JP6401226B2 - 窒素を含む複素環式エポキシ硬化剤、組成物及び方法 - Google Patents

窒素を含む複素環式エポキシ硬化剤、組成物及び方法 Download PDF

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JP6401226B2
JP6401226B2 JP2016222869A JP2016222869A JP6401226B2 JP 6401226 B2 JP6401226 B2 JP 6401226B2 JP 2016222869 A JP2016222869 A JP 2016222869A JP 2016222869 A JP2016222869 A JP 2016222869A JP 6401226 B2 JP6401226 B2 JP 6401226B2
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amine
epoxy
curing agent
aliphatic
amines
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JP2017095703A (ja
JP2017095703A5 (enExample
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ジュヨン シイン
ジュヨン シイン
アナンタチャー サディル
アナンタチャー サディル
ニサラリ ファゼル シャフィク
ニサラリ ファゼル シャフィク
イアン クック マイケル
イアン クック マイケル
マルヨ テオドール ラシング ロベルト
マルヨ テオドール ラシング ロベルト
カオ ウェイ
カオ ウェイ
ヤン テイスマ エトゼ
ヤン テイスマ エトゼ
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エボニック デグサ ゲゼルシャフト ミット ベシュレンクテル ハフツング
エボニック デグサ ゲゼルシャフト ミット ベシュレンクテル ハフツング
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073—Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5006—Amines aliphatic
    • C08G59/502—Polyalkylene polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/508—Amines heterocyclic containing only nitrogen as a heteroatom having three nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/508—Amines heterocyclic containing only nitrogen as a heteroatom having three nitrogen atoms in the ring
    • C08G59/5086—Triazines; Melamines; Guanamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C08G59/60—Amines together with other curing agents with amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Epoxy Resins (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
JP2016222869A 2015-11-17 2016-11-16 窒素を含む複素環式エポキシ硬化剤、組成物及び方法 Active JP6401226B2 (ja)

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Application Number Priority Date Filing Date Title
US201562256262P 2015-11-17 2015-11-17
US62/256,262 2015-11-17
US15/343,632 US10556985B2 (en) 2015-11-17 2016-11-04 Nitrogen-containing heterocyclic epoxy curing agents, compositions and methods
US15/343,632 2016-11-04

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JP2017095703A JP2017095703A (ja) 2017-06-01
JP2017095703A5 JP2017095703A5 (enExample) 2017-08-17
JP6401226B2 true JP6401226B2 (ja) 2018-10-10

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US (1) US10556985B2 (enExample)
EP (1) EP3170849B1 (enExample)
JP (1) JP6401226B2 (enExample)
KR (1) KR101903956B1 (enExample)
CN (1) CN107099021B (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10465039B2 (en) 2015-11-17 2019-11-05 Evonik Degussa Gmbh Epoxy curing agents, compositions and uses thereof
EP3339391B1 (en) * 2016-12-23 2020-02-05 Evonik Operations GmbH Apcha as a building block in curing agent formulations for structural adhesives
US10450406B2 (en) * 2017-08-30 2019-10-22 Saudi Arabian Oil Company Fluorinated polyimide-based epoxy materials
JP7242694B2 (ja) 2018-03-05 2023-03-20 エボニック オペレーションズ ゲーエムベーハー エポキシ配合物のための脂環式アミン：エポキシ系のための新規な硬化剤
US10696888B2 (en) 2018-08-30 2020-06-30 Saudi Arabian Oil Company Lost circulation material compositions and methods of isolating a lost circulation zone of a wellbore
US11168243B2 (en) * 2018-08-30 2021-11-09 Saudi Arabian Oil Company Cement compositions including epoxy resin systems for preventing fluid migration
US11352541B2 (en) 2018-08-30 2022-06-07 Saudi Arabian Oil Company Sealing compositions and methods of sealing an annulus of a wellbore
EP3798246B1 (en) * 2019-09-27 2024-01-31 Henkel AG & Co. KGaA One component (1k) composition based on modified epoxy resin
US11891476B2 (en) * 2019-11-08 2024-02-06 Evonik Operations Gmbh Phenalkamine epoxy curing agents from methylene bridged poly(cyclohexyl-aromatic) amines and epoxy resin compositions containing the same
US11332656B2 (en) 2019-12-18 2022-05-17 Saudi Arabian Oil Company LCM composition with controlled viscosity and cure time and methods of treating a lost circulation zone of a wellbore
US11370956B2 (en) 2019-12-18 2022-06-28 Saudi Arabian Oil Company Epoxy-based LCM compositions with controlled viscosity and methods of treating a lost circulation zone of a wellbore
US11193052B2 (en) 2020-02-25 2021-12-07 Saudi Arabian Oil Company Sealing compositions and methods of plugging and abandoning of a wellbore
US11236263B2 (en) 2020-02-26 2022-02-01 Saudi Arabian Oil Company Method of sand consolidation in petroleum reservoirs
CN115803358A (zh) * 2020-07-10 2023-03-14 赢创运营有限公司 环氧-胺加合物
US12173113B2 (en) 2021-03-17 2024-12-24 Evonik Operations Gmbh Waterborne epoxy curing agent
WO2023010442A1 (en) 2021-08-05 2023-02-09 Evonik Operations Gmbh Amine composition, epoxy system prepared from the amine composition and an epoxy resin, and use of the epoxy system
US11827841B2 (en) 2021-12-23 2023-11-28 Saudi Arabian Oil Company Methods of treating lost circulation zones
CN117327433B (zh) * 2023-09-28 2025-05-06 江苏进华重防腐涂料有限公司 建筑物排水用铸铁管和铸铁配件的环氧漆及其制备和应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2643977A (en) 1951-01-29 1953-06-30 Cities Service Res & Dev Co Method of inhibiting corrosion of metals
GB1424702A (en) 1972-04-27 1976-02-11 Kanebo Ltd Method of decolourizing waste coloured aqueous liquid
CA1101448A (en) 1977-06-21 1981-05-19 Edward L. Manigault Self bonding refractory composition of alumina and chrome oxide
DE2861106D1 (en) 1978-02-11 1981-12-03 Schering Ag Hardening agents and process for preparing epoxy resin polyadducts
DE2922176C3 (de) * 1979-05-31 1995-11-09 Akzo Gmbh Wasserhärtbare Polyisocyanat- oder Polyepoxid-Gemische
US4533682A (en) 1983-04-29 1985-08-06 Desoto, Inc. Imidazolidine-blocked amine polymers
US4877578A (en) 1985-03-29 1989-10-31 Petrolite Corporation Corrosion inhibitors
DE69133280T2 (de) 1990-05-21 2004-05-06 Dow Global Technologies, Inc., Midland Latente Katalysatoren, Härtungsinhibierte Epoxyharzzusammensetzungen und daraus hergestellte Laminate
US5280091A (en) 1992-02-07 1994-01-18 Air Products And Chemicals, Inc. Epoxy resins cured with mixed methylene bridged poly(cyclohexyl-aromatic)amine curing agents
US5618905A (en) * 1995-04-11 1997-04-08 Air Products And Chemicals, Inc. Partially methylated polyamines as epoxy curing agents
PT1114076E (pt) 1998-09-14 2003-07-31 Vantico Ag Aceleradores para sistemas endureciveis
CA2564780C (en) * 2004-04-20 2010-11-23 Dendritic Nanotechnologies, Inc. Dendritic polymers with enhanced amplification and interior functionality
US8518547B2 (en) * 2007-02-07 2013-08-27 Air Products And Chemicals, Inc. Alkylated polyalkylene polyamines and uses thereof
US8168296B2 (en) 2007-02-07 2012-05-01 Air Products And Chemicals, Inc. Benzylated polyalkylene polyamines and uses thereof
US8143331B2 (en) 2007-02-07 2012-03-27 Air Products And Chemicals, Inc. Alkylated polyalkyleneamines and uses thereof
US8147964B2 (en) 2007-02-07 2012-04-03 Air Products And Chemicals, Inc. Benzylated polyalkylene polyamines and uses thereof
JP5408612B2 (ja) 2009-04-13 2014-02-05 奥野製薬工業株式会社 アルミニウム合金の陽極酸化皮膜用封孔処理方法
JP6008958B2 (ja) 2011-06-30 2016-10-19 ダウ グローバル テクノロジーズ エルエルシー アミン硬化剤の混合物及び過剰のエポキシ基を含む硬化性エポキシ樹脂系
JP2014095027A (ja) 2012-11-08 2014-05-22 Tosoh Corp エポキシ硬化剤用アミン組成物
CN103333136B (zh) 2013-07-05 2015-07-22 河北工业大学 一种多胺基酰胺阳离子沥青乳化剂的制备方法

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EP3170849A1 (en) 2017-05-24
CN107099021A (zh) 2017-08-29
KR101903956B1 (ko) 2018-10-02
US20170137562A1 (en) 2017-05-18
JP2017095703A (ja) 2017-06-01
KR20170066220A (ko) 2017-06-14
EP3170849B1 (en) 2019-08-28
US10556985B2 (en) 2020-02-11
CN107099021B (zh) 2019-09-13

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