CN108867041A - A kind of short rayon fiber oiling agent and its application - Google Patents
A kind of short rayon fiber oiling agent and its application Download PDFInfo
- Publication number
- CN108867041A CN108867041A CN201810477347.3A CN201810477347A CN108867041A CN 108867041 A CN108867041 A CN 108867041A CN 201810477347 A CN201810477347 A CN 201810477347A CN 108867041 A CN108867041 A CN 108867041A
- Authority
- CN
- China
- Prior art keywords
- agent
- preferred
- rayon fiber
- polyoxyethylene ether
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Abstract
The present invention relates to a kind of development of short rayon fiber oiling agent and its application, belong to the auxiliary agent manufacturing technology field in synthetic fibers processing technology.A kind of short rayon fiber oiling agent of the present invention, including:Smooth agent 30~80%;Poising agent 10~60%;Antistatic agent 5~16%.The present invention provides a kind of short rayon fiber spinning oils, it is good using antistatic effect when the patent finish in the case where weather humidity changes greatly, there is good flatness and convergence, it is able to satisfy short rayon fiber spinning technique requirement, and the textile auxiliary that biological degradability is good.
Description
Technical field
The present invention relates to a kind of development of short rayon fiber oiling agent and its applications, belong to the auxiliary agent in synthetic fibers processing technology
Manufacturing technology field.
Background technique
The main production raw material of viscose rayon is cotton linter, wood pulp and bagasse, and raw materials for production are resourceful, manufacture at
This is low, and viscose rayon good hygroscopicity, and easy to dye, fabric is comfortable and easy to wear.It is blended with synthetic fibers with it, it can also promote fabric
Wearability.Viscose staple fibre purposes therein is most wide, pure can spin it is pure knit, can also blended union, for producing clothing with knitting
Object.
Viscose rayon has intensity low, and porous structure is presented in fiber surface, has rough section, easily moisture absorption
Basic Physical Properties.Corresponding to this physical characteristic, the requirement to short rayon fiber oiling agent is:Viscose fiber strength is lower than terylene, because
This needs to improve the flatness of finish, reduces the damage in spinning process to fiber;The hygroscopicity of viscose rayon is stronger, for river
Zhejiang local climate humidity changes greatly, and needs finish starting monomer to change humidity insensitive, when oiling, has to fiber certain
Convergence and antistatic property.
Current domestic short rayon fiber oiling agent is compared with import short rayon fiber oiling agent, and it is poor that there are still climate adaptabilities, after oiling
Short rayon fiber spinnability in later process performance compared with using import finish poor.
Number of patent application is:CN 1118385A, patent name are:Short rayon fiber oiling agent, mainly using open chain quaternary ammonium salt,
Polyol esters of fatty acids, fatty alcohol and aliphatic ester smooth agent, alcohol ether type nonionic surfactant and water.Open chain quaternary ammonium salt is
A kind of cationic surfactant, poor chemical stability is volatile, larger to human toxicity and irritation, and to Weaving device
There is certain corrosivity.
Number of patent application is:CN201210271788.0, patent name are:A kind of viscose fiber spinning oiling agent, main group
At component:42~55 parts of arctic sperm oil sodium sulfovinate, 20~35 parts of laurilsulfate sodium, polyol esters of fatty acids 5~10
Part, 3~5 parts of nonionic surfactant, 12~17 parts of neutral oil, 2~5 parts of polyethers.Forbid from the United Nations's animal protection tissue
After catching and killing whale, with whale, related product almost disappeares at home, on the market without industrial arctic sperm oil Related product.
Number of patent application is:CN201010282874.2, patent name are viscose fiber spinning oiling agent, are mainly formed into
Part:30~40 parts of arctic sperm oil sodium sulfovinate, 5~10 parts of polyol esters of fatty acids, 20~30 parts of whale oil sodium sulfovinate, oleyl alcohol are poly-
Ethylene oxide(5)10~20 parts of ether, 20~30 parts of mineral oil.Also arctic sperm oil sodium sulfovinate and whale oil sulfuric acid are used in the patent
Ester sodium, problem are same as above.
Number of patent application is:CN200810234629.7, patent name are:Viscose oil agent, main constituent component:Ingot
Seed oil 30~45%, turkey red oil 10~20%, OP-10 5~10%, triethanolamine 2~3%, softening agent DC 2~5%, water 20~
40%.Antistatic agent is not used in the patent, in weather humidity hour, antistatic property is obviously inadequate;And in the viscose oil agent
OP-10 uses more than 5%, OP-10 and belongs to a kind of alkylbenzene polyoxyethylene ether product(APEO), APEO product is to eyes and skin
It is irritant, there is teratogenesis, induced pain, mutagens are anisotropic, are not easily decomposed in the environment, easily accumulate.Present European Union member countries are to spinning
The APEO that fabric kimonos is loaded onto has clearly limitation regulation.There is a fixing to outlet using the textile containing the substance finish
It rings.
Summary of the invention
The object of the present invention is to provide a kind of short rayon fiber spinning oils to make in the case where weather humidity changes greatly
It is good with antistatic effect when the patent finish, there is good flatness and convergence, be able to satisfy short rayon fiber spinning technique and want
It asks, and biological degradability is good, is a kind of environmentally friendly textile auxiliary.In order to achieve the above objectives, the technical side that the present invention takes
Case is:
A kind of short rayon fiber oiling agent, including:Smooth agent 30~80%;Poising agent 10~60%;Antistatic agent 5~15%.
A kind of short rayon fiber oiling agent, it is preferable that smooth agent is 45~70%, poising agent 15~40%, antistatic agent 6~15%.
The preferred mineral oil of the smooth agent, C8~C24 fatty alcohol acid ester, polyol esters of fatty acids or C10~C24 fat
One of alcohol polyoxyethylene ether fatty ester or a variety of mixtures.
Preferred C10~C24 the aliphatic alcohol polyether of the poising agent, cithrol, castor oil polyoxyethylene ether or
One of Isosorbide Dinitrate or a variety of mixtures.
The antistatic agent preferred anionic surfactant and amphoteric surfactant;The anionic surfactant
It is preferred that sodium secondary alkyl sulfonate, one of fatty alcohol polyoxyethylene ether phosphate or fatty acid sulfoalkyl amide or a variety of mixing
Object;The preferred betaine type amphoteric surfactant of antistatic agent amphoteric surfactant.
The preferred 15# white oil of mineral oil, 26# white oil or 32# white oil;The preferred C12- of C8~C24 fatty alcohol acid ester
C14 fatty alcohol oleate, oleyl alcohol stearate or C16-C18 fatty acid octanol ester;The preferred stearic acid of polyol esters of fatty acids is sweet
Grease, pentaerythrite laurate, pentaerythritol oleate or dioctyl sebacate;C10~C24 aliphatic alcohol polyethenoxy
The ether fatty acid ester alcohol polyoxyethylene ether laurate of preferred C12~14, isomery C13 alcohol polyoxyethylene ether cocounut oil acid esters or octanol are poly-
Ethylene oxide oleic acid ester;
The preferably secondary dodecyl polyoxyethylene ether of C10~C24 aliphatic alcohol polyether, the alcohol polyoxyethylene polyoxypropylene of C12~14
Ether or the aliphatic alcohol polyether of C16~18;The preferred PEG264 oleic acid monoester of cithrol, PEG400 lauric acid are double
Ester, PEG400 oleic acid monoester or dibasic acid esters, PEG800 Glycol Oleic Acid Ester or PEG400 laurel acid diester;The castor oil polyoxyethylene ether
It is preferred that castor oil polyoxyethylene ether(10EO)~(90EO);The preferred Span-20 of Isosorbide Dinitrate, Span-40 or
Span-80。
The preferably secondary dodecyl sodium sulfate of the sodium secondary alkyl sulfonate, the preferred octanol of aliphatic alcohol polyoxyvinethene phosphate salt
Polyoxyethylene ether phosphate sylvite, positive C10 polyoxyethylene ether phosphate sylvite, C12-14 alcohol polyoxyethylene ether phosphate sylvite,
Isomery C13 alcohol polyoxyethylene ether phosphate sylvite or C16-18 aliphatic alcohol polyoxyvinethene phosphate sylvite;The fatty acid sulphur
The preferred N- oleoyl-N methyl taurine sodium of alkylamide or N- cocoyl-N methyl taurine sodium.
The preferred sulfobetaines of betaine type amphoteric surfactant.
A kind of short rayon fiber oiling agent is applied to be used as short rayon fiber oiling agent.
The betaine type amphoteric surfactant is preferably but not limited to sulfobetaines.Betaine type amphoteric surfactant is preferred
But it is not limited to sulfobetaines.Sulfobetaines has good emulsibility and antistatic property and bactericidal properties and suppression mouldiness.
Make wear-resistant, anticorrosive additive in the lubricant, no related betaine type amphoteric surfactant is as short rayon fiber antistatic agent.
In view of the smooth agent for also having higher percent in short-fiber oil agent(That is lubricant), the sulfo group of certain percentage is used in this patent
Glycine betaine obtains good effect mainly as antistatic agent and wear-resistant, the anticorrosive additive of smooth agent.By using
The short rayon fiber oiling agent that the present invention obtains, effective component are 90% or so, 4g/L aqueous solution 24 hours not stratified, no precipitatings;?
Process conditions when chemical fibre factory's use are:2.0~5.0g/L, upper oil temperature are 35 DEG C, attachment of 6 short-fiber oil agent of polyamide fibre to fiber
Amount is usually 0.15~0.3% relative to the weight percent of fiber.
Specific embodiment
Embodiment 1
By 8kg castor oil polyoxyethylene ether(90EO), the alcohol of 3kg C12~14 polyoxyethylene (4EO) polyethenoxy ether(5PO)With
The combined balance system agent of 5kg PEG264 oleic acid monoester, the secondary dodecyl sodium sulfate of 9kg and 6kg N- oleoyl-N methyl taurine
The antistatic agent of sodium, the mixing smooth agent of 24kg15# white oil, 16.5kg dioctyl sebacate and 17kg oleic acid stearate, 9kg
Deionized water, 2kg oleic acid, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C, and the time is 2 small
When, short rayon fiber oiling agent is made after filtering.
Embodiment 2
By 7kg ethoxylated dodecyl alcohol(8EO)Oleate, 4.5kg PEG264 oleic acid monoester and 4kg castor oil polyoxyethylene
Ether(20EO)Combined balance system agent, 3kg N- cocoyl-N methyl taurine sodium and 3kg cetyl sulfobetaines it is mixed
Conjunction antistatic agent, the mixing smooth agent of 21kg32# white oil, 25kg tristerin and 20kg C12-14 fatty alcohol oleate,
The deionized water of 9kg, 3kg tetradecyl alchohol, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C, the time
It is 2 hours, short rayon fiber oiling agent is made after filtering.
Embodiment 3
By 26kg PEG400 Glycol Oleic Acid Ester, 14kg isomerous tridecanol polyoxyethylene ether(7EO)Combined balance system agent, positive ten alcohol of 3Kg
Phosphoric acid ester APEO(5EO)Phosphate kalium salt, the antistatic agent of 3kg dodecyl sulfobetaine, 25kg26# white oil,
12kg oleic acid stearate, the mixing smooth agent of 8kg pentaerythritol oleate, the deionized water of 8.5kg, 1kg oleic acid, 0.5kg
Preservative is mixed evenly in reaction kettle, and whipping temp is 60 DEG C, and the time is 2 hours, and short rayon fiber oil is made after filtering
Agent.
Embodiment 4
By the fatty alcohol polyoxyethylene ether of 8kg C12~14(7EO), 7kg PEG400 Glycol Oleic Acid Ester combined balance system agent, 6.5kg
The fatty alcohol polyoxyethylene ether of C12~14(7EO), 2kg N- cocoyl-N methyl taurine sodium mixing antistatic agent,
35kg15# white oil, 10kg oleic acid polyoxyethylene(4EO)The mixing smooth agent of laurate, the deionized water of 7kg, 2kg oil
Acid, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C, and the time is 2 hours, are made viscous after filtering
Glue short-fiber oil agent.
Embodiment 5
By 20kg C16-18 fatty alcohol polyoxyethylene ether(7EO), 15kg castor oil polyoxyethylene ether(90EO)Combined balance system
Agent, 5kg octanol polyoxyethylene ether(5EO)The mixing antistatic agent of the secondary dodecyl sodium sulfate of phosphate kalium salt, 8kg, 28kg season
Penta tetrol laurate, 22kg octanol polyoxyethylene ether(9EO)The mixing smooth agent of oleate, the deionized water of 8.5kg, 3kg
Oleic acid, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C, and the time is 2 hours, are made after filtering
Short rayon fiber oiling agent.
Embodiment 6
By 10kg isomery C13 alcohol polyoxyethylene ether(7EO)With 9kg castor oil polyoxyethylene ether(20EO)Combined balance system agent, 4kg
Isomery C13 alcohol polyoxyethylene ether(3EO)The mixing antistatic agent of phosphate kalium salt and 6.5kg myristyl sulfobetaines,
18kg26# white oil, 28kg tristerin, 12kg C16-18 fatty acid octanol ester mixing smooth agent, the deionization of 9kg
Water, 3kg oleic acid, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C, and the time is 2 hours, filtering
Short rayon fiber oiling agent is made afterwards.
Comparative example 1
By 19kgPEG400 oleic acid monoester, 16kg castor oil polyoxyethylene ether(80EO)With the combined balance system agent of 6kgSpan-80,
The mixing of the antistatic agent of 2.5kg myristyl sulfobetaines, 20kg26# white oil and 20kgC16-18 glycerol trioleate is flat
Lubrication prescription, the deionized water of 8kg, 1kg oleic acid, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C,
Time is 2 hours, and short rayon fiber oiling agent is made after filtering.
Comparative example 2
By 11kgPEG264 oleic acid monoester, 4kg castor oil polyoxyethylene ether(60EO)With 4.5kg isomery C13 polyoxyethylene ether
(7EO)Combined balance system agent, the mixing smooth agent of 31kg15# white oil, 28kg tristerin, the deionized water of 8kg, 2kg
Oleic acid, 0.5kg preservative are mixed evenly in reaction kettle, and whipping temp is 60 DEG C, and the time is 2 hours, are made after filtering
Short rayon fiber oiling agent.(The present embodiment does not add electrostatic agent)
A kind of short rayon fiber spinning oil obtained through this embodiment changes compared with existing domestic finish in weather humidity
It is good using antistatic effect when the patent finish in biggish situation, there is good flatness and convergence, be able to satisfy viscose glue
Short fibre spinning technique requirement, does not have corrosivity to equipment, and biological degradability is good, is a kind of environmentally friendly textile auxiliary.
Two comparative example finishes are chosen, and in embodiment finish together in cotton product(1.11dtex*38mm)Viscose glue
It is tried out on short fibre, investigates its practical textile processibility energy, process conditions are 3.5g/L for the emulsion concentration that oils, upper oil temperature
It is 35 DEG C.Finish rear short rayon fiber quality index on probation is mainly reflected in the service performance investigation of finish, is glued after practical probation
The short fine quality index of glue is as shown in table 1.
The short fine quality index of 1 viscose of table
Claims (10)
1. a kind of short rayon fiber oiling agent, it is characterised in that including:Smooth agent 30~80%;Poising agent 10~60%;Antistatic agent 5~
15%。
2. a kind of short rayon fiber oiling agent as described in claim 1, it is characterised in that including:Smooth agent is 45~70%, poising agent
15~40%, antistatic agent 6~15%.
3. a kind of short rayon fiber oiling agent as described in claim 1, it is characterised in that:The preferred mineral oil of the smooth agent, C8
~C24 fatty alcohol acid ester, one of polyol esters of fatty acids or C10~C24 fatty alcohol polyoxyethylene ether aliphatic ester or more
The mixture of kind.
4. a kind of short rayon fiber oiling agent as described in claim 1, it is characterised in that:Preferred C10~C24 the fat of poising agent
One of alcohol polyethers, cithrol, castor oil polyoxyethylene ether or Isosorbide Dinitrate or a variety of mixtures.
5. a kind of short rayon fiber oiling agent as described in claim 1, it is characterised in that:Antistatic agent preferred anionic surface
Activating agent and amphoteric surfactant;The preferred sodium secondary alkyl sulfonate of anionic surfactant, fatty alcohol polyoxyethylene ether
One of phosphate or fatty acid sulfoalkyl amide or a variety of mixtures;The antistatic agent amphoteric surfactant is preferred
Betaine type amphoteric surfactant.
6. a kind of short rayon fiber oiling agent as claimed in claim 3, it is characterised in that:The preferred 15# white oil of mineral oil, 26#
White oil or 32# white oil;The preferred C12-C14 fatty alcohol oleate of C8~C24 fatty alcohol acid ester, oleyl alcohol stearate or
C16-C18 fatty acid octanol ester;The preferred tristerin of polyol esters of fatty acids, pentaerythrite laurate, pentaerythrite
Oleate or dioctyl sebacate;C10~C24 fatty alcohol polyoxyethylene ether aliphatic ester preferred C12~14 alcohol polyoxy second
Alkene ether laurate, isomery C13 alcohol polyoxyethylene ether cocounut oil acid esters or octanol polyoxyethylene oleic acid ester.
7. a kind of short rayon fiber oiling agent as claimed in claim 4, it is characterised in that:C10~C24 aliphatic alcohol polyether is preferred
Secondary dodecyl polyoxyethylene ether, the alcohol of C12~14 polyoxyethylene poly-oxygen propylene aether or the aliphatic alcohol polyether of C16~18;The poly- second
The preferred PEG264 oleic acid monoester of diol fatty acid ester, PEG400 laurel acid diester, PEG400 oleic acid monoester or dibasic acid esters, PEG800 oil
Acid diester or PEG400 laurel acid diester;The preferred castor oil polyoxyethylene ether of castor oil polyoxyethylene ether(10EO)~
(90EO);Isosorbide Dinitrate preferred Span-20, Span-40 or the Span-80.
8. a kind of short rayon fiber oiling agent as claimed in claim 5, it is characterised in that:The sodium secondary alkyl sulfonate preferably secondary 12
Sodium alkyl sulfonate, the preferred octanol polyoxyethylene ether phosphate sylvite of aliphatic alcohol polyoxyvinethene phosphate salt, positive C10 polyoxyethylene
Ether phosphate sylvite, C12-14 alcohol polyoxyethylene ether phosphate sylvite, isomery C13 alcohol polyoxyethylene ether phosphate sylvite or C16-
18 aliphatic alcohol polyoxyvinethene phosphate sylvite;The preferred N- oleoyl-N methyl taurine sodium of fatty acid sulfoalkyl amide
Or N- cocoyl-N methyl taurine sodium.
9. a kind of short rayon fiber oiling agent as claimed in claim 5, it is characterised in that:The betaine type amphoteric surfactant is preferred
Sulfobetaines.
10. a kind of short rayon fiber oiling agent as described in claim 1 is applied to be used as short rayon fiber oiling agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810477347.3A CN108867041A (en) | 2018-05-18 | 2018-05-18 | A kind of short rayon fiber oiling agent and its application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810477347.3A CN108867041A (en) | 2018-05-18 | 2018-05-18 | A kind of short rayon fiber oiling agent and its application |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108867041A true CN108867041A (en) | 2018-11-23 |
Family
ID=64333827
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810477347.3A Pending CN108867041A (en) | 2018-05-18 | 2018-05-18 | A kind of short rayon fiber oiling agent and its application |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108867041A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110952319A (en) * | 2018-12-13 | 2020-04-03 | 竹本油脂株式会社 | Treating agent for synthetic fiber and method for producing synthetic fiber |
CN113373687A (en) * | 2020-02-25 | 2021-09-10 | 三吉油脂株式会社 | Agent for treating artificial silk ear barrel and artificial silk ear barrel using same |
CN114351450A (en) * | 2022-01-13 | 2022-04-15 | 沈阳浩博实业有限公司 | Oil agent for semi-continuous spinning viscose filament yarn and preparation method and application thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2738324A (en) * | 1952-08-29 | 1956-03-13 | American Cyanamid Co | Anti-static rayon oils |
CN101858036A (en) * | 2010-06-04 | 2010-10-13 | 上海里奥纤维企业发展有限公司 | Solvent method fiber treatment oil solution |
CN102535168A (en) * | 2012-02-15 | 2012-07-04 | 成都丽雅纤维股份有限公司 | Oil agent for producing pupa protein viscose staple fibers and preparation method thereof |
CN102912640A (en) * | 2012-10-25 | 2013-02-06 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
CN105064019A (en) * | 2015-07-31 | 2015-11-18 | 浙江皇马科技股份有限公司 | Nylon 6 short fiber spinning oil agent, preparation method and application thereof |
CN106245326A (en) * | 2016-08-17 | 2016-12-21 | 河北科技大学 | A kind of rayon staple spinning oil preparation |
JP2018071013A (en) * | 2016-10-26 | 2018-05-10 | 竹本油脂株式会社 | Fiber treatment agent for span lace and manufacturing method of span lace unwoven fabric |
-
2018
- 2018-05-18 CN CN201810477347.3A patent/CN108867041A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2738324A (en) * | 1952-08-29 | 1956-03-13 | American Cyanamid Co | Anti-static rayon oils |
CN101858036A (en) * | 2010-06-04 | 2010-10-13 | 上海里奥纤维企业发展有限公司 | Solvent method fiber treatment oil solution |
CN102535168A (en) * | 2012-02-15 | 2012-07-04 | 成都丽雅纤维股份有限公司 | Oil agent for producing pupa protein viscose staple fibers and preparation method thereof |
CN102912640A (en) * | 2012-10-25 | 2013-02-06 | 上虞市皇马化学有限公司 | Crude-oil polyester industrial yarn finish and preparation method thereof |
CN105064019A (en) * | 2015-07-31 | 2015-11-18 | 浙江皇马科技股份有限公司 | Nylon 6 short fiber spinning oil agent, preparation method and application thereof |
CN106245326A (en) * | 2016-08-17 | 2016-12-21 | 河北科技大学 | A kind of rayon staple spinning oil preparation |
JP2018071013A (en) * | 2016-10-26 | 2018-05-10 | 竹本油脂株式会社 | Fiber treatment agent for span lace and manufacturing method of span lace unwoven fabric |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110952319A (en) * | 2018-12-13 | 2020-04-03 | 竹本油脂株式会社 | Treating agent for synthetic fiber and method for producing synthetic fiber |
CN113373687A (en) * | 2020-02-25 | 2021-09-10 | 三吉油脂株式会社 | Agent for treating artificial silk ear barrel and artificial silk ear barrel using same |
CN114351450A (en) * | 2022-01-13 | 2022-04-15 | 沈阳浩博实业有限公司 | Oil agent for semi-continuous spinning viscose filament yarn and preparation method and application thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108867041A (en) | A kind of short rayon fiber oiling agent and its application | |
DE2335044C2 (en) | laundry detergent | |
CN101629130B (en) | Fabric one-bath deoiling agent | |
EP0743358B1 (en) | Composition for washing and cleaning of textile materials | |
WO2011117079A1 (en) | Washing, cleaning or pretreatment composition with increased fat dissolving power | |
AT510811A2 (en) | WET DETERGENT CLOTH | |
EP2804937B1 (en) | Washing, cleaning or pre-treatment agent with increased cleaning power | |
US20050262643A1 (en) | Lubrication of textile fibres | |
WO2013186170A1 (en) | Detergent, cleaning agent, or pretreatment agent having greater cleaning power ii | |
JPH0756112B2 (en) | Concentrated softening agent for clothing | |
JP2019182970A (en) | Liquid detergent for fiber product | |
JP7344418B2 (en) | Softener | |
US4426298A (en) | Textile processing oils | |
JPH0437185B2 (en) | ||
JP4791404B2 (en) | Scouring agent composition for polyurethane fiber and polyurethane mixed fiber | |
CH661743A5 (en) | STABLE AQUEOUS LIQUID DETERGENT. | |
EP2631287B1 (en) | Washing with fibres | |
JP4468685B2 (en) | Softener composition | |
DE1769585A1 (en) | Melt for the textile industry | |
AT212473B (en) | Cleaning preparations | |
DE102013210271A1 (en) | Washing, cleaning or pretreatment agent with increased cleaning power III | |
AT210380B (en) | Fat- and oil-free lubricants for the wool industry | |
AU2003206786B2 (en) | Use of ethoxylated fatty acids as smoothing agents for synthetic and natural fibres | |
JPH11350344A (en) | Lubricant composition for textile fiber | |
CN101248232A (en) | Spinning baths |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |