JP6333146B2 - トナー粒子および現像剤 - Google Patents
トナー粒子および現像剤 Download PDFInfo
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- JP6333146B2 JP6333146B2 JP2014200569A JP2014200569A JP6333146B2 JP 6333146 B2 JP6333146 B2 JP 6333146B2 JP 2014200569 A JP2014200569 A JP 2014200569A JP 2014200569 A JP2014200569 A JP 2014200569A JP 6333146 B2 JP6333146 B2 JP 6333146B2
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- toner particles
- diol
- acid
- toner
- hydrogenated
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Classifications
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- G03G9/08742—Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
- G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
- G03G9/0806—Preparation methods whereby the components are brought together in a liquid dispersing medium whereby chemical synthesis of at least one of the toner components takes place
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08791—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by the presence of specified groups or side chains
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Description
目的のバイオポリエステルを単独で使用するか、またはトナーに用いられる1種類以上の他の既知の樹脂と組み合わせて使用する。
混合物(例えば、アモルファス樹脂と結晶性ポリエステル樹脂)を使用する場合、結晶性ポリエステル樹脂とアモルファスポリエステル樹脂の比率は、約1:99〜約30:70の範囲であってもよい。
そのため、トナー組成物または試薬は、界面活性剤を含む分散物の状態であってもよい。ポリマーおよびトナーの他の要素を組み合わせる乳化凝集方法は、1種類以上の界面活性剤を使用し、エマルションを作製することができる。
トナー粒子と混合する担体粒子の例としては、トナー粒子と反対の極性を有する電荷を摩擦電気から得ることが可能な粒子が挙げられる。適切な担体粒子の実例としては、顆粒状ジルコン、顆粒状ケイ素、ガラス、鋼鉄、ニッケル、フェライト、鉄フェライト、二酸化ケイ素、1種類以上のポリマーなどが挙げられる。
目的のトナー組成物および現像剤を、例えば、画像を作成するという目的のために、目的のトナー組成物および現像剤を運ぶための専用のデバイスに組み込んでもよい。したがって、詳細に記載されたトナーを運ぶデバイスが知られており、目的のトナー調製物または現像剤を含んでいてもよい。このようなデバイスとしては、カートリッジ、タンク、容器などが挙げられ、交換可能、使い捨て、再利用可能であってもよい。
1L Buchi反応器に、主にデヒドロアビエチン酸で構成されるロジン(195.7g)、グリセリンカーボネート(83.4g)およびテトラエチルアンモニウムブロミド触媒(1.63g)を加えた。この混合物を170℃まで加熱し、酸価が1mgKOH/kg未満になるまで9時間維持した。次いで、この混合物に、ネオペンチルグリコール(63.9g)、ジプロピレングリコール(47.4g)、トリプロピレングリコール(28.3g)、テレフタル酸(215.8g)、コハク酸(20.85g)およびFASCAT 4100触媒(2.0g)を加えた。この混合物を165℃〜205℃で5時間加熱し、一晩維持し、その後、軟化点が113℃〜123℃になるまで、温度を215℃まで上げた(表1を参照)。HMWは、高分子量であり、LMWは、低分子量である。
オーバーヘッドミキサーを取り付けた2リットルガラス反応器に、307.58gの標準的な転相乳化(PIE)プロセスによって調製された樹脂1のエマルション(19.78重量%)(粒径は120.6nm)、23.38gのCPE(35.60重量%)、36.94gのIGIワックス分散物(29.97重量%)および48.09gのシアン顔料PB15:3(14.96重量%)を加えた。別個に、均質化しつつ、1.11gのAl2(SO4)3(27.85重量%)をフロック形成剤(凝集剤)として加えた。300rpmで撹拌しつつ、この混合物を46.4℃まで加熱し、粒子を凝集させた。コア粒子が体積平均粒径4.17μm、GSDv 1.25に達するまで、粒径をCOULTER COUNTERを用いて監視し、次いで、169.87gの上述の樹脂1エマルションをシェル材料として加え、平均粒径が5.65μm、GSDvが1.25のコア−シェル構造の粒子を得た。その後、4重量%のNaOH溶液を用い、次いで4.62gのEDTA(39wt%)を用いて反応スラリーのpHを7.8まで上げ、トナー粒子の成長を凍結させた。凍結させた後、反応混合物を85℃まで加熱し、pH5.7の酢酸/酢酸ナトリウム(HAc/NaAc)バッファー溶液を用い、融着のためにpHを7.00まで下げた。トナースラリーをRTまで冷却し、ふるい分け(25mm)によって分離し、濾過し、洗浄し、凍結乾燥させた。
オーバーヘッドミキサーを取り付けた2リットルガラス反応器に、260.56gの標準的なPIEプロセスによって調製された樹脂2のエマルション(23.35重量%)(粒径は161.3nm)、23.38gのCPE(35.60重量%)、36.94gのIGIワックス分散物(29.97重量%)および48.09gのシアン顔料PB15:3(14.96重量%)を加えた。別個に、均質化しつつ、1.22gのAl2(SO4)3(27.85重量%)をフロック形成剤として加えた。300rpmで撹拌しつつ、この混合物を38.2℃まで加熱し、粒子を凝集させた。コア粒子が体積平均粒径4.54μm、GSDv 1.25に達するまで、粒径をCOULTER COUNTERを用いて監視し、次いで、143.9gの上述の樹脂2エマルションをシェル材料として加え、平均粒径が6.48μm、GSDvが1.22のコア−シェル構造の粒子を得た。その後、次いで、4重量%のNaOH溶液を用い、次いで4.62gのEDTA(39wt%)を用いて反応スラリーのpHを7.8まで上げ、トナー粒子の成長を凍結させた。凍結させた後、反応混合物を85℃まで加熱し、pH5.7のHAc/NaAcバッファー溶液を用い、融着のためにpHを7まで下げた。トナースラリーをRTまで冷却し、ふるい分け(25mm)によって分離し、濾過し、洗浄し、凍結乾燥させた。
DC12複写機(Xerox)を用い、融合していないすべての画像を作成した。CXS紙(Color Xpressions Select、90gsm、コーティングされていない、Xerox No.3R11540)の上に置かれるトナーの量としてTMA(単位面積あたりのトナーの質量)1.00mg/cm2を使用し、光沢、しわおよびホットオフセットの測定に使用した。光沢/しわの標的は、当該技術分野で知られるように、ページの中心に置かれた四角の画像であった。一般的に、望ましいTMAを達成するために、現像バイアス電圧を調整しつつ、2つがDC12を通すことが必要であった。次いで、サンプルを、新しいフューザー(Toshiba)ロールおよび剥離フィンガーを用いて供給されたXerox融合固定機を用い、オフラインで融合させた。100Csの油粘度を有する加圧ロールおよびクリーニングウェブを固定機に供給し、フューザーロールの速度を596ミリメートル/秒(mm/s)に設定した。フューザーロールの爪の幅を測定し、13.5±0.2mmであると決定され、爪の滞留時間22.8ミリ秒(ms)を得た。シリコーン油の速度は、0.05mg/複写物〜約0.35mg/複写物であった。120部/分(ppm)で動く機械において、複写物上に存在する名目上の油は、約0.05mg/複写物である。ある時間で、1枚のシートは、フューザーを通って送られ、最初の数枚のシートについて、複写紙上の油は、通常は、動いている油の速度よりも大きかった。融合中、フューザーロールの設定温度は、コールドオフセット(約150℃)からホットオフセット(つまり、約210℃まで)までさまざまであった。設定温度を変えた後、フューザーロールおよび加圧ロールは、融合していないサンプルをフューザーに送る前に10分間待つことによって平衡状態に達した。複写シート上の油は、種々の融合温度で保持されていた。
各サンプルについて、約50gのトナーを、シリカ、チタニアおよびステアリン酸亜鉛を含む添加剤パッケージとともにSKMミルに加え、次いで、約12500rpmで約30秒間ブレンドした。表面添加剤は、1.29%のRY50Lシリカ、0.86%のRX50シリカ、0.88%のSTT100Hチタニア、1.73%のX24ゾルゲルコロイド状シリカおよび0.2%のPTFE粒子であり、商業的な販売業者から購入した。
Claims (19)
- 生物由来ポリマー及びワックスを含むトナー粒子であって、
前記生物由来ポリマーが、(a)ロジンジオールと、(b)ネオペンチルグリコールと、(c)コハク酸と、(d)芳香族ジカルボン酸と、(e)ジプロピレングリコール又はトリプロピレングリコールとの反応生成物であり、
前記ロジンジオールが、ロジン酸とグリセリンカーボネートとの反応生成物であって、1つのロジン部分のみを含む、
トナー粒子。 - 表面添加剤を更に有する、請求項1に記載のトナー粒子。
- 前記ロジンジオールが、アビエチン−ジオール、パルストリン−ジオール、デヒドロアビエチン−ジオール、neo−アビエチン−ジオール、levo−ピマル−ジオール、ピマル−ジオール、サンダラコピマル−ジオール、iso−ピマル−ジオール、水素化アビエチン−ジオール、水素化パルストリン−ジオール、水素化デヒドロアビエチン−ジオール、水素化neo−アビエチン−ジオール、水素化levo−ピマル−ジオール、水素化ピマル−ジオール、水素化サンダラコピマル−ジオールおよび水素化iso−ピマル−ジオールからなる群から選択される、請求項1に記載のトナー粒子。
- 前記生物由来ポリマーの軟化点Tsが少なくとも110℃である、請求項1に記載のトナー粒子。
- 前記芳香族ジカルボン酸が、フタル酸、イソフタル酸およびテレフタル酸からなる群から選択される、請求項1に記載のトナー粒子。
- 前記トナー粒子が凝集粒子及びシェルを有する、請求項1に記載のトナー粒子。
- 前記シェルが前記トナー粒子の1質量%〜80質量%の量で含まれる、請求項6に記載のトナー粒子。
- 前記生物由来ポリマーが少なくとも10の酸価を有する、請求項1に記載のトナー粒子。
- 前記生物由来ポリマーのガラス転移温度Tgが少なくとも40℃である、請求項1に記載のトナー粒子。
- 滑沢剤を含む、請求項1に記載のトナー粒子。
- 電荷添加剤を含む、請求項1に記載のトナー粒子。
- 追加の樹脂を含む、請求項1に記載のトナー粒子。
- 前記追加の樹脂がアモルファスポリエステル樹脂を含む、請求項12に記載のトナー粒子。
- 前記追加の樹脂がアモルファスポリエステル樹脂及び結晶性樹脂を含む、請求項12に記載のトナー粒子。
- 前記追加の樹脂が結晶性樹脂を含む、請求項12に記載のトナー粒子。
- 着色剤を含む、請求項1に記載のトナー粒子。
- 乳化/凝集トナーである、請求項1に記載のトナー粒子。
- 請求項1に記載のトナー粒子を含む、現像剤。
- 担体を含む、請求項18に記載の現像剤。
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US14/059,840 US9360782B2 (en) | 2013-10-22 | 2013-10-22 | Toner comprised of a sustainable polyester resin |
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US9791795B2 (en) | 2015-06-01 | 2017-10-17 | Xerox Corporation | Low fixing temperature sustainable toner |
US9535348B1 (en) | 2015-07-01 | 2017-01-03 | Xerox Corporation | Continuous coalescence process for sustainable toner |
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JPS60170864A (ja) * | 1984-02-15 | 1985-09-04 | Minolta Camera Co Ltd | 電子写真用トナ− |
JPH079546B2 (ja) * | 1986-11-17 | 1995-02-01 | 日本合成化学工業株式会社 | トナ−用のバインダ− |
JPH0495968A (ja) * | 1990-08-07 | 1992-03-27 | Nippon Synthetic Chem Ind Co Ltd:The | トナー用バインダー |
JPH04303848A (ja) * | 1991-03-29 | 1992-10-27 | Nippon Synthetic Chem Ind Co Ltd:The | トナー用バインダー |
JP2005350597A (ja) * | 2004-06-11 | 2005-12-22 | Mitsui Chemicals Inc | トナー用バインダー樹脂及び電子写真用トナー |
US8652731B2 (en) * | 2011-04-15 | 2014-02-18 | Fuji Xerox Co., Ltd | Electrostatic image developing toner, electrostatic image developer, toner cartridge, process cartridge, image forming apparatus and image forming method |
US8574803B2 (en) * | 2011-12-23 | 2013-11-05 | Xerox Corporation | Toner compositions of biodegradable amorphous polyester resins |
JP5884592B2 (ja) * | 2012-03-26 | 2016-03-15 | 富士ゼロックス株式会社 | 静電荷像現像剤、プロセスカートリッジ、画像形成装置及び画像形成方法 |
US8735033B2 (en) * | 2012-03-29 | 2014-05-27 | Xerox Corporation | Toner process using acoustic mixer |
JP5423920B2 (ja) * | 2013-04-30 | 2014-02-19 | 富士ゼロックス株式会社 | 静電荷像現像用トナー及びその製造方法、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成方法、並びに、画像形成装置 |
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