JP6533002B1 - Treatment agent for synthetic fiber and method for producing synthetic fiber - Google Patents

Treatment agent for synthetic fiber and method for producing synthetic fiber Download PDF

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JP6533002B1
JP6533002B1 JP2018233077A JP2018233077A JP6533002B1 JP 6533002 B1 JP6533002 B1 JP 6533002B1 JP 2018233077 A JP2018233077 A JP 2018233077A JP 2018233077 A JP2018233077 A JP 2018233077A JP 6533002 B1 JP6533002 B1 JP 6533002B1
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synthetic fiber
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synthetic fibers
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JP2020094303A (en
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岳人 加藤
岳人 加藤
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Takemoto Oil and Fat Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/252Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)

Abstract

【課題】ストレート給油で合成繊維用処理剤を付与する紡糸工程において発生する糸揺れを低減することができる合成繊維用処理剤及び合成繊維の製造方法を提供する。【解決手段】本発明の合成繊維用処理剤は、平滑剤として分子中にエステル結合を3つ以上有するエステル化合物、及び分子中に硫黄元素を有するエステル化合物から選ばれる少なくとも一種のエステル化合物を含み、ストレート給油に用いられる合成繊維用処理剤であって、水分が0.1〜5質量%であることを特徴とする。また、本発明の合成繊維の製造方法は、合成繊維用処理剤を、紡糸工程において、合成繊維にストレート給油することを特徴とする。【選択図】なしThe present invention provides a synthetic fiber treating agent and synthetic fiber manufacturing method capable of reducing yarn sway occurring in a spinning step of applying a synthetic fiber treating agent by straight oil feeding. SOLUTION: The treating agent for synthetic fiber of the present invention comprises at least one ester compound selected from an ester compound having three or more ester bonds in the molecule and an ester compound having a sulfur element in the molecule as a smoothing agent. It is a processing agent for synthetic fibers used for straight refueling, and it is characterized by having a moisture of 0.1 to 5% by mass. Further, the method for producing a synthetic fiber of the present invention is characterized in that the synthetic fiber treating agent is directly supplied to the synthetic fiber in the spinning step. 【Selection chart】 None

Description

本発明は、ストレート給油用設備を用いる合成繊維の紡糸工程における糸揺れを効果的に低減することができる合成繊維用処理剤及びかかる処理剤を付着させる合成繊維の製造方法に関する。   The present invention relates to a synthetic fiber treating agent capable of effectively reducing yarn swaying in a synthetic fiber spinning step using a straight oiling facility, and a method of producing the synthetic fiber to which such a treating agent is attached.

一般に、合成繊維の紡糸工程において、摩擦を低減し、糸切れ等の繊維の損傷を防止する観点から、合成繊維のフィラメント糸条の表面に合成繊維用処理剤を付着する処理が行われることがある。その付着処理の形態は、合成繊維用処理剤を水に希釈する場合(エマルション給油)と、合成繊維用処理剤を低粘度鉱物油等の希釈剤で希釈又は希釈せずそのままの状態で付与する場合(ストレート給油)がある。   Generally, in the process of spinning synthetic fibers, from the viewpoint of reducing friction and preventing damage to the fibers such as thread breakage, a treatment for applying a treating agent for synthetic fibers to the surface of filament yarns of synthetic fibers is performed. is there. When the treatment agent for synthetic fiber is diluted in water (emulsion refueling), the form of the adhesion treatment is applied as it is without diluting or diluting the agent for synthetic fiber with a diluent such as low viscosity mineral oil. There is a case (straight refueling).

従来、特許文献1〜4に開示される合成繊維用処理剤が知られている。特許文献1は、減圧処理により脱気した合成繊維用処理剤について開示する。特許文献2は、平滑剤、乳化剤、制電剤を含み、粘度が規定された合成繊維用処理剤について開示する。特許文献3は、鉱物油、脂肪酸エステル、高級アルコールのアルキレンオキシド付加物、高級脂肪族不飽和モノカルボン酸を含有した合成繊維用処理剤について開示する。特許文献4は、有機亜鉛化合物を含み、エステル化合物、ポリエーテル化合物、鉱物油のうち少なくとも1種を含む合成繊維用処理剤について開示する。   Conventionally, the processing agent for synthetic fibers indicated by patent documents 1-4 is known. Patent Document 1 discloses a treating agent for synthetic fiber degassed by reduced pressure treatment. Patent Document 2 discloses a treatment agent for synthetic fibers having a defined viscosity, which contains a leveling agent, an emulsifying agent, and an antistatic agent. Patent Document 3 discloses a treating agent for synthetic fibers containing a mineral oil, a fatty acid ester, an alkylene oxide adduct of a higher alcohol, and a higher aliphatic unsaturated monocarboxylic acid. Patent Document 4 discloses a treating agent for synthetic fibers which contains an organozinc compound and which contains at least one of an ester compound, a polyether compound and a mineral oil.

特開平11−158770号公報Japanese Patent Application Laid-Open No. 11-158770 特開平6−57541号公報Unexamined-Japanese-Patent No. 6-57541 特開昭61−19871号公報Japanese Patent Application Laid-Open No. 61-19871 特開2013−7141号公報JP, 2013-7141, A

ところが、これら従来の合成繊維用処理剤では、ストレート給油に用いられる時、紡糸工程における糸揺れの低減に十分に対応できていなかった。
本発明が解決しようとする課題は、ストレート給油で合成繊維用処理剤を付与する紡糸工程において発生する糸揺れを低減することができる合成繊維用処理剤及び合成繊維の製造方法を提供する処にある。
However, these conventional processing agents for synthetic fibers, when used for straight refueling, have not been able to sufficiently cope with the reduction of yarn fluctuation in the spinning process.
The problem to be solved by the present invention is to provide a synthetic fiber treating agent and synthetic fiber manufacturing method capable of reducing yarn sway generated in a spinning process of applying a synthetic fiber treating agent by straight oil feeding. is there.

本発明者らは、前記の課題を解決するべく研究した結果、紡糸工程においてストレート給油する合成繊維用処理剤において、平滑剤として所定のエステル化合物を含み、所定の割合の水分を有することが正しく好適であることを見出した。   As a result of research conducted to solve the above problems, the present inventors have found that a treating agent for synthetic fiber fed straight in a spinning process contains a predetermined ester compound as a smoothing agent and has a predetermined proportion of water. It was found to be suitable.

すなわち本発明の一態様は、平滑剤として分子中にエステル結合を3つ以上有するエステル化合物、及び分子中に硫黄元素を有するエステル化合物から選ばれる少なくとも一種のエステル化合物を含み、ストレート給油に用いられる合成繊維用処理剤であって、前記合成繊維用処理剤中における水分量が0.1〜5質量%であることを特徴とする合成繊維用処理剤が提供される。   That is, one aspect of the present invention includes at least one ester compound selected from an ester compound having three or more ester bonds in a molecule and an ester compound having a sulfur element in the molecule as a smoothing agent, and is used for straight refueling It is a processing agent for synthetic fibers, Comprising: The water content in the said processing agent for synthetic fibers is 0.1-5 mass%, The processing agent for synthetic fibers characterized by the above-mentioned is provided.

前記合成繊維用処理剤は、さらに非イオン界面活性剤、及びイオン界面活性剤を含むことが好ましい。
前記イオン界面活性剤が、2級アルカンスルホン酸化合物を含み、前記平滑剤、前記非イオン界面活性剤、及び前記イオン界面活性剤の含有割合の合計を100質量%とすると、前記2級アルカンスルホン酸化合物の含有割合が0.01〜10質量%であることが好ましい。
It is preferable that the treatment agent for synthetic fibers further contains a nonionic surfactant and an ionic surfactant.
When the ionic surfactant contains a secondary alkanesulfonic acid compound, and the total content of the leveling agent, the nonionic surfactant, and the ionic surfactant is 100% by mass, the secondary alkanesulfone It is preferable that the content rate of an acid compound is 0.01-10 mass%.

前記イオン界面活性剤が、有機リン酸エステル化合物を含み、前記平滑剤、前記非イオン界面活性剤、及び前記イオン界面活性剤の含有割合の合計を100質量%とすると、前記有機リン酸エステル化合物の含有割合が0.01〜10質量%であることが好ましい。   The organic phosphoric acid ester compound includes the organic phosphoric acid ester compound, and the total content of the leveling agent, the nonionic surfactant, and the ionic surfactant is 100% by mass. The content ratio of is preferably 0.01 to 10% by mass.

前記平滑剤、前記非イオン界面活性剤、及び前記イオン界面活性剤の含有割合の合計を100質量部とすると、希釈剤を0.1〜400質量部の割合で含むことが好ましい。
前記合成繊維用処理剤中の水分量が0.5〜2.0質量%であることが好ましい。
The total content of the leveling agent, the nonionic surfactant, and the ionic surfactant is preferably 100 parts by mass, and the diluent is preferably contained in a ratio of 0.1 to 400 parts by mass.
It is preferable that the water content in the said process agent for synthetic fibers is 0.5-2.0 mass%.

本発明の別の態様は、前記合成繊維用処理剤を、紡糸工程において、合成繊維にストレート給油することを特徴とする合成繊維の製造方法が提供される。   Another aspect of the present invention provides a method for producing a synthetic fiber, which is characterized in that the treatment agent for synthetic fiber is directly fed to the synthetic fiber in a spinning step.

本発明によると、紡糸工程において発生する糸揺れを低減できる。   According to the present invention, it is possible to reduce the yarn fluctuation generated in the spinning process.

(第1実施形態)
先ず、本発明に係る合成繊維用処理剤(以下、処理剤という)を具体化した第1実施形態について説明する。本実施形態の処理剤は、平滑剤として所定のエステル化合物を含み、ストレート給油に用いられる合成繊維用処理剤であって、処理剤中の水分量が0.1〜5質量%のものである。好ましくは、さらに非イオン界面活性剤、及びイオン界面活性剤を含有し、水分量が0.1〜5質量%のものである。さらに好ましくは、処理剤中の水分量が0.5〜2.0質量%のものである。特に好ましくは、処理剤中の水分量が0.7〜1.5質量%のものである。かかる構成により、本発明の効果、つまり紡糸工程において発生する糸揺れをより低減することができる。
First Embodiment
First, a first embodiment in which the treatment agent for synthetic fiber according to the present invention (hereinafter referred to as a treatment agent) is embodied will be described. The treating agent of the present embodiment is a treating agent for synthetic fibers which contains a predetermined ester compound as a smoothing agent and is used for straight refueling, and the water content in the treating agent is 0.1 to 5% by mass. . Preferably, the surfactant further contains a nonionic surfactant and an ionic surfactant, and has a water content of 0.1 to 5% by mass. More preferably, the water content in the treatment agent is 0.5 to 2.0% by mass. Particularly preferably, the water content in the treatment agent is 0.7 to 1.5% by mass. According to such a configuration, the effect of the present invention, that is, the yarn fluctuation generated in the spinning process can be further reduced.

合成繊維用処理剤に含まれる水分量は、製造時や紡糸直前に合成繊維処理剤中に水を添加することにより調節してもよい、減圧、加熱のような一般的に知られる脱水方法によって水分量を調節してもよい。合成繊維用処理剤中に水分として添加される水は、工業用水や水道水等でもよく、イオン交換樹脂、膜、蒸留等で精製を行った水でもよく、処理剤構成物の原料中にその他成分等として持ち込まれる水でもよい。これらの中でも、水の電気伝導率が300μS/cm以下の水が好ましく、100μS/cm以下の水がより好ましく、10μS/cm以下の精製水がさらに好ましい。または、水の硬度(炭酸カルシウムとして)は100mg/L以下が好ましく、10mg/L以下がより好ましく、5mg/L以下がさらに好ましい。混合する水は、減圧のような公知の方法によって脱気されたものでも良く、大気中の酸素、窒素、二酸化炭素等を含んだものでもよい。また、pHは、中性付近、例えば5.5〜8.0の範囲のものが好ましい。合成繊維用処理剤中の水分量は、水の添加量及び合成繊維処理剤の構成物質の原料中の水分量から計算して求めることができる。原料中の水分量が不明な場合は、カールフィッシャー滴定やガスクロマトグラフィーのような公知の分析方法から求めてもよい。   The amount of water contained in the treatment agent for synthetic fiber may be adjusted by adding water to the treatment agent for synthetic fiber at the time of production or immediately before spinning, by a generally known dehydration method such as decompression or heating. The amount of water may be adjusted. Water to be added as moisture in the processing agent for synthetic fibers may be industrial water, tap water, etc., may be ion exchange resin, water purified by membrane, distillation, etc. It may be water brought in as an ingredient or the like. Among these, water having an electric conductivity of 300 μS / cm or less is preferable, water having 100 μS / cm or less is more preferable, and purified water having 10 μS / cm or less is more preferable. Alternatively, the hardness (as calcium carbonate) of water is preferably 100 mg / L or less, more preferably 10 mg / L or less, and still more preferably 5 mg / L or less. The water to be mixed may be one that has been degassed by a known method such as reduced pressure, or may be one that contains oxygen in the atmosphere, nitrogen, carbon dioxide, and the like. The pH is preferably around neutral, for example, in the range of 5.5 to 8.0. The water content in the synthetic fiber treatment agent can be calculated from the amount of water added and the water content in the raw material of the component of the synthetic fiber treatment agent. If the water content in the raw material is unknown, it may be determined from known analytical methods such as Karl-Fischer titration or gas chromatography.

本実施形態の処理剤に供する平滑剤としては、分子中にエステル結合を3つ以上有するエステル化合物、及び分子中に硫黄元素を有するエステル化合物から選ばれる少なくとも一種のエステル化合物を含むものが適用される。かかる構成により、本発明の効果、つまり紡糸工程において発生する糸揺れを低減することができる。また、ローラー汚れをより低減することができ、更に後加工工程においてより均一な染色ができる。分子中にエステル結合を3つ以上有するエステル化合物としては、例えば(1)トリメチロールプロパントリラウラート、トリメチロールプロパントリオレアート、グリセリントリオレアート、ペンタエリスリトールテトラオクタノアート、トリメチロールプロパン−ヤシ脂肪酸エステル等の多価アルコールと一価カルボン酸とのエステル化合物、(2)トリオクチルトリメリタート、クエン酸トリエチル等の多価カルボン酸と一価アルコールとのエステル化合物、(3)ひまし油、パーム油、ナタネ白絞油等の天然油脂等が挙げられる。これらのエステル化合物の中でもトリメチロールプロパン−ヤシ脂肪酸エステル、パーム油が好ましい。分子中に硫黄元素を有するエステル化合物は、例えば(4)ジイソセチルチオジプロピオナート、ジイソステアリルチオジプロピオナート、ジオレイルチオジプロピオナート等の二価カルボン酸と一価アルコールとのエステル化合物、(5)ラウリルメルカプトプロピオナート、オクチルメルカプトプロピオナート、ラウリルチオプロピオン酸オレイル等の1価カルボン酸と1価アルコールとのエステル化合物等が挙げられる。これらのエステル化合物の中でもジイソセチルチオジプロピオナート、ジイソステアリルチオジプロピオナートが好ましい。これらの成分は、1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。   As the leveling agent to be used for the processing agent of the present embodiment, one containing at least one ester compound selected from ester compounds having three or more ester bonds in the molecule and ester compounds having sulfur element in the molecule is applied Ru. Such a configuration can reduce the effects of the present invention, that is, the yarn fluctuation generated in the spinning process. In addition, roller stain can be further reduced, and more uniform dyeing can be performed in the post-processing step. Examples of ester compounds having three or more ester bonds in the molecule include (1) trimethylolpropane trilaurate, trimethylolpropane trioleate, glycerin trioleate, pentaerythritol tetraoctanoate, trimethylolpropane-cocotic fatty acid ester Etc., ester compounds of polyvalent alcohol and monohydric carboxylic acid, (2) trioctyl trimellitate, ester compounds of polyvalent carboxylic acid such as triethyl citrate and monohydric alcohol, (3) castor oil, palm oil, Natural fats and oils such as rapeseed oil and the like may be mentioned. Among these ester compounds, trimethylolpropane-coconut fatty acid ester and palm oil are preferable. The ester compound having a sulfur element in the molecule is, for example, an ester of a dihydric carboxylic acid such as (4) diisocetyl thiodipropionate, diisostearyl thiodipropionate, dioleyl thiodipropionate and a monohydric alcohol. Examples thereof include compounds, (5) lauryl mercapto propionate, octyl mercapto propionate, and ester compounds of monohydric carboxylic acids such as oleyl lauryl thiopropionate and monohydric alcohols. Among these ester compounds, diisocetyl thiodipropionate and diisostearyl thiodipropionate are preferable. One of these components may be used alone, or two or more thereof may be used in combination.

本実施形態の処理剤に供する非イオン界面活性剤の具体例としては、特に制限はなく、例えば(1)有機酸、有機アルコール、有機アミン、及び有機アミドから選ばれる少なくとも一種に炭素数2〜4のアルキレンオキサイドを付加した化合物、より具体的には、例えばポリオキシエチレンラウリン酸エステル、ポリオキシエチレンオレイン酸エステル、ポリオキシエチレンラウリン酸エステルメチルエーテル、ポリオキシエチレンオクチルエーテル、ポリオキシプロピレンラウリルエーテルメチルエーテル、ポリオキシブチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシエチレンポリオキシプロピレンノニルフェニルエーテル、ポリオキシエチレンラウリルアミノエーテル、ポリオキシエチレンラウロアミドエーテル等のエーテル型ノニオン界面活性剤、(2)ソルビタンモノオレアート、ソルビタントリオレアート、グリセリンモノラウラート等の多価アルコール部分エステル型ノニオン界面活性剤、(3)ポリエチレングリコールジオレアート、ポリオキシエチレンソルビタンモノオレアート、ポリオキシブチレンソルビタントリオレアート、ポリオキシエチレングリセリントリオレアート、ポリオキシプロピレンひまし油、ポリオキシエチレン硬化ひまし油、ポリオキシエチレンプロピレン硬化ひまし油トリオレアート、ポリオキシエチレン硬化ひまし油トリラウラート、ひまし油のエチレンオキサイド(以下、EOという)付加物及び硬化ひまし油のEO付加物から選ばれる少なくとも1種の化合物と、モノカルボン酸及びジカルボン酸とを縮合させたエーテルエステル化合物等のポリオキシアルキレン多価アルコール脂肪酸エステル型ノニオン界面活性剤、(4)ジエタノールアミンモノラウロアミド等のアルキルアミド型ノニオン界面活性剤等が挙げられる。これらの成分は、1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。   There are no particular limitations on the specific examples of the nonionic surfactant to be used in the treatment agent of the present embodiment, and for example, (1) at least one selected from organic acids, organic alcohols, organic amines, and organic amides having 2 to 2 carbon atoms Compounds to which 4 alkylene oxides are added, more specifically, for example, polyoxyethylene laurate, polyoxyethylene oleate, polyoxyethylene laurate methyl ether, polyoxyethylene octyl ether, polyoxypropylene lauryl ether Methyl ether, polyoxybutylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxyethylene polyoxypropylene nonylphenyl ether, polyoxyethylene lauryl amino ether, polyoxyethylene Ether type nonionic surfactants such as len lauro amide ether, (2) Polyhydric alcohol partial ester type nonionic surfactants such as sorbitan monooleate, sorbitan trioleate, glycerin monolaurate, (3) polyethylene glycol dioleate , Polyoxyethylene sorbitan monooleate, polyoxybutylene sorbitan trioleate, polyoxyethylene glycerine trioleate, polyoxypropylene glycerin castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene propylene hydrogenated castor oil trioleate, polyoxyethylene hydrogenated castor oil trilaurate, At least one compound selected from ethylene oxide (hereinafter referred to as EO) adduct of castor oil and EO adduct of hardened castor oil, and monocarboxylic acid Polyoxyalkylene polyhydric alcohol fatty acid ester type nonionic surfactant of an ether ester compound or the like by condensing fine dicarboxylic acid, (4) alkyl amide type nonionic surfactants such as diethanol monolauroyl amide. One of these components may be used alone, or two or more thereof may be used in combination.

本実施形態の処理剤に供するイオン界面活性剤としては、アニオン界面活性剤が好ましい。本実施形態の処理剤に供するアニオン界面活性剤の具体例としては、特に制限はなく、例えば(1)オクタン酸カリウム塩、オレイン酸カリウム塩、アルケニルコハク酸カリウム塩等のカルボン酸石鹸型イオン界面活性剤、(2)2級アルカンスルホン酸ナトリウム塩、ドデシルベンゼンスルホン酸ナトリウム塩、ジオクチルスルホコハク酸ナトリウム塩等のスルホン酸エステル型イオン界面活性剤、(3)ポリオキシエチレンラウリル硫酸エステルナトリウム塩、ヘキサデシル硫酸カリウム塩、牛脂硫化油、ひまし油硫化油等の硫酸エステル型イオン界面活性剤等が挙げられる。アニオン界面活性剤の中でも、2級アルカンスルホン酸化合物、有機リン酸化合物を含有することが好ましい。2級アルカンスルホン酸化合物としては、特に、下記化1で示される2級アルカンスルホン酸塩がより好ましく、そのナトリウム塩がさらに好ましい。有機リン酸化合物としては、特にオレイルホスフェートEO5(EOの付加モル数を示す。以下同じ。)ステアリルアミノエーテル塩、イソセチルホスフェートEO10ラウリルアミノエーテル塩がより好ましい。これらの成分は、1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。   As the ionic surfactant to be provided to the treatment agent of the present embodiment, an anionic surfactant is preferable. There is no restriction | limiting in particular as a specific example of the anionic surfactant used for the processing agent of this embodiment, For example, carboxylic acid soap type ion interfaces, such as (1) octanoic acid potassium salt, oleic acid potassium salt, alkenyl succinic acid potassium salt etc. Activators, (2) Secondary alkanesulfonic acid sodium salts, sodium dodecylbenzenesulfonic acid salts, sulfonic acid ester type ionic surfactants such as dioctyl sulfosuccinate sodium salts, (3) polyoxyethylene lauryl sulfate sodium salts, hexadecyl Examples include sulfuric acid ester type ionic surfactants such as potassium sulfate, tallow sulfurized oil, castor oil sulfurized oil and the like. Among the anionic surfactants, secondary alkanesulfonic acid compounds and organic phosphoric acid compounds are preferably contained. As the secondary alkanesulfonic acid compound, in particular, a secondary alkanesulfonic acid salt represented by the following chemical formula 1 is more preferable, and its sodium salt is more preferable. As the organic phosphoric acid compound, in particular, oleyl phosphate EO5 (the addition mole number of EO is shown. The same applies to the following.) Stearyl aminoether salt and isocetyl phosphate EO10 lauryl aminoether salt are more preferable. One of these components may be used alone, or two or more thereof may be used in combination.

(化1において、
a,b:それぞれ0以上の整数であってa+b=5〜17、
M:アルカリ金属、アンモニウム基、又は有機アミン基。)
本実施形態の処理剤は、さらに希釈剤を配合してもよい。本実施形態の処理剤に供する希釈剤の具体例としては、(1)キシレン、トルエン、ベンゼン、フェノール等の芳香族炭化水素、(2)アセトン、メチルエチルケトン等のケトン、(3)メタノール、エタノール、プロパノール、2−エチルヘキサノール、ドデカノール等のアルコール、(4)ヘキサン、へプタン、オクタン、デカン、ウンデカン、ドデカン、トリデカン、テトラデカン、オクタデカン等の直鎖飽和炭化水素、(5)イソヘキサン、イソへプタン、イソオクタン、イソデカン、イソウンデカン、イソドデカン、イソトリデカン、イソテトラデカン、イソオクタデカン、イソエイコサン等の分岐炭化水素、(6)シクロヘキサン、シクロオクタン、シクロドデカン、シクロオクタデカン、シクロイコサン等の環状飽和炭化水素、(7)メチルオクタート、エチルラウラート、プロピルパルミテート、イソブチルステアラート、ノルマルブチルステアラート等の低分子量エステル化合物、(8)パラフィン系炭化水素、ナフテン系炭化水素、オレフィン系炭化水素、芳香族炭化水素のうち少なくとも一種から選ばれる鉱物油等の水以外の溶媒が挙げられる。これらの成分は、1種を単独で使用してもよく、2種以上を組み合わせて使用してもよい。希釈剤は、紡糸工程中に揮発させることが好ましく、紡糸前後で70質量%程度以上揮発していることがより好ましい。また、希釈剤は、合成繊維処理剤の製造時だけでなく紡糸直前に添加してもよい。これらの中でも40℃でレッドウッド粘度が100秒以下の鉱物油、直鎖飽和炭化水素(C10−C15)、イソブチルステアラート、ノルマルブチルステアラートが好ましい。
(In chemical formula 1,
a and b are each an integer of 0 or more, and a + b = 5 to 17,
M: alkali metal, ammonium group or organic amine group. )
The treatment agent of the present embodiment may further contain a diluent. Specific examples of the diluent used for the treatment agent of the present embodiment include (1) aromatic hydrocarbons such as xylene, toluene, benzene and phenol, (2) ketones such as acetone and methyl ethyl ketone, and (3) methanol, ethanol, Alcohols such as propanol, 2-ethylhexanol, dodecanol, (4) hexane, heptane, octane, decane, undecane, dodecane, dodecane, tridecane, tridecane, tetradecane, straight chain saturated hydrocarbons such as octadecane, (5) isohexane, isoheptane, Branched hydrocarbons such as isooctane, isodecane, isoundecane, isododecane, isotridecane, isotetradecane, isooctadecane, isoeicosane, (6) cyclic saturated hydrocarbons such as cyclohexane, cyclooctane, cyclododecane, cyclooctadecane, cycloicosane (7) Low molecular weight ester compounds such as methyl octatate, ethyl laurate, propyl palmitate, isobutyl stearate, normal butyl stearate, etc., (8) paraffin hydrocarbons, naphthene hydrocarbons, olefin hydrocarbons, aromatics Solvents other than water, such as mineral oil chosen from at least 1 sort among hydrocarbon, are mentioned. One of these components may be used alone, or two or more thereof may be used in combination. The diluent is preferably volatilized during the spinning process, and more preferably approximately 70% by mass or more before and after spinning. The diluent may be added not only at the time of production of the synthetic fiber treatment agent but also immediately before spinning. Among them, mineral oil having a redwood viscosity of 100 seconds or less at 40 ° C., linear saturated hydrocarbon (C10-C15), isobutyl stearate and normal butyl stearate are preferable.

本実施形態の処理剤において、上述した平滑剤の他、非イオン界面活性剤、及びイオン界面活性剤をさらに含む場合、各成分の含有比率に特に制限ない。本実施形態の処理剤がイオン界面活性剤として2級アルカンスルホン酸化合物を含む場合、平滑剤、非イオン界面活性剤、及びイオン界面活性剤の含有割合の合計を100質量%とすると、2級アルカンスルホン酸化合物の含有割合を0.01〜10質量%とすることが好ましい。かかる構成により、本発明の効果、つまり紡糸工程において発生する糸揺れをより低減することができる。また、後加工工程においてより均一な染色ができる。   When the processing agent of the present embodiment further includes a nonionic surfactant and an ionic surfactant in addition to the above-described smoothing agent, the content ratio of each component is not particularly limited. When the treating agent of the present embodiment contains a secondary alkanesulfonic acid compound as an ionic surfactant, the secondary agent is considered to have a total content of 100% by mass of the smoothing agent, the nonionic surfactant, and the ionic surfactant. It is preferable to make the content rate of an alkanesulfonic acid compound into 0.01 to 10 mass%. According to such a configuration, the effect of the present invention, that is, the yarn fluctuation generated in the spinning process can be further reduced. In addition, more uniform dyeing can be performed in the post-processing step.

本実施形態の処理剤がイオン界面活性剤として有機リン酸エステル化合物を含む場合、平滑剤、非イオン界面活性剤、及びイオン界面活性剤の含有割合の合計を100質量%とすると、有機リン酸エステル化合物の含有割合を0.01〜10質量%とすることが好ましい。かかる構成により、本発明の効果、つまり紡糸工程において発生する糸揺れをより低減することができる。また、ローラー汚れをより低減することができ、更に後加工工程においてより均一な染色ができる。   When the treating agent of the present embodiment contains an organic phosphoric acid ester compound as an ionic surfactant, the organic phosphoric acid is contained, assuming that the total content of the smoothing agent, the nonionic surfactant, and the ionic surfactant is 100% by mass. It is preferable to make the content rate of an ester compound into 0.01 to 10 mass%. According to such a configuration, the effect of the present invention, that is, the yarn fluctuation generated in the spinning process can be further reduced. In addition, roller stain can be further reduced, and more uniform dyeing can be performed in the post-processing step.

本実施形態の処理剤が希釈剤を含む場合、平滑剤、非イオン界面活性剤、及びイオン界面活性剤の含有割合の合計を100質量部とすると、希釈剤を0.1〜400質量部の割合で含有するものが好ましい。かかる配合量範囲に規定することにより、本発明の効果、つまり紡糸工程において発生する糸揺れを低減することができる。また、ローラー汚れをより低減することができ、更に後加工工程においてより均一な染色ができる。   When the treatment agent of the present embodiment contains a diluent, if the total content of the smoothing agent, nonionic surfactant and ionic surfactant is 100 parts by mass, the amount of the diluent is 0.1 to 400 parts by mass. Those containing in proportion are preferred. By defining the compounding amount range, the effect of the present invention, that is, the yarn fluctuation generated in the spinning process can be reduced. In addition, roller stain can be further reduced, and more uniform dyeing can be performed in the post-processing step.

(第2実施形態)
次に、本発明による合成繊維の製造方法を具体化した第2実施形態を説明する。本実施形態の合成繊維の製造方法は、第1実施形態の処理剤を紡糸工程において合成繊維にストレート給油により付着させる工程を含む製造方法である。製造する合成繊維の具体例としては、特に制限はなく、例えば(1)ポリエチレンテレフタレート、ポリプロピレンテレフタレート、ポリ乳酸エステル等のポリエステル系繊維、(2)ナイロン6、ナイロン66等のポリアミド系繊維、(3)ポリアクリル、モダアクリル等のポリアクリル系繊維、(4)ポリエチレン、ポリプロピレン等のポリオレフィン系繊維等が挙げられる。製造する合成繊維の繊度としては、特に制限はないが、好ましくは150デシテックス以上であり、さらに好ましくは500デシテックス以上であり、特に好ましいのは1000デシテックス以上である。また、製造する合成繊維の強度としては、特に制限はないが、好ましくは5.0cN/dtex以上であり、さらに好ましくは6.0cN/dtex以上、特に好ましくは7.0cN/dtex以上である。
Second Embodiment
Next, a second embodiment of the method for producing synthetic fibers according to the present invention will be described. The method for producing the synthetic fiber of the present embodiment is a production method including the step of causing the treatment agent of the first embodiment to adhere to the synthetic fiber by straight oil feeding in the spinning step. Specific examples of the synthetic fiber to be produced are not particularly limited. For example, (1) polyester fibers such as polyethylene terephthalate, polypropylene terephthalate and polylactic acid ester, (2) polyamide fibers such as nylon 6 and nylon 66, (3 ) Polyacrylic fibers such as polyacrylic and modacrylic, and (4) polyolefin fibers such as polyethylene and polypropylene. The fineness of the synthetic fiber to be produced is not particularly limited, but is preferably 150 dtex or more, more preferably 500 dtex or more, and particularly preferably 1000 dtex or more. The strength of the synthetic fiber to be produced is not particularly limited, but is preferably 5.0 cN / dtex or more, more preferably 6.0 cN / dtex or more, and particularly preferably 7.0 cN / dtex or more.

第1実施形態の処理剤を合成繊維に付着させる割合に特に制限はないが、第1実施形態の処理剤を合成繊維に対し0.1〜3質量%(希釈剤と水を含まない)の割合となるよう付着させることが好ましい。かかる構成により、本発明の効果をより向上させる。また、第1実施形態の処理剤を付着させる方法は、特に制限はなく、例えばローラー給油法、計量ポンプを用いたガイド給油法、浸漬給油法、スプレー給油法等の公知の方法を採用することができ、付着させる工程も紡糸工程であれば特に制限はなく、例えば延伸若しくは熱処理工程において、150℃以上のローラーを通過させる工程を有する製造設備、工程での使用により、発明の効果がより期待できる。   There is no particular limitation on the ratio of adhering the treating agent of the first embodiment to the synthetic fiber, but 0.1 to 3% by mass (not including diluent and water) of the treating agent of the first embodiment with respect to the synthetic fiber It is preferable to attach it so that it becomes a ratio. With this configuration, the effects of the present invention are further improved. Further, the method for adhering the treatment agent of the first embodiment is not particularly limited, and for example, a known method such as a roller oiling method, a guide oiling method using a measuring pump, an immersion oiling method, a spray oiling method There is no particular limitation as long as the step of attaching is also a spinning step, for example, in the drawing or heat treatment step, the effect of the invention is more expected by use in a production facility or step having a step of passing a roller at 150 ° C. or higher. it can.

上記実施形態の処理剤及びその製造方法によれば、以下のような効果を得ることができる。
上記実施形態の処理剤では、ストレート給油で用いられる処理剤において、平滑剤として所定のエステル化合物を含み、処理剤中に含有する水分量を規定した。したがって、合成繊維の紡糸工程においてゴデットローラーで発生する糸揺れを効果的に低減することができる。また、ゴデットローラー周りに発生するタール汚れを効果的に低減することができ、更に後加工工程において均一な染色を可能とする。それにより得られる本実施形態の合成繊維は、優れた工程通過性を発揮することができる。また、処理剤中にさらに非イオン界面活性剤、イオン界面活性剤を配合して構成した場合、上記効果をより向上させる。
According to the treatment agent of the above embodiment and the method for producing the same, the following effects can be obtained.
In the treatment agent of the above embodiment, in the treatment agent used in straight refueling, a predetermined ester compound is contained as a smoothing agent, and the amount of water contained in the treatment agent is specified. Therefore, it is possible to effectively reduce the yarn swing generated by the godet roller in the process of spinning synthetic fibers. In addition, tar stains generated around the godet roller can be effectively reduced, and uniform dyeing is possible in the post-processing step. The synthetic fiber of this embodiment obtained thereby can exhibit excellent process passability. Further, in the case where a nonionic surfactant and an ionic surfactant are further blended in the treatment agent, the above effect is further improved.

なお、上記実施形態は以下のように変更してもよい。
・本実施形態の処理剤には、本発明の効果を阻害しない範囲内において、処理剤の品質保持のための安定化剤や制電剤、つなぎ剤、酸化防止剤、紫外線吸収剤等の通常合成繊維の処理剤に用いられる成分をさらに配合してもよい。
The above embodiment may be modified as follows.
-The treatment agent of the present embodiment is usually a stabilizer, an antistatic agent for maintaining the quality of the treatment agent, a binder, an antioxidant, an ultraviolet absorber, etc., as long as the effects of the present invention are not impaired. You may further mix | blend the component used for the processing agent of a synthetic fiber.

以下、本発明の構成及び効果をより具体的にするため、実施例等を挙げるが、本発明がこれらの実施例に限定されるというものではない。尚、以下の実施例及び比較例において、部は質量部を、また%は質量%を意味する。   Hereinafter, examples and the like will be described in order to make the configuration and effects of the present invention more specifically, but the present invention is not limited to these examples. In the following examples and comparative examples, "part" means "mass part" and "%" means mass%.

試験区分1(合成繊維用処理剤の調整)
・合成繊維用処理剤(実施例1)の調整
平滑剤としてトリメチロールプロパン−ヤシ脂肪酸エステル(L−1)を50部、ジイソステアリルチオジプロピオナート(LS−1)を5部、非イオン界面活性剤として硬化ひまし油1モルに対しEO10モル付加したもの(N−1)10部、硬化ひまし油1モルに対しEO20モル付加したものをオレイン酸3モルでエステル化した化合物(N−3)10部、硬化ひまし油1モルに対しEO25モル付加したものをアジピン酸で架橋し、ステアリン酸で末端エステル化した化合物(MW5000)(N−6)5部、ポリエチレングリコール(分子量600)ジオレアート(N−7)10部、イオン界面活性剤として上記化1の構造の2級アルカンスルホン酸ナトリウム(a+b=8〜11)(S−1)5部、オレイルホスフェート(EO5)ステアリルアミノエーテル塩(P−1)5部を均一混合し、混合物を得た。
Test division 1 (adjustment of processing agent for synthetic fiber)
Preparation of a treating agent for synthetic fiber (Example 1) 50 parts of trimethylolpropane-cocoal fatty acid ester (L-1), 5 parts of diisostearyl thiodipropionate (LS-1) as a smoothing agent, non-ionic Compound (N-3) obtained by esterifying 10 parts of EO added with 10 moles of EO (N-1) per 1 mol of hardened castor oil as surfactant and 20 moles added of EO with 1 mol of hardened castor oil with 3 moles of oleic acid Part, 25 parts of EO added per 1 mol of hardened castor oil is crosslinked with adipic acid, and 5 parts of a compound (MW 5000) (N-6) end-esterified with stearic acid, polyethylene glycol (molecular weight 600) dioleate (N-7) Sodium hydroxide (a + b = 8 to 11) (S-) of the structure of the above-mentioned chemical formula 1 as an ionic surfactant 1) 5 parts of oleyl phosphate (EO5) stearylaminoether salt (P-1) were mixed uniformly to obtain a mixture.

さらに、前記混合物を100質量部としたとき1.00質量部のイオン交換水、次いで希釈剤として直鎖飽和炭化水素(C12−15)(M−1)10質量部を加えて均一混合し、処理剤中における水分が0.9%となるように実施例1の合成繊維用処理剤を調製した。使用したイオン交換水は、電気伝導率が0.2μS/cmで硬度が0mg/Lのものを使用した。   Furthermore, when the mixture is 100 parts by mass, 1.00 parts by mass of ion exchange water, and then 10 parts by mass of linear saturated hydrocarbon (C12-15) (M-1) as a diluent are added and uniformly mixed, The treatment agent for synthetic fiber of Example 1 was prepared such that the water content in the treatment agent was 0.9%. The ion-exchanged water used had an electric conductivity of 0.2 μS / cm and a hardness of 0 mg / L.

・合成繊維用処理剤(実施例2)の調製
実施例1の合成繊維処理剤と同様の方法にて調製した。但し、表1の原料以外に酸化防止剤として1,1,3−トリス(2−メチル−4−ハイドロキシ−5−t−ブチルフェニル)ブタンを希釈剤添加前の処理剤100部に対し0.8部の割合で添加した。
Preparation of Treating Agent for Synthetic Fiber (Example 2) The agent was prepared in the same manner as the treating agent for synthetic fiber of Example 1. However, in addition to the raw materials shown in Table 1, 0, 1 based on 100 parts of the processing agent before addition of the diluent, 1,1,3-tris (2-methyl-4-hydroxy-5-t-butylphenyl) butane as an antioxidant. It was added in the proportion of 8 parts.

・合成繊維用処理剤(実施例3〜8及び比較例1〜3)の調製
実施例1の合成繊維処理剤の調製と同様に、実施例3〜8及び比較例1〜3の合成繊維用処理剤を調製し、結果を表1に示した。なお、表1においては、合成繊維用処理剤中における各成分の種類を示すとともに、希釈剤及び水以外の成分を100%とした場合の配合比率(%)を示す。また、合成繊維用処理剤中における希釈剤及び水以外の成分を100部とした場合の希釈剤及び水の添加率(部)を示す。また、処理剤中における水の含有量(%)を示す。
Preparation of processing agents for synthetic fibers (Examples 3 to 8 and Comparative Examples 1 to 3) For the synthetic fibers of Examples 3 to 8 and Comparative Examples 1 to 3 in the same manner as the preparation of the synthetic fiber processing agent of Example 1 The treatment agents were prepared and the results are shown in Table 1. In addition, in Table 1, while showing the kind of each component in the processing agent for synthetic fibers, the compounding ratio (%) at the time of setting components other than a diluent and water to 100% is shown. In addition, the addition ratio (parts) of the diluent and water when the components other than the diluent and water in the processing agent for synthetic fiber are 100 parts is shown. It also shows the water content (%) in the treatment agent.

表1において、
L−1:トリメチロールプロパン−ヤシ脂肪酸エステル、
L−2:パーム油、
LS−1:ジイソステアリルチオジプロピオナート、
LS−2:ジイソセチルチオジプロピオナート、
rL−1:イソステアリルオレアート、
N−1:硬化ひまし油1モルに対しEO10モル付加したもの、
N−2:硬化ひまし油1モルに対しEO20モル付加したもの、
N−3:硬化ひまし油1モルにEO20モル付加したものをオレイン酸3モルでエステル化した化合物、
N−4:硬化ひまし油1モルにEO40モル付加したものをオレイン酸2モルでエステル化した化合物、
N−5:ひまし油1モルにEO25モル付加したものをラウリン酸3モルでエステル化した化合物、
N−6:硬化ひまし油1モルに対しEO25モル付加したものをアジピン酸で架橋し、ステアリン酸で末端エステル化した化合物(MW5000)、
N−7:ポリエチレングリコール(分子量600)ジオレアート、
N−8:ソルビタンモノオレアート、
S−1:2級アルカンスルホン酸ナトリウム(上記[化1]においてa+b=8〜11)、
S−2:2級アルカンスルホン酸ナトリウム(上記[化1]においてa+b=11〜14)、
rS−1:ジオクチルスルホコハク酸ナトリウム、
P−1:オレイルホスフェート(EO5)ステアリルアミノエーテル塩、
P−2:イソセチルホスフェート(EO10)ラウリルアミノエーテル塩、
M−1:直鎖飽和炭化水素(C12−15)、
M−2:鉱物油(40℃でレッドウッド粘度が80秒)、
M−3:イソブチルステアラート、
M−4:ノルマルブチルステアラート、
を示す。
In Table 1,
L-1: trimethylolpropane-coconut fatty acid ester,
L-2: Palm oil,
LS-1: diisostearylthiodipropionate,
LS-2: diisocetyl thiodipropionate,
rL-1: isostearyl oleate,
N-1: 10 mol of EO added to 1 mol of hardened castor oil,
N-2: 20 mol of EO added to 1 mol of hardened castor oil,
N-3: a compound obtained by esterifying 20 mol of EO added to 1 mol of hardened castor oil with 3 mol of oleic acid,
N-4: A compound obtained by esterifying 40 moles of EO added to 1 mole of hydrogenated castor oil with 2 moles of oleic acid,
N-5: a compound obtained by esterifying 25 moles of EO added to 1 mole of castor oil with 3 moles of lauric acid,
N-6: a compound obtained by adding 25 moles of EO to 1 mole of hardened castor oil is crosslinked with adipic acid and terminated with stearic acid (MW 5000)
N-7: polyethylene glycol (molecular weight 600) dioleate,
N-8: sorbitan monooleart,
S-1: Sodium secondary alkane sulfonate (a + b = 8 to 11 in the above [Chemical formula 1]),
S-2: secondary alkanesulfonic acid sodium (a + b = 1 to 14 in the above [Chemical formula 1]),
rS-1: sodium dioctyl sulfosuccinate,
P-1: oleyl phosphate (EO5) stearyl amino ether salt,
P-2: Isocetyl phosphate (EO 10) lauryl amino ether salt,
M-1: linear saturated hydrocarbon (C12-15),
M-2: mineral oil (red wood viscosity at 40 ° C. for 80 seconds),
M-3: isobutyl stearate,
M-4: Normal butyl stearate,
Indicates

試験区分2(合成繊維処理剤の評価)
・耐熱性タールの評価
ポリエチレンテレフタレートのチップを常法により乾燥した後、エクストルーダーを用いて溶融紡糸し、口金から吐出して冷却固化した後の走行糸条に、前記処理剤を、計量ポンプを用いたガイド給油法にて付着させた。合成繊維処理剤の付着量が0.6質量%(希釈剤、水を含まない)となるように給油した。その後、ガイドで集束させて、245℃の延伸ロール、弛緩ロールを介して全延伸倍率5.5倍となるように延伸し、1100デシテックス192フィラメントの延伸糸を10kg捲きチーズとして得た。耐熱性(タール)について、48時間紡糸した後のゴデットローラー(GR)の汚れ(タール)として下記のように評価した。結果を表1に示す。
Test division 2 (evaluation of synthetic fiber treatment agent)
· Evaluation of heat-resistant tar After drying the chips of polyethylene terephthalate according to a conventional method, melt spinning is performed using an extruder, and the processing agent is added to the running yarn after discharging from the die and cooling and solidifying. It was made to adhere by the used guide oiling method. It was refueled so that the adhesion amount of the synthetic fiber treatment agent became 0.6 mass% (diluent, water not included). Then, it was converged with a guide and stretched through a stretching roll at 245 ° C. and a relaxation roll so as to have a total draw ratio of 5.5 times to obtain a stretched yarn of 1100 dtex 192 filaments as a 10 kg cut cheese. The heat resistance (tar) was evaluated as described below as soiling (tar) of a godet roller (GR) after spinning for 48 hours. The results are shown in Table 1.

・GR汚れの評価基準
◎:汚れ(タール)がほとんど認められない。
○:汚れ(タール)がわずかに認められる。
×:汚れ(タール)が認められる。
· Evaluation criteria for GR stain ◎: Almost no stain (tar) is observed.
○: Slight (tar) is slightly recognized.
X: Dirt (tar) is recognized.

・糸揺れの評価
前記紡糸工程において、ゴデットローラー上での糸揺れを観察し、次の基準で評価した。結果を表1に示す。
Evaluation of yarn sway In the spinning step, yarn sway on a godet roller was observed and evaluated according to the following criteria. The results are shown in Table 1.

・糸揺れの評価基準
◎:ローラー上での糸揺れが認められない。
○:ローラー上での糸揺れがわずかに認められる。
×:ローラー上での糸揺れが認められる。
-Evaluation criteria for yarn shake :: No yarn shake on the roller is recognized.
○: Slight vibration on the roller is observed.
X: Yarn on the roller is observed.

・染色性の評価
前記の紡糸工程において得られた繊維360本を経糸とし、緯糸として560デシテックス−96フィラメントのポリエステル糸を用いて緯糸密度21本/インチで51mm幅のシートベルト用生機を用い、精錬することなしに以下の染液(水1Lに対してDianix Red S−4G 3.4g、Dianix Yellow S−6G 3.3g、Dianix S−2G 3.3gを添加した溶液)に浸漬させ、連続して220℃の発色槽で2分間の処理を行うことにより染色を行った。この時のシートベルト2000m当たりの染色欠点数から以下の基準により染色性を評価した。結果を表1に示す。
-Evaluation of dyeability The 360 fibers obtained in the above spinning process are used as warp yarns, and polyester yarns of 560 dtex-96 filaments are used as weft yarns, using a sheet belt loom with a weft density of 21 yarns / inch and a width of 51 mm. Immerse in the following dye solution (a solution in which 3.4 g of Dinix Red S-4G, 3.3 g of Dinix Yellow S-6G, and 3.3 g of Dinix S-2G were added to 1 L of water) without refining and continuous Then, staining was performed by performing a treatment for 2 minutes in a coloring bath at 220 ° C. The dyeability was evaluated according to the following criteria from the number of staining defects per 2000 m of the seat belt at this time. The results are shown in Table 1.

・染色性の評価基準
◎:染色欠点数0〜3。
○:染色欠点数4〜10。
×:染色欠点数11以上。
Evaluation criteria for dyeability ◎: number of staining defects 0 to 3.
○: number of staining defects 4 to 10.
X: The number of staining defects is 11 or more.

表1の結果からも明らかなように、各実施例の合成繊維処理剤は、糸揺れ、ローラー汚れ、染色性の評価がいずれも良好であった。本発明によれば、合成繊維の紡糸工程において、ゴデットローラー上での糸揺れ、ゴデットローラーの汚れを低減し、染色性の良好な合成繊維を得ることができるという効果が生じる。   As is clear from the results in Table 1, the synthetic fiber treatment agent of each example was good in all of the evaluation of yarn sway, roller stain, and dyeability. According to the present invention, in the process of spinning synthetic fibers, the effect of reducing yarn sway on the godet roller and dirt of the godet roller can be reduced, and synthetic fibers with good dyeability can be obtained.

Claims (7)

平滑剤として分子中にエステル結合を3つ以上有するエステル化合物、及び分子中に硫黄元素を有するエステル化合物から選ばれる少なくとも一種のエステル化合物を含み、ストレート給油に用いられる合成繊維用処理剤であって、前記合成繊維用処理剤中における水分量が0.1〜5質量%であることを特徴とする合成繊維用処理剤。   A treating agent for synthetic fibers used for straight refueling, comprising at least one ester compound selected from ester compounds having three or more ester bonds in the molecule and ester compounds having sulfur element in the molecule as a leveling agent. A processing agent for synthetic fiber, wherein the water content in the processing agent for synthetic fiber is 0.1 to 5% by mass. さらに非イオン界面活性剤、及びイオン界面活性剤を含む請求項1に記載の合成繊維用処理剤。   The processing agent for synthetic fibers according to claim 1, further comprising a nonionic surfactant and an ionic surfactant. 前記イオン界面活性剤が、2級アルカンスルホン酸化合物を含み、
前記平滑剤、前記非イオン界面活性剤、及び前記イオン界面活性剤の含有割合の合計を100質量%とすると、前記2級アルカンスルホン酸化合物の含有割合が0.01〜10質量%である請求項2に記載の合成繊維用処理剤。
The ionic surfactant comprises a secondary alkanesulfonic acid compound,
The total content of the leveling agent, the nonionic surfactant, and the ionic surfactant is 100% by mass, and the content ratio of the secondary alkanesulfonic acid compound is 0.01 to 10% by mass. The processing agent for synthetic fibers as described in item 2.
前記イオン界面活性剤が、有機リン酸エステル化合物を含み、
前記平滑剤、前記非イオン界面活性剤、及び前記イオン界面活性剤の含有割合の合計を100質量%とすると、前記有機リン酸エステル化合物の含有割合が0.01〜10質量%である請求項2又は3に記載の合成繊維用処理剤。
The ionic surfactant comprises an organic phosphoric acid ester compound,
The total content ratio of the leveling agent, the nonionic surfactant, and the ionic surfactant is 100% by mass, and the content ratio of the organic phosphoric acid ester compound is 0.01 to 10% by mass. The processing agent for synthetic fibers as described in 2 or 3.
前記平滑剤、前記非イオン界面活性剤、及び前記イオン界面活性剤の含有割合の合計を100質量部とすると、希釈剤を0.1〜400質量部の割合で含む請求項2〜4のいずれか一項に記載の合成繊維用処理剤。   The total content of the leveling agent, the nonionic surfactant, and the ionic surfactant is 100 parts by mass, and the diluent is contained in a ratio of 0.1 to 400 parts by mass. The processing agent for synthetic fibers according to any one of the preceding claims. 前記合成繊維用処理剤中の水分量が0.5〜2.0質量%である請求項1〜5のいずれか一項に記載の合成繊維用処理剤。   The water content in the said process agent for synthetic fibers is 0.5-2.0 mass%, The process agent for synthetic fibers as described in any one of Claims 1-5. 請求項1〜6のいずれか一項に記載の合成繊維用処理剤を、紡糸工程において、合成繊維にストレート給油することを特徴とする合成繊維の製造方法。   A method for producing a synthetic fiber, comprising straight feeding the synthetic fiber according to any one of claims 1 to 6 in the spinning step.
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KR20220154124A (en) 2020-03-27 2022-11-21 마쓰모토유시세이야쿠 가부시키가이샤 Treatment agent for synthetic fibers and its use
KR20240015632A (en) 2021-05-31 2024-02-05 마쓰모토유시세이야쿠 가부시키가이샤 Dilution of treatment agent for synthetic fibers and its use
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