JP6587998B2 - 異なる隣接層の間に良好な層間接着を有するゴルフボール - Google Patents
異なる隣接層の間に良好な層間接着を有するゴルフボール Download PDFInfo
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- JP6587998B2 JP6587998B2 JP2016216643A JP2016216643A JP6587998B2 JP 6587998 B2 JP6587998 B2 JP 6587998B2 JP 2016216643 A JP2016216643 A JP 2016216643A JP 2016216643 A JP2016216643 A JP 2016216643A JP 6587998 B2 JP6587998 B2 JP 6587998B2
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- silane
- polyurethane
- golf ball
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- 239000011229 interlayer Substances 0.000 title description 8
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
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- JCEZOHLWDIONSP-UHFFFAOYSA-N 3-[2-[2-(3-aminopropoxy)ethoxy]ethoxy]propan-1-amine Chemical compound NCCCOCCOCCOCCCN JCEZOHLWDIONSP-UHFFFAOYSA-N 0.000 description 2
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-M 4-aminobenzoate Chemical compound NC1=CC=C(C([O-])=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-M 0.000 description 2
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- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 description 2
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- 238000002360 preparation method Methods 0.000 description 2
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- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
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- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical compound NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 2
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- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
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- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0075—Three piece balls, i.e. cover, intermediate layer and core
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B45/00—Apparatus or methods for manufacturing balls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0076—Multi-piece balls, i.e. having two or more intermediate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/54—Balls
- B29L2031/546—Golf balls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(1)ポリウレタン、例えば、ポリオールまたはポリアミンおよびジイソシアネートまたはポリイソシアネートおよび、/またはそれらのプレポリマーから準備されたもの、ならびに、米国特許第5,33,4673号、同第6,506,851号に開示されているもの。
(2)ポリ尿素、例えば、米国特許第5,484,870号および同第6,835,794号に開示されているもの。
(3)ウレタンまたは尿素セグメントを含む、ポリウレタン−尿素ハイブリッド、ブレンドまたはコポリマー。
以下、ここで説明した技術的特徴を列挙する。
[技術的特徴1]
第1のポリマー性組成物を有する第1層であって、上記第1のポリマー性組成物と異なる第2のポリマー性組成物を有する第2層に包囲され、上記第2層と隣接する上記第1層を有するゴルフボールにおいて、
上記第1層および上記第2層の一方のみが、さらに、少なくとも1つのシラン含有接着助長剤を、約0.1wt%から約5.0wt%の量だけ全体に渡って有し、かつ、
上記第1層および上記第2層はたった1つのシラン含有助長剤によっても表面処理されないことを特徴とするゴルフボール。
[技術的特徴2]
上記少なくとも1つのシラン含有接着助長剤は、有機シランまたは有機シロキサンからなるグループから選択される技術的特徴1記載のゴルフボール。
[技術的特徴3]
上記少なくとも1つのシラン含有接着助長剤は、上記第1のポリマー性組成物または上記第2のポリマー性組成物のプレポリマ−と混合されて硬化剤と混合されるシラン含有プレポリマーを形成する技術的特徴1記載のゴルフボール。
[技術的特徴4]
上記少なくとも1つのシラン含有接着助長剤は、上記第1のポリマー性組成物または上記第2のポリマー性組成物の硬化剤と混合されてプレポリマーと混合されるシラン含有硬化剤を形成する技術的特徴1記載のゴルフボール。
[技術的特徴5]
上記第1層または上記第2層は、シラン含有マスターバッチと、上記第1のポリマー性組成物または上記第2のポリマー性組成物とを有する技術的特徴1記載のゴルフボール。
[技術的特徴6]
上記第1のポリマー性組成物または上記第2のポリマー性組成物は、上記第1のポリマー性組成物または上記第2のポリマー性組成物を有する少なくとも1つのペレットに、上記少なくとも1つのシラン含有接着助長剤を添加することにより、上記少なくとも1つのシラン含有接着助長剤と組み合わされる技術的特徴1記載のゴルフボール。
[技術的特徴7]
上記少なくとも1つのペレットは、上記少なくとも1つのシラン含有接着助長剤を有する溶液中に浸され、または漬けられる技術的特徴6記載のゴルフボール。
[技術的特徴8]
上記少なくとも1つのシラン含有接着助長剤は、かき混ぜて上記第1のポリマー性組成物または上記第2のポリマー性組成物と混合される技術的特徴1記載のゴルフボール。
[技術的特徴9]
上記第1層は上記少なくとも1つのシラン含有接着助長剤および上記第1のポリマー性組成物を有し、上記第2層は上記第2のポリマー性組成物を有し;上記第1のポリマー性組成物は、熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムのうちの少なくとも1つを有し;上記第2のポリマー性組成物は、少なくとも1つの異なる熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムを有する技術的特徴1記載のゴルフボール。
[技術的特徴10]
上記第1層は上記第1のポリマー性組成物を有し、上記第2層は上記少なくとも1つのシラン含有接着助長剤および上記第2のポリマー性組成物を有し;上記第1のポリマー性組成物は、熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムのうちの少なくとも1つを有し;上記第2のポリマー性組成物は、少なくとも1つの異なる熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムを有する技術的特徴1記載のゴルフボール。
[技術的特徴11]
上記第1のポリマー性組成物は非ポリウレタンの組成物であり、上記第2のポリマー性組成物はポリウレタン組成物である技術的特徴1記載のゴルフボール。
[技術的特徴12]
上記第1のポリマー性組成物はポリウレタン組成物であり、上記第2のポリマー性組成物は非ポリウレタンの組成物である技術的特徴1記載のゴルフボール。
[技術的特徴13]
上記非ポリウレタンの組成物はアイオノマーを有する技術的特徴12記載のゴルフボール。
[技術的特徴14]
上記第1のポリマー性組成物は非ゴムの組成物であり、上記第2のポリマー性組成物は異なる非ゴムの組成物である技術的特徴1記載のゴルフボール。
[技術的特徴15]
上記第1層は、不透明、透明、および半透明の少なくとも1つであり、上記第2層は、透明および半透明の少なくとも1つである技術的特徴1記載のゴルフボール。
[技術的特徴16]
上記第2層は、ポリブタジエンを有するコアを包囲する技術的特徴1記載のゴルフボール。
[技術的特徴17]
上記少なくとも1つのシラン含有接着助長剤は少なくとも二つの官能基を有する技術的特徴1記載のゴルフボール。
[技術的特徴18]
上記第2層は上記少なくとも1つのシラン含有接着助長剤を有し、当該第2層は、上記第2のポリマー性組成物と異なる第3のポリマー性組成物からなり、表面処理されず、また、少なくとも1つのシラン含有接着助長剤を含むことがない第3層により包囲され、上記第3層と隣接する技術的特徴1記載のゴルフボール。
[技術的特徴19]
上記第1層は熱硬化性ポリウレタン、ポリ尿素またはポリウレタン/尿素ハイブリッドの組成物からなり、上記第2層はアイオノマー組成物を有し、上記第3層は熱可塑性ポリウレタン、ポリ尿素、またはポリウレタン/尿素ハイブリッドの組成物からなる技術的特徴18記載のゴルフボール。
[技術的特徴20]
ゴルフボール製造方法において、
第1のポリマー性組成物を有する第1層を準備するステップと、
上記第1のポリマー性組成物と異なる第2のポリマー性組成物を有する第2層を、上記第1層に隣接させ、その周りに形成するステップとを有し、
上記第1層および上記第2層の一方のみが、さらに、少なくとも1つのシラン含有接着助長剤を、約0.1wt%から約5.0wt%の量だけ全体に渡って有し、かつ、
上記第1層および上記第2層はたった1つのシラン含有助長剤によっても表面処理されないことを特徴とするゴルフボール製造方法。
[技術的特徴21]
上記少なくとも1つのシラン含有接着助長剤は、有機シランまたは有機シロキサンからなるグループから選択される技術的特徴20記載のゴルフボール製造方法。
[技術的特徴22]
上記少なくとも1つのシラン含有接着助長剤は、上記第1のポリマー性組成物または上記第2のポリマー性組成物のプレポリマ−と混合されて硬化剤と混合されるシラン含有プレポリマーを形成する技術的特徴20記載のゴルフボール製造方法。
[技術的特徴23]
上記少なくとも1つのシラン含有接着助長剤は、上記第1のポリマー性組成物または上記第2のポリマー性組成物の硬化剤と混合されてプレポリマーと混合されるシラン含有硬化剤を形成する技術的特徴20記載のゴルフボール製造方法。
[技術的特徴24]
上記第1層または上記第2層は、シラン含有マスターバッチと、上記第1のポリマー性組成物または上記第2のポリマー性組成物とを有する技術的特徴20記載のゴルフボール製造方法。
[技術的特徴25]
上記第1のポリマー性組成物または上記第2のポリマー性組成物は、上記第1のポリマー性組成物または上記第2のポリマー性組成物を有する少なくとも1つのペレットに、上記少なくとも1つのシラン含有接着助長剤を添加することにより、上記少なくとも1つのシラン含有接着助長剤と組み合わされる技術的特徴20記載のゴルフボール製造方法。
[技術的特徴26]
上記少なくとも1つのペレットは、上記少なくとも1つのシラン含有接着助長剤を有する溶液中に浸され、または漬けられる技術的特徴25記載のゴルフボール製造方法。
[技術的特徴27]
上記少なくとも1つのシラン含有接着助長剤は、かき混ぜて上記第1のポリマー性組成物または上記第2のポリマー性組成物と混合される技術的特徴20記載のゴルフボール製造方法。
[技術的特徴28]
上記第1層は上記少なくとも1つのシラン含有接着助長剤および上記第1のポリマー性組成物を有し、上記第2層は上記第2のポリマー性組成物を有し;上記第1のポリマー性組成物は、熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムのうちの少なくとも1つを有し;上記第2のポリマー性組成物は、少なくとも1つの異なる熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムを有する技術的特徴20記載のゴルフボール製造方法。
[技術的特徴29]
上記第1層は上記第1のポリマー性組成物を有し、上記第2層は上記少なくとも1つのシラン含有接着助長剤および上記第2のポリマー性組成物を有し;上記第1のポリマー性組成物は、熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムのうちの少なくとも1つを有し;上記第2のポリマー性組成物は、少なくとも1つの異なる熱可塑性または熱硬化性ポリウレタン、尿素、ポリウレタン/尿素ハイブリッド、アイオノマー、ポリアミド、ポリエステル、またはゴムを有する技術的特徴20記載のゴルフボール製造方法。
[技術的特徴30]
上記第2層は上記少なくとも1つのシラン含有接着助長剤を有し、当該第2層は、上記第2のポリマー性組成物と異なる第3のポリマー性組成物からなり、表面処理されず、また、少なくとも1つのシラン含有接着助長剤を含むことがない第3層により包囲され、上記第3層と隣接する技術的特徴20記載のゴルフボール製造方法。
[技術的特徴31]
上記第1層および上記第2層は、圧縮成形;射出成型;およびキャスティングからなるグループから選択される成型プロセスにより形成される技術的特徴20記載のゴルフボール製造方法。
[技術的特徴32]
上記第1のポリマー性組成物は非ゴムの組成物であり、上記第2のポリマー性組成物は異なる非ゴムの組成物である技術的特徴20記載のゴルフボール製造方法。
Claims (2)
- アイオノマー組成物を有する内側層と、上記内側層を包囲し、上記内側層と隣接する、ポリウレタン、ポリ尿素、またはポリウレタン・ポリ尿素ハイブリッドの組成物を有するカバー層とを有するゴルフボールにおいて、
上記内側層および上記カバー層は、圧縮成型、射出成型、およびキャスティングからなるグループから選択される成型プロセスにより形成され、
上記カバー層のみが、さらに、当該カバー層の中の成分を架橋し結合する官能基に加えて上記カバー層および上記内側層を結合するのに有益な十分な官能基を有する、少なくとも1つのシラン含有接着助長剤を、0.1wt%から5.0wt%の量だけ全体に渡って有し、かつ、
上記内側層および上記カバー層は、それらの界面において、たった1つの接着助長剤によっても表面処理されないことを特徴とするゴルフボール。 - ゴルフボール製造方法において、
アイオノマー組成物を有する内側層を準備するステップと、
ポリウレタン、ポリ尿素、またはポリウレタン・ポリ尿素ハイブリッドの組成物を有するカバー層を、上記内側層に隣接させ、その周りに形成するステップとを有し、
上記内側層および上記カバー層は、圧縮成型、射出成型、およびキャスティングからなるグループから選択される成型プロセスにより形成され、
上記カバー層のみが、さらに、当該カバー層の中の成分を架橋し結合する官能基に加えて上記カバー層および上記内側層を結合するのに有益な十分な官能基を有する、少なくとも1つのシラン含有接着助長剤を、0.1wt%から5.0wt%の量だけ全体に渡って有し、かつ、
上記内側層および上記カバー層は、それらの界面において、たった1つの接着助長剤によっても表面処理されないことを特徴とするゴルフボール製造方法。
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US14/943,314 | 2015-11-17 | ||
US14/943,314 US9713748B2 (en) | 2015-11-17 | 2015-11-17 | Golf ball with excellent interlayer adhesion between adjacent differing layers |
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KR102589141B1 (ko) * | 2017-07-31 | 2023-10-13 | 쿠라레이 아메리카 인코포레이티드 | 향상된 접착 특성을 갖는 아이오노머 중간층 |
JP2020058797A (ja) * | 2018-10-12 | 2020-04-16 | アクシュネット カンパニーAcushnet Company | シラン含有接着助長剤助長剤を組み込んだTiO2顔料着色層と隣接する異なる層との間の接着性が改善されたゴルフボール |
JP7484159B2 (ja) | 2019-12-20 | 2024-05-16 | ブリヂストンスポーツ株式会社 | ゴルフボール及びその製造方法 |
JP7415547B2 (ja) | 2019-12-24 | 2024-01-17 | ブリヂストンスポーツ株式会社 | ゴルフボール及びその製造方法 |
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-
2015
- 2015-11-17 US US14/943,314 patent/US9713748B2/en active Active
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2016
- 2016-11-04 JP JP2016216643A patent/JP6587998B2/ja active Active
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US20170282018A1 (en) | 2017-10-05 |
US9713748B2 (en) | 2017-07-25 |
JP2017099864A (ja) | 2017-06-08 |
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