 in the flexible laminated member 2 is the pressure-sensitive adhesive layer 11 of the pressure-sensitive adhesive sheet 1 described above.

  The flexible laminated member 2 is the flexible display itself or a member forming a part of the flexible display. Here, the flexible display is a bendable display, preferably a display that can be repeatedly bent (including bending), and includes, for example, an organic electroluminescence (organic EL) display and an electrophoretic display (electronic paper). A liquid crystal display using a plastic substrate (film) as a substrate, a foldable display, etc. may be mentioned, and a touch panel may be used.

  The first flexible member 21 and the second flexible member 22 are bendable members, preferably members that can be repeatedly bent (including bending), and include, for example, a cover film, a barrier film, a polarizing film, and a polarizer. , Retardation film, viewing angle compensation film, brightness enhancement film, contrast enhancement film, diffusion film, transflective film, electrode film, transparent conductive film, metal mesh film, film sensor, liquid crystal polymer film, light emitting polymer film, film Liquid crystal module, organic EL module (organic EL film), electronic paper module (film electronic paper), and the like.

  Among the above, at least one of the first flexible member 21 and the second flexible member 22 is a flexible display element, specifically, a liquid crystal polymer film, a light emitting polymer film, a film-shaped liquid crystal module, an organic EL module (organic EL module). It is preferably an EL film) or an electronic paper module (electronic paper film).

  The Young's modulus of each of the first flexible member 21 and the second flexible member 22 is preferably 0.1 to 10 GPa, particularly preferably 0.5 to 7 GPa, and further 1.0 to 5 GPa. Preferably. By setting the Young's modulus of the first flexible member 21 and the second flexible member 22 in such a range, it becomes easy to repeatedly bend each flexible member.

  The thickness of each of the first flexible member 21 and the second flexible member 22 is preferably 10 to 3000 μm, particularly preferably 25 to 1000 μm, and further preferably 50 to 500 μm. By setting the thicknesses of the first flexible member 21 and the second flexible member 22 in such a range, it becomes easy to repeatedly bend each flexible member.

  The interlayer adhesion (adhesive force) between the first flexible member 21 and the second flexible member 22 is preferably 1 N / 25 mm or more as a lower limit, and particularly preferably 2 N / 25 mm or more, Further, it is preferably 5 N / 25 mm or more. When the interlayer adhesion is 1 N / 25 mm or more, the flexible display has excellent bending resistance. The upper limit of the interlayer adhesion is preferably 30 N / 25 mm or less, more preferably 25 N / 25 mm or less, and particularly preferably 20 N / 25 mm or less. It can be said that the reworkability is excellent when the interlayer adhesion is 20 N / 25 mm or less. Thus, even if a bonding error occurs between the flexible members, they can be easily separated, and the flexible member (especially expensive flexible member) can be reused.

  Here, the interlayer adhesive force (adhesive force) in the present specification basically means an adhesive force measured by a 180-degree peeling method according to JIS Z0237: 2009, but the measurement sample has a width of 25 mm and a length of 100 mm. , A first flexible member / a pressure-sensitive adhesive layer / a second flexible member is produced, and after pressurizing at 0.5 MPa and 50 ° C. for 20 minutes, the conditions are normal pressure, 23 ° C., and 50% RH. After leaving it for 24 hours, the peeling speed is measured at 300 mm / min.

  In order to manufacture the flexible laminated member 2, as an example, one release sheet 12a of the pressure-sensitive adhesive sheet 1 is peeled off to expose the exposed pressure-sensitive adhesive layer 11 of the pressure-sensitive adhesive sheet 1 on one surface of the first flexible member 21. To paste.

  After that, the other release sheet 12b is peeled from the pressure-sensitive adhesive layer 11 of the pressure-sensitive adhesive sheet 1, and the exposed pressure-sensitive adhesive layer 11 of the pressure-sensitive adhesive sheet 1 and the second flexible member 22 are bonded together to obtain the flexible laminated member 2. .. Further, as another example, the bonding order of the first flexible member 21 and the second flexible member 22 may be exchanged.

[Flexible display]
The flexible display according to the present embodiment includes the above-mentioned flexible laminated member 2, and may be made up of only the flexible laminated member 2, or one or a plurality of flexible laminated members 2 and another flexible member. It may be provided. When one flexible laminated member 2 and another flexible laminated member 2 are laminated, or when the flexible laminated member 2 and another flexible member are laminated, they are laminated via the pressure-sensitive adhesive layer 11 of the pressure-sensitive adhesive sheet 1 described above. Preferably.

  The flexible display according to the present embodiment is a stack of flexible members using the pressure-sensitive adhesive layer 11 having excellent bending resistance, and therefore when the flexible member is repeatedly bent at a predetermined portion, the pressure-sensitive adhesive layer 11 has a different shape. It is possible to prevent the appearance and the visibility from being deteriorated at the bent portion.

  The embodiments described above are described to facilitate the understanding of the present invention, and are not described to limit the present invention. Therefore, each element disclosed in the above-described embodiment is intended to include all design changes and equivalents within the technical scope of the present invention.

  For example, one or both of the release sheets 12a and 12b in the pressure-sensitive adhesive sheet 1 may be omitted, and a desired optical member may be laminated instead of the release sheets 12a and / or 12b.

  Hereinafter, the present invention will be described more specifically with reference to Examples and the like, but the scope of the present invention is not limited to these Examples and the like.

[Example 1]
1. Preparation of (meth) acrylic acid ester polymer (A) n-butyl acrylate 47.8 parts by mass, 2-ethylhexyl acrylate 47.8 parts by mass, acrylic acid 4 parts by mass and 2-hydroxypropyl acrylate 0.4. By mass-polymerizing, a (meth) acrylic acid ester polymer (A) was prepared. When the molecular weight of this (meth) acrylic acid ester polymer (A) was measured by the method described below, the weight average molecular weight (Mw) was 600,000.

2. Preparation of Adhesive Composition 100 parts by mass of (meth) acrylic acid ester polymer (A) obtained in the above step 1 (solid content conversion value; the same applies below) and trimethylolpropane-modified triester as crosslinking agent (B) 0.9 parts by mass of diisocyanate (manufactured by Toyochem Co., Ltd., product name “BHS8515”) was mixed, sufficiently stirred, and diluted with methyl ethyl ketone to obtain a coating solution of the adhesive composition.

3. Production of pressure-sensitive adhesive sheet A heavy-peelable release sheet (manufactured by Lintec Co., product name "SP-PET752150") obtained by subjecting the obtained coating solution of the pressure-sensitive adhesive composition to release treatment on one side of a polyethylene terephthalate film with a silicone-based release agent. The treated surface was coated with a knife coater. Then, the coating layer was heated at 90 ° C. for 1 minute to form a coating layer.

  Then, a light release type release sheet obtained by release-treating the coating layer on the heavy release type release sheet obtained above and one side of a polyethylene terephthalate film with a silicone-based release agent (manufactured by Lintec Co., product name "SP-PET382120") And the light-peelable release sheet with the release-treated surface in contact with the coating layer, and aged for 7 days under the conditions of 23 ° C. and 50% RH to give a pressure-sensitive adhesive layer having a thickness of 25 μm. A pressure-sensitive adhesive sheet having the same, that is, a pressure-sensitive adhesive sheet having a structure of heavy release type release sheet / pressure sensitive adhesive layer (thickness: 25 μm) / light release type release sheet was prepared. The thickness of the pressure-sensitive adhesive layer is a value measured by using a constant pressure thickness meter (manufactured by Teclock Co., product name “PG-02”) according to JIS K7130.

Here, Table 1 shows each formulation (solid content conversion value) of the adhesive composition when the (meth) acrylic acid ester polymer (A) was 100 parts by mass (solid content conversion value). Details of the abbreviations and the like shown in Table 1 are as follows.
[(Meth) acrylic acid ester polymer (A)]
BA: n-butyl acrylate 2EHA: 2-ethylhexyl acrylate AA: acrylic acid 2HPA: 2-hydroxypropyl acrylate 4HBA: 4-hydroxybutyl acrylate MMA: methyl methacrylate HEA: 2-hydroxyethyl acrylate ACMO: N -Acryloylmorpholine IBXA: isobornyl acrylate
[Crosslinking agent (B)]
TDI: trimethylolpropane modified tolylene diisocyanate (manufactured by Toyochem, product name "BHS8515")
XDI: trimethylolpropane modified xylylene diisocyanate (manufactured by Soken Chemical Industry Co., Ltd., product name "TD-75")
Epoxy type: 1,3-bis (N, N'-diglycidylaminomethyl) cyclohexane (Mitsubishi Gas Chemical Co., product name "TETRAD-C")

[Examples 2 to 3, Comparative Examples 1 to 5]
Type and ratio of each monomer constituting the (meth) acrylic acid ester polymer (A), weight average molecular weight (Mw) of the (meth) acrylic acid ester polymer (A), and type and composition of the cross-linking agent (B). A pressure-sensitive adhesive sheet was produced in the same manner as in Example 1 except that the amount was changed as shown in Table 1.

[Test Example 1] (Measurement of glass transition temperature)
The glass transition temperature (Tg) of the (meth) acrylic acid ester polymer (A) produced and used in Examples and Comparative Examples was measured by a differential scanning calorimeter (manufactured by TA Instruments Japan, Inc., product name). "DSC Q2000") at a temperature rising / falling rate of 20 ° C / min. The results are shown in Table 1.

[Test Example 2] (Measurement of storage elastic modulus (G '))
A plurality of pressure-sensitive adhesive layers of the pressure-sensitive adhesive sheets prepared in Examples and Comparative Examples were laminated to form a laminate having a thickness of 3 mm. A columnar body (height: 3 mm) having a diameter of 8 mm was punched out from the obtained laminated body of the pressure-sensitive adhesive layer and used as a sample.

The storage elastic modulus (G ′) (MPa) of the above sample was measured under the following conditions by a torsion shearing method using a viscoelasticity measuring instrument (manufactured by REOMETRIC, DYNAMIC ANALAYZER) according to JIS K7244-6. The results are shown in Table 1.
Measurement frequency: 1 Hz
Measurement temperature: -20 ℃, 0 ℃, 23 ℃, 40 ℃

When the storage elastic modulus at −20 ° C. is G ′ (− 20) and the storage elastic modulus at 40 ° C. is G ′ (40), the elastic modulus change rate derived by the following formula (1) was calculated. .. The results are shown in Table 1.
Elastic modulus change rate (%) = (G ′ (− 20) / G ′ (40)) × 100 (1)

[Test Example 3] (Measurement of gel fraction)
The pressure-sensitive adhesive sheets obtained in Examples and Comparative Examples were cut into a size of 80 mm × 80 mm, the pressure-sensitive adhesive layer was wrapped in a polyester mesh (mesh size 200), and the mass was weighed with a precision balance to obtain the above mesh. The mass of the adhesive alone was calculated by subtracting the mass of the individual. The mass at this time is M1.

  Next, the pressure-sensitive adhesive wrapped in the polyester mesh was immersed in ethyl acetate at room temperature (23 ° C.) for 24 hours. After that, the adhesive was taken out, air-dried for 24 hours in an environment of a temperature of 23 ° C. and relative humidity of 50%, and further dried in an oven of 80 ° C. for 12 hours. After drying, the mass was weighed with a precision balance, and the mass of the mesh alone was subtracted to calculate the mass of the adhesive alone. The mass at this time is M2. The gel fraction (%) is represented by (M2 / M1) × 100. The results are shown in Table 1.

[Test Example 4] (Measurement of total light transmittance)
The pressure-sensitive adhesive layers of the pressure-sensitive adhesive sheets obtained in Examples and Comparative Examples were laminated on glass, and this was used as a measurement sample. After performing background measurement with glass, the sample for measurement was measured according to JIS K7361-1: 1997 using a haze meter (manufactured by Nippon Denshoku Industries Co., Ltd., product name "NDH-2000"). The transmittance (%) was measured. The results are shown in Table 1.

[Test Example 5] (Measurement of adhesive strength (interlayer adhesion))
In an environment of 23 ° C. and 50% RH, the light release type release sheet was released from the adhesive sheets obtained in Examples and Comparative Examples, and the exposed adhesive layer was used as a polyethylene terephthalate film as a first flexible member. (Toyobo Co., Ltd., product name “Cosmo Shine 4300”, thickness: 100 μm) was attached to one surface. Then, the heavy release type release sheet is peeled off, and the exposed pressure-sensitive adhesive layer is a polyethylene terephthalate film having a transparent conductive film made of tin-doped indium oxide (ITO) on one surface as a second flexible member (Oike Kogyo Co., Ltd. It was attached to the surface of the transparent conductive film side of ITO film, thickness: 125 μm manufactured by Mfg. Co., Ltd. The autoclave manufactured by Kurihara Seisakusho Co., Ltd. was used to apply pressure at 0.5 MPa and 50 ° C. for 20 minutes, and then allowed to stand under conditions of 23 ° C. and 50% RH for 24 hours. The thus obtained PET film / adhesive layer / ITO film laminate (flexible laminate member) was cut into a width of 25 mm and a length of 100 mm to obtain a sample.

  Using the universal tensile tester (manufactured by Orientec Co., Ltd., product name "Tensilon UTM-4-100") for the above sample, the PET film was peeled off under the conditions of a peeling speed of 300 mm / min and a peeling angle of 180 degrees, and the interlayer adhesion strength was measured. The adhesive force (N / 25 mm) was measured. Conditions other than those described here were measured according to JIS Z 0237: 2009. The results are shown in Table 1.

[Test Example 6] (Measurement of Young's modulus of flexible member)
The first and second flexible members (PET film and ITO film) used in Test Example 5 were cut into 10 mm × 70 mm test pieces. Then, the Young's modulus at 23 ° C. and 50% RH was measured according to JIS K7161: 1994. Specifically, the test piece was set to a chuck distance of 20 mm with a universal tensile tester (manufactured by Orientec Co., Ltd., product name "Tensilon RTA-T-2M"), and then pulled at a speed of 200 mm / min. A test was conducted and Young's modulus (unit: GPa) was measured. As a result, both the PET film and the ITO film had a Young's modulus of 4.2 GPa.

[Test Example 7] (Flex resistance test)
At 23 ° C. and 50% RH, the light release type release sheet was released from the adhesive sheets obtained in Examples and Comparative Examples, and the exposed adhesive layer was covered with a polyethylene terephthalate film (manufactured by Toyobo Co., Ltd., product The name "Cosmo Shine 4300", thickness: 100 μm) was attached to one surface. Then, the heavy release type release sheet was released, and the exposed adhesive layer was attached to one surface of another polyethylene terephthalate film (manufactured by Toyobo Co., Ltd., product name “Cosmoshine 4300”, thickness: 100 μm). .. The autoclave manufactured by Kurihara Seisakusho Co., Ltd. was used to apply pressure at 0.5 MPa and 50 ° C. for 20 minutes, and then allowed to stand under conditions of 23 ° C. and 50% RH for 24 hours. The thus obtained PET film / adhesive layer / PET film laminate was cut to a width of 50 mm and a length of 200 mm to obtain a sample.

The obtained sample was repeatedly bent under the following conditions using an endurance tester (manufactured by Yuasa System Instruments Co., Ltd., product name "planar body unloaded U-shaped stretch tester"). Then, the sample was placed on a horizontal table, one end of the sample in the longitudinal direction was fixed to the table surface, and the vertical distance (bending amount) from the table surface of the other end of the sample was measured. The results are shown in Table 1.
Minimum bending diameter: 4 mmφ
Number of bends: 30,000 times Test temperature: 23 ° C

Further, the appearance of the bent portion of the sample after the test was visually evaluated according to the following criteria. The results are shown in Table 1.
⊚: There is no bent line.
◯: A bent line exists, but when viewed from the front, the line is hardly noticed.
Δ: There is a bent line, and the presence of the line can be confirmed when viewed from the front, but the line is not clouded.
X: A line of a bent portion is present, and the line is cloudy and conspicuous. Alternatively, the adhesive is peeled off from the base material.

  As can be seen from Table 1, the pressure-sensitive adhesive layers of the pressure-sensitive adhesive sheets of Examples were excellent in bending resistance and optical characteristics. Moreover, the flexible laminated member obtained by using the pressure-sensitive adhesive sheet of the example had a good interlayer adhesion.

  INDUSTRIAL APPLICABILITY The present invention is suitable for laminating one flexible member (for example, various films) constituting a flexible display and another flexible member (for example, display element).

DESCRIPTION OF SYMBOLS 1 ... Adhesive sheet 11 ... Adhesive layer 12a, 12b ... Release sheet 2 ... Flexible laminated member 21 ... First flexible member 22 ... Second flexible member

Claims (9)

A flexible display adhesive for laminating one flexible member and another flexible member constituting a flexible display that is repeatedly bent with a single-layer adhesive layer ,
The storage elastic modulus G ′ (−20) at −20 ° C. is 0.1 MPa or more and less than 1 MPa,
Based on the storage elastic modulus G ′ (− 20) and the storage elastic modulus G ′ (40) at 40 ° C., the elastic modulus change rate derived by the following formula (1) is 500% or more and 10000% or less. ,
The gel fraction is 60% or more and 100% or less,
The glass transition temperature of the main polymer of the flexible display pressure-sensitive adhesive (Tg) of, -80 ° C. or higher state, and are -40 ℃ or less,
A polymer obtained by copolymerizing a (meth) acrylic acid alkyl ester having an alkyl group with 2 to 20 carbon atoms and a reactive functional group-containing monomer;
A crosslinking agent that reacts with the reactive functional group of the reactive functional group-containing monomer and crosslinks the polymer by heating.
A pressure-sensitive adhesive for flexible displays, comprising a pressure-sensitive adhesive composition containing the compound.
Elastic modulus change rate (%) = (G ′ (− 20) / G ′ (40)) × 100 (1) A pressure-sensitive adhesive sheet having a single-layer pressure-sensitive adhesive layer for laminating one flexible member and another flexible member constituting a flexible display that is repeatedly bent,
The pressure-sensitive adhesive sheet, wherein the pressure-sensitive adhesive layer comprises the pressure-sensitive adhesive for flexible display according to claim 1 . The pressure-sensitive adhesive sheet comprises two release sheets,
The pressure-sensitive adhesive sheet according to claim 2 , wherein the pressure-sensitive adhesive layer is sandwiched between the release sheets so as to come into contact with the release surfaces of the two release sheets. One flexible member and another flexible member that form a flexible display that is repeatedly bent,
A flexible laminated member comprising a single pressure-sensitive adhesive layer for laminating the one flexible member and the other flexible member to each other,
A flexible laminated member, wherein the pressure-sensitive adhesive layer is the pressure-sensitive adhesive layer of the pressure-sensitive adhesive sheet according to claim 2 or 3 . The flexible laminated member according to claim 4 , wherein at least one of the one flexible member and the other flexible member is a flexible display element. The Young's modulus of each of the one flexible member and the other flexible member is 0.1 to 10 GPa, respectively, and the flexible laminated member according to claim 4 or 5 . The flexible laminated member according to any one of claims 4 to 6 , wherein each of the one flexible member and the other flexible member has a thickness of 10 to 3000 µm. The interlayer adhesion between the one flexible member and the other flexible member is 1 to 30 N / 25 mm, and the flexible laminated member according to any one of claims 4 to 7 . A flexible display that is repeatedly bent, comprising the flexible laminated member according to any one of claims 4 to 8 .

Images