JP6330230B2 - マルチブロックコポリマー及び使用方法 - Google Patents

マルチブロックコポリマー及び使用方法 Download PDF

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Publication number
JP6330230B2
JP6330230B2 JP2016501268A JP2016501268A JP6330230B2 JP 6330230 B2 JP6330230 B2 JP 6330230B2 JP 2016501268 A JP2016501268 A JP 2016501268A JP 2016501268 A JP2016501268 A JP 2016501268A JP 6330230 B2 JP6330230 B2 JP 6330230B2
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JP
Japan
Prior art keywords
poly
styrene
butadiene
membrane
methylstyrene
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Expired - Fee Related
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JP2016501268A
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English (en)
Japanese (ja)
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JP2016514049A (ja
JP2016514049A5 (https=
Inventor
ウィリアム エー． フィリップ，
ウィリアム エー． フィリップ，
ブライアン ダブリュー． ヴォードリス，
ブライアン ダブリュー． ヴォードリス，
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Purdue Research Foundation
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Purdue Research Foundation
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011—Casting solutions therefor
    • B01D67/00113—Pretreatment of the casting solutions, e.g. thermal treatment or ageing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0016—Coagulation
    • B01D67/00165—Composition of the coagulation baths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/281—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/40—Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/401—Polymers based on the polymerisation of acrylic acid, e.g. polyacrylate
    • B01D71/4011—Polymethylmethacrylate
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/021—Pore shapes
    • B01D2325/0212—Symmetric or isoporous membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02832—1-10 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/04—Characteristic thickness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Water Supply & Treatment (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
JP2016501268A 2013-03-11 2014-03-11 マルチブロックコポリマー及び使用方法 Expired - Fee Related JP6330230B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361851615P 2013-03-11 2013-03-11
US61/851,615 2013-03-11
US201361874776P 2013-09-06 2013-09-06
US61/874,776 2013-09-06
PCT/US2014/023497 WO2014164793A2 (en) 2013-03-11 2014-03-11 Multiblock copolymers and methods of use

Publications (3)

Publication Number Publication Date
JP2016514049A JP2016514049A (ja) 2016-05-19
JP2016514049A5 JP2016514049A5 (https=) 2017-04-20
JP6330230B2 true JP6330230B2 (ja) 2018-05-30

Family

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JP2016501268A Expired - Fee Related JP6330230B2 (ja) 2013-03-11 2014-03-11 マルチブロックコポリマー及び使用方法

Country Status (6)

Country Link
US (1) US10022679B2 (https=)
EP (1) EP2969155A4 (https=)
JP (1) JP6330230B2 (https=)
KR (1) KR20160020404A (https=)
CN (1) CN105263610A (https=)
WO (1) WO2014164793A2 (https=)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9527041B2 (en) 2011-05-04 2016-12-27 Cornell University Multiblock copolymer films, methods of making same, and uses thereof
US10029207B2 (en) * 2013-11-14 2018-07-24 The University Of Melbourne Composite gas separation membrane
US10384167B2 (en) 2013-11-21 2019-08-20 Oasys Water LLC Systems and methods for improving performance of osmotically driven membrane systems
ES2782081T3 (es) * 2014-11-25 2020-09-10 Anheuser Busch Inbev Sa Concentrado de cerveza
KR101570304B1 (ko) 2014-11-28 2015-11-19 한국기계연구원 하이브리드 형 액체 여과 구조체
EP3448551B1 (en) * 2016-04-28 2024-07-17 Terapore Technologies, Inc. Charged isoporous materials for electrostatic separations
TWI757350B (zh) 2016-10-04 2022-03-11 紐西蘭商艾克福特士技術有限公司 熱感應溶液及其使用方法
CN110475602B (zh) * 2016-11-17 2022-05-03 特拉波雷技术有限公司 含有高分子量亲水性添加剂的均孔自组装嵌段共聚物膜及其制备方法
WO2018097988A1 (en) 2016-11-22 2018-05-31 3M Innovative Properties Company Porous membranes including pentablock copolymers and method of making the same
EP3545023B1 (en) 2016-11-22 2020-11-04 3M Innovative Properties Company Pentablock copolymers
KR102308806B1 (ko) * 2017-02-22 2021-10-07 테라포어 테크놀로지스, 인코포레이티드 리간드 결합 mbp 멤브레인, 사용 및 제조방법
JP2020519734A (ja) 2017-05-12 2020-07-02 テラポア テクノロジーズ，インコーポレイテッド 耐薬品性フッ素化マルチブロック重合体構造物、製造方法及びその使用
JP7095231B2 (ja) * 2017-05-19 2022-07-05 Dic株式会社 気体分離膜、積層体、及びガス分離モジュール
CA3071140A1 (en) * 2017-07-25 2019-01-31 Terapore Technologies, Inc. Porous materials from complex block copolymer architectures
MX2020003098A (es) * 2017-09-19 2020-07-28 Terapore Tech Inc Estructura entrelazada isoporosa de copolimero de bloques quimicamente resistente.
AU2018346086B2 (en) 2017-10-03 2024-08-01 Aquafortus Technologies Limited A salt recovery solution and processes of use thereof
KR20200130387A (ko) * 2018-03-12 2020-11-18 테라포어 테크놀로지스, 인코포레이티드 마크로보이드들을 갖는 이소포러스 메조포러스 비대칭 블록 코폴리머 재료들 및 이의 제조 방법
MX2020009509A (es) * 2018-03-12 2021-01-15 Terapore Tech Inc Materiales de copolimero de bloques libremente plegados y metodo de fabricacion de los mismos.
CN112074339A (zh) * 2018-04-04 2020-12-11 特拉波雷技术有限公司 包封颗粒分馏装置和系统以及该装置和系统的使用方法
US20210370237A1 (en) * 2018-10-05 2021-12-02 Terapore Technologies, Inc. Method of filtering liquids or gases for electronics production
WO2020092612A2 (en) * 2018-10-30 2020-05-07 University Of Notre Dame Du Lac Block polymer composite membranes
CN110187565B (zh) * 2019-05-23 2021-11-02 Tcl华星光电技术有限公司 显示器及其制造方法
US11241657B2 (en) * 2019-11-22 2022-02-08 Pall Corporation Filter for removing silica from ultra pure water and method of use
EP4178701A4 (en) 2020-07-10 2024-07-10 Aquafortus Technologies Limited A solvent drying solution and processes therefor
WO2022060691A1 (en) * 2020-09-15 2022-03-24 University Of Notre Dame Du Lac Asymmetric nanopore membrane (anm) filtration for high-efficiency virus enrichment and purification
KR102572120B1 (ko) * 2021-05-25 2023-08-30 한국과학기술원 탄소와 귀금속을 포함하는 복합소재의 제조 및 복합구조체의 형성 방법
CN114292373B (zh) * 2022-01-25 2023-03-17 南京工业大学 一种甘油调节液相合成共价有机框架纳米片的方法
CN115608175B (zh) * 2022-10-13 2025-01-07 合肥工业大学 一种二维离子对膜的制备方法及其应用
WO2025039009A1 (en) * 2023-08-17 2025-02-20 Cornell University Porous functionalized multiblock copolymer films, methods of making and using same, and products thereof
CN119113830B (zh) * 2024-09-11 2025-07-11 哈尔滨工业大学 一种三元多功能立体架构介导的高氨氮选择性聚酰胺反渗透膜的制备方法和应用

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5911343B2 (ja) * 1979-11-27 1984-03-14 東ソー株式会社 両性イオン交換体
JPS62193604A (ja) * 1986-02-21 1987-08-25 Bio Material Yunibaasu:Kk グラフト重合法による外部刺激応答性膜の製造
US4828705A (en) * 1986-10-31 1989-05-09 Kingston Technologies, Inc. Pressure-dependent anisotropic-transport membrane system
US5098570A (en) * 1990-12-06 1992-03-24 Exxon Research And Engineering Company Multi-block polymer comprising a urea prepolymer chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations
CA2231077A1 (en) * 1997-03-04 1998-09-04 Guojun Liu Polymeric material and process for production thereof
RU2166984C2 (ru) * 1998-06-15 2001-05-20 Институт высокомолекулярных соединений РАН Способ получения полимерных мультислойных первапорационных мембран
DE19829397A1 (de) * 1998-07-01 2000-01-05 Basf Ag Verwendung mikrophasenseparierter Polymermischungen für die Herstellung von permeablen Membranen
RU2211725C2 (ru) * 2000-07-20 2003-09-10 Кононова Светлана Викторовна Способ получения композиционных полимерных диффузионных мембран и диффузионные мембраны, полученные этим способом
EP1552878A4 (en) 2002-10-18 2006-03-22 Asahi Kasei Pharma Corp MICROPOR SE HYDROPHILIC MEMBRANE
CN1829564B (zh) 2003-06-02 2010-12-15 Ge奥斯莫尼克斯公司 用于处理非水混合物的材料及其制备方法
RU2372983C2 (ru) * 2005-04-07 2009-11-20 Пюр Уотер Пьюрификейшн Продактс, Инк. Материалы фильтров для воды и фильтры для воды, содержащие смесь микропористых и мезопористых углеродных частиц
US9233846B2 (en) * 2005-10-14 2016-01-12 The Regents Of The University Of California Formation and encapsulation of molecular bilayer and monolayer membranes
CN101443099B (zh) * 2006-04-11 2012-03-14 麻省理工学院 用聚丙烯腈接枝共聚物形成的抗污垢膜
DE102006045282C5 (de) * 2006-09-22 2012-11-22 Helmholtz-Zentrum Geesthacht Zentrum für Material-und Küstenforschung GmbH Isoporöse Membran und Verfahren zu ihrer Herstellung
CN101583657B (zh) * 2007-01-11 2012-04-25 日东电工株式会社 聚合物多微孔体制造方法以及聚合物多微孔体及分离膜
JP2008272636A (ja) * 2007-04-26 2008-11-13 Asahi Kasei Corp 多層微多孔膜
US8420704B2 (en) * 2007-07-20 2013-04-16 Regents Of The University Of Minnesota Nano-structured polymer composites and process for preparing same
JP2009256592A (ja) * 2008-03-18 2009-11-05 Fujifilm Corp 多孔質膜
JP5519684B2 (ja) 2008-10-28 2014-06-11 アーケマ・インコーポレイテッド 水分流動性ポリマー膜
EP2345682B1 (en) 2008-11-04 2017-08-23 LG Chem, Ltd. Polymer electrolyte membrane
US9527041B2 (en) * 2011-05-04 2016-12-27 Cornell University Multiblock copolymer films, methods of making same, and uses thereof

Also Published As

Publication number Publication date
WO2014164793A2 (en) 2014-10-09
US10022679B2 (en) 2018-07-17
WO2014164793A3 (en) 2014-11-27
EP2969155A4 (en) 2016-11-23
CN105263610A (zh) 2016-01-20
KR20160020404A (ko) 2016-02-23
JP2016514049A (ja) 2016-05-19
US20160023171A1 (en) 2016-01-28
EP2969155A2 (en) 2016-01-20

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