JP6694490B2 - Fabric base fabric for airbags - Google Patents

Fabric base fabric for airbags Download PDF

Info

Publication number
JP6694490B2
JP6694490B2 JP2018209966A JP2018209966A JP6694490B2 JP 6694490 B2 JP6694490 B2 JP 6694490B2 JP 2018209966 A JP2018209966 A JP 2018209966A JP 2018209966 A JP2018209966 A JP 2018209966A JP 6694490 B2 JP6694490 B2 JP 6694490B2
Authority
JP
Japan
Prior art keywords
fabric
yarn
warp
base fabric
woven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2018209966A
Other languages
Japanese (ja)
Other versions
JP2019023377A (en
Inventor
田中 剛
剛 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Original Assignee
Asahi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Corp filed Critical Asahi Kasei Corp
Priority to JP2018209966A priority Critical patent/JP6694490B2/en
Publication of JP2019023377A publication Critical patent/JP2019023377A/en
Application granted granted Critical
Publication of JP6694490B2 publication Critical patent/JP6694490B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Description

本発明は、エアバッグ用織物基布に関する。より詳しくは、本発明は、気密性が高く柔軟であり、収納性に優れ、かつ、生産性の高いエアバッグ用織物基布に関する。   The present invention relates to a textile base fabric for airbags. More specifically, the present invention relates to a woven fabric base fabric for an airbag, which is highly airtight and flexible, has excellent storability, and has high productivity.

エアバッグは、事故時の衝突の衝撃や、車内装備品と人体の接触を軽減するものである。そのために、エアバッグには気密性が求められている。詳しくは膨張部と非膨張部の境界部分の気密性がバッグ全体の気密性に影響を与えるが、特に、インフレータ作動時の高温ガスが存在する環境下での前述した部分の気密性は特に重要である。他方、昨今の傾向として車両の居住空間拡大等によってエアバッグの収容スペースが限られてきている為に、収納性も重要な項目として挙げられるようになった。
これを解決すべく、以下の特許文献1には、低繊度糸を適用し、構成糸の引き抜き強力、引張強力での300N時の伸び、剛軟度、目付を特定の領域に設計することで軽量化、収納性、気密性を達成する技術が開示されている。この技術は収納性と気密性を実現することができるものの、これを達成する為に低繊度糸の高密度製織を余儀なくされているため、生産性が低く、コストが高くなりやすいという欠点を有する。また、以下の特許文献2には、扁平単糸で構成される糸条を用い、特定の糸幅に製織することで高気密かつ安価な製品を提供することが開示されている。これには扁平糸が必須であり、扁平糸は、丸断面と比較して強力が低下しやすく、昨今のエアバッグはインフレータの高出力化もあり、必ずしも十分な強力を有しているとは言えない。
このように、十分な機械強度を有し、気密性が高く、収納性の優れた基布を効率よく生産できる技術は未だ開示されていない。
The airbag reduces the impact of a collision at the time of an accident and the contact between in-vehicle accessories and the human body. Therefore, the air bag is required to have airtightness. Specifically, the airtightness of the boundary between the inflated part and the non-inflated part affects the airtightness of the entire bag, but the airtightness of the above-mentioned part is particularly important in the environment where high temperature gas is present when the inflator is activated. Is. On the other hand, as a recent tendency is that the accommodation space of the airbag is limited due to the expansion of the living space of the vehicle and the like, the storability has come to be mentioned as an important item.
In order to solve this, in Patent Document 1 below, a low-fineness yarn is applied, and the pull-out strength of the constituent threads, the elongation at 300 N at tensile strength, the bending resistance, and the basis weight are designed in specific areas. A technique for achieving weight reduction, storability, and airtightness is disclosed. Although this technology can achieve storage and airtightness, it has the drawback of low productivity and high cost because it requires high density weaving of low-definition yarn to achieve this. .. In addition, Patent Document 2 below discloses that a highly airtight and inexpensive product is provided by using a yarn composed of flat single yarns and weaving to a specific yarn width. Flat yarn is indispensable for this, and the strength of the flat yarn is likely to be lower than that of the round cross section, and recent airbags also have a high output of an inflator, and it is not always said that they have sufficient strength. I can not say.
As described above, a technique capable of efficiently producing a base fabric having sufficient mechanical strength, high airtightness, and excellent storability has not been disclosed yet.

特開2012−52280号公報JP 2012-52280 A 特開2005−105446号公報JP, 2005-105446, A

かかる技術の現状の下、本発明が解決しようとする課題は、袋体としたときの膨張部と非膨張部の境界部分の目開きが抑制され、かつ、収納性に優れた安価な織物基布を提供することである。   Under the current state of the art, the problem to be solved by the present invention is to suppress the opening of the boundary portion between the inflatable portion and the non-inflatable portion when the bag body is formed, and an inexpensive woven fabric base excellent in storability. Is to provide the cloth.

本発明者は、繊維表面に特定の物質を特定量存在させることで製織時の糸条にかかる応力を利用し、糸条の扁平化を促進させた。更に、丸断面の単糸によって、織張力による糸条同士の滑りがスムーズに行われ、先述した表面物質の効果と相まって扁平化をより促進させることで、基布としたときの気密性が向上し、織り込み密度を低下させても気密性が維持できることを見出し発明に至ったものである。   The present inventor promoted flattening of the yarn by utilizing the stress applied to the yarn during weaving by allowing a specific amount of a specific substance to exist on the fiber surface. In addition, the single yarn with a round cross-section allows the yarns to slide smoothly due to the weaving tension, and in combination with the effect of the above-mentioned surface material, promotes flattening, thereby improving the airtightness of the base fabric. However, the inventors have found that the airtightness can be maintained even if the weaving density is reduced, and the present invention has been completed.

すなわち、本発明は以下のとおりのものである。
[1]単糸繊度1.5以上4dtex以下の丸断面である熱可塑性樹脂の経糸及び緯糸の糸条で平織された織物基布であって、以下の要件:
(1)下記式1:
Z=(Ww×Dw+Wf×Df)−50.8
{式中、Ww=経糸最大幅(mm)、Dw=経糸密度(本/inch)、Wf=緯糸最大幅(mm)、Df=緯糸密度(本/inch)}で表されるZ値が0〜7である;
(2)下記式2:
Q=q/S
{式中、q=ASTM_D6476で測定された30〜70kPa間のADAP(mm/s)、S=基布目付(g/m)}で表されるQ値が0.5〜2.5である;
(3)下記式3:
CF=((Tw/ρ)0.5×Dw)+(Tf/ρ)0.5×Df)
{式中、Tw=経糸繊度(Dtex)、Tf=緯糸繊度(Dtex)、ρ=繊維密度(g/cm)}で表されるカバーファクター(CF)が1984〜2050である;
(4)シリコン樹脂が、該織物基布の繊維表面に該繊維重量に対し60〜1100ppmで存在している;
(5)該基布の経引裂き強力は、210N以上である;
(6)該基布の緯引裂き強力は、205N以上である;
(7)該基布を構成する経糸の幅を厚みで除した値が、2.5〜5である;
(8)該基布を構成する緯糸の幅を厚みで除した値が、3.1〜5である;及び
(9)該基布の通気量が、280mm/s以下である;
を満たす前記織物基布。
[2]前記経糸及び緯糸の糸条の繊度が共に300以上800dtex未満である、前記[1]に記載の織物基布。
[3]前記織物基布を構成する経糸及び緯糸の引き抜き抵抗値が共に20〜150N/cm/cmである、前記[1]又は[2]に記載の織物基布。
[4]前記[1]〜[3]のいずれかに記載の織物基布の反物であって、該反物両端の絡み糸と地糸の間に、地糸以外の、繊度が20以上70dtex未満の糸が左右合計4本以上織り込まれていることを特徴とする、前記反物。
[5]前記[1]〜[3]のいずれかに記載の織物基布の反物ロールであって、該ロール中央部の直径Dと該ロール端部の直径dの比d/Dが1.07未満であることを特徴とする、前記反物ロール。
[6]前記[1]〜[3]のいずれかに記載の基布から構成されたノンコートエアバッグ。
[7]前記[4]に記載の反物又は前記[5]に記載の反物ロールを用いる工程を含む、ノンコートエアバッグの製造方法。
That is, the present invention is as follows.
[1] A woven fabric base cloth plain-woven with thermoplastic resin warp and weft yarns having a circular cross section with a single yarn fineness of 1.5 or more and 4 dtex or less, and the following requirements:
(1) The following formula 1:
Z = (Ww x Dw + Wf x Df) -50.8
Z value represented by {Ww = maximum width of warp ( mm ), Dw = warp density (thread / inch), Wf = maximum width of weft ( mm ), Df = weft density (thread / inch)} is 0 ~ 7;
(2) The following formula 2:
Q = q / S
{Wherein q = ADAP (mm / s) between 30 and 70 kPa measured by ASTM_D6476, S = base fabric weight (g / m 2 )}, and the Q value is 0.5 to 2.5. is there;
(3) The following formula 3:
CF = ((Tw / ρ) 0.5 × Dw) + (Tf / ρ) 0.5 × Df)
The cover factor (CF) represented by {wherein Tw = warp yarn fineness (Dtex), Tf = weft yarn fineness (Dtex), ρ = fiber density (g / cm 3 )} is 1984 to 2050 ;
(4) Silicone resin is present on the fiber surface of the woven base fabric at 60 to 1100 ppm based on the weight of the fiber;
(5) The warp tear strength of the base fabric is 210 N or more;
(6) The weft tear strength of the base fabric is 205 N or more;
(7) The value obtained by dividing the width of the warp constituting the base cloth by the thickness is 2.5 to 5;
(8) The value obtained by dividing the width of the weft constituting the base cloth by the thickness is 3.1 to 5; and (9) the air permeability of the base cloth is 280 mm / s or less;
The woven base fabric satisfying the above.
[2] The woven base fabric according to the above [1], wherein the fineness of the warp yarn and the weft yarn is both 300 or more and less than 800 dtex.
[3] The woven fabric according to the above [1] or [2], wherein the warp yarns and the wefts constituting the woven fabric have pull-out resistance values of 20 to 150 N / cm / cm.
[4] The fabric of the woven fabric according to any one of [1] to [3], wherein the fineness other than the ground yarn is 20 or more and less than 70 dtex between the entangled yarn and the ground yarn at both ends of the fabric. The above-mentioned piece of cloth is characterized in that a total of 4 or more threads are woven on the left and right.
[5] In the fabric roll of the woven fabric according to any one of [1] to [3], the ratio d / D of the diameter D of the roll central portion and the diameter d of the roll end portion is 1. It is less than 07, The said cloth roll.
[6] A non-coated airbag made of the base fabric according to any one of [1] to [3].
[7] A method for manufacturing a non-coated airbag, which includes a step of using the cloth material according to [4] or the cloth material roll according to [5].

本発明に係る織物基布は、柔軟かつ気密性に優れた基布であり、生産効率の高い基布である。   The woven base fabric according to the present invention is a base fabric that is flexible and excellent in airtightness, and has high production efficiency.

引き抜き抵抗の測定方法を説明するための概略図である。It is a schematic diagram for explaining a measuring method of pull-out resistance. 展開試験用バッグの概略図である。It is a schematic diagram of a deployment test bag.

以下、本発明の実施形態を詳細に説明する。
本発明に係る織物基布は、柔軟で収納性に優れ、かつ、丸断面単糸と経緯糸の表面処理による摩擦力調整及び高張力製織とあいまって糸条の扁平を促進し、通気性を実用なレベルまで抑制することができるものである。
本発明に係る織物を構成する繊維は、単糸繊度1.5〜7dtexの丸断面であり、好ましくは単糸繊度2〜4dtexである。単糸繊度1.5dtex未満であれば、単糸強力が弱くなり、製織時の筬や綜絖での摩擦において毛羽や糸切れ等の工程トラブルが増加する。また、単糸繊度が7dtexを超える場合は糸束が広がって十分な気密を維持できなくなる。また、本発明に使用する繊維の単糸断面は丸断面である。扁平断面であると製織時に単糸が再配置しても単糸の向きにより大きく気密性に変化を与えるため、気密性の向上が不足する場合がある。
Hereinafter, embodiments of the present invention will be described in detail.
The woven base fabric according to the present invention is flexible and excellent in storability, and promotes flatness of the yarn by adjusting the frictional force by the surface treatment of the round cross section single yarn and the warp and high tension weaving, and improves the air permeability. It can be suppressed to a practical level.
The fibers constituting the woven fabric according to the present invention have a circular cross section with a single yarn fineness of 1.5 to 7 dtex, and preferably have a single yarn fineness of 2 to 4 dtex. When the single yarn fineness is less than 1.5 dtex, the single yarn strength is weakened, and process troubles such as fluff and yarn breakage are increased due to friction in the reed and the heddle during weaving. When the single yarn fineness exceeds 7 dtex, the yarn bundle spreads and it becomes impossible to maintain sufficient airtightness. The single yarn cross section of the fiber used in the present invention is a round cross section. With a flat cross section, even if the single yarns are rearranged during weaving, the airtightness is greatly changed depending on the direction of the single yarns, so that the improvement of the airtightness may be insufficient.

本発明に係る織物基布においては、下記式1:
Z=(Ww×Dw+Wf×Df)−50.8
{式中、Ww=経糸最大幅(μm)、Dw=経糸密度(本/inch)、Wf=緯糸最大幅(μm)、Df=緯糸密度(本/inch)}で表されるZ値が0〜7であり、好ましくは2〜5であり、より好ましくは2〜3である。0未満であると基布の気密性が十分とは言えず、バッグとしたときの膨張部と非膨張部分の目開きが拡大しやすくなり気密性が急激に悪化する場合があり、また、7を超えると必要以上の糸条の広がりとなる為、過大な経緯間の摩擦が発生し、基布の引裂き強力の低下よりバッグとしたときの縫目部からの破壊が発生する場合がある。
In the woven base fabric according to the present invention, the following formula 1:
Z = (Ww x Dw + Wf x Df) -50.8
Z value represented by {Ww = maximum warp width (μm), Dw = warp density (thread / inch), Wf = weft maximum width (μm), Df = weft density (thread / inch)} is 0 -7, preferably 2-5, more preferably 2-3. When it is less than 0, the airtightness of the base fabric cannot be said to be sufficient, and the opening between the inflated part and the non-inflated part when the bag is formed may be easily expanded, and the airtightness may be rapidly deteriorated. If the value exceeds the above range, the yarns will spread more than necessary, and excessive friction between the warp and weft may occur, which may cause breakage from the seam when the bag is formed due to the decrease in tear strength of the base fabric.

また、本発明に係る織物基布においては、下記式2:
Q=q/S
{式中、q=ASTM_D6476で測定された30〜70kPa間のADAP(mm/s)、S=基布目付(g/m)}で表されるQ値が0.5〜2.5であり、好ましくは1〜2である。0.5未満であれば、基布は硬くなりやすく、収納性が悪化する場合があり、また、2.5を超えると気密性が損なわれる場合がある。
Further, in the woven base fabric according to the present invention, the following formula 2:
Q = q / S
{Wherein q = ADAP (mm / s) between 30 and 70 kPa measured by ASTM_D6476, S = base fabric weight (g / m 2 )}, and the Q value is 0.5 to 2.5. Yes, and preferably 1-2. If it is less than 0.5, the base fabric tends to be hard and the storage properties may deteriorate, and if it exceeds 2.5, the airtightness may be impaired.

また、本発明に係る織物基布においては、下記式3:
CF=((Tw/ρ)0.5×Dw)+(Tf/ρ)0.5×Df)
{式中、Tw=経糸繊度(Dtex)、Tf=緯糸繊度(Dtex)、ρ=繊維密度(g/cm)}で表されるカバーファクター(CF)が1850〜2200であり、好ましくは1900〜2100であり、さらに好ましくは1950〜2050である。1850未満であれば気密性が損なわれる場合があり、また、2200を超える場合は基布の剛軟度が高くなり、目的の柔軟な基布が得られなくなる。
Further, in the woven base fabric according to the present invention, the following formula 3:
CF = ((Tw / ρ) 0.5 × Dw) + (Tf / ρ) 0.5 × Df)
The cover factor (CF) represented by {In the formula, Tw = warp yarn fineness (Dtex), Tf = weft yarn fineness (Dtex), ρ = fiber density (g / cm 3 )} is 1850 to 2200, and preferably 1900. ˜2100, more preferably 1950 to 2050. If it is less than 1850, the airtightness may be impaired, and if it exceeds 2200, the bending resistance of the base fabric becomes high and the desired soft base fabric cannot be obtained.

また、本発明に係る織物基布においては、基布特性を発現させるために、ポリオレフィン樹脂、シリコン樹脂、及びエステル類からなる群から選択されたいずれか1種又は2種以上の混合物が、該織物基布の繊維表面に該繊維重量に対し100〜3000ppmで存在している必要があり、好ましくは500〜2000ppmである。100ppm未満であれば目的の経緯糸間の摩擦力が高くなって製織時の糸束の十分な扁平化ができない為にZ値が小さくなる場合がある。3000ppmを超える場合は摩擦力低下が過剰となってバッグとしたときに膨張部と非膨張部分の境目の目開きが起きやすくなり、縫製部分の気密性が損なわれたり、燃焼性を規格内に維持できなくなる可能性がある。ここで表面とは、繊維を構成している単糸の表面を指す。   Further, in the woven base fabric according to the present invention, in order to express the base fabric characteristics, any one kind or a mixture of two or more kinds selected from the group consisting of a polyolefin resin, a silicone resin, and an ester, It is necessary to be present in the fiber surface of the woven fabric at 100 to 3000 ppm, preferably 500 to 2000 ppm, based on the weight of the fiber. If it is less than 100 ppm, the desired frictional force between the warp and weft threads becomes high and the yarn bundle cannot be sufficiently flattened at the time of weaving, so that the Z value may become small. When it exceeds 3000 ppm, the frictional force is excessively reduced, and when the bag is made, the opening between the inflated part and the non-inflated part is easily opened, the airtightness of the sewn part is impaired, and the combustibility falls within the specifications. It may not be maintained. Here, the surface refers to the surface of the single yarn that constitutes the fiber.

繊維を構成している単糸の表面に前述した処理剤付着させる方法としては、紡糸段階若しくは経糸整経時に給油ロールを設けて付与するか、熱セット工程の前で浸漬付与する。また、付与する工程は前述した工程のどれか一つ又はいくつかの工程に分けて付与することができる。付着する物質は、ポリオレフィン類としては、例えば、ポリエチレン、ポリプロピレン樹脂、脂肪酸エステル類としては、2塩基酸と1価アルコールや多価アルコールと1塩基酸のエステル、又は多価アルコールと2塩基酸のエステル、シリコン樹脂類としては、ジメチルシリコン又はその変性体を使用することができる。付与する形態としては、炭化水素等の有機溶液、水溶液、エマルジョンの形態があるが、工程安全性より、水を使用する方が好ましく、エマルションが最も好ましい。熱可塑性繊維としては、ポリアミド類及びポリエステル類からなる群から選択されるものがコストや物性等でバランスが取れていて好適である。特に、ナイロン66やポリエチレンテレフタレート繊維が好適に使用でき、耐熱性、摩擦特性、強伸度を考慮すると、ナイロン66が最も好適である。当該繊維は溶融紡糸によりマルチフィラメントを得て、冷却後、油剤を付与し、熱ロールにて延伸し、圧力空気により交絡を付与して得られる。   As a method for adhering the above-mentioned treatment agent to the surface of the single yarn constituting the fiber, it is applied by providing an oiling roll at the spinning stage or warp preparation time, or by dipping before the heat setting step. Further, the applying step can be applied by dividing one of the above-mentioned steps or some steps. Examples of the substance to be attached include polyolefins such as polyethylene and polypropylene resin, and fatty acid esters such as dibasic acid and monohydric alcohol or polyhydric alcohol and monobasic acid ester, or polyhydric alcohol and dibasic acid. As the ester or silicone resin, dimethyl silicone or a modified product thereof can be used. The form to be applied may be an organic solution such as a hydrocarbon, an aqueous solution, or an emulsion, but water is preferably used and the emulsion is most preferable in terms of process safety. As the thermoplastic fiber, one selected from the group consisting of polyamides and polyesters is suitable because it is well balanced in cost and physical properties. In particular, nylon 66 and polyethylene terephthalate fiber can be preferably used, and nylon 66 is most preferable in consideration of heat resistance, frictional characteristics, and high elongation. The fiber is obtained by obtaining a multifilament by melt spinning, cooling, applying an oil agent, stretching with a hot roll, and confounding with pressurized air.

本発明の織物基布を構成する繊維束の断面の幅を高さで除した値が2.5〜5.0であると柔軟性と気密性がより好適に発現する。2.5以上であると基布に力が加わった場合、構成する繊維が程度に移動し、引裂き強力が有利に働く。また、5.0以下であれば経緯糸の拘束力が向上し、気密性が有利になる。   When the value obtained by dividing the width of the cross section of the fiber bundle constituting the woven base fabric of the present invention by the height is 2.5 to 5.0, flexibility and airtightness are more suitably expressed. When it is 2.5 or more, when a force is applied to the base fabric, the constituent fibers move to a certain extent, and the tear strength works advantageously. Further, when it is 5.0 or less, the binding force of the warp and weft yarns is improved, and the airtightness becomes advantageous.

本発明の基布を構成する経糸及び緯糸の糸条の繊度は共に300〜800dtexであるとより好適である。300dtex以上では柔軟性向上により収納性がより向上する。また、800dtex以下であれば密度は少なくて済むために、より生産性に有利になる。より好ましくは、400〜700dtexである。   It is more preferable that the fineness of both the warp yarn and the weft yarn constituting the base fabric of the present invention is 300 to 800 dtex. When it is 300 dtex or more, the flexibility is improved and the storability is further improved. Further, if it is 800 dtex or less, the density is small, which is more advantageous in productivity. More preferably, it is 400 to 700 dtex.

本発明の織物基布を構成する糸の引き抜き抵抗値は、20〜150N/cm/cmであると気密性をより良く維持することができる。20N/cm/cm以上であると糸条の自由度が高いことより、柔軟な基布となり柔軟性かつ、引裂き強力が有利に働く。他方、150N/cm/cm以下であれば経緯糸間の摩擦が大きくなり、縫製部分の気密性維持に有利である。この範囲の引き抜き抵抗は、0.22cN/dtex以上の経糸張力で製織することが好ましいが、あまり張力を上げ過ぎると綜絖や筬によって毛羽が発生する場合があり、筬の1羽当たりの入れ数やテンプル、綜絖の材質、形状等の工夫が必要である。本発明の織物基布の両端には耳緩み防止のために、織物の地糸とは同種及び/又は別種の糸を適用する。例えば、絡み糸と力糸である。   The airtightness can be better maintained when the withdrawal resistance value of the yarn constituting the woven fabric of the present invention is 20 to 150 N / cm / cm. When it is 20 N / cm / cm or more, the degree of freedom of the yarn is high, so that it becomes a flexible base fabric, and flexibility and tear strength work advantageously. On the other hand, if it is 150 N / cm / cm or less, the friction between the warp and weft yarns becomes large, which is advantageous for maintaining the airtightness of the sewn portion. The pull-out resistance in this range is preferably weaving with a warp tension of 0.22 cN / dtex or more, but if the tension is raised too much, fluff may occur due to the heddle or the reed, and the number of inserts per reed It is necessary to devise materials, shapes, etc. for the temples and heddle. To prevent loosening of the ears, the same type and / or different type of yarn as the ground yarn of the woven fabric is applied to both ends of the woven base fabric of the present invention. For example, entanglement yarn and strength yarn.

前記したように、本発明の基布を構成する糸条の幅を厚みで除した値は2.5〜5が好ましい。2.5以上であれば厚みの効果で耐熱性に有利となる。5以下では扁平化が進み、柔軟性、気密性に有利である。上記値の範囲とするには、0.25cN/dtex以上の経糸張力で製織することが好ましいが、あまり張力を上げ過ぎると綜絖や筬によって毛羽が発生する場合があり、バランスさせることが必要であるが、単糸数を多くすると製織張力も低くできる場合がある。   As described above, the value obtained by dividing the width of the yarn constituting the base fabric of the present invention by the thickness is preferably 2.5 to 5. When it is 2.5 or more, the effect of thickness is advantageous in heat resistance. When it is 5 or less, flattening proceeds, which is advantageous for flexibility and airtightness. To achieve the above value range, it is preferable to weave with a warp tension of 0.25 cN / dtex or more, but if the tension is excessively increased, fluff may occur due to the heddle or the reed, and it is necessary to balance the fluff. However, if the number of single yarns is increased, the weaving tension may be lowered in some cases.

本発明の織物基布を作製するに際しては、絡み糸と増し糸を用いる方が品質向上に好適である。絡み糸は、一番反物の端に配置して、耳部のほつれや緩みを防止する。絡み糸は、通常2本1組で両耳部分にレノ装置にて織物に織り込む。15〜100dtexのモノフィラメントを適用した場合、耳部の締まりが良く、耳部のたるみや、これに起因するフレアおよび経糸密度のばらつきを有効に軽減できる。絡み糸は15dtex以上であると耳部の締まりが特によく、100dtex以下では適度に太い糸である為にハンドリングが容易である。   When manufacturing the woven base fabric of the present invention, it is preferable to use the entwined yarn and the additional yarn for quality improvement. The entanglement thread is placed at the end of the most cloth material to prevent fraying and loosening of the ears. The entangled yarns are usually woven into a woven fabric by a leno device at both ear portions in pairs. When a monofilament of 15 to 100 dtex is applied, the selvages of the selvages are well tightened, and the sagging of the selvages and the flare and warp density variations caused thereby can be effectively reduced. If the entangled yarn is 15 dtex or more, the tightness of the ears is particularly good, and if the entangled yarn is 100 dtex or less, the yarn is a moderately thick yarn, so that the handling is easy.

更に増し糸と称する糸を反物地糸と両反端絡み糸の間に片側当たり2本以上存在させると反物の緩み防止により有効となる。これは別の給糸台より供給する。反物両端の絡み糸と地糸の間に、繊度が20以上100dtex未満の増し糸が左右合計4本以上織り込まれていることが好ましい。増し糸には、モノフィラメント、捲縮加工糸、スパン糸、地糸と同種の糸を単独で又は組み合わせて使用できる。これらは、耳部のしわや緩み、製品ロールの耳高さを見ながら張力や適用する糸種を適宜選択する。また、増し糸部は平織組織が一般的に採用されるが、耳部の状態により変更でき、特に限定されない。   Furthermore, if two or more yarns called additional yarns are present on one side between the piece of anti-textile material and the two end-entangled threads, it is more effective for preventing loosening of the article. This is supplied from another yarn feeder. It is preferable that four or more total left and right additional yarns having a fineness of 20 or more and less than 100 dtex are woven between the entangled yarn and the ground yarn at both ends of the cloth. As the additional yarn, a monofilament, a crimped yarn, a spun yarn, and a yarn of the same kind as the ground yarn can be used alone or in combination. For these, the tension and the thread type to be applied are appropriately selected while observing the wrinkles and looseness of the ears and the height of the ears of the product roll. A plain weave design is generally adopted for the additional yarn portion, but the additional yarn portion can be changed depending on the state of the selvage portion and is not particularly limited.

本発明の織物基布を製織する場合に使用する織機の緯入れ機構は、レピア、ウォータジェット、エアージェット、シャットル、プロジェクタイル等一般的な装置を選択できる。   As the weft inserting mechanism of the loom used for weaving the woven base fabric of the present invention, general devices such as rapier, water jet, air jet, shuttle, and projectile can be selected.

本発明の織物基布を得るためのセット加工において、熱セットを行う場合もある。その時のセット方法は特に限定されず、公知の方法が選択できる。例えば、熱水槽に通した後に乾燥し、テンター等の熱固定炉にて熱固定する方法や、テンターを省略した方法も選択できる。熱固定時には経方向では供給ロールと炉内固定具の進行速度差により張力をかける方法が一般的にとられる。また、緯方向では、例えばピン、クリップ固定や、炉内ロールと織物との摩擦のみで緯方向の収縮を抑制する方法が採用できる。加熱においても電気やガス燃焼加熱空気を循環させる方法や赤外線ヒーターでの輻射を利用してもよい。この時のセット温度は100〜200℃の範囲が好適である。また、熱セット時にテンターを用いる場合は、下記式4:
テンターオーバーフィード率=(Vw−Vs)/Vs×100
{式中、Vs=反物精錬後の加熱セット機への供給速度(m/min)、Vw=反物精錬後の加熱セット機内速度(m/min)}で表されるテンターオーバーフィード率を−10〜2%に調整し、さらに、下記式5:
テンター横幅変化率=(Dw−Ds)/Ds*100
{式中、Ds=反物精錬後の加熱セット機への供給反物幅(mm)、Dw=反物精錬後の加熱セット機内の反物幅(mm)}で表されるテンター横幅変化率を−10〜2%程度の範囲で調整することで、密度分布の小さい品質の良い基布が得られる。
In the set process for obtaining the woven base fabric of the present invention, heat setting may be performed. The setting method at that time is not particularly limited, and a known method can be selected. For example, a method of drying after passing through a hot water tank and heat setting in a heat fixing furnace such as a tenter, or a method of omitting the tenter can be selected. When heat-fixing, a method is generally used in which tension is applied in the longitudinal direction due to the difference in moving speed between the supply roll and the in-furnace fixture. In the weft direction, for example, a method of fixing a pin or a clip, or a method of suppressing shrinkage in the weft direction only by friction between a furnace roll and a fabric can be adopted. Also for heating, a method of circulating electricity or gas-combustion heated air or radiation from an infrared heater may be used. The set temperature at this time is preferably in the range of 100 to 200 ° C. When a tenter is used for heat setting, the following formula 4:
Tenter overfeed rate = (Vw−Vs) / Vs × 100
The tenter overfeed rate represented by {wherein Vs = supply speed (m / min) to the heating set machine after the refining of the refining product, Vw = internal speed (m / min) of the heating set after refining of the refining product} is −10. Adjusted to ~ 2%, and further the following formula 5:
Tenter width change rate = (Dw-Ds) / Ds * 100
{In the formula, Ds = the width (mm) of the supplied cloth to the heating set machine after the refining of the cloth, Dw = the width of the cloth inside the heating machine after the refining of the cloth (mm)}, the rate of change of the tenter width, which is −10 By adjusting in the range of about 2%, it is possible to obtain a high-quality base cloth having a small density distribution.

また、テンター等の加熱セット機を用いず、精錬後そのまま乾燥のみを実施してもよい。この場合には、下記式6:
精錬オーバーフィード率=(Sw−Ss)/Ss*100
{式中、Ss=反物の精錬機への供給速度(m/min)、Sw=反物の巻き取り速度(m/min)}で表される精錬オーバーフィード率を−15〜0%程度とすることが好ましい。
Further, without using a heating set machine such as a tenter, only drying may be performed as it is after refining. In this case, the following equation 6:
Refining overfeed rate = (Sw-Ss) / Ss * 100
The refining overfeed rate represented by {In the formula, Ss = supply speed (m / min) of the cloth to the refining machine, Sw = winding speed (m / min) of the cloth) is about -15 to 0%. Preferably.

本発明に係る織物基布が巻かれてロールとなった場合、当該ロール中央部と端部の直径比は7%である、すなわち、ロール中央部の直径Dとロール端部の直径dの比d/Dが1.07未満であることが好ましい。7%未満とすることで、製品の耳部のしわがより少ない品質の良い反物が得られ、ロール運搬時に反物耳部が床面や包装材と擦れるなどの損傷リスクがより低い製品を作製することができる。   When the woven base fabric according to the present invention is wound into a roll, the diameter ratio of the roll center part to the end part is 7%, that is, the ratio of the diameter D of the roll center part to the diameter d of the roll end part. It is preferable that d / D is less than 1.07. By setting the content to be less than 7%, it is possible to obtain a high-quality piece of fabric with less wrinkles on the ears of the product, and to produce a product with a lower risk of damage such as the ears of the article rub against the floor surface or packaging material during roll transport. be able to.

本発明に係る織物基布は、特に、エアバッグ用基布として好適に用いることができる。バッグは縫製又は袋織により形成可能であり、運転席、助手席、サイドカーテン、ニーバッグ、歩行者保護用バッグとして用いることができる。   The woven base fabric according to the present invention can be particularly suitably used as a base fabric for an airbag. The bag can be formed by sewing or hollow weave, and can be used as a driver's seat, a passenger seat, a side curtain, a knee bag, and a pedestrian protection bag.

以下、実施例、比較例によって本発明を具体的に説明するが、本発明はこれらの実施例のみに限定されるものではない。
先ず、実施例等において用いた各種測定方法及び評価方法を説明する。
(1)繊維の繊度、強度、及び伸度は、JIS L1013に従って測定した。
(2)繊維の密度は密度勾配管により測定した。
(3)基布重量:10cm正方を3点切り出し、電子天秤にて小数点3ケタまで測定し、その平均より1m当たりの重量として求めた。
(4)基布密度;TEXTEST社製FX3255を用い経、緯それぞれ5点測定し、その平均を密度とした。
(5)基布の強力及び伸度はJIS L1096のストリップ法に従って測定した。
Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples.
First, various measuring methods and evaluation methods used in Examples and the like will be described.
(1) The fineness, strength, and elongation of the fiber were measured according to JIS L1013.
(2) The fiber density was measured by a density gradient tube.
(3) Base cloth weight: 10 cm square was cut out at 3 points, measured with an electronic balance to three decimal places, and determined as the weight per 1 m 2 from the average.
(4) Base fabric density: Five points were measured for each of the warp and weft using FX3255 manufactured by TEXTTEST, and the average was taken as the density.
(5) The tenacity and the elongation of the base fabric were measured according to the strip method of JIS L1096.

(6)基布の引裂き強力はJIS L1096のシングルタング法にて測定した。
(7)製織停台:2日間製織を実施し、1日当たりの停台を見た。但し、緯糸交換よる停台は除外した。
(8)布残留シリコン樹脂付着量は、基布をノルマルヘキサンにてソックスレー抽出後、抽出液を乾燥させ、残留分を蛍光X線分析にてシリコン原子含有量より算出した。
(9)基布残留オレフィン樹脂付着量は、基布をノルマルヘキサンにてソックスレー抽出後、抽出液を乾燥させ、残留分をGPCにて分離し、含有量を算出した。
(10)基布残留エステル類は、単独付着の場合、基布をノルマルヘキサンにてソックスレー抽出後、抽出液を乾燥させ、その重量より算出した。シリコン及び/又はオレフィン樹脂と混合した場合は、全量をソックスレー抽出にて測定後、各々の量を差し引いて求めた。
(6) The tear strength of the base fabric was measured by the single tongue method of JIS L1096.
(7) Weaving stop: Weaving was carried out for 2 days, and the stop per day was observed. However, the stop by weft replacement was excluded.
(8) The cloth residual silicon resin adhesion amount was calculated by soxhlet extraction of the base cloth with normal hexane, the extract was dried, and the residue was calculated from the silicon atom content by fluorescent X-ray analysis.
(9) The amount of the residual olefin resin adhered to the base cloth was calculated by soxhlet-extracting the base cloth with normal hexane, drying the extract, and separating the residue with GPC.
(10) In the case where the base cloth residual ester was adhered alone, the base cloth was subjected to Soxhlet extraction with normal hexane, the extract was dried, and the weight thereof was calculated. When mixed with silicone and / or olefin resin, the total amount was measured by Soxhlet extraction, and then the respective amounts were subtracted.

(11)基布を構成する繊維の幅と厚みはリガク製高分解能X線顕微鏡nano3DXを用い、X線ターゲットにCu、管電圧40kV/30mAでX線を発生し、サンプルを撮影し、寸法を求めた。
(12)引き抜き抵抗値は、図1に示す引き抜き抵抗測定試料(サンプル)を作製し、A&D社製テンシロンにおいて10mm/minの速度にて幅方向に3か所測定し、下記式7:
P=F(Dx/2.54)/(15×2.54/Dy)
{式中、P=引き抜き抵抗力(N/cm/cm)、F=引き抜き測定値(N)、Dx=測定方向の織密度(本/inch)、Dy=測定方向と直交する方向の織密度(本/inch)}により算出した。
(13)織密度:TEXTEST社製FX3255を用いた。
(14)基布通気量;TEXTEST社製FX3350にて400ccタンクを用い、初期圧170kPaにて測定し、30kPaから70kPaの平均の動的通気量を測定した。
(15)縫目通気量:織物より縦38cm×横15cmの布2枚を切り出し、1350dtexの撚糸からなる縫い糸にて50針/dmの本縫で縫合し、糸両端を結ぶ。これを織物の経方向同士の合わせ及び緯方向同士の合わせの縫合で経、緯用の試料を作製した。その後、A&D社製テンシロンにおいてチャック幅60mmにはさみ、100mm/分の速度にて1500Nの荷重をかけた後に、一旦張力を開放し、3時間放置した。この試料をTEXTEST社製FX3350にて400ccタンクを用い、初期圧300kPaにて測定し、30kPaから70kPaの平均の動的通気量を測定した。
(11) The width and thickness of the fibers constituting the base cloth were measured by using a high resolution X-ray microscope nano3DX manufactured by Rigaku, generating X-rays with an X-ray target of Cu and a tube voltage of 40 kV / 30 mA, and photographing the sample. I asked.
(12) The pull-out resistance value was obtained by making a pull-out resistance measurement sample (sample) shown in FIG. 1 and measuring it at three locations in the width direction at a speed of 10 mm / min with A & D Tensilon.
P = F (Dx / 2.54) / (15 × 2.54 / Dy)
{In the formula, P = pulling resistance (N / cm / cm), F = pullout measurement value (N), Dx = weaving density in the measuring direction (books / inch), Dy = weaving density in the direction orthogonal to the measuring direction (Book / inch)}.
(13) Weaving density: FX3255 manufactured by TEXTEST was used.
(14) Aeration amount of base cloth; measured using an FX3350 manufactured by TEXTEST Co., Ltd. using a 400 cc tank at an initial pressure of 170 kPa, and an average dynamic air amount of 30 kPa to 70 kPa.
(15) Seam ventilation amount: Two pieces of fabric having a length of 38 cm and a width of 15 cm are cut out from the woven fabric, and sewn with a sewing thread made of a twisted yarn of 1350 dtex with 50 stitches / dm of the main stitch, and both ends of the thread are tied. This was sewn by aligning warp directions of the fabric and aligning weft directions to prepare a sample for weft. After that, in a Tensilon manufactured by A & D Co., a chuck width was sandwiched by 60 mm, a load of 1500 N was applied at a speed of 100 mm / min, the tension was once released, and the mixture was left for 3 hours. This sample was measured with an EX3350 manufactured by TEXTEST Co., Ltd. using a 400 cc tank at an initial pressure of 300 kPa, and an average dynamic air flow rate of 30 kPa to 70 kPa was measured.

(16)ロール形状指数(d/D):ロール中央部の直径Dとロール端部の直径を測定し、算出した。
(17)バッグ展開評価:織物より幅8cm×長さ10cmガス導入口を有した直径30cmのバッグを1350dtexの撚糸からなる縫い糸にて65針/dmの本縫で縫合し作製した。これを表裏反転させバッグとして、図2に示すバッグを作製した。これをマイクロシス社製CGSシステムを用い、圧力5MPa、オリフィス0.6インチ、タンク容量250ccの条件でヘリウムガスを瞬時に供給したときの展開後の該バッグの様子を観察した。縫目部の一番開いている部分を目視にて測定し、3mm以下を小、3〜6mmを中、6mm以上を大として評価した。
(16) Roll shape index (d / D): A diameter D at the center of the roll and a diameter at the end of the roll were measured and calculated.
(17) Bag development evaluation: A bag having a width of 8 cm and a length of 10 cm and a gas inlet of 30 cm and having a diameter of 30 cm was sewn with a stitching thread made of a twisted yarn of 1350 dtex with a stitch of 65 needles / dm. The bag shown in FIG. 2 was manufactured by reversing this inside and out. Using a CGS system manufactured by Microsys, the state of the bag after deployment was observed when helium gas was instantaneously supplied under the conditions of a pressure of 5 MPa, an orifice of 0.6 inch, and a tank capacity of 250 cc. The most open portion of the seam portion was visually measured, and 3 mm or less was evaluated as small, 3 to 6 mm as medium, and 6 mm or more as large.

[実施例1]
ポリアミド6・6樹脂を300℃で溶融紡糸し、冷却しながら紡糸油剤を繊維に対し0.8%付与し、その後200℃の熱延伸ロールにて4.9倍に延伸し、圧縮空気にて交絡を付与後、繊度470dtex、フィラメント数136本の原糸を得た。原糸の強度は8.56cN/dtex、破断伸び率は21%であった。この原糸を用い、糊付けすることなく豊田自動織機社製LWT710の織幅2.3mにて、経糸密度45.2本/inch、緯糸設定密度44本/inch、織物幅230cm、経糸張力0.32cN/dtex、織機回転数600rpmで平織製織を行った。緯入れ装置は自由飛送のみで挿入するタイプを用いた。両耳部分は絡み糸として22dtexナイロン66モノフィラメント片側2本ずつ使用した。増し糸は22dtexナイロン66モノフィラメントを絡み糸と地糸の間に片側2本ずつ使用して、平織とした。その後、80℃の湯浴に精錬時オーバーフィード率は−10%の設定で400Nの張力下で60秒間処理した後、固形分1500ppmのシリコン樹脂エマルションに浸漬し、その後ピンテンターにてテンターオーバーフィード−4%、テンター横幅設定率−2%、熱セット温度180℃で、目的のノンコート基布を得た。この基布について織密度、製織時の停台数、構成糸の厚みと幅、基布の引張強伸度、引き抜き抵抗、剛軟度、縫目開き後通気量、ロール形状、バッグ展開試験を実施し、以下の表1に示す結果を得た。
[Example 1]
Polyamide 6.6 resin was melt-spun at 300 ° C, 0.8% of spinning oil was added to the fiber while cooling, and then stretched 4.9 times by a hot stretching roll at 200 ° C, and compressed air was used. After the entanglement, a yarn having a fineness of 470 dtex and a filament number of 136 was obtained. The strength of the raw yarn was 8.56 cN / dtex and the elongation at break was 21%. Using this raw yarn, with a weft width of 2.3 m of LWT710 manufactured by Toyota Industries Corporation without sizing, warp density 45.2 yarns / inch, weft set density 44 yarns / inch, fabric width 230 cm, warp tension 0. Plain weaving was performed at 32 cN / dtex and a loom rotational speed of 600 rpm. The weft insertion device used was a type that was inserted only by free flight. 22dtex nylon 66 monofilament, two on each side, were used as entwined yarns for both ears. As the additional yarn, 22 dtex nylon 66 monofilament was used as a plain weave by using two twin yarns on each side between the entangled yarn and the ground yarn. Then, in an 80 ° C. water bath, the overfeed rate during refining was set to −10% under a tension of 400 N for 60 seconds, then immersed in a silicone resin emulsion having a solid content of 1500 ppm, and then a tenter overfeed was performed with a pin tenter. The target non-coated base fabric was obtained at 4%, a tenter width setting rate of -2%, and a heat setting temperature of 180 ° C. About this base cloth, weaving density, number of stops during weaving, thickness and width of constituent threads, tensile strength / elongation of base cloth, pullout resistance, bending resistance, ventilation after seam opening, roll shape, bag expansion test Then, the results shown in Table 1 below were obtained.

[実施例2]
実施例1と同じ糸条を用い、整経時に実施例1と同じシリコン樹脂エマルションを固形分濃度3.0%に調整した物をタッチロールにて付与した。タッチロールと経糸の接触長は30mmとして糸速100m/min、ロール回転数15rpmとして経糸を準備し、実施例1と同じ製織条件で生機を得た。この後、80℃の湯浴に400Nの張力下で60秒間処理し、その時の精錬オーバーフィード率−10%で処理し、乾燥ドラムにて110℃で60秒間乾燥し、目的の基布を得た。この基布について実施例1と同様の評価を行い、以下の表1に示す結果を得た。
[Example 2]
Using the same yarn as in Example 1, the same silicone resin emulsion as in Example 1 adjusted to a solid content concentration of 3.0% was applied with a touch roll over time. The contact length between the touch roll and the warp was set to 30 mm, the yarn speed was set to 100 m / min, and the roll speed was set to 15 rpm to prepare the warp, and a weaving machine was obtained under the same weaving conditions as in Example 1. Then, it was treated in a hot water bath at 80 ° C. under a tension of 400 N for 60 seconds, at a refining overfeed rate of −10% at that time, and dried at 110 ° C. for 60 seconds on a drying drum to obtain a target base fabric. It was This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[参考例3]
ポリアミド6・6樹脂を300℃で溶融紡糸し、冷却しながら紡糸油剤を繊維に対し0.8%付与し、その後200℃の熱延伸ロールにて4.7倍に延伸し、圧縮空気にて交絡を付与後、繊度470dtex、フィラメント数216本の原糸を得た。原糸の強度は8.6cN/dtex、破断伸び率は20%であった。この原糸を用いて経糸張力を0.36cN/dtexとした以外は実施例2と同様の製織を実施した。次いで、精錬槽に通すことなく精錬オーバーフィード率−6%で処理し、乾燥ドラムにて110℃で60秒間乾燥し、目的の基布を得た。この基布について実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Reference Example 3]
Polyamide 6.6 resin is melt-spun at 300 ° C., while adding 0.8% of a spinning oil agent to the fiber while being cooled, it is then stretched 4.7 times by a hot stretching roll at 200 ° C. and compressed air is used. After the entanglement, a yarn having a fineness of 470 dtex and a filament number of 216 was obtained. The strength of the raw yarn was 8.6 cN / dtex and the elongation at break was 20%. Weaving was performed in the same manner as in Example 2 except that the warp tension was set to 0.36 cN / dtex using this raw yarn. Then, the mixture was treated at a refining overfeed rate of -6% without passing through a refining tank, and dried at 110 ° C for 60 seconds on a drying drum to obtain a target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[参考例4]
実施例2と同じ経糸ビームを用い、製織時に経糸張力を0.22cN/dtexとした以外は同じ製織条件とした。後加工は参考例3と同様にして目的の基布を得た。この基布について実施例1と同様に評価した結果を以下の表1に示す。
[Reference Example 4]
The same weaving conditions were used except that the same warp beam as in Example 2 was used and the warp tension during weaving was 0.22 cN / dtex. The post-processing was carried out in the same manner as in Reference Example 3 to obtain the target base fabric. The results of evaluating this base cloth in the same manner as in Example 1 are shown in Table 1 below.

[実施例5]
実施例1と同じ製織後、同じシリコン樹脂エマルションを固形分5000ppmに調整して浸漬し、熱水槽を通すことなく乾燥ドラムにて110℃、60secで乾燥し目的の基布を得た。この基布について実施例1と同様に評価した結果を以下の表1に示す。
[Example 5]
After the same weaving as in Example 1, the same silicone resin emulsion was adjusted to a solid content of 5000 ppm and immersed, and dried at 110 ° C. for 60 seconds on a drying drum without passing through a hot water tank to obtain a target base fabric. The results of evaluating this base cloth in the same manner as in Example 1 are shown in Table 1 below.

[参考例6]
実施例1と同じ糸条を用い、整経は、ポリプロピレン樹脂を付与した以外は実施例2と同じとした。この経糸ビームを用いて実施例2と同様な製織を実施し、後加工は参考例3と同じとして目的の基布を得た。この基布について実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Reference Example 6]
The same yarn as in Example 1 was used, and the warping was the same as in Example 2 except that a polypropylene resin was added. Using this warp beam, weaving was performed in the same manner as in Example 2, and the post-processing was performed in the same manner as in Reference Example 3 to obtain the target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[参考例7]
繊維をポリエチレンテレフタレートに変更し、他は参考例6と同様な製織条件、加工条件として目的の基布を得た。この基布について実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Reference Example 7]
The target base fabric was obtained under the same weaving and processing conditions as in Reference Example 6 except that the fiber was changed to polyethylene terephthalate. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[参考例8]
実施例1と同様な糸条を使用し、経糸整経時に樹脂等を付与することなく経糸ビームを作製し、実施例1と同様な条件で製織した。これを参考例3と同様な後加工を実施して目的の基布を得た。この基布を実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Reference Example 8]
Using a yarn similar to that in Example 1, a warp beam was produced without applying resin or the like during warp warping and weaving was performed under the same conditions as in Example 1. This was post-processed in the same manner as in Reference Example 3 to obtain the target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[参考例9]
実施例1と同様な糸条を使用し、経糸整経時に樹脂等を付与することなく経糸ビームを作製し、実施例1と同様な条件で製織した。これを実施例2と同様な条件にて後加工を行い、目的の基布を得た。この基布を実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Reference Example 9]
Using a yarn similar to that in Example 1, a warp beam was produced without applying resin or the like during warp warping and weaving was performed under the same conditions as in Example 1. This was post-processed under the same conditions as in Example 2 to obtain the target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[参考例10]
ポリアミド6・6樹脂を300℃において溶融紡糸し、冷却しながら紡糸油剤を繊維に対し0.8%付与し、その後200℃の熱延伸ロールにて4.9倍に延伸し、圧縮空気にて交絡を付与後、繊度235dtex、フィラメント数36本の原糸を得た。原糸の強度は8.90cN/dtex、破断伸び率は21%であった。この糸条を経密度65本/inchとした以外は実施例2と同じ条件で整経ビームを得た。これを緯密度66本/inchとした以外は実施例1と同様な条件で製織した。後加工は参考例3の条件と同じとして目的の基布を得た。この基布ついて実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Reference Example 10]
Polyamide 6.6 resin was melt-spun at 300 ° C., a spinning oil was added to the fiber at 0.8% while cooling, and then stretched 4.9 times by a hot stretching roll at 200 ° C., and compressed air was used. After the entanglement, a yarn having a fineness of 235 dtex and a filament number of 36 was obtained. The strength of the raw yarn was 8.90 cN / dtex and the elongation at break was 21%. A warped beam was obtained under the same conditions as in Example 2 except that this yarn had a warp density of 65 yarns / inch. This was woven under the same conditions as in Example 1 except that the weft density was 66 threads / inch. The post-processing was performed under the same conditions as in Reference Example 3 to obtain the target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

[実施例11]
増し糸を110dtexポリアミド糸に変更した以外は実施例2と同じ経糸ビーム、製織条件とした。後加工条件は参考例3と同様にして目的の織物を得た。この基布について実施例1と同様な評価を実施し、以下の表1に示す結果を得た。
[Example 11]
The warp beam and weaving conditions were the same as in Example 2 except that the additional yarn was changed to 110 dtex polyamide yarn. The post-processing conditions were the same as in Reference Example 3 to obtain the desired woven fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 1 below were obtained.

Figure 0006694490
Figure 0006694490

前記発明[1]の範囲内の物は柔軟性と気密性の両立が出来ており、バッグ展開後も目開きが抑制された基布が得られた。   The product within the range of the invention [1] was able to achieve both flexibility and airtightness, and a base fabric in which the opening of the bag was suppressed even after the bag was developed was obtained.

[比較例1]
ポリアミド6・6樹脂を300℃において溶融紡糸し、冷却しながら紡糸油剤を繊維に対し0.8%付与し、その後200℃の熱延伸ロールにて4.85倍に延伸し、圧縮空気にて交絡を付与後、繊度470dtxex、フィラメント数36本の原糸を得た。原糸の強度は8.56cN/dtex、破断伸び率は20%であった。この糸条を実施例2と同様な整経、製織を行い、後加工は実施例3と同様としたて目的の基布を得た。この基布について実施例1と同様な評価を実施し、以下の表2に示す結果を得た。比較例1では、単糸繊度の大きい糸条を用いたことによってZ値が小さくなり、気密性が維持できない結果となった。またバッグ展開にてバーストが発生した。
[Comparative Example 1]
Polyamide 6/6 resin was melt-spun at 300 ° C., 0.8% of a spinning oil was added to the fiber while cooling, and then stretched 4.85 times with a hot stretching roll at 200 ° C. and compressed air. After the entanglement, a yarn having a fineness of 470 dtxex and a filament number of 36 was obtained. The strength of the raw yarn was 8.56 cN / dtex and the elongation at break was 20%. This yarn was warped and woven in the same manner as in Example 2, and the post-processing was performed in the same manner as in Example 3 to obtain the target base fabric. The same evaluation as in Example 1 was performed on this base fabric, and the results shown in Table 2 below were obtained. In Comparative Example 1, the Z value was reduced by using the yarn having a large single yarn fineness, and the result was that the airtightness could not be maintained. In addition, a burst occurred when the bag was deployed.

[比較例2]
ポリアミド6・6樹脂を300℃において溶融紡糸し、冷却しながら紡糸油剤を繊維に対し0.8%付与し、その後200℃の熱延伸ロールにて4.75倍に延伸し、圧縮空気にて交絡を付与後、繊度155dtxex、フィラメント数136本の原糸を得た。原糸の強度は8.1cN/dtex、破断伸び率は25%であった。この糸条を3本合糸して465dtexとした。これを比較例1と同様に整経し、同様な条件で製織を実施した。その後、実施例2と同じ後加工を実施し目的の基布を得た。この基布について実施例1と同様な評価を実施し、以下の表2に示す結果を得た。この基布は、単糸繊度が小さい為に抵触時の停台、また得られた基布はZ値が大きく、繊維の自由度が無い為に引裂が低い基布となった。この展開試験はバーストが発生した。
[Comparative example 2]
Polyamide 6/6 resin was melt-spun at 300 ° C., 0.8% of spinning oil was added to the fiber while cooling, and then stretched 4.75 times with a hot stretching roll at 200 ° C. and compressed air. After the entanglement, a yarn having a fineness of 155 dtxex and a filament number of 136 was obtained. The strength of the raw yarn was 8.1 cN / dtex and the elongation at break was 25%. Three of these yarns were combined to form 465 dtex. This was warped in the same manner as in Comparative Example 1 and weaving was performed under the same conditions. Then, the same post-processing as in Example 2 was carried out to obtain the target base fabric. The same evaluation as in Example 1 was performed on this base fabric, and the results shown in Table 2 below were obtained. This base fabric was a stop at the time of contact due to a small single yarn fineness, and the obtained base fabric had a large Z value and had a low degree of tear due to lack of fiber freedom. This deployment test caused a burst.

[比較例3]
実施例1と同様な整経ビームを用い、同様な製織を実施した。後加工では水洗槽の前にバスを設け、固形分1%に希釈した実施例1と同様なシリコン樹脂エマルションに基布を浸漬し、精錬することなく110℃の乾燥ドラムにて60sec乾燥させ目的の基布を得た。この基布について比較例1と同様な評価を実施し、以下の表2に示す結果を得た。この基布は過剰な加工剤の存在によって目開き後通気量が高い基布となり、展開試験ではバーストが発生した。
[Comparative Example 3]
The same weaving was performed using the same warping beam as in Example 1. In the post-processing, a bath was provided in front of the washing tank, the base cloth was immersed in the same silicone resin emulsion as in Example 1 diluted to a solid content of 1%, and dried for 60 seconds on a 110 ° C drying drum without refining. I got the base cloth. The same evaluation as in Comparative Example 1 was performed on this base fabric, and the results shown in Table 2 below were obtained. Due to the presence of an excessive amount of the processing agent, this base fabric became a base fabric having a high air permeability after opening, and burst occurred in the development test.

[比較例4]
実施例1と同じ糸条を用い、整経時に樹脂エマルションの代わりに直鎖アルキル硫酸塩を1%含む水溶液を塗布し経糸を巻き取った。この糸条を実施例2と同じ製織と後加工を実施し、目的の基布を得た。得られた基布に残留していたものはエステル類20ppmであった。この基布について実施例1と同様な評価を実施し、以下の表2に示す結果を得た。比較例4では、製織停台が多く、得られた基布も引裂き強力が低くなり、バッグ展開試験にてバーストが発生した。
[Comparative Example 4]
Using the same yarn as in Example 1, an aqueous solution containing 1% of a linear alkyl sulfate was applied in place of the resin emulsion after aging and the warp was wound. The yarn was subjected to the same weaving and post-processing as in Example 2 to obtain an intended base fabric. The amount of esters remaining in the obtained base cloth was 20 ppm. The same evaluation as in Example 1 was performed on this base fabric, and the results shown in Table 2 below were obtained. In Comparative Example 4, there were many weaving stops, the resulting base fabric also had a low tear strength, and bursts occurred in the bag deployment test.

[比較例5]
実施例2と同じ糸条を用い、経密度を52本/inchとした以外は、同様な整経を行った。この経糸を用いて緯糸密度設計を53本/inch、両耳部分は絡み糸として22dtexナイロン66モノフィラメント片側2本ずつ使用した。増し糸は22dtexナイロン66モノフィラメントを絡み糸と地糸の間に片側4本ずつ使用して、平織とした。その後、参考例3と同様な後加工を実施し、目的の基布を得た。この基布を実施例1と同様な評価を行い、以下の表2に示す結果を得た。この条件は織密度が過剰に高すぎる為に、基布の剛軟度が非常に高い物となった。
[Comparative Example 5]
The same warping was performed except that the same yarn as in Example 2 was used and the warp density was 52 threads / inch. Using this warp, a weft density design was 53 yarns / inch, and 22 dtex nylon 66 monofilaments were used as entwined yarns at both ears, two on each side. As the additional yarn, 22 dtex nylon 66 monofilament was used as a plain weave by using four filaments on each side between the entangled yarn and the ground yarn. Then, the same post-processing as in Reference Example 3 was carried out to obtain the target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 2 below were obtained. Under this condition, the weave density was excessively high, and the base fabric had a very high bending resistance.

[比較例6]
実施例2と同じ糸条を用い、経密度を38本/inchとした以外は、同様な整経を行った。この経糸を用いて緯糸密度を39本/inchとしてそれ以外は実施例2と同じ条件で製織し、参考例3と同じ条件で加工を行い、目的の基布を得た。この基布について実施例1と同様な評価を行い、以下の表2に示す結果を得た。この条件は織密度が低すぎる為に、気密性が損なわれ、作製したバッグのバーストが認められた。
[Comparative Example 6]
Using the same yarn as in Example 2, the same warping was performed except that the warp density was 38 threads / inch. Using this warp, the weft density was set to 39 yarns / inch, and the weaving was performed under the same conditions as in Example 2 except for that, and the processing was performed under the same conditions as in Reference Example 3 to obtain the target base fabric. This base cloth was evaluated in the same manner as in Example 1, and the results shown in Table 2 below were obtained. Under this condition, since the weaving density was too low, the airtightness was impaired, and burst of the produced bag was observed.

Figure 0006694490
Figure 0006694490

比較例1〜6から明らかなように、前記発明[1]の範囲外の物は、縫目に負荷がかかった場合に縫目部分の気密性の維持が出来なくなったり、引裂き強力が低下し、作製したバッグにバーストが発生する不具合や、基布が硬くなって課題が達成できないことが認められた。   As is clear from Comparative Examples 1 to 6, the products outside the scope of the invention [1] cannot maintain the airtightness of the seam part when the load is applied to the seam, or the tear strength is lowered. It was confirmed that the problem could not be achieved because the bag produced had bursts and the base fabric was hard.

本発明に係る織物基布は、気密性が高く柔軟で、収納性に優れかつ、生産性の高いエアバッグ用基布として好適に利用可能である。   INDUSTRIAL APPLICABILITY The woven base fabric according to the present invention can be suitably used as a base fabric for an airbag, which has high airtightness, flexibility, excellent storability, and high productivity.

Claims (7)

単糸繊度1.5以上4dtex以下の丸断面である熱可塑性樹脂の経糸及び緯糸の糸条で平織された織物基布であって、以下の要件:
(1)下記式1:
Z=(Ww×Dw+Wf×Df)−50.8
{式中、Ww=経糸最大幅(mm)、Dw=経糸密度(本/inch)、Wf=緯糸最大幅(mm)、Df=緯糸密度(本/inch)}で表されるZ値が0〜7である;
(2)下記式2:
Q=q/S
{式中、q=ASTM_D6476で測定された30〜70kPa間のADAP(mm/s)、S=基布目付(g/m)}で表されるQ値が0.5〜2.5である;
(3)下記式3:
CF=((Tw/ρ)0.5×Dw)+(Tf/ρ)0.5×Df)
{式中、Tw=経糸繊度(Dtex)、Tf=緯糸繊度(Dtex)、ρ=繊維密度(g/cm)}で表されるカバーファクター(CF)が1984〜2050である;
(4)シリコン樹脂が、該織物基布の繊維表面に該繊維重量に対し60〜1100ppmで存在している;
(5)該基布の経引裂き強力は、210N以上である;
(6)該基布の緯引裂き強力は、205N以上である;
(7)該基布を構成する経糸の幅を厚みで除した値が、2.5〜5である;
(8)該基布を構成する緯糸の幅を厚みで除した値が、3.1〜5である;及び
(9)該基布の通気量が、280mm/s以下である;
を満たす前記織物基布。
A woven fabric base cloth woven from thermoplastic resin warp threads and weft threads having a circular cross section with a single yarn fineness of 1.5 or more and 4 dtex or less, and the following requirements:
(1) The following formula 1:
Z = (Ww x Dw + Wf x Df) -50.8
Z value represented by {Ww = maximum width of warp ( mm ), Dw = warp density (thread / inch), Wf = maximum width of weft ( mm ), Df = weft density (thread / inch)} is 0 ~ 7;
(2) The following formula 2:
Q = q / S
{Wherein q = ADAP (mm / s) between 30 and 70 kPa measured by ASTM_D6476, S = base fabric weight (g / m 2 )}, and the Q value is 0.5 to 2.5. is there;
(3) The following formula 3:
CF = ((Tw / ρ) 0.5 × Dw) + (Tf / ρ) 0.5 × Df)
The cover factor (CF) represented by {wherein Tw = warp yarn fineness (Dtex), Tf = weft yarn fineness (Dtex), ρ = fiber density (g / cm 3 )} is 1984 to 2050 ;
(4) Silicone resin is present on the fiber surface of the woven base fabric at 60 to 1100 ppm based on the weight of the fiber;
(5) The warp tear strength of the base fabric is 210 N or more;
(6) The weft tear strength of the base fabric is 205 N or more;
(7) The value obtained by dividing the width of the warp constituting the base cloth by the thickness is 2.5 to 5;
(8) The value obtained by dividing the width of the weft constituting the base cloth by the thickness is 3.1 to 5; and (9) the air permeability of the base cloth is 280 mm / s or less;
The woven base fabric satisfying the above.
前記経糸及び緯糸の糸条の繊度が共に300以上800dtex未満である、請求項1に記載の織物基布。   The woven base fabric according to claim 1, wherein the warp yarns and the weft yarns each have a fineness of 300 or more and less than 800 dtex. 前記織物基布を構成する経糸及び緯糸の引き抜き抵抗値が共に20〜150N/cm/cmである、請求項1又は2に記載の織物基布。   The woven fabric base fabric according to claim 1 or 2, wherein the warp yarns and the weft yarns constituting the woven fabric fabric fabric each have a pull-out resistance value of 20 to 150 N / cm / cm. 請求項1〜3のいずれか1項に記載の織物基布の反物であって、該反物両端の絡み糸と地糸の間に、地糸以外の、繊度が20以上70dtex未満の糸が左右合計4本以上織り込まれていることを特徴とする、前記反物。   The fabric of the woven fabric according to any one of claims 1 to 3, wherein yarns having a fineness of 20 or more and less than 70 dtex other than the ground yarn are left and right between the entangled yarn and the ground yarn at both ends of the fabric. The said piece of cloth is characterized by being woven in total of four or more. 請求項1〜3のいずれか1項に記載の織物基布の反物ロールであって、該ロール中央部の直径Dと該ロール端部の直径dの比d/Dが1.07未満であることを特徴とする、前記反物ロール。   It is a cloth roll of the textile base fabric according to any one of claims 1 to 3, and ratio d / D of diameter D of the roll central part and diameter d of the roll end is less than 1.07. The said thing cloth roll characterized by the above-mentioned. 請求項1〜3のいずれか1項に記載の基布から構成されたノンコートエアバッグ。   A non-coated airbag made of the base fabric according to claim 1. 請求項4に記載の反物又は請求項5に記載の反物ロールを用いる工程を含む、ノンコートエアバッグの製造方法。   A method for manufacturing a non-coated airbag, comprising the step of using the piece of fabric according to claim 4 or the piece of fabric roll according to claim 5.
JP2018209966A 2018-11-07 2018-11-07 Fabric base fabric for airbags Active JP6694490B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2018209966A JP6694490B2 (en) 2018-11-07 2018-11-07 Fabric base fabric for airbags

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2018209966A JP6694490B2 (en) 2018-11-07 2018-11-07 Fabric base fabric for airbags

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2014060328A Division JP2015183309A (en) 2014-03-24 2014-03-24 Woven base cloth for air-bag

Publications (2)

Publication Number Publication Date
JP2019023377A JP2019023377A (en) 2019-02-14
JP6694490B2 true JP6694490B2 (en) 2020-05-13

Family

ID=65368786

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2018209966A Active JP6694490B2 (en) 2018-11-07 2018-11-07 Fabric base fabric for airbags

Country Status (1)

Country Link
JP (1) JP6694490B2 (en)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001271247A (en) * 2000-03-24 2001-10-02 Toray Ind Inc Base fabric for air bag and air bag
JP2002363835A (en) * 2001-06-06 2002-12-18 Toray Ind Inc Woven fabric for air bag, method for producing the same and air bag
JP5365272B2 (en) * 2008-03-21 2013-12-11 東レ株式会社 Fabric for airbag and method for producing fabric for airbag
JP2010174390A (en) * 2009-01-28 2010-08-12 Toray Ind Inc Woven fabric for airbag, and method for producing the same
JP4940382B2 (en) * 2010-06-24 2012-05-30 松本油脂製薬株式会社 Synthetic fiber treatment agent for airbag, synthetic fiber filament for airbag, and base fabric for airbag
US9352718B2 (en) * 2012-03-09 2016-05-31 Asahi Kasei Fibers Corporation Base fabric for airbags
BR112014027034B1 (en) * 2012-05-11 2022-01-04 Toyobo Co., Ltd UNCOATED BASE FABRIC FOR USE IN THE MANUFACTURE OF AIR-BAG, METHOD FOR MANUFACTURING AN UNCOATED BASE FABRIC FOR USE IN THE MANUFACTURE OF AIR-BAG, AND AIR-BAG FORMED BY CUTTING AND SEWING THE UNCOATED BASE FABRIC
EP2868789A4 (en) * 2012-06-29 2016-05-25 Kolon Inc Fabric for airbag and method for manufacturing same

Also Published As

Publication number Publication date
JP2019023377A (en) 2019-02-14

Similar Documents

Publication Publication Date Title
KR101569328B1 (en) Woven fabric and process for producing same
JP5100895B2 (en) Airbag base fabric
US9834167B2 (en) Airbag fabric and airbag
JP6601395B2 (en) Polyester base fabric for airbag, polyester airbag and method for producing polyester base fabric for airbag
JP6013710B2 (en) Airbag fabrics and airbags
BR112019022728A2 (en) FABRIC FABRIC WITH LOW PERMEABILITY AND HIGH RESISTANCE AND METHODS FOR THE PRODUCTION OF THE SAME
WO2023037982A1 (en) Airbag fabric and airbag
JP5241165B2 (en) Manufacturing method for air bag base fabric
WO2014123090A1 (en) Fabric for airbag and fabric roll
JP2008081873A (en) Airbag base fabric, airbag, and method for producing airbag base fabric
WO2024048153A1 (en) Airbag fabric
JP7188393B2 (en) Airbag base fabric and airbag including the same
JP6694490B2 (en) Fabric base fabric for airbags
JP2015183309A (en) Woven base cloth for air-bag
US10385482B2 (en) Woven fabric
JP3745627B2 (en) High density fabric
JP2007023411A (en) Woven fabric for air bag, air bag and method for producing woven fabric for air bag
JP2015110857A (en) Air bag base fabric
CN111155219B (en) Fabric for airbag, method for producing same, and airbag
JP3544179B2 (en) Weaving method of high density fabric
JP4496451B2 (en) Weaving method of high density fabric
WO2022196191A1 (en) Non-coated textile for airbag
WO2015025842A1 (en) Fabric for airbag

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20181107

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20191112

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20200110

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20200407

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200417

R150 Certificate of patent or registration of utility model

Ref document number: 6694490

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150