JP6205005B2 - 無溶剤耐熱性塗料 - Google Patents
無溶剤耐熱性塗料 Download PDFInfo
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- JP6205005B2 JP6205005B2 JP2016031791A JP2016031791A JP6205005B2 JP 6205005 B2 JP6205005 B2 JP 6205005B2 JP 2016031791 A JP2016031791 A JP 2016031791A JP 2016031791 A JP2016031791 A JP 2016031791A JP 6205005 B2 JP6205005 B2 JP 6205005B2
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- weight
- solvent
- resistant paint
- free heat
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003973 paint Substances 0.000 title claims description 13
- 239000003822 epoxy resin Substances 0.000 claims description 13
- 229920000647 polyepoxide Polymers 0.000 claims description 13
- 229920002050 silicone resin Polymers 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229920001225 polyester resin Polymers 0.000 claims description 3
- 239000004645 polyester resin Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- -1 methoxy, dimethoxy, trimethoxy, ethoxy Chemical group 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 description 8
- 150000004706 metal oxides Chemical class 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000454 talc Substances 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- BQCFCWXSRCETDO-UHFFFAOYSA-N [Fe].[Mn].[Cu] Chemical compound [Fe].[Mn].[Cu] BQCFCWXSRCETDO-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 3
- 229910000165 zinc phosphate Inorganic materials 0.000 description 3
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 206010008428 Chemical poisoning Diseases 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 229940093858 ethyl acetoacetate Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
それらの耐熱性塗料にはキシレンやトルエンなどの第2種有機溶剤(労働安全衛生法の規定に基づく有機溶剤中毒予防規則に準拠する)が含まれており、これは耐熱性塗料の操作性並びに塗布性を向上させるために使用されているのであるが、人体の健康に被害を与えない無溶剤耐熱性塗料の範疇には入らず、皮膚や粘膜、肺から吸収され中毒や障害を引き起こすなど人体に悪影響を与える恐れがある。
この混合溶液に銅鉄マンガン複合酸化物25重量部とタルク5重量部を加えて均一混合懸濁液とし、リン酸亜鉛8重量部とリン酸アルミニウム8重量部を加えて均一混合懸濁液とする。
この均一混合懸濁液にアルミニウムトリス(アセチルアセトネート)0.5重量部とテトラブチルチタネート0.5重量部を加えて良く混合することにより無溶剤耐熱性塗料の溶液を作製する。
Claims (3)
- 5〜30重量%のシリコーン樹脂、1〜10重量%のアルコキシシラン類、1〜10重量%のエポキシ樹脂、1〜10重量%のポリエステル樹脂、1〜20重量%のリン酸塩、5〜30重量%の金属酸化物を主成分として、硬化触媒として0.5〜1.0重量%の金属塩、1〜10重量%の有機酸無水物を含むことを特徴とする無溶剤耐熱性塗料。
- 前記シリコーン樹脂は、シリコーンオリゴマーからなることを特徴とする請求項1記載の無溶剤耐熱性塗料。
- 前記アルコキシシラン類は、アルキルアルコキシシラン若しくはアリールアルコキシシランであり、アルキル基がメチル、ジメチル、n−プロピル、アリール基がフェニル、アルコキシ基がメトキシ、ジメトキシ、トリメトキシ、エトキシ、ジエトキシ、トリエトキシからなることを特徴とする請求項1記載の無溶剤耐熱性塗料。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016031791A JP6205005B2 (ja) | 2016-02-23 | 2016-02-23 | 無溶剤耐熱性塗料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016031791A JP6205005B2 (ja) | 2016-02-23 | 2016-02-23 | 無溶剤耐熱性塗料 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017149815A JP2017149815A (ja) | 2017-08-31 |
JP6205005B2 true JP6205005B2 (ja) | 2017-09-27 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016031791A Active JP6205005B2 (ja) | 2016-02-23 | 2016-02-23 | 無溶剤耐熱性塗料 |
Country Status (1)
Country | Link |
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JP (1) | JP6205005B2 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110305582B (zh) * | 2019-07-24 | 2021-04-09 | 浙江德创环保科技股份有限公司 | 一种耐高温挡板门及其制造方法 |
JP7461187B2 (ja) | 2020-03-23 | 2024-04-03 | シーシーアイ株式会社 | コーティング組成物 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5248902B2 (ja) * | 1974-05-31 | 1977-12-13 | ||
JPS55153063A (en) * | 1979-05-17 | 1980-11-28 | Canon Inc | Electronic equipment |
JPS63156867A (ja) * | 1986-12-19 | 1988-06-29 | Yokohama Rubber Co Ltd:The | コ−テイング材組成物 |
JPH06212114A (ja) * | 1992-05-29 | 1994-08-02 | Ube Ind Ltd | 耐熱性塗料 |
JP3819219B2 (ja) * | 2000-06-20 | 2006-09-06 | 大日精化工業株式会社 | 粉体塗料組成物 |
JP3993861B2 (ja) * | 2004-04-26 | 2007-10-17 | 進興ペイント株式会社 | 無溶剤の常温硬化性組成物及び塗料 |
-
2016
- 2016-02-23 JP JP2016031791A patent/JP6205005B2/ja active Active
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