JP6511199B2 - アルカリ金属水酸化物の使用と、非水性変換剤の遅延添加とによるカルシウムスルホネートグリースの製造 - Google Patents
アルカリ金属水酸化物の使用と、非水性変換剤の遅延添加とによるカルシウムスルホネートグリースの製造 Download PDFInfo
- Publication number
- JP6511199B2 JP6511199B2 JP2018535335A JP2018535335A JP6511199B2 JP 6511199 B2 JP6511199 B2 JP 6511199B2 JP 2018535335 A JP2018535335 A JP 2018535335A JP 2018535335 A JP2018535335 A JP 2018535335A JP 6511199 B2 JP6511199 B2 JP 6511199B2
- Authority
- JP
- Japan
- Prior art keywords
- added
- grease
- calcium
- conversion
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004519 grease Substances 0.000 title claims description 564
- 238000006243 chemical reaction Methods 0.000 title claims description 429
- 239000011575 calcium Substances 0.000 title claims description 418
- 229910052791 calcium Inorganic materials 0.000 title claims description 406
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims description 384
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 title claims description 306
- 239000003795 chemical substances by application Substances 0.000 title claims description 208
- 150000008044 alkali metal hydroxides Chemical class 0.000 title claims description 118
- 230000003111 delayed effect Effects 0.000 title description 82
- 238000004519 manufacturing process Methods 0.000 title description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 320
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 246
- 239000000203 mixture Substances 0.000 claims description 212
- 238000000034 method Methods 0.000 claims description 177
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 165
- 238000002156 mixing Methods 0.000 claims description 163
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 162
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 160
- 239000002253 acid Substances 0.000 claims description 131
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 claims description 121
- 239000002199 base oil Substances 0.000 claims description 116
- 230000000536 complexating effect Effects 0.000 claims description 108
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 106
- 239000000920 calcium hydroxide Substances 0.000 claims description 104
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 104
- 238000010438 heat treatment Methods 0.000 claims description 104
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical group CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 78
- -1 glycol ethers Chemical class 0.000 claims description 63
- 239000002585 base Substances 0.000 claims description 61
- 229940114072 12-hydroxystearic acid Drugs 0.000 claims description 60
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 60
- 150000007513 acids Chemical class 0.000 claims description 56
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 47
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 46
- 239000000292 calcium oxide Substances 0.000 claims description 45
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 42
- 229940051250 hexylene glycol Drugs 0.000 claims description 39
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 23
- 239000004327 boric acid Substances 0.000 claims description 23
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 21
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 18
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 6
- 150000002334 glycols Chemical class 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 230000009466 transformation Effects 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 1
- 238000007792 addition Methods 0.000 description 243
- 239000003513 alkali Substances 0.000 description 80
- 239000002562 thickening agent Substances 0.000 description 69
- 229960000583 acetic acid Drugs 0.000 description 64
- 230000035515 penetration Effects 0.000 description 60
- 239000002245 particle Substances 0.000 description 59
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 46
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 45
- 230000008569 process Effects 0.000 description 44
- 235000012255 calcium oxide Nutrition 0.000 description 43
- 229940087373 calcium oxide Drugs 0.000 description 43
- 235000013305 food Nutrition 0.000 description 42
- 239000012362 glacial acetic acid Substances 0.000 description 39
- 238000003756 stirring Methods 0.000 description 36
- 229940092714 benzenesulfonic acid Drugs 0.000 description 30
- 229910021532 Calcite Inorganic materials 0.000 description 23
- 235000014113 dietary fatty acids Nutrition 0.000 description 23
- 239000000194 fatty acid Substances 0.000 description 23
- 229930195729 fatty acid Natural products 0.000 description 23
- 150000004665 fatty acids Chemical class 0.000 description 18
- 230000006872 improvement Effects 0.000 description 18
- 238000001816 cooling Methods 0.000 description 17
- 238000001704 evaporation Methods 0.000 description 17
- 230000008020 evaporation Effects 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 17
- 239000000344 soap Substances 0.000 description 17
- 230000008719 thickening Effects 0.000 description 17
- 239000008256 whipped cream Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- 239000003963 antioxidant agent Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 15
- 230000014759 maintenance of location Effects 0.000 description 15
- 230000007935 neutral effect Effects 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 239000007787 solid Substances 0.000 description 15
- 230000003078 antioxidant effect Effects 0.000 description 14
- 150000004982 aromatic amines Chemical class 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 239000000843 powder Substances 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 12
- 239000001506 calcium phosphate Substances 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 11
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 11
- 229940078499 tricalcium phosphate Drugs 0.000 description 11
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 11
- 235000019731 tricalcium phosphate Nutrition 0.000 description 11
- 229940095564 anhydrous calcium sulfate Drugs 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 230000000996 additive effect Effects 0.000 description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 235000010755 mineral Nutrition 0.000 description 8
- 239000011707 mineral Substances 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 239000002530 phenolic antioxidant Substances 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 230000001050 lubricating effect Effects 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000005649 metathesis reaction Methods 0.000 description 5
- 239000002105 nanoparticle Substances 0.000 description 5
- 229920013639 polyalphaolefin Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229940043430 calcium compound Drugs 0.000 description 4
- 230000001934 delay Effects 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 229920002367 Polyisobutene Polymers 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052586 apatite Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 3
- 150000001674 calcium compounds Chemical class 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229940095643 calcium hydroxide Drugs 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- 238000007062 Kim reaction Methods 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007866 anti-wear additive Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- LPTWEDZIPSKWDG-UHFFFAOYSA-N benzenesulfonic acid;dodecane Chemical compound OS(=O)(=O)C1=CC=CC=C1.CCCCCCCCCCCC LPTWEDZIPSKWDG-UHFFFAOYSA-N 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 229960002645 boric acid Drugs 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 description 1
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- RVWOWEQKPMPWMQ-UHFFFAOYSA-N methyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OC RVWOWEQKPMPWMQ-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000004682 monohydrates Chemical group 0.000 description 1
- 231100000219 mutagenic Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229940082615 organic nitrates used in cardiac disease Drugs 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000015227 regulation of liquid surface tension Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 229920002545 silicone oil Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001331 thermoregulatory effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/089—Overbased salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/990,473 US9976101B2 (en) | 2011-10-31 | 2016-01-07 | Method of manufacturing calcium sulfonate greases using delayed addition of non-aqueous converting agents |
| US14/990,473 | 2016-01-07 | ||
| US15/130,422 US9976102B2 (en) | 2011-10-31 | 2016-04-15 | Composition and method of manufacturing calcium sulfonate greases using alkali metal hydroxide and delayed addition of non-aqueous converting agents |
| US15/130,422 | 2016-04-15 | ||
| PCT/US2016/066578 WO2017120000A1 (en) | 2016-01-07 | 2016-12-14 | Manufacturing calcium sulfonate greases using alkali metal hydroxide and delayed addition of non-aqueous converting agents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019501266A JP2019501266A (ja) | 2019-01-17 |
| JP6511199B2 true JP6511199B2 (ja) | 2019-05-15 |
Family
ID=59273880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018535335A Active JP6511199B2 (ja) | 2016-01-07 | 2016-12-14 | アルカリ金属水酸化物の使用と、非水性変換剤の遅延添加とによるカルシウムスルホネートグリースの製造 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP3400280B1 (zh) |
| JP (1) | JP6511199B2 (zh) |
| KR (1) | KR102095188B1 (zh) |
| CN (1) | CN108473910B (zh) |
| AU (1) | AU2016385438B2 (zh) |
| BR (1) | BR112018013843B1 (zh) |
| CA (1) | CA3010739C (zh) |
| MX (1) | MX2018008341A (zh) |
| WO (1) | WO2017120000A1 (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7187104B2 (ja) * | 2017-05-22 | 2022-12-12 | コスモ石油ルブリカンツ株式会社 | 食品機械用グリース組成物 |
| CN108949328B (zh) * | 2018-09-05 | 2020-03-10 | 西南交通大学 | 一种复合磺酸钙润滑脂及其制备方法 |
| US20200157459A1 (en) * | 2018-11-20 | 2020-05-21 | Nch Corporation | Composition and Method of Manufacturing Sulfonate-Based Greases Using a Glycerol Derivative |
| CN115820321B (zh) * | 2022-11-22 | 2023-11-14 | 中国石油化工股份有限公司 | 一种复合钙基润滑脂组合物及其制备方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3492231A (en) | 1966-03-17 | 1970-01-27 | Lubrizol Corp | Non-newtonian colloidal disperse system |
| GB1028063A (en) | 1962-04-06 | 1966-05-04 | Lubrizol Corp | Grease composition |
| US3242079A (en) | 1962-04-06 | 1966-03-22 | Lubrizol Corp | Basic metal-containing thickened oil compositions |
| GB1044148A (en) | 1963-09-16 | 1966-09-28 | Lubrizol Corp | Carbonated calcium sulfonate complexes |
| US3377283A (en) | 1967-03-09 | 1968-04-09 | Lubrizol Corp | Process for preparing thickened compositions |
| CA949055A (en) | 1968-05-08 | 1974-06-11 | Continental Oil Company | Method for preparing highly basic grease and rust inhibiting compositions |
| US3671012A (en) | 1970-03-16 | 1972-06-20 | Continental Oil Co | Grease compositions containing polymers |
| US3661622A (en) | 1970-03-16 | 1972-05-09 | Continental Oil Co | Method of improving resistance to corrosion of metal surfaces and resultant article |
| US3746643A (en) | 1970-10-21 | 1973-07-17 | Continental Oil Co | Grease and rust inhibitor compositions |
| US4560489A (en) | 1983-09-14 | 1985-12-24 | Witco Chemical Corporation | High performance calcium borate modified overbased calcium sulfonate complex greases |
| US4929371A (en) | 1986-02-18 | 1990-05-29 | Amoco Corporation | Steel mill grease |
| US4902435A (en) | 1986-02-18 | 1990-02-20 | Amoco Corporation | Grease with calcium soap and polyurea thickener |
| US4787992A (en) | 1986-02-18 | 1988-11-29 | Amoco Corporation | Calcium soap thickened front-wheel drive grease |
| US4830767A (en) | 1986-02-18 | 1989-05-16 | Amoco Corporation | Front-wheel drive grease |
| US4904399A (en) | 1989-03-31 | 1990-02-27 | Amoco Corporation | Process for preventing grease fires in steel mills and other metal processing mills |
| US5126062A (en) | 1991-01-15 | 1992-06-30 | Nch Corporation | Calcium sulfonate grease and method of manufacture |
| US5338467A (en) * | 1993-03-03 | 1994-08-16 | Witco Corporation | Sulfonate grease improvement |
| US5308514A (en) | 1993-03-03 | 1994-05-03 | Witco Corporation | Sulfonate greases |
| US6534450B1 (en) * | 2001-09-28 | 2003-03-18 | Chevron Oronite Company Llc | Dispersed hydrated sodium borate compositions having improved properties in lubricating oil compositions |
| JP2003301190A (ja) * | 2002-02-06 | 2003-10-21 | Nsk Ltd | グリース組成物及び転動装置 |
| JP5363722B2 (ja) | 2006-12-01 | 2013-12-11 | 昭和シェル石油株式会社 | グリース組成物 |
| CN101705143B (zh) * | 2009-11-09 | 2012-12-19 | 鞍山海华油脂化学有限公司 | 一种高极压抗水防锈润滑脂及其制备方法 |
| CN101993767B (zh) | 2010-11-09 | 2014-04-16 | 江苏惠源石油科技有限公司 | 一种含纳米碳酸钙的复合磺酸钙润滑脂及其生产方法 |
| CN102051257B (zh) * | 2010-12-31 | 2013-04-17 | 鞍山海华油脂化学有限公司 | 复合锂基润滑脂及其生产工艺 |
| EP2773589B1 (en) * | 2011-10-31 | 2019-03-13 | NCH Corporation | Calcium hydroxyapatite based calcium sulfonate grease compositions and method of manufacture |
| US9976102B2 (en) * | 2011-10-31 | 2018-05-22 | Nch Corporation | Composition and method of manufacturing calcium sulfonate greases using alkali metal hydroxide and delayed addition of non-aqueous converting agents |
| US9458406B2 (en) * | 2011-10-31 | 2016-10-04 | Nch Corporation | Calcium hydroxyapatite based sulfonate grease compositions and method of manufacture |
| CN103740435B (zh) * | 2014-02-11 | 2015-06-17 | 上海禾泰特种润滑科技股份有限公司 | 一种复合磺酸钙润滑脂组合物及其制备方法 |
| CN104327906A (zh) | 2014-10-25 | 2015-02-04 | 中国石油化工股份有限公司 | 一种改善高温性能的复合磺酸钙基润滑脂的组合物及制备方法 |
| CN104711080B (zh) * | 2015-03-12 | 2018-05-08 | 上海禾泰特种润滑科技股份有限公司 | 改性复合磺酸钙润滑脂及其制备方法 |
-
2016
- 2016-12-14 CN CN201680078383.1A patent/CN108473910B/zh active Active
- 2016-12-14 CA CA3010739A patent/CA3010739C/en active Active
- 2016-12-14 EP EP16884167.4A patent/EP3400280B1/en active Active
- 2016-12-14 BR BR112018013843-6A patent/BR112018013843B1/pt active IP Right Grant
- 2016-12-14 JP JP2018535335A patent/JP6511199B2/ja active Active
- 2016-12-14 AU AU2016385438A patent/AU2016385438B2/en active Active
- 2016-12-14 WO PCT/US2016/066578 patent/WO2017120000A1/en active Application Filing
- 2016-12-14 MX MX2018008341A patent/MX2018008341A/es unknown
- 2016-12-14 KR KR1020187022789A patent/KR102095188B1/ko active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| AU2016385438B2 (en) | 2019-04-18 |
| CA3010739A1 (en) | 2017-07-13 |
| KR20180101478A (ko) | 2018-09-12 |
| WO2017120000A1 (en) | 2017-07-13 |
| AU2016385438A1 (en) | 2018-07-05 |
| BR112018013843B1 (pt) | 2022-08-09 |
| BR112018013843A2 (pt) | 2018-12-11 |
| MX2018008341A (es) | 2019-01-31 |
| JP2019501266A (ja) | 2019-01-17 |
| CN108473910A (zh) | 2018-08-31 |
| EP3400280A4 (en) | 2018-11-14 |
| EP3400280A1 (en) | 2018-11-14 |
| EP3400280B1 (en) | 2023-10-04 |
| CN108473910B (zh) | 2020-02-14 |
| CA3010739C (en) | 2019-02-19 |
| KR102095188B1 (ko) | 2020-03-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2773589B1 (en) | Calcium hydroxyapatite based calcium sulfonate grease compositions and method of manufacture | |
| US9976102B2 (en) | Composition and method of manufacturing calcium sulfonate greases using alkali metal hydroxide and delayed addition of non-aqueous converting agents | |
| US9976101B2 (en) | Method of manufacturing calcium sulfonate greases using delayed addition of non-aqueous converting agents | |
| JP6511199B2 (ja) | アルカリ金属水酸化物の使用と、非水性変換剤の遅延添加とによるカルシウムスルホネートグリースの製造 | |
| JP6591702B2 (ja) | 従来の非水性変換剤を用いないカルシウムマグネシウムスルホネートグリースの組成物及び製造方法 | |
| JP6586249B2 (ja) | カルシウムマグネシウムスルホネートグリース組成物及びその製造方法 | |
| WO2017119999A1 (en) | Method of manufacturing calcium sulfonate greases using delayed addition of non-aqueous converting agents | |
| US20210363453A1 (en) | Composition and Method of Manufacturing Calcium Magnesium Sulfonate Greases | |
| AU2017267546B2 (en) | Composition and method of manufacturing calcium sulfonate and calcium magnesium sulfonate greases using a delay after addition of facilitating acid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180907 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180907 |
|
| A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20180907 |
|
| A975 | Report on accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A971005 Effective date: 20181109 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20181211 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190305 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190326 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190405 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6511199 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |