JP6516728B2 - 層状物質含有液及びその製造方法 - Google Patents
層状物質含有液及びその製造方法 Download PDFInfo
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- JP6516728B2 JP6516728B2 JP2016513680A JP2016513680A JP6516728B2 JP 6516728 B2 JP6516728 B2 JP 6516728B2 JP 2016513680 A JP2016513680 A JP 2016513680A JP 2016513680 A JP2016513680 A JP 2016513680A JP 6516728 B2 JP6516728 B2 JP 6516728B2
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- 125000005489 p-toluenesulfonic acid group Chemical group 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229910000269 smectite group Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- VDNSGQQAZRMTCI-UHFFFAOYSA-N sulfanylidenegermanium Chemical compound [Ge]=S VDNSGQQAZRMTCI-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- ALRFTTOJSPMYSY-UHFFFAOYSA-N tin disulfide Chemical compound S=[Sn]=S ALRFTTOJSPMYSY-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- XWPGCGMKBKONAU-UHFFFAOYSA-N zirconium(4+);disulfide Chemical compound [S-2].[S-2].[Zr+4] XWPGCGMKBKONAU-UHFFFAOYSA-N 0.000 description 1
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Description
1−1.イオン液体
1−1−1.カチオン
1−1−2.アニオン
1−2.層状物質
1−3.他の材料
2.層状物質含有液の製造方法
2−1.層状物質含有液の調製
2−2.層状物質含有液の精製
3.作用及び効果
まず、層状物質含有液の構成について説明する。
イオン液体は、液体の塩であり、カチオン及びアニオンを含んでいる。
カチオンは、下記の式(1)で表される陽イオンのうちのいずれか1種類又は2種類以上を含んでいる。
アニオンは、任意の陰イオンのうちのいずれか1種類又は2種類以上を含んでいる。
層状物質は、上記したように、2種類以上の元素を構成元素として含んでいる層状の薄い物質(多元素層状物質)であり、いわゆるナノシートである。
尚、層状物質含有液は、上記したイオン液体及び層状物質と一緒に、他の材料のうちのいずれか1種類又は2種類以上を含んでいてもよい。
次に、上記した層状物質含有液の製造方法について説明する。尚、以下では、複数の層状物質が積層された多層構造を有する積層物を「層状積層物」という。
層状物質含有液を調製する場合には、最初に、例えば、任意の合成手順により、式(1)に示したカチオンのうちのいずれか1種類又は2種類以上を含むイオン液体を合成する。尚、アニオンの種類は、任意でよい。
層状物質含有液を調整した後、必要に応じて、その層状物質含有液を精製してもよい。
上記した層状物質含有液及びその製造方法によれば、式(1)に示したカチオンを含むイオン液体に層状積層物を含有させて、その層状積層物を含有するイオン液体に音波等を照射している。この場合には、含有処理及び照射処理という簡単な処理だけを用いているにも関わらず、層状積層物から層状物質が容易に剥離するため、その層状物質がイオン液体中において高濃度に分散される。しかも、層状物質は安定かつ再現性よく剥離するため、その層状物質の層数は均一化すると共に、剥離時において層状物質は破損しにくいため、その層状物質の面積は十分に大きくなる。よって、層状物質が2種類以上の元素を構成元素として含んでいる場合においても、高品質な層状物質を容易に得ることができる。
1.イオン液体の合成
2.層状物質含有液の製造
3.層状物質含有液の評価
[合成例1]
以下の手順により、イオン液体として化合物2を合成した。
また、国際公開公報(WO/2014/175449)に記載されている手順により、イオン液体として化合物3〜5を合成した。
次に、上記したイオン液体(化合物2〜5)を用いて、層状物質含有液を製造した。
イオン液体0.7mlに、層状積層物(二硫化モリブデン:MoS2 )13mgを混合させた。イオン液体の種類は、表1に示した通りである。続いて、乳鉢を用いて混合物を磨り潰して(15分間)、イオン液体中に層状積層物が分散された混合液を得た。この場合には、アルドリッチ社製の二硫化モリブデン(平均粒径(D50)は<2μm,純度=99%)を用いた。続いて、マイクロウェーブ合成装置(Biotage社製Initiator+ )用のバイアル(0.5ml)に混合液0.58gを投入した後、そのバイアルを密閉した。続いて、マイクロウェーブ合成装置を用いて混合液にマイクロ波を照射した。この場合には、出力=17W、照射時間=6時間とした。これにより、層状物質含有液が得られた。
イオン液体(化合物2)1mlに、層状積層物25mgを混合した。層状積層物の種類は、表1に示した通りである。具体的には、層状積層物として、窒化ホウ素(BN,アルドリッチ社製,平均粒径D50=1μm,純度=98%)、二硫化スズ(SnS2 ,三津和化学薬品株式会社製)、テルル化モリブデン(MoTe2 ,三津和化学薬品株式会社製)、硫化ゲルマニウム(GeS,三津和化学薬品株式会社製)、二硫化ジルコニウム(ZrS2 ,三津和化学薬品株式会社製)、セレン化ニオブ(NbSe2 ,三津和化学薬品株式会社製)、タルク(和光純薬工業株式会社製)及び合成雲母(和光純薬工業株式会社製)を用いた。この後、実験例1〜4と同様の手順を経て、層状物質含有液を得た。
次に、X線回折(XRD)法を用いて、層状物質含有液を分析した。この場合には、照射処理前の層状物質含有液及び照射処理後の層状物質含有液のそれぞれを試料板の表面に塗布して、分析用サンプルを作製した。また、XRD法として、集中法を採用した。
Claims (5)
- 下記の式(1)で表されるカチオンを含むイオン液体と、
2種類以上の元素を構成元素として含む層状物質と
を含有し、
前記層状物質は、金属カルコゲン化物、金属酸化物・金属オキシハロゲン化物、金属リン酸塩、粘土鉱物・ケイ酸塩、複水酸化物、層状チタン酸化物、層状ペロブスカイト酸化物及び窒化ホウ素類のうちの少なくとも1種を含む、
層状物質含有液。
- 下記の式(1)で表されるカチオンを含むイオン液体に、2種類以上の元素を構成元素として含む層状物質の積層物を含有させて、
その積層物を含有するイオン液体に、音波及び電波のうちの少なくとも一方を照射し、
前記層状物質は、金属カルコゲン化物、金属酸化物・金属オキシハロゲン化物、金属リン酸塩、粘土鉱物・ケイ酸塩、複水酸化物、層状チタン酸化物、層状ペロブスカイト酸化物及び窒化ホウ素類のうちの少なくとも1種を含む、
層状物質含有液の製造方法。
- 前記音波として超音波を用いると共に、前記電波としてマイクロ波を用いる、
請求項2記載の層状物質含有液の製造方法。 - 音波及び電波のうちの少なくとも一方が照射された前記イオン液体を遠心分離する、
請求項2又は請求項3に記載の層状物質含有液の製造方法。 - 遠心分離された前記イオン液体から液相を回収する、
請求項4記載の層状物質含有液の製造方法。
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US20150004733A1 (en) * | 2013-06-27 | 2015-01-01 | The Board Of Trustees Of The University Of Alabama | Exfoliation of thermoelectric materials and transition metal dichalcogenides using ionic liquids |
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CN106414336B (zh) | 2019-08-13 |
KR102301298B1 (ko) | 2021-09-10 |
KR20160146789A (ko) | 2016-12-21 |
TW201540709A (zh) | 2015-11-01 |
EP3144279A4 (en) | 2018-04-18 |
WO2015159635A1 (ja) | 2015-10-22 |
US20170095784A1 (en) | 2017-04-06 |
CN106414336A (zh) | 2017-02-15 |
TWI702213B (zh) | 2020-08-21 |
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