JP6230671B2 - 噴霧ドリフト減少剤 - Google Patents
噴霧ドリフト減少剤 Download PDFInfo
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- JP6230671B2 JP6230671B2 JP2016173434A JP2016173434A JP6230671B2 JP 6230671 B2 JP6230671 B2 JP 6230671B2 JP 2016173434 A JP2016173434 A JP 2016173434A JP 2016173434 A JP2016173434 A JP 2016173434A JP 6230671 B2 JP6230671 B2 JP 6230671B2
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- Prior art keywords
- surfactant
- hlb
- spray
- surfactants
- surfonic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007921 spray Substances 0.000 title claims description 32
- 239000003638 chemical reducing agent Substances 0.000 title description 4
- 239000004094 surface-active agent Substances 0.000 claims description 58
- 239000000203 mixture Substances 0.000 claims description 29
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002245 particle Substances 0.000 description 10
- 238000005507 spraying Methods 0.000 description 9
- 241000607479 Yersinia pestis Species 0.000 description 8
- 239000004009 herbicide Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- -1 alkyl ether sulfates Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 1
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical group CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 1
- 241001340526 Chrysoclista linneella Species 0.000 description 1
- 239000005562 Glyphosate Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 150000001719 carbohydrate derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 150000002634 lipophilic molecules Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920003226 polyurethane urea Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Description
本発明は一般的に農業用途における使用のためのドリフト減少剤に関するが、標的−外付着(off−target deposition)を減少させることが有益である他の用途においても適用され得る。
噴霧ドリフトは、適用時又はそのすぐ後における空気輸送(airborne)噴霧粒子の空気を介する標的−外部位への物理的な動きとしてを定義され得る。農業の状況において、より大きい噴霧ドリフト特性を有する調剤は、標的部位と相互作用する調剤がより少量であるので、典型的に好ましくない。噴霧ドリフトに対抗するために、典型的にドリフト減少剤を噴霧混合物に加えて、起こる噴霧ドリフトの量を減少させる。
驚くべきことに、比較的低い親水−親油バランス(HLB)の界面活性剤を噴霧ドリフト減少剤として使用できることが見出された。そのような界面活性剤は一般に、噴霧の間に生成する微粒子の量を減少させる。確かに、他の界面活性剤は通常、噴霧タンクに加えられると、低下した張力が噴霧滴の破壊をより容易にするので、微粒子の量を増加させる。
は、Griffin(W.C.Griffin,J.Cosmet.Chem.,1,311,1949)により開発された実験的スケール基づいて測定される。このスケールは0から20の範囲であり、0は完全に親油性の分子の場合であり、20は完全に親水性の分子の場合である。界面活性剤の機能を一般にそれらのHLB数により記述することができる。脱泡性界面活性剤は1〜3のHLB範囲を有する。油中水型乳化剤は3〜6のHLB範囲を有する。湿潤剤は7〜9のHLB範囲を有する。水中油型乳化剤は8〜18のHLB範囲を有する。洗剤は13〜15のHLB範囲を有する。可溶化剤は15〜18のHLB範囲を有する。
SURFONIC(R) T−5界面活性剤は、平均で5モルのEOを有するタロウアミンエトキシレートであり、HLB=9.0である。
表1は粒度データを示す。噴霧粒子の粒度分布(spray particle size distribution)及び微粒子のパーセントを、ASTM Standard Test Method E2798:“Characterization of Performance of Pesticide Spray Drift Reduction Adjuvants for Ground Applicatio
n.”を用いて測定することができる。40psigにおいてノズル(XR8004VS)を介して試料溶液を噴霧した。
Claims (1)
- 低親水−親油バランス界面活性剤を、より高い親水−親油バランスを有する第2の界面活性剤と配合して、7〜9の低親水−親油バランスを有するブレンドをつくる、ただし該低親水−親油バランス界面活性剤は平均で3モルのエチレンオキシド基を有する直鎖状C 10 〜 12 もしくはC 12 〜 16 又は分枝鎖状C 13 アルコールエトキシレート界面活性剤である、噴霧ドリフト減少剤組成物の調製方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161477251P | 2011-04-20 | 2011-04-20 | |
US61/477,251 | 2011-04-20 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014506438A Division JP6227524B2 (ja) | 2011-04-20 | 2012-04-05 | 低親水−親油バランス界面活性剤を含んでなる噴霧ドリフト減少剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017036286A JP2017036286A (ja) | 2017-02-16 |
JP6230671B2 true JP6230671B2 (ja) | 2017-11-15 |
Family
ID=47041879
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014506438A Active JP6227524B2 (ja) | 2011-04-20 | 2012-04-05 | 低親水−親油バランス界面活性剤を含んでなる噴霧ドリフト減少剤 |
JP2016173434A Active JP6230671B2 (ja) | 2011-04-20 | 2016-09-06 | 噴霧ドリフト減少剤 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014506438A Active JP6227524B2 (ja) | 2011-04-20 | 2012-04-05 | 低親水−親油バランス界面活性剤を含んでなる噴霧ドリフト減少剤 |
Country Status (11)
Country | Link |
---|---|
US (2) | US20130150241A1 (ja) |
EP (1) | EP2699089B1 (ja) |
JP (2) | JP6227524B2 (ja) |
CN (1) | CN103442559B (ja) |
AR (1) | AR086105A1 (ja) |
AU (1) | AU2012245869B2 (ja) |
BR (1) | BR112013024083A8 (ja) |
CA (1) | CA2830518C (ja) |
ES (1) | ES2756799T3 (ja) |
MX (1) | MX352462B (ja) |
WO (1) | WO2012145177A1 (ja) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2699089B1 (en) * | 2011-04-20 | 2019-09-04 | Huntsman Petrochemical LLC | Use of spray drift reduction agents comprising low hydrophilic-lipophilic balance surfactants |
EP2755476B1 (en) | 2011-09-12 | 2017-10-25 | Rhodia Operations | Agricultural pesticide compositions |
AU2013315338A1 (en) * | 2012-09-11 | 2015-04-30 | Vitel Australia Pty Ltd | Spray drift adjuvant formulation and method of use |
IN2015DN03002A (ja) * | 2012-10-12 | 2015-09-25 | Dow Agrosciences Llc | |
US10888091B2 (en) | 2013-08-14 | 2021-01-12 | Croda, Inc. | Adjuvancy combination |
WO2016055344A1 (de) * | 2014-10-08 | 2016-04-14 | Evonik Degussa Gmbh | Verwendung von hydrophoben, selbstemulgierenden polyglycerinestern als adjuvantien und anti-spray-drift mittel |
US20160374334A1 (en) | 2015-06-29 | 2016-12-29 | Lamberti Spa | Method for reducing spray drift |
CN112741102A (zh) * | 2020-12-30 | 2021-05-04 | 浙江新安化工集团股份有限公司 | 一种精草铵膦除草剂 |
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US6797673B1 (en) * | 2002-05-01 | 2004-09-28 | Platte Chemical Company | Lecithin-containing drift reduction composition for use in spraying agricultural acreage |
WO2003096807A1 (en) * | 2002-05-14 | 2003-11-27 | Huntsman Petrochemical Corporation | Agricultural formulations containing enhanced surfactants |
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EP2699089B1 (en) * | 2011-04-20 | 2019-09-04 | Huntsman Petrochemical LLC | Use of spray drift reduction agents comprising low hydrophilic-lipophilic balance surfactants |
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2012
- 2012-04-05 EP EP12773871.4A patent/EP2699089B1/en active Active
- 2012-04-05 CN CN201280013357.2A patent/CN103442559B/zh active Active
- 2012-04-05 ES ES12773871T patent/ES2756799T3/es active Active
- 2012-04-05 MX MX2013011447A patent/MX352462B/es active IP Right Grant
- 2012-04-05 AU AU2012245869A patent/AU2012245869B2/en active Active
- 2012-04-05 BR BR112013024083A patent/BR112013024083A8/pt not_active IP Right Cessation
- 2012-04-05 US US13/696,826 patent/US20130150241A1/en not_active Abandoned
- 2012-04-05 WO PCT/US2012/032265 patent/WO2012145177A1/en active Application Filing
- 2012-04-05 CA CA2830518A patent/CA2830518C/en active Active
- 2012-04-05 JP JP2014506438A patent/JP6227524B2/ja active Active
- 2012-04-18 AR ARP120101321A patent/AR086105A1/es active IP Right Grant
-
2016
- 2016-01-04 US US14/987,126 patent/US10123532B2/en active Active
- 2016-09-06 JP JP2016173434A patent/JP6230671B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
JP2014512383A (ja) | 2014-05-22 |
BR112013024083A8 (pt) | 2018-01-16 |
CN103442559A (zh) | 2013-12-11 |
AU2012245869A1 (en) | 2013-09-19 |
ES2756799T3 (es) | 2020-04-27 |
EP2699089B1 (en) | 2019-09-04 |
MX2013011447A (es) | 2013-10-17 |
CA2830518C (en) | 2019-07-16 |
WO2012145177A1 (en) | 2012-10-26 |
BR112013024083A2 (pt) | 2016-08-09 |
JP2017036286A (ja) | 2017-02-16 |
CA2830518A1 (en) | 2012-10-26 |
MX352462B (es) | 2017-11-27 |
EP2699089A1 (en) | 2014-02-26 |
EP2699089A4 (en) | 2014-09-03 |
JP6227524B2 (ja) | 2017-11-08 |
AU2012245869B2 (en) | 2015-12-03 |
US20160219873A1 (en) | 2016-08-04 |
AR086105A1 (es) | 2013-11-20 |
US20130150241A1 (en) | 2013-06-13 |
US10123532B2 (en) | 2018-11-13 |
CN103442559B (zh) | 2017-03-22 |
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